The study of small-molecule activation by f-block elements still lags far behind that of transition metals.Although a few uranium complexes have been reported to activate dinitrogen,reports on the activation of heavie...The study of small-molecule activation by f-block elements still lags far behind that of transition metals.Although a few uranium complexes have been reported to activate dinitrogen,reports on the activation of heavier congeners,such as white phosphorus(P_(4)),by uranium species are extremely rare,and no example of uranium-mediated activation of elemental arsenic has appeared.展开更多
基金supported by the National Natural Science Foundation of China(grant nos.21772088 and 91961116)the Fundamental Research Funds for the Central Universities(nos.14380216 and 14380262)Programs for high-level entrepreneurial and innovative talents introduction of Jiangsu Province(individual and group programs).L.M.is a senior member of the Institut Universitaire de France.The Humboldt Foundation and Chinese Academy of Science are acknowledged for financial support。
文摘The study of small-molecule activation by f-block elements still lags far behind that of transition metals.Although a few uranium complexes have been reported to activate dinitrogen,reports on the activation of heavier congeners,such as white phosphorus(P_(4)),by uranium species are extremely rare,and no example of uranium-mediated activation of elemental arsenic has appeared.
