With the unprecedented prevalence of Industrial Internet of Things(IIoT)and 5G technology,various applications supported by industrial communication systems have generated exponentially increased processing tasks,whic...With the unprecedented prevalence of Industrial Internet of Things(IIoT)and 5G technology,various applications supported by industrial communication systems have generated exponentially increased processing tasks,which makes task assignment inefficient due to insufficient workers.In this paper,an Intelligent and Trustworthy task assignment method based on Trust and Social relations(ITTS)is proposed for scenarios with many tasks and few workers.Specifically,ITTS first makes initial assignments based on trust and social influences,thereby transforming the complex large-scale industrial task assignment of the platform into the small-scale task assignment for each worker.Then,an intelligent Q-decision mechanism based on workers'social relation is proposed,which adopts the first-exploration-then-utilization principle to allocate tasks.Only when a worker cannot cope with the assigned tasks,it initiates dynamic worker recruitment,thus effectively solving the worker shortage problem as well as the cold start issue.More importantly,we consider trust and security issues,and evaluate the trust and social circles of workers by accumulating task feedback,to provide the platform a reference for worker recruitment,thereby creating a high-quality worker pool.Finally,extensive simulations demonstrate ITTS outperforms two benchmark methods by increasing task completion rates by 56.49%-61.53%and profit by 42.34%-47.19%.展开更多
Aim To investigate the NMR spectroscopy of amlodipine and risperidone.Methods 1D NMR and 2D NMR experimental techniques of gCOSY, gHSQC and gHMBC were wsed. Results Theassignments of the ~1H and ^(13) C NMR data for t...Aim To investigate the NMR spectroscopy of amlodipine and risperidone.Methods 1D NMR and 2D NMR experimental techniques of gCOSY, gHSQC and gHMBC were wsed. Results Theassignments of the ~1H and ^(13) C NMR data for the two drugs were performed and confirmed by theevidence of J_(HF) and J_(CF). Conclusion The structures of amlodipine and risperidone wereconfirmed by careful analysis of regular 1D and 2D NMR spectroscopy.展开更多
This article presents a comprehensive mathematical model for the design and analysis of Dynamic Cellular Manufacturing Systems （DCMS）. The proposed DCMS model considers several manufacturing attributes such as multi...This article presents a comprehensive mathematical model for the design and analysis of Dynamic Cellular Manufacturing Systems （DCMS）. The proposed DCMS model considers several manufacturing attributes such as multi period production planning, dynamic system reconfiguration, duplicate machines, machine capacity, the available time for workers, worker assignments, and machine procurement. The objective is to minimize total costs; consisting of holding cost, outsourcing cost, inter-cell material handling cost, maintenance and overhead cost, machine relocation cost. While a study of published articles in the area of Cellular Manufacturing Systems （CMS） shows that workforce management issues have not sufficiently been addressed in the literature, the model presented also incorporates CMS workforce management issues such as salaries, hiring and firing costs of workers in addition to the manufacturing attributes. In-depth discussions on the results for two numerical examples are presented to illustrate applications of the proposed model. The model developed aims to raise the envelope by expanding and improving several CMS models previously presented in the literature.展开更多
Abstract:Comments on students’assignments are important for English course.The loopholes in teachers’working schemes-comments of their students’written assignments are the clues around which the paper spreads.In th...Abstract:Comments on students’assignments are important for English course.The loopholes in teachers’working schemes-comments of their students’written assignments are the clues around which the paper spreads.In the process of teaching,some English teachers pay so much attention to the contents taught in class but ignore the comments on students’written assignments.Consequently,it is not applicable for students to correct their mistakes in time and they probably make the same mistakes repeatedly.展开更多
Aim To investigate the structure of mogroside Ⅳa isolated from traditionalChinese medicine fructus mo-mordicae [fruits of Siraitia grosvenori (Swingle) C. Jeffery] andsummarize the NMR characteristics of the structur...Aim To investigate the structure of mogroside Ⅳa isolated from traditionalChinese medicine fructus mo-mordicae [fruits of Siraitia grosvenori (Swingle) C. Jeffery] andsummarize the NMR characteristics of the structure. Methods Common extraction, separation andpurification methods were used. Various NMR techniques including ~1H NMR, ^(13)C NMR, DEPT, ~1H-~1HCOSY, HSQC, HMBC, NOESY and molecular model simulated by computer were used to elucidate thestructure. Results ~1H and ^(13)C NMR signals of mogroside Ⅳa were assigned, and spectroscopicbasis was obtained for identification of such type of compounds. Conclusion 1D and 2D NMR techniquesincluding ~1H-~1H COSY, HSQC, HMBC, NOESY spectra are powerful tools for structure analysis. Thestructure determined by NMR methods is identical with energy minimized conformation simulated bycomputer.展开更多
A graphically oriented interactive program for assignments of rotationally resolved molecular spectra has been devised. The program functions by grouping spectral lines in term of the second difference principle. and ...A graphically oriented interactive program for assignments of rotationally resolved molecular spectra has been devised. The program functions by grouping spectral lines in term of the second difference principle. and graphing spectral intensity versus frequency in a bar graph of the selected groups, distinguished by color and/or line-type. This allows for easy detection of regular patterns buried in the observed spectrum. Furthermore, it includes a Loomis-Wood view for assisting in spectral assignments. As an example, the program was applied in assigning the molecular spectrum of the production in the discharge of PCl3 buffered by helium gas, which may belong to several species. The results suggest that the program is highly efficient and quite useful in the assignment and the analysis of molecular spectra, especially those of symmetric top, slightly asymmetric top and linear molecules. The accuracy and efficiency of this program will likely ensure its wide application in the processing of molecular spectra.展开更多
1H-NMR and 13C-NMR assignments of 12-oleanene-3,11-dione (compound 1) were completely described for the first time through conventional 1D NMR and 2D shift-correlated NMR experiments using 1H-1HCOSY, HMQC, HMBC techni...1H-NMR and 13C-NMR assignments of 12-oleanene-3,11-dione (compound 1) were completely described for the first time through conventional 1D NMR and 2D shift-correlated NMR experiments using 1H-1HCOSY, HMQC, HMBC techniques. Based on its NMR data, the assignments of 28-hydroxyolean-12-ene-3,11-dione (compound 2) were partially revised.展开更多
Energy spectrum of yrast band for ^(122)Cs is studied by using particle-rotor model(PRM)of odd-odd nuclei,in which special attention is paid to the model basis accounting for the effect of the instabilityγvibration p...Energy spectrum of yrast band for ^(122)Cs is studied by using particle-rotor model(PRM)of odd-odd nuclei,in which special attention is paid to the model basis accounting for the effect of the instabilityγvibration perturbation around axial symmetry.In order to check the assignments of this band,two calculation schemes are put into practice.The first one is for previousπh11/2 vg7/2 configuration with bandhead spin I_(0)=(6^(-))which was obtained from cranked shell model(CSM)calculation,and the other one is forπh_(11/2) vh_(11/2) configuration with I_(0)=(9^(+))supported by the systematic analyses of experimental data.A qualitative comparison between the present PRM calculation and that of CSM has also been made.The results indicate that,rather thanπh_(11/2) vg_(7/2) I_(0)=(6^(-)),πh_(11/2) vh_(11/2) with I_(0)=(9^(+))is a more reasonable assignment to the yrast band in ^(122)Cs.展开更多
For a given graph G, a k-role assignment of G is a surjective function ?such that , where N(x) and N(y) are the neighborhoods of x and y, respectively. Furthermore, as we limit the number of different roles in the nei...For a given graph G, a k-role assignment of G is a surjective function ?such that , where N(x) and N(y) are the neighborhoods of x and y, respectively. Furthermore, as we limit the number of different roles in the neighborhood of an individual, we call r a restricted size k-role assignment. When the hausdorff distance between the sets of roles assigned to their neighbors is at most 1, we call r a k-threshold close role assignment. In this paper we study the graphs that have k-role assignments, restricted size k-role assignments and k-threshold close role assignments, respectively. By the end we discuss the maximal and minimal graphs which have k-role assignments.展开更多
Bile acids are the main body of enterohepatic circulation in vivo.They have essential functions such as emulsifying fat,bacteriostasis and regulating multiple metabolic pathways as signal molecules.However,the assignm...Bile acids are the main body of enterohepatic circulation in vivo.They have essential functions such as emulsifying fat,bacteriostasis and regulating multiple metabolic pathways as signal molecules.However,the assignments of NMR signals for some lowconcentration bile acids are still needed.This study combined 1D nuclear magnetic resonance(NMR)and 2D NMR techniques including 1He1H correlation spectroscopy(COSY),1He1H total correlation spectroscopy(TOCSY),1H J-resolved spectroscopy(J-Res),1He13C heteronuclear single quantum coherence spectroscopy(HSQC),and 1He13C heteronuclear multiple bond correlation spectroscopy(HMBC)to assign the 1H and 13C signals of six bile acids in aqueous solution at physiological pH(~7.4)and nine bile acids in methanol.These data are of importance to the NMR-based studies on lipid digestion,absorption,and metabolism.展开更多
基金supported by the National Natural Science Foundation of China under Grant No.62072475 and No.62302062in part by the Hunan Provincial Natural Science Foundation of China under Grant Number 2023JJ40081。
文摘With the unprecedented prevalence of Industrial Internet of Things(IIoT)and 5G technology,various applications supported by industrial communication systems have generated exponentially increased processing tasks,which makes task assignment inefficient due to insufficient workers.In this paper,an Intelligent and Trustworthy task assignment method based on Trust and Social relations(ITTS)is proposed for scenarios with many tasks and few workers.Specifically,ITTS first makes initial assignments based on trust and social influences,thereby transforming the complex large-scale industrial task assignment of the platform into the small-scale task assignment for each worker.Then,an intelligent Q-decision mechanism based on workers'social relation is proposed,which adopts the first-exploration-then-utilization principle to allocate tasks.Only when a worker cannot cope with the assigned tasks,it initiates dynamic worker recruitment,thus effectively solving the worker shortage problem as well as the cold start issue.More importantly,we consider trust and security issues,and evaluate the trust and social circles of workers by accumulating task feedback,to provide the platform a reference for worker recruitment,thereby creating a high-quality worker pool.Finally,extensive simulations demonstrate ITTS outperforms two benchmark methods by increasing task completion rates by 56.49%-61.53%and profit by 42.34%-47.19%.
文摘Aim To investigate the NMR spectroscopy of amlodipine and risperidone.Methods 1D NMR and 2D NMR experimental techniques of gCOSY, gHSQC and gHMBC were wsed. Results Theassignments of the ~1H and ^(13) C NMR data for the two drugs were performed and confirmed by theevidence of J_(HF) and J_(CF). Conclusion The structures of amlodipine and risperidone wereconfirmed by careful analysis of regular 1D and 2D NMR spectroscopy.
文摘This article presents a comprehensive mathematical model for the design and analysis of Dynamic Cellular Manufacturing Systems （DCMS）. The proposed DCMS model considers several manufacturing attributes such as multi period production planning, dynamic system reconfiguration, duplicate machines, machine capacity, the available time for workers, worker assignments, and machine procurement. The objective is to minimize total costs; consisting of holding cost, outsourcing cost, inter-cell material handling cost, maintenance and overhead cost, machine relocation cost. While a study of published articles in the area of Cellular Manufacturing Systems （CMS） shows that workforce management issues have not sufficiently been addressed in the literature, the model presented also incorporates CMS workforce management issues such as salaries, hiring and firing costs of workers in addition to the manufacturing attributes. In-depth discussions on the results for two numerical examples are presented to illustrate applications of the proposed model. The model developed aims to raise the envelope by expanding and improving several CMS models previously presented in the literature.
文摘Abstract:Comments on students’assignments are important for English course.The loopholes in teachers’working schemes-comments of their students’written assignments are the clues around which the paper spreads.In the process of teaching,some English teachers pay so much attention to the contents taught in class but ignore the comments on students’written assignments.Consequently,it is not applicable for students to correct their mistakes in time and they probably make the same mistakes repeatedly.
文摘Aim To investigate the structure of mogroside Ⅳa isolated from traditionalChinese medicine fructus mo-mordicae [fruits of Siraitia grosvenori (Swingle) C. Jeffery] andsummarize the NMR characteristics of the structure. Methods Common extraction, separation andpurification methods were used. Various NMR techniques including ~1H NMR, ^(13)C NMR, DEPT, ~1H-~1HCOSY, HSQC, HMBC, NOESY and molecular model simulated by computer were used to elucidate thestructure. Results ~1H and ^(13)C NMR signals of mogroside Ⅳa were assigned, and spectroscopicbasis was obtained for identification of such type of compounds. Conclusion 1D and 2D NMR techniquesincluding ~1H-~1H COSY, HSQC, HMBC, NOESY spectra are powerful tools for structure analysis. Thestructure determined by NMR methods is identical with energy minimized conformation simulated bycomputer.
基金This work was supported by the National Natural Science Foundation of China （NSFC No.10574045 and No.10434060）and Science and Technology Commission of Shanghai Municipality（No.04DZ14009）.The authors are grateful to Hua-huiZhu for his valuable suggestions.
文摘A graphically oriented interactive program for assignments of rotationally resolved molecular spectra has been devised. The program functions by grouping spectral lines in term of the second difference principle. and graphing spectral intensity versus frequency in a bar graph of the selected groups, distinguished by color and/or line-type. This allows for easy detection of regular patterns buried in the observed spectrum. Furthermore, it includes a Loomis-Wood view for assisting in spectral assignments. As an example, the program was applied in assigning the molecular spectrum of the production in the discharge of PCl3 buffered by helium gas, which may belong to several species. The results suggest that the program is highly efficient and quite useful in the assignment and the analysis of molecular spectra, especially those of symmetric top, slightly asymmetric top and linear molecules. The accuracy and efficiency of this program will likely ensure its wide application in the processing of molecular spectra.
基金Project (Nos. 20375036 and 20472073) supported by the NationalNatural Science Foundation of China
文摘1H-NMR and 13C-NMR assignments of 12-oleanene-3,11-dione (compound 1) were completely described for the first time through conventional 1D NMR and 2D shift-correlated NMR experiments using 1H-1HCOSY, HMQC, HMBC techniques. Based on its NMR data, the assignments of 28-hydroxyolean-12-ene-3,11-dione (compound 2) were partially revised.
基金Supported by the National Natural Science Foundation of China under Grant No.19475030。
文摘Energy spectrum of yrast band for ^(122)Cs is studied by using particle-rotor model(PRM)of odd-odd nuclei,in which special attention is paid to the model basis accounting for the effect of the instabilityγvibration perturbation around axial symmetry.In order to check the assignments of this band,two calculation schemes are put into practice.The first one is for previousπh11/2 vg7/2 configuration with bandhead spin I_(0)=(6^(-))which was obtained from cranked shell model(CSM)calculation,and the other one is forπh_(11/2) vh_(11/2) configuration with I_(0)=(9^(+))supported by the systematic analyses of experimental data.A qualitative comparison between the present PRM calculation and that of CSM has also been made.The results indicate that,rather thanπh_(11/2) vg_(7/2) I_(0)=(6^(-)),πh_(11/2) vh_(11/2) with I_(0)=(9^(+))is a more reasonable assignment to the yrast band in ^(122)Cs.
文摘For a given graph G, a k-role assignment of G is a surjective function ?such that , where N(x) and N(y) are the neighborhoods of x and y, respectively. Furthermore, as we limit the number of different roles in the neighborhood of an individual, we call r a restricted size k-role assignment. When the hausdorff distance between the sets of roles assigned to their neighbors is at most 1, we call r a k-threshold close role assignment. In this paper we study the graphs that have k-role assignments, restricted size k-role assignments and k-threshold close role assignments, respectively. By the end we discuss the maximal and minimal graphs which have k-role assignments.
文摘Bile acids are the main body of enterohepatic circulation in vivo.They have essential functions such as emulsifying fat,bacteriostasis and regulating multiple metabolic pathways as signal molecules.However,the assignments of NMR signals for some lowconcentration bile acids are still needed.This study combined 1D nuclear magnetic resonance(NMR)and 2D NMR techniques including 1He1H correlation spectroscopy(COSY),1He1H total correlation spectroscopy(TOCSY),1H J-resolved spectroscopy(J-Res),1He13C heteronuclear single quantum coherence spectroscopy(HSQC),and 1He13C heteronuclear multiple bond correlation spectroscopy(HMBC)to assign the 1H and 13C signals of six bile acids in aqueous solution at physiological pH(~7.4)and nine bile acids in methanol.These data are of importance to the NMR-based studies on lipid digestion,absorption,and metabolism.
