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Multi-objective optimal design of asymmetric base-isolated structures using NSGA-Ⅱ algorithm for improving torsional resistance
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作者 Zhang Jiayu Qi Ai Yang Mianyue 《Earthquake Engineering and Engineering Vibration》 2025年第3期811-825,共15页
Finding an optimal isolator arrangement for asymmetric structures using traditional conceptual design methods that can significantly minimize torsional response while ensuring efficient horizontal seismic isolation is... Finding an optimal isolator arrangement for asymmetric structures using traditional conceptual design methods that can significantly minimize torsional response while ensuring efficient horizontal seismic isolation is cumbersome and inefficient.Thus,this work develops a multi-objective optimization method to enhance the torsional resistance of asymmetric base-isolated structures.The primary objective is to simultaneously minimize the interstory rotation of the superstructure,the rotation of the isolation layer,and the interstory displacement of the superstructure without exceeding the isolator displacement limits.A fast non-dominated sorting genetic algorithm(NSGA-Ⅱ)is employed to satisfy this optimization objective.Subsequently,the isolator arrangement,encompassing both positions and categories,is optimized according to this multi-objective optimization method.Additionally,an optimization design platform is developed to streamline the design operation.This platform integrates the input of optimization parameters,the output of optimization results,the finite element analysis,and the multi-objective optimization method proposed herein.Finally,the application of this multi-objective optimization method and its associated platform are demonstrated on two asymmetric base-isolated structures of varying heights and plan configurations.The results indicate that the optimal isolator arrangement derived from the optimization method can further improve the control over the lateral and torsional responses of asymmetric base-isolated structures compared to conventional conceptual design methods.Notably,the interstory rotation of the optimal base-isolated structure is significantly reduced,constituting only approximately 33.7%of that observed in the original base-isolated structure.The proposed platform facilitates the automatic generation of the optimal design scheme for the isolators of asymmetric base-isolated structures,offering valuable insights and guidance for the burgeoning field of intelligent civil engineering design. 展开更多
关键词 asymmetric base-isolated structures isolator arrangement multi-objective optimization NSGA-Ⅱalgorithm optimization design platform
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Seismic Responses of Asymmetric Base-Isolated Structures under Near-Fault Ground Motion 被引量:1
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作者 叶昆 李黎 方秦汉 《Journal of Southwest Jiaotong University(English Edition)》 2008年第4期335-345,共11页
An inter-story shear model of asymmetric base-isolated structures incorporating deformation of each isolation bearing was built, and a method to simultaneously simulate bi-directional near-fault and far-field ground m... An inter-story shear model of asymmetric base-isolated structures incorporating deformation of each isolation bearing was built, and a method to simultaneously simulate bi-directional near-fault and far-field ground motions was proposed. A comparative study on the dynamic responses of asymmetric base-isolated structures under near-fault and far-field ground motions were conducted to investigate the effects of eccentricity in the isolation system and in the superstructures, the ratio of the uncoupled torsional to lateral frequency of the superstructure and the pulse period of near-fault ground motions on the nonlinear seismic response of asymmetric base-isolated structures. Numerical results show that eccentricity in the isolation system makes asymmetric base-isolated structure more sensitive to near-fault ground motions, and the pulse period of near-fault ground motions plays an import role in governing the seismic responses of asymmetric base-isolated structures. 展开更多
关键词 asymmetric base-isolated structure Near-fault ground motion Far-field ground motion Nonlinear seismic response
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The role of viscoelastic damping on retrofitting seismic performance of asymmetric reinforced concrete structures
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作者 Zeshan Alam Chunwei Zhang Bijan Samali 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2020年第1期223-237,共15页
The primary purpose of this research is to improve the seismic response of a complex asymmetric tall structure using viscoelastic(VE) dampers. Asymmetric structures have detrimental effects on the seismic performance ... The primary purpose of this research is to improve the seismic response of a complex asymmetric tall structure using viscoelastic(VE) dampers. Asymmetric structures have detrimental effects on the seismic performance because such structures create abrupt changes in the stiffness or strength that may lead to undesirable stress concentrations at weak locations. Structural control devices are one of the effective ways to reduce seismic impacts, particularly in asymmetric structures. For passive vibration control of structures, VE dampers are considered among the most preferred devices for energy dissipation. Therefore, in this research, VE dampers are implemented at strategic locations in a realistic case study structure to increase the level of distributed damping without occupying significant architectural space and reducing earthquake vibrations in terms of story displacements(drifts) and other design forces. It has been concluded that the seismic response of the considered structure retrofitted with supplemental VE dampers corresponded well in controlling the displacement demands. Moreover, it has been demonstrated that seismic response in terms of interstory drifts was effectively mitigated with supplemental damping when added up to a certain level. Exceeding the supplemental damping from this level did not contribute to additional mitigation of the seismic response of the considered structure. In addition, it was found that the supplemental damping increased the total acceleration of the considered structure at all floor levels, which indicates that for irregular tall structures of this type, VE dampers were only a good retrofitting measure for earthquake induced interstory deformations and their use may not be suitable for acceleration sensitive structures. Overall, the research findings demonstrate how seismic hazards to these types of structures can be reduced by introducing additional damping into the structure. 展开更多
关键词 viscoelastic dampers seismic analysis asymmetric structure nonlinear modal time history analysis
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Misalignment analysis of journal bearing influenced by asymmetric deflection,based on a simple stepped shaft model 被引量:12
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作者 Zhen-peng HE Jun-hong ZHANG +2 位作者 Wei-song XIE Zhou-yu LI Gui-chang ZHANG 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2012年第9期647-664,共18页
The effects of journal misalignment on a journal bearing caused by an asymmetric rotor structure are presented in this study.A new model considering the asymmetric deflection is applied.Also,the thermo-hydrodynamic of... The effects of journal misalignment on a journal bearing caused by an asymmetric rotor structure are presented in this study.A new model considering the asymmetric deflection is applied.Also,the thermo-hydrodynamic of the oil film in the journal bearing and straightforward elasticity theory are considered in the analysis.Based on the structure stiffness equivalent characteristic,a simple stepped shaft can reflect the entire complex structure model.The existing lubrication model,which does not consider this angle component,is not very precise for journal bearings.Film pressure,misalignment angle,velocity field,oil leakage,and temperature field were calculated and compared in the journal bearing analysis.The results indicate that bearing performances are greatly affected by misalignment caused by the asymmetric structure.A simple stepped shaft can effectively represent a misaligned journal bearing in a rotor-bearing system. 展开更多
关键词 MISALIGNMENT Stepped shaft asymmetric structure Journal bearing
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12.6μm-Thick Asymmetric Composite Electrolyte with Superior Interfacial Stability for Solid-State Lithium-Metal Batteries 被引量:4
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作者 Zheng Zhang Jingren Gou +4 位作者 Kaixuan Cui Xin Zhang Yujian Yao Suqing Wang Haihui Wang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第9期397-409,共13页
Solid-state lithium metal batteries(SSLMBs)show great promise in terms of high-energy-density and high-safety performance.However,there is an urgent need to address the compatibility of electrolytes with high-voltage ... Solid-state lithium metal batteries(SSLMBs)show great promise in terms of high-energy-density and high-safety performance.However,there is an urgent need to address the compatibility of electrolytes with high-voltage cathodes/Li anodes,and to minimize the electrolyte thickness to achieve highenergy-density of SSLMBs.Herein,we develop an ultrathin(12.6μm)asymmetric composite solid-state electrolyte with ultralight areal density(1.69 mg cm^(−2))for SSLMBs.The electrolyte combining a garnet(LLZO)layer and a metal organic framework(MOF)layer,which are fabricated on both sides of the polyethylene(PE)separator separately by tape casting.The PE separator endows the electrolyte with flexibility and excellent mechanical properties.The LLZO layer on the cathode side ensures high chemical stability at high voltage.The MOF layer on the anode side achieves a stable electric field and uniform Li flux,thus promoting uniform Li^(+)deposition.Thanks to the well-designed structure,the Li symmetric battery exhibits an ultralong cycle life(5000 h),and high-voltage SSLMBs achieve stable cycle performance.The assembled pouch cells provided a gravimetric/volume energy density of 344.0 Wh kg^(−1)/773.1 Wh L^(−1).This simple operation allows for large-scale preparation,and the design concept of ultrathin asymmetric structure also reveals the future development direction of SSLMBs. 展开更多
关键词 Solid-state lithium metal batteries Composite solid-state electrolyte Ultrathin asymmetric structure Pouch cells
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Enhancing performance of GaN-based LDs by using GaN/InGaN asymmetric lower waveguide layers 被引量:3
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作者 Wen-Jie Wang Ming-Le Liao +2 位作者 Jun Yuan Si-Yuan Luo Feng Huang 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第7期321-326,共6页
The effects of Ga N/In Ga N asymmetric lower waveguide(LWG)layers on photoelectrical properties of In Ga N multiple quantum well laser diodes(LDs)with an emission wavelength of around 416 nm are theoretically investig... The effects of Ga N/In Ga N asymmetric lower waveguide(LWG)layers on photoelectrical properties of In Ga N multiple quantum well laser diodes(LDs)with an emission wavelength of around 416 nm are theoretically investigated by tuning the thickness and the indium content of In Ga N insertion layer(In Ga N-IL)between the Ga N lower waveguide layer and the quantum wells,which is achieved with the Crosslight Device Simulation Software(PIC3D,Crosslight Software Inc.).The optimal thickness and the indium content of the In Ga N-IL in lower waveguide layers are found to be 300 nm and 4%,respectively.The thickness of In Ga N-IL predominantly affects the output power and the optical field distribution in comparison with the indium content,and the highest output power is achieved to be 1.25 times that of the reference structure(symmetric Ga N waveguide),which is attributed to the reduced optical absorption loss as well as the concentrated optical field nearby quantum wells.Furthermore,when the thickness and indium content of In Ga N-IL both reach a higher level,the performance of asymmetric quantum wells LDs will be weakened rapidly due to the obvious decrease of optical confinement factor(OCF)related to the concentrated optical field in the lower waveguide. 展开更多
关键词 asymmetric waveguide structure InGaN multiple quantum wells optical absorption loss optical field distribution
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Recent Progress on Asymmetric Carbon- and Silica-Based Nanomaterials: From Synthetic Strategies to Their Applications 被引量:2
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作者 Haitao Li Liang Chen +2 位作者 Xiaomin Li Daoguang Sun Haijiao Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2022年第3期134-168,共35页
Carbon-and silica-based nanomaterials possess a set of merits including large surface area,good structural stability,diversified morphology,adjustable structure,and biocompatibility.These outstanding features make the... Carbon-and silica-based nanomaterials possess a set of merits including large surface area,good structural stability,diversified morphology,adjustable structure,and biocompatibility.These outstanding features make them widely applied in different fields.However,limited by the surface free energy effect,the current studies mainly focus on the symmetric structures,such as nanospheres,nanoflowers,nanowires,nanosheets,and core-shell structured composites.By comparison,the asymmetric structure with ingenious adjustability not only exhibits a larger effective surface area accompanied with more active sites,but also enables each component to work independently or corporately to harness their own merits,thus showing the unusual performances in some specific applications.The current review mainly focuses on the recent progress of design principles and synthesis methods of asymmetric carbon-and silica-based nanomaterials,and their applications in energy storage,catalysis,and biomedicine.Particularly,we provide some deep insights into their unique advantages in related fields from the perspective of materials’structure-performance relationship.Furthermore,the challenges and development prospects on the synthesis and applications of asymmetric carbon-and silica-based nanomaterials are also presented and highlighted. 展开更多
关键词 Carbon-and silica-based nanoparticles asymmetric structure Synthetic strategies Energy storage and conversion BIOMEDICINE
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AN ANALYSIS OF THE ASYMMETRICAL STRUCTURE OF TYPHOON AERE'S PRECIPITATION 被引量:2
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作者 濮江平 吕梅 邹力 《Journal of Tropical Meteorology》 SCIE 2010年第1期91-95,共5页
The structural characteristics of 2004 typhoon Aere's precipitation are analyzed using the high-resolution data from the Tropical Rainfall Measuring Mission(TRMM) of the National Aeronautics Space Administration(N... The structural characteristics of 2004 typhoon Aere's precipitation are analyzed using the high-resolution data from the Tropical Rainfall Measuring Mission(TRMM) of the National Aeronautics Space Administration(NASA).It is found that the typhoon's characteristics vary at different stages of its development.To analyze the asymmetric causation of precipitation distribution,data from the National Center for Environmental Prediction(NCEP) reanalysis are used to calculate the vertical integral of the water vapor flux vector.The results show that because of this process,along with the unique phenomenon of twin-typhoon circulation,the easterly air current of the typhoon's northern side and the southwesterly air current of its southern side play a joint role in transporting water vapor.Furthermore,its transport effects vary greatly at the different stages of development,showing the peculiarity of the water source for this typhoon process.The distributions of the typhoon convection area—characterized by heavy precipitation and a maximum-value area of the water vapor flux,as well as a strong ascending-motion area—differ at different stages of the typhoon's development.The non-uniform distribution of water vapor flux and the vertical motion bring about asymmetrical distribution of the typhoon precipitation. 展开更多
关键词 typhoon precipitation TRMM vapor flux vector asymmetrical structure
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Stable single longitudinal mode erbium-doped silica fiber laser based on an asymmetric linear three-cavity structure 被引量:2
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作者 冯亭 延凤平 +4 位作者 李琦 彭万敬 冯素春 谭思宇 温晓东 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第1期268-272,共5页
We present a stable linear-cavity single longitudinal mode (SLM) erbium-doped silica fiber laser. It consists of four fiber Bragg gratings (FBGs) directly written in a section of photosensitive erbium-doped fiber ... We present a stable linear-cavity single longitudinal mode (SLM) erbium-doped silica fiber laser. It consists of four fiber Bragg gratings (FBGs) directly written in a section of photosensitive erbium-doped fiber (EDF) to form an asymmetric three-cavity structure. The stable SLM operation at a wavelength of 1545.112 nm with a 3-dB bandwidth of 0.012 nm and an optical signal-to-noise ratio (OSNR) of about 60 dB is verified experimentally. Under laboratory conditions, the performance of a power fluctuation of less than 0.05 dB observed from the power meter for 6 h and a wavelength variation of less than 0.01 nm obtained from the optical spectrum analyzer (OSA) for about 1.5 h are demonstrated. The gain fiber length is no longer limited to only several centimeters for SLM operation because of the excellent mode-selecting ability of the asymmetric three-cavity structure. The proposed scheme provides a simple and cost-effective approach to realizing a stable SLM fiber laser. 展开更多
关键词 asymmetric three-cavity structure single longitudinal mode erbium-doped fiber laser linear cavity
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A Single-Board Integrated Millimeter-Wave Asymmetric Full-Digital Beamforming Array for B5G/6G Applications 被引量:1
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作者 Qingqing Lin Jun Xu +9 位作者 Kai Chen Long Wang Wei Li Zhiqiang Yu Guangqi Yang Jianyi Zhou Zhe Chen Jixin Chen Xiaowei Zhu Wei Hong 《Engineering》 SCIE EI CAS CSCD 2024年第10期35-50,共16页
In this article,a single-board integrated millimeter-wave(mm-Wave)asymmetric full-digital beamforming(AFDBF)array is developed for beyond-fifth-generation(B5G)and sixth-generation(6G)communications.The proposed integr... In this article,a single-board integrated millimeter-wave(mm-Wave)asymmetric full-digital beamforming(AFDBF)array is developed for beyond-fifth-generation(B5G)and sixth-generation(6G)communications.The proposed integrated array effectively addresses the challenge of arranging a large number of ports in a full-digital array by designing vertical connections in a three-dimensional space and successfully integrating full-digital transmitting(Tx)and receiving(Rx)arrays independently in a single board.Unlike the traditional symmetric array,the proposed asymmetric array is composed of an 8×8 Tx array arranged in a square shape and an 8+8 Rx array arranged in an L shape.The center-to-center distance between two adjacent elements is 0.54k0 for both the Tx and Rx arrays,where k0 is the free-space wavelength at 27 GHz.The proposed AFDBF array possesses a more compact structure and lower system hardware cost and power consumption compared with conventional brick-type full-digital arrays.In addition,the energy efficiency of the proposed AFDBF array outperforms that of a hybrid beamforming array.The measurement results indicate that the operating frequency band of the proposed array is 24.25–29.50 GHz.An eight-element linear array within the Tx array can achieve a scanning angle ranging from-47°to+47°in both the azimuth and the elevation planes,and the measured scanning range of each eight-element Rx array is–45°to+45°.The measured maximum effective isotropic radiated power(EIRP)of the eight-element Tx array is 43.2 dBm at 28.0 GHz(considering the saturation point).Furthermore,the measured error vector magnitude(EVM)is less than 3%when 64-quadrature amplitude modulation(QAM)waveforms are used. 展开更多
关键词 Full-digital beamforming array asymmetric structure Single-board integrated Beyond fifth-generation and sixthgeneration Millimeter-wave communication Complex modulation Printed circuit board Vertical connection
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Energy Absorption Characteristics of a Novel Asymmetric and Rotatable Re-entrant Honeycomb Structure 被引量:1
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作者 Huifeng Xi Jiachu Xu +1 位作者 Shende Cen Shiqing Huang 《Acta Mechanica Solida Sinica》 SCIE EI CSCD 2021年第4期550-560,共11页
Based on the symmetric re-entrant honeycomb(S-RH)structure with negative Poisson’s ratios,a novel asymmetric and rotatable re-entrant honeycomb(AR-RH)structure was proposed.Both the S-RH structure and AR-RH structure... Based on the symmetric re-entrant honeycomb(S-RH)structure with negative Poisson’s ratios,a novel asymmetric and rotatable re-entrant honeycomb(AR-RH)structure was proposed.Both the S-RH structure and AR-RH structure were produced by the 3D printing technology.Through experimental test and finite element simulation,the deformation mechanism and energy absorption characteristics of the AR-RH structure and the S-RH structure with negative Poisson’s ratios at different impact velocities were compared.The experimental test and finite element simulation results show that the novel AR-RH structure with negative Poisson’s ratios has stronger energy absorption capacity than the S-RH structure,and it has been verified that the rotatability of AR-RH can indeed absorb energy.Furthermore,the degree of asymmetry of the AR-RH structure was discussed. 展开更多
关键词 asymmetric and rotatable re-entrant honeycomb structure Dynamic compression Energy absorption characteristics Metal 3D printing technology
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Wide angle space laser communication receiver based on asymmetric array structure 被引量:1
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作者 WANG Yuehui ZHAO Zeping +2 位作者 ZHANG Zhike LIU Haifeng LIU Jianguo 《Optoelectronics Letters》 EI 2021年第11期678-682,共5页
In this paper, an asymmetric array structure of space laser communication receiver is proposed. This structure can greatly reduce alignment requirement, and lighten the signal strength jitter caused by atmospheric tur... In this paper, an asymmetric array structure of space laser communication receiver is proposed. This structure can greatly reduce alignment requirement, and lighten the signal strength jitter caused by atmospheric turbulence. A prototype of the proposed structure is fabricated and a 2.5 Mbit/s on-off keying(OOK) modulated demonstration link over 40 m free space is built. This asymmetric array structure can effectively collect optical signal while rotating in a window angle of ±17°, and the bit error ratio(BER) keeps zero. 展开更多
关键词 Wide angle space laser communication receiver based on asymmetric array structure
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Torsionally coupled dynamic performance analysis of asymmetric offshore platforms subjected to wave and earthquake loadings
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作者 He Xiaoyu Li Hongnan 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2010年第2期247-258,共12页
The dynamic equations of motion of asymmetric offshore platforms under three different environmental conditions:seismic action,wave action and their combination are established in this paper.In establishing these moti... The dynamic equations of motion of asymmetric offshore platforms under three different environmental conditions:seismic action,wave action and their combination are established in this paper.In establishing these motion equations,three typical eccentricity types including mass eccentricity,rigidity eccentricity and their combination were considered,as are eccentricities that occur un-idirectionally and bi-directionally.The effects of the eccentricity type,the dynamic characteristics and the environmental conditions on the torsional coupling response of platforms are investigated and compared.An effort has also been made to analyze the inffluence of accidental eccentricity on asymmetric platforms with different eccentricity in two horizontally orthogonal directions.The results are given in terms of non-dimensional parameters,accounting for the uncoupled torsional to lateral frequency ratio.Numerical results reveal that the eccentricity type has a great inffluence on the torsionally coupled response under different environmental conditions.Therefore,it is necessary to consider the combination of earthquake and wave action in the seismic response analysis of some offshore platforms. 展开更多
关键词 offshore platform asymmetric structure accidental eccentricity torsion coupling earthquake load wave load
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Recent Advances in Asymmetric Structural Composites for Excellent Electromagnetic Interference Shielding:A Review
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作者 Ying Zhou Bai Xue +2 位作者 Lan Xie Chang-Mei Wu Qiang Zheng 《Chinese Journal of Polymer Science》 SCIE EI CAS CSCD 2024年第6期693-710,共18页
Since electromagnetic pollution is detrimental to human health and the environment,numerous efforts have been successively made to achieve excellent electromagnetic interference shielding effectiveness(EMI SE)via desi... Since electromagnetic pollution is detrimental to human health and the environment,numerous efforts have been successively made to achieve excellent electromagnetic interference shielding effectiveness(EMI SE)via designing the hierarchical structures for electromagnetic interference(EMI)shielding polymer composites.Among the plentiful structures,the asymmetric structures are currently a hot spot,principally categorizing into multi-layered,porous,fibrous,and segregated asymmetric structures,which endows the high EMI shielding performance for polymer composites incorporated with magnetic,conductive,and/or dielectric micro/nano-fillers,due to the“absorption-reflection-reabsorption”shielding mechanism.Therefore,this review provides the retrospection and summary of the efforts with respect to abundant asymmetric structures and multifunctional micro/nano-fillers for enhancing EMI shielding properties,which is conducive to the booming development of polymeric EMI shielding materials for the promising prospect in modern electronics and 5-generation(5G)technology. 展开更多
关键词 asymmetric structure Micro/nano functional fller Polymer composite Electromagnetic interference shielding
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Asymmetric Ni/PVC Films for High-performance Electromagnetic Interference Shielding
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作者 张扬 Xiao-xia Fang 温变英 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2015年第6期899-907,共9页
A novel asymmetric Ni/PVC film has been developed by solution casting method. The structure, electrical conductivity, electromagnetic interference (EMI) shielding, and impact resistance were investigated. The result... A novel asymmetric Ni/PVC film has been developed by solution casting method. The structure, electrical conductivity, electromagnetic interference (EMI) shielding, and impact resistance were investigated. The results showed that the Ni particles were asymmetrically distributed along the thickness direction in the film. The top surface resistivity increased with film thickness, while the bottom surface exhibited the different trend. EMI shielding effectiveness (SE) depended on formation of closed packed conductive Ni network, which was influenced by both Ni content and film thickness. A linear relationship was observed between EMI SE and film thickness. The films with lower Ni content showed the faster increasing rate of EMI SE with film thickness. Some of the films show appreciably high EMI SE (〉 40 dB), indicating the promising application in EMI shielding field. Moreover, the films exhibit different impact performance under different impacting directions. All the experimental facts demonstrate that the asymmetric structure endows the film achieving high-performance EMI shielding function. 展开更多
关键词 asymmetric structure Electrical conductivity Electromagnetic interference shielding.
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Asymmetric N,O-Coordinated Single Atomic Co Sites for Stable Lithium Metal Anodes
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作者 Yifan Li Daliang Fang +8 位作者 Xue Liang Li Dong Yan Shibo Xi Tian Chen Li Congjian Lin Shaozhuan Huang Jianbei Qiu Xuhui Xu Hui Ying Yang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第5期425-431,共7页
Lithium metal has been considered one of the most promising anodes for next-generation rechargeable batteries,but its practical application is largely hindered by the uncontrollable dendrite growth and infinite volume... Lithium metal has been considered one of the most promising anodes for next-generation rechargeable batteries,but its practical application is largely hindered by the uncontrollable dendrite growth and infinite volume change.Here,inspired by superior catalytic effects of single-atom catalysts,carbon-supported single atomic Co with asymmetric N,O-coordination(Co-N/O)is developed for Li metal battery.Experimental results and theoretical calculations indicate that single atomic Co atoms with asymmetric N,O-coordination present enhanced binding ability toward Li in comparison with N-coordinated atomic Co site and isolated O site,enabling uniform Li plating/stripping.Moreover,the asymmetric N,O-coordination around Co atoms induces co-activation effects,lowering the energy barriers toward Li^(+)to Li^(0)conversion and largely promoting the deposition kinetics.When used as a Li deposition host,the Co-N/O achieves a high average coulombic efficiency of 98.6%at a current density of 1 mA cm^(-2)and a capacity of 2 mAh cm^(-2),long cycling life of 2000 h in symmetrical cells,and excellent rate performance(voltage hysteresis of 23 mV at 8 mA cm^(-2)).This work provides a comprehensive understanding of single atomic metals with asymmetric heteroatom coordination in the design of Li metal anode. 展开更多
关键词 asymmetric atomic structure lithiophilicity lithium metal anode N O-coordination single atomic Co
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SYNTHESIS AND STRUCTURE OF AN ASYMMETRIC TRICOBALT COMPOUND Co_3(o-HOC_6H_4S)_2(o-OC_6H_4S)_2(PEt_3)_3
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作者 Yong Jin XU Bei Sheng KANG Xue Tai CHEN Yong Han HU Fujian Institute of Research on the Structure of Matter and Fuzhou Laboratory of Structural Chemistry Chinese Academy of Science,Fuzhou,Fujian 350002 《Chinese Chemical Letters》 SCIE CAS CSCD 1992年第12期1017-1018,共2页
Compound Co_3(o-HOC_6H_4S)_2(o-OC_6H_4S)_2(PEt_3)_3 was obtained by reaction of CoCl_2, o-HOC_6H_4SH(H_2mD)and PEt_3 in ethanol in the presence of NaOCH_3.The three Co atoms are triangularly arranged and asymmetricall... Compound Co_3(o-HOC_6H_4S)_2(o-OC_6H_4S)_2(PEt_3)_3 was obtained by reaction of CoCl_2, o-HOC_6H_4SH(H_2mD)and PEt_3 in ethanol in the presence of NaOCH_3.The three Co atoms are triangularly arranged and asymmetrically bridged by four S and one O atoms from the four H_2mp ligands and terminally ligated by one O and three P atoms.Two free hydroxyl groups form two internal hydrogen bonds with adjacent oxo donor atoms. 展开更多
关键词 Co PEt3 SYNTHESIS AND STRUCTURE OF AN asymmetric TRICOBALT COMPOUND Co3 o-HOC6H4S o-OC6H4S OC
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The Analysis of the Asymmetric Precipitation Caused by the No.10 Tropical Cyclone “Damrey” in 2012 Based on Observation and Numerical Simulation
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作者 Jian Li Jiqiu Liu 《Journal of Geoscience and Environment Protection》 2022年第8期145-157,共13页
The No.10 tropical cyclone “Damrey” in 2012 is the first landing typhoon on the north of the Yangtze River after 1949. After its landing, Damrey showed an obvious asymmetric structure and precipitation. Using the ER... The No.10 tropical cyclone “Damrey” in 2012 is the first landing typhoon on the north of the Yangtze River after 1949. After its landing, Damrey showed an obvious asymmetric structure and precipitation. Using the ERA-interim reanalysis data from the European Centre for Medium-Range Weather Forecasting (ECMWF), the study simulated the whole process of Damrey from pre-landing to extinct by using WRF model. Based on the model result and FY-2E satellite data and observation data, the study analysis the causes of the asymmetric structure of Damrey. It is found that the descending motion is strong on the west and south sides of the typhoon, they blocked the southwest water vapor transport. So the development of convective cloud system was hindered, and the wind shear on the west and south sides on the typhoon was stronger than on the east and north. It caused the result of the precipitation on the east and north sides of typhoon much more than on the west and south. Q-vector, upper level jets and other factors are also analyzed in this study. 展开更多
关键词 Typhoon Damrey asymmetric Structure Q-Vector WRF Model
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Flexible asymmetric supercapacitor based on MnO_2 honeycomb structure
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作者 Yuling Chen Chao Chen +4 位作者 Ruitao Lv Wanci Shen Feiyu Kang Nyanhwa Tai Zhenghong Huang 《Chinese Chemical Letters》 SCIE CAS CSCD 2018年第4期616-619,共4页
A flexible asymmetric supercapacitor with high energy density was constructed by using a flexible substrate of carbonized silk-fabrics decorated with carbon nanotube, electroplating MnO2 nanosheets and dip-coating act... A flexible asymmetric supercapacitor with high energy density was constructed by using a flexible substrate of carbonized silk-fabrics decorated with carbon nanotube, electroplating MnO2 nanosheets and dip-coating activated carbon powders as the positive and the negative electrodes, respectively. By controlling the electroplating time, the MnO2 nanosheets can be self-assembled to honeycomb structure and showed excellent electrochemical performance in 1 mol/L Na2SO4 electrolyte with SC950-EP30 performing the best. It exhibited a high specific capacitance(1110.85 F/g at a current density of 1 A/g based on the mass of MnO2) and superior rate capability(77.44% capacity retention from 1 A/g to 10 A/g).Thus, the optimal asymmetric device assembled with this material as positive electrode can deliver a maximum energy density of 43.84 Wh/kg and a maximum power density of 6.62 kW/kg. 展开更多
关键词 Electroplating Self-assembling nanosheets Honeycomb structure MnO2 asymmetric supercapacitors High energy density
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Numerical simulation of size contraction of Typhoon Cempaka(2021)
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作者 Lingfeng Sun Qingqing Li 《Atmospheric and Oceanic Science Letters》 2025年第2期29-35,共7页
In 2021,Cempaka,a tiny tropical cyclone,made landfall in China.As the TC intensified prior to landfall,the tropical cyclone size measured with precipitation decreased significantly.A numerical simulation was conducted... In 2021,Cempaka,a tiny tropical cyclone,made landfall in China.As the TC intensified prior to landfall,the tropical cyclone size measured with precipitation decreased significantly.A numerical simulation was conducted to examine the possible processes modulating the storm size.Azimuthally mean potential vorticity(PV)was found to decrease mainly in the middle to upper troposphere between 50-and 80-km radii.The PV budget results indicate that the advection and generation of mean PV associated with asymmetric processes,rather than the symmetric processes,primarily contributed to the decrease in mean PV.These asymmetric processes leading to a negative PV tendency were likely associated with inactive outer rainbands.In contrast,the tangential winds simultaneously expanded radially outward,possibly related to inner-core diabatic heating.The findings here emphasize the importance of outer rainband activity in tropical cyclone size change. 展开更多
关键词 Typhoon cempaka Vortex size contraction Potential vorticity budget asymmetric structure Outer rainband
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