A suit of online self-adapting control （OSAC） approach has been developed to predict and optimize annealing craft system. The approach consists of three critical parts including prediction module, self-adapting opti...A suit of online self-adapting control （OSAC） approach has been developed to predict and optimize annealing craft system. The approach consists of three critical parts including prediction module, self-adapting optimization module, and self-learning amendment module. Firstly, the prediction module and self- adapting optimization module are based on the modeling methods. The self-adapting optimization module consists of two parts including ＂reappearance of annealed process＂ and ＂optimization of subsequent annealing process＂. Secondly, the self-learning amendment module, based on furnace atmosphere, equipment performance, and compensation coefficients, is designed to improve the accuracy of optimization results. The results obtained from the proposed approach, usually finished in about 3 min, are in good agreement with the test values, such as the deviation of temperature for hot-spot and cold-spot are within 10 K, the relative errors are within 1.1%, and the accuracy of annealing for heating period is increased by using self-learning amendment module.展开更多
The mathematic model of heating chamber for implementing the prediction of the annealing craft and improving the self adapting with the expansion of the new annealing furnace form, new annealing crafts and new kinds o...The mathematic model of heating chamber for implementing the prediction of the annealing craft and improving the self adapting with the expansion of the new annealing furnace form, new annealing crafts and new kinds of steel coil has been established. The model developed which including the temperature for gas in heating chamber and the heating cover is based on the characteristics of anneal craft and the situations of locale production run. Firstly, the characteristic of the heating cover which limits the temperature was considered. Secondly, the locale production run condition and dispatching condition were considered. Finally, combining with the models and the simulation system, the numerical simulation research of the anneal process for the high performance hydrogen bell-type annealer as well as the spot experiment test were carried out. The results obtained from the developed models, usually finished less than thirty seconds, are in fair agreement with the test values, such as the relative errors of annealing times were within ±5%, and the quality＇ of the annealed steels were guaranteed.展开更多
High-temperature-annealed Al N(HTA-Al N) templates provide ideal substrates for high-quality Al Ga N epitaxy. However, the significant compressive stress accumulated within the Al Ga N layer makes it challenging to ac...High-temperature-annealed Al N(HTA-Al N) templates provide ideal substrates for high-quality Al Ga N epitaxy. However, the significant compressive stress accumulated within the Al Ga N layer makes it challenging to achieve a smooth surface free of hexagonal hillocks on these templates. To address this issue, we investigate the mechanism of compressive stress accumulation during the growth of Al Ga N-based epilayers on HTA-Al N templates using in-situ curvature analysis in this study. To verify the mechanism, a low-Al-content Al Ga N interlayer is introduced between the Al N epilayer and the subsequent Al Ga N epilayer. The larger a-plane lattice constant of this interlayer relative to the Al Ga N epilayer slows the accumulation rate of compressive stress. The hexagonal hillock can be effectively suppressed and the surface of Al Ga N epilayer can be significantly regulated by adopting various low-Al-content Al Ga N interlayers. This work provides a comprehension on the stress accumulation mechanism in Al Ga N epilayers and a feasible method to obtain hillock-free surface of Al Ga N epilayers on HTA-Al N templates,which will be beneficial for fabricating Al Ga N based devices.展开更多
In this study,multilayer lamination welding was employed to prepare graphene/copper(Gr/Cu)composite billets from graphene-coated copper foils,followed by multi-pass cold drawing to produce Φ1 mm Gr/Cu composite wires...In this study,multilayer lamination welding was employed to prepare graphene/copper(Gr/Cu)composite billets from graphene-coated copper foils,followed by multi-pass cold drawing to produce Φ1 mm Gr/Cu composite wires.Microstructure and property analyses in both the cold-drawn and annealed states show that the incorporation of graphene significantly improves the ductility and electrical conductivity of the copper wire.After annealing at 350℃ for 30 minutes,the composite wire demonstrates a tensile strength of 270 MPa and an electrical conductivity of 102.74%IACS,both superior to those of pure copper wire under identical conditions.At 150℃,the electrical conductivity of the annealed composite wire reaches 72.60%IACS,notably higher than the 68.19%IACS of pure copper.The results suggest that graphene is uniformly distributed within the composite wire,with minimal impact on conductivity,while effectively refining the copper grain structure to enhance ductility.Moreover,graphene suppresses copper lattice vibrations at elevated temperatures,reducing the rate of conductivity degradation.展开更多
Giant magnetoimpedance(GMI)sensors are increasingly employed in modern magnetic sensing technologies.However,improving the GMI performance of magnetic cores remains challenging due to intrinsic limitations in material...Giant magnetoimpedance(GMI)sensors are increasingly employed in modern magnetic sensing technologies.However,improving the GMI performance of magnetic cores remains challenging due to intrinsic limitations in material properties and structural stability.In this work,we explore the use of Joule heating to enhance the GMI response of Fe_(20)Ni_(80)/Cu composite wires.By applying a current of 1.8 A for 10 min,notable improvements in magnetic domain uniformity and a reduction in domain spacing are observed.Under these conditions,GMI ratios reach 1870% in the non-diagonal mode and1147%in the diagonal mode,respectively,highlighting their potential for applications in high-precision weak magnetic field sensing.展开更多
Ambient-air,moisture-assisted annealing is widely used in fabricating perovskite solar cells(PSCs).However,the inherent sensitivity of perovskite intermediate-phase to moisture—due to fast and spontaneous intermolecu...Ambient-air,moisture-assisted annealing is widely used in fabricating perovskite solar cells(PSCs).However,the inherent sensitivity of perovskite intermediate-phase to moisture—due to fast and spontaneous intermolecular exchange reaction—requires strict control of ambient humidity and immediate thermal annealing treatment,raising manufacturing costs and causing fast nucleation of perovskite films.We report herein a self-buffered molecular migration strategy to slow down the intermolecular exchange reaction by introducing a n-butylammonium bromide shielding layer,which limits moisture diffusion into intermediate-phase film.This further endows the notably wide nucleation time and humidity windows for perovskite crystallization in ambient air.Consequently,the optimized 1.68 e V-bandgap n-i-p structured PSC reaches a record-high reverse-scan(RS)PCE of 22.09%.Furthermore,the versatility and applicability of as-proposed self-buffered molecular migration strategy are certified by employing various shielding materials and 1.53 eV-/1.77 eV-bandgap perovskite materials.The n-i-p structured PSCs based on 1.53 eV-and 1.77 eV-bandgap perovskite films achieve outstanding RS PCEs of 25.23%and 19.09%,respectively,both of which are beyond of the state-of-the-art ambient-air processed PSCs.展开更多
To investigate the aging mechanisms and elucidate the correlations between unstable microstructure and performance in biodegradable Zn alloys,the accelerated aging experiment was conducted on a high-performance wrough...To investigate the aging mechanisms and elucidate the correlations between unstable microstructure and performance in biodegradable Zn alloys,the accelerated aging experiment was conducted on a high-performance wrought Zn−0.1Mg alloy by annealing at 200℃ for varying durations.The findings reveal that the tensile strength of the alloy rapidly and significantly declines with prolonged annealing time,decreasing from 383 MPa for the as-received alloy to 102 MPa for the alloy subjected to 1440 min of annealing.The primary factors contributing to this considerable reduction in strength are static recrystallization,grain coarsening,and dislocation annihilation.Initially,the ductility of the alloy shows fluctuations,ultimately experiencing a marked decrease after extended annealing.This decline is linked to the grain growth and heightened texture intensity,while the unusual increase in ductility observed between 30 and 120 min of annealing is likely due to the formation of twins.In addition,due to rapid grain growth and an increase in precipitates and twins,the corrosion resistance of the alloy in Hank’s solution has worsened,with the corrosion rate rising from 0.037 to 0.069 mm/a following 300 min of annealing.展开更多
350 keV He^(+) ions were injected into laser powder bed fusion(LPBF)-processed 304L stainless steel and traditional rolled 304L stainless steel with a flux of 1×10^(17) ions/cm^(2) at room temperature,followed by...350 keV He^(+) ions were injected into laser powder bed fusion(LPBF)-processed 304L stainless steel and traditional rolled 304L stainless steel with a flux of 1×10^(17) ions/cm^(2) at room temperature,followed by annealing at 750℃ for 10,100,and 300 h,respectively.The results showed that material swelling due to helium bubble coarsening was almost not observed in either the LPBF or rolled samples after 10 h of annealing duration.Rapid coarsening and swelling of bubbles occurred in the rolled samples,but only moderate bubble growth occurred in the LPBF sample after annealing for 100 h.After annealing for 300 h,the helium bubbles in both samples tended to grow steadily.For 10 h of annealing,the irradiated samples were in a disequilibrium state,and the apparent activation energy(E^(act))calculated by the Arrhenius model determined that helium atoms tended to diffuse through the displacement mechanism,and helium bubbles grew under the migration and coalescence(MC)mechanism.With annealing times over 100 h,the high-density dislocations and nano-oxide particles in the LPBF sample still had a strong trapping effect on the movement and growth of helium bubbles.After annealing for 300 h,the cellular subgrains in the LPBF sample decomposed,and the nano-oxide particles had no trapping effect on the helium bubbles.At this time,the dislocation structure played a primary role in suppressing the growth of helium bubbles,and the radiation resistance of the LPBF sample remained superior to that of the rolled samples.展开更多
Efficient multiple unmanned aerial vehicles(UAVs)path planning is crucial for improving mission completion efficiency in UAV operations.However,during the actual flight of UAVs,the flight time between nodes is always ...Efficient multiple unmanned aerial vehicles(UAVs)path planning is crucial for improving mission completion efficiency in UAV operations.However,during the actual flight of UAVs,the flight time between nodes is always influenced by external factors,making the original path planning solution ineffective.In this paper,the multi-depot multi-UAV path planning problem with uncertain flight time is modeled as a robust optimization model with a budget uncertainty set.Then,the robust optimization model is transformed into a mixed integer linear programming model by the strong duality theorem,which makes the problem easy to solve.To effectively solve large-scale instances,a simulated annealing algorithm with a robust feasibility check(SA-RFC)is developed.The numerical experiment shows that the SA-RFC can find high-quality solutions within a few seconds.Moreover,the effect of the task location distribution,depot counts,and variations in robustness parameters on the robust optimization solution is analyzed by using Monte Carlo experiments.The results demonstrate that the proposed robust model can effectively reduce the risk of the UAV failing to return to the depot without significantly compromising the profit.展开更多
The interfacial properties of Schottky contacts crucially affect the performance of power devices. While a few studies have explored the impact of fluorine on Schottky contacts, a comprehensive theoretical explanation...The interfacial properties of Schottky contacts crucially affect the performance of power devices. While a few studies have explored the impact of fluorine on Schottky contacts, a comprehensive theoretical explanation supported by experimental evidence remains lacking. This work investigates the effects of fluorine incorporation and electrothermal annealing(ETA) on the current transport process at Ni/β-Ga_(2)O_(3) Schottky contacts. X-ray photoelectron spectroscopy and first-principles calculations confirm the presence of fluorine substitutions for oxygen and oxygen vacancies and their lowering effect on the Schottky barrier heights. Additionally, accurate electrothermal hybrid TCAD simulations validates the extremely short-duration high temperatures(683 K) induced by ETA, which facilitates lattice rearrangement and reduces interface trap states. The interface trap states are quantitatively resolved through frequency-dependent conductance technique, showing the trap density(DT)reduction from(0.88-2.48) × 10^(11) cm^(-2)·eV^(-1) to(0.46-2.09) × 10^(11) cm^(-2)·eV^(-1). This investigation offers critical insights into the β-Ga_(2)O_(3) contacts with the collaborative treatment and solids the promotion of high-performance β-Ga_(2)O_(3) power devices.展开更多
An optimized volt-ampere reactive(VAR)control framework is proposed for transmission-level power systems to simultaneously mitigate voltage deviations and active-power losses through coordinated control of large-scale...An optimized volt-ampere reactive(VAR)control framework is proposed for transmission-level power systems to simultaneously mitigate voltage deviations and active-power losses through coordinated control of large-scale wind/solar farms with shunt static var generators(SVGs).The model explicitly represents reactive-power regulation characteristics of doubly-fed wind turbines and PV inverters under real-time meteorological conditions,and quantifies SVG high-speed compensation capability,enabling seamless transition from localized VAR management to a globally coordinated strategy.An enhanced adaptive gain-sharing knowledge optimizer(AGSK-SD)integrates simulated annealing and diversity maintenance to autonomously tune voltage-control actions,renewable source reactive-power set-points,and SVG output.The algorithm adaptively modulates knowledge factors and ratios across search phases,performs SA-based fine-grained local exploitation,and periodically re-injects population diversity to prevent premature convergence.Comprehensive tests on IEEE 9-bus and 39-bus systems demonstrate AGSK-SD’s superiority over NSGA-II and MOPSO in hypervolume(HV),inverse generative distance(IGD),and spread metrics while maintaining acceptable computational burden.The method reduces network losses from 2.7191 to 2.15 MW(20.79%reduction)and from 15.1891 to 11.22 MW(26.16%reduction)in the 9-bus and 39-bus systems respectively.Simultaneously,the cumulative voltage-deviation index decreases from 0.0277 to 3.42×10^(−4) p.u.(98.77%reduction)in the 9-bus system,and from 0.0556 to 0.0107 p.u.(80.76%reduction)in the 39-bus system.These improvements demonstrate significant suppression of line losses and voltage fluctuations.Comparative analysis with traditional heuristic optimization algorithms confirms the superior performance of the proposed approach.展开更多
Universal quantum computers are far from achieving practical applications.The D-Wave quantum computer is initially designed for combinatorial optimizations.Therefore,exploring the potential applications of the D-Wave ...Universal quantum computers are far from achieving practical applications.The D-Wave quantum computer is initially designed for combinatorial optimizations.Therefore,exploring the potential applications of the D-Wave device in the field of cryptography is of great importance.First,although we optimize the general quantum Hamiltonian on the basis of the structure of the multiplication table(factor up to 1005973),this study attempts to explore the simplification of Hamiltonian derived from the binary structure of the integers to be factored.A simple factorization on 143 with four qubits is provided to verify the potential of further advancing the integer-factoring ability of the D-Wave device.Second,by using the quantum computing cryptography based on the D-Wave 2000 Q system,this research further constructs a simple version of quantum-classical computing architecture and a Quantum-Inspired Simulated Annealing(QISA)framework.Good functions and a high-performance platform are introduced,and additional balanced Boolean functions with high nonlinearity and optimal algebraic immunity can be found.Further comparison between QISA and Quantum Annealing(QA)on six-variable bent functions not only shows the potential speedup of QA,but also suggests the potential of architecture to be a scalable way of D-Wave annealer toward a practical cryptography design.展开更多
As-forged WSTi6421 titanium alloy billet afterβannealing was investigated.Abnormally coarse grains larger than adjacent grains could be observed in the microstructures,forming abnormal grain structures with uneven si...As-forged WSTi6421 titanium alloy billet afterβannealing was investigated.Abnormally coarse grains larger than adjacent grains could be observed in the microstructures,forming abnormal grain structures with uneven size distribution.Through electron backscattered diffraction(EBSD),the forged microstructure at various locations of as-forged WSTi6421 titanium alloy billet was analyzed,revealing that the strength of theβphase cubic texture generated by forging significantly influences the grain size afterβannealing.Heat treatment experiments were conducted within the temperature range from T_(β)−50°C to T_(β)+10°C to observe the macro-and micro-morphologies.Results show that the cubic texture ofβphase caused by forging impacts the texture of the secondaryαphase,which subsequently influences theβphase formed during the post-βannealing process.Moreover,the pinning effect of the residual primaryαphase plays a crucial role in the growth ofβgrains during theβannealing process.EBSD analysis results suggest that the strength ofβphase with cubic texture formed during forging process impacts the orientation distribution differences ofβgrains afterβannealing.Additionally,the development of grains with large orientations within the cubic texture shows a certain degree of selectivity duringβannealing,which is affected by various factors,including the pinning effect of the primaryαphase,the strength of the matrix cubic texture,and the orientation relationship betweenβgrain and matrix.Comprehensively,the stronger the texture in a certain region,the less likely the large misoriented grains suffering secondary growth,thereby aggregating the difference in microstructure and grain orientation distribution across different regions afterβannealing.展开更多
Pore structure engineering has been acknowledged as suitable approach to creating active sites and en-hancing ion transport capabilities of hard carbon anodes.However,conventional porous carbon materials exhibit high ...Pore structure engineering has been acknowledged as suitable approach to creating active sites and en-hancing ion transport capabilities of hard carbon anodes.However,conventional porous carbon materials exhibit high BET and surface defects.Additionally,the sodium storage mechanism predominantly occurs in the slope region.This contradicts practical application requirements because the capacity of the plateau region is crucial for determining the actual capacity of batteries.In our work,we prepared a novel“core-shell”carbon framework(CNA1200).Introducingclosedporesand carboxylgroupsinto coal-basedcarbon materials to enhance its sodium storage performance.The closed pore structure dominates in the“core”structure,which is attributed to the timely removal of sodium hydroxide(NaOH)to prevent further for-mation of active carbon structure.The presence of closed pores is beneficial for increasing sodium ion storage in the low-voltage plateau region.And the“shell”structure originates from coal tar pitch,it not only uniformly connects hard carbon particles together to improve cycling stability,but is also rich in carboxyl groups to enhance the reversible sodium storage performance in slope region.CNA1200 has ex-cellent electrochemical performance,it exhibits a specific capacity of 335.2 mAh g^(−1)at a current density of 20 mA g^(−1)with ICE=51.53%.In addition,CNA1200 has outstanding cycling stability with a capac-ity retention of 91.8%even when cycling over 200 times.When CNA1200 is used as anode paired with Na_(3)V_(2)(PO_(4))_(3)cathode,it demonstrates a capacity of 109.54 mAh g^(−1)at 0.1 C and capacity retention of 94.64%at 0.5 C.This work provides valuable methods for regulating the structure of sodium-ion battery(SIBs)anode and enhances the potential for commercialization.展开更多
Pre-stretching and annealing treatments were conducted on twin roll cast Mg-2Al-1Zn-1Ca(AZX211,in wt.%)plates with a rare earth-like texture.Varying amounts of deformation were applied along the rolling direction(RD)a...Pre-stretching and annealing treatments were conducted on twin roll cast Mg-2Al-1Zn-1Ca(AZX211,in wt.%)plates with a rare earth-like texture.Varying amounts of deformation were applied along the rolling direction(RD)and transverse direction(TD)of AZX211 alloy in order to modify its mechanical proper-ties at room temperature.The results demonstrate that pre-stretching treatment effectively enhances the yield strength(YS),especially along the RD.The strengthening mechanism is attributed to the production of a large number of dislocations and sub-grain boundaries,but the work-hardening ability of the plate will be greatly weakened.Additionally,annealing treatment substantially improves the plasticity and in-plane anisotropy and restores the work-hardening ability.The notable distinction in the pre-stretching process between different directions lies in the underlying deformation mechanism.In case of RD,de-formation is predominantly governed by the slip mechanism of{0002}{11−20}basal slip and{10−10}{11−20}prismatic slip,while along the TD,deformation is primarily controlled by{0002}{11−20}basal slip without significant twinning deformation.When a 6%pre-stretching is conducted,the initial rare earth-like texture of the sample transforms into a symmetrically distributed double-peak basal texture,accompanied by grain refinement.This texture transformation is chiefly due to the dominance of{0002}{11−20}basal slip-driven deformation.Moreover,the annealed sample maintains a strong basal texture,owing to strain-induced recrystallization.展开更多
The effects of drawing strain during intermediate annealing on the microstructure and properties of Cu-20 wt%Fe alloy wires while maintaining constant total deformation were investigated.Intermediate annealing effecti...The effects of drawing strain during intermediate annealing on the microstructure and properties of Cu-20 wt%Fe alloy wires while maintaining constant total deformation were investigated.Intermediate annealing effectively removes work hardening in both the Cu matrix and Fe fibers,restoring their plastic deformation capacity and preserving fiber continuity during subsequent redrawing.The process also refines the Fe phase,leading to a more uniform size distribution and straighter,better-aligned Cu/Fe phase interfaces,thereby enhancing the comprehensive properties of the alloy.The magnitude of drawing strain during intermediate annealing plays a critical role in balancing the mechanical strength and electrical conductivity of redrawn wires.A lower initial drawing strain requires greater redrawing strain,leading to excessive hardening of the Fe fibers,which negatively impacts the electrical conductivity and tensile plasticity.Conversely,a higher initial drawing strain can result in insufficient work hardening during the redrawing deformation process,yielding minimal strength improvements.Among the tested alloys,H/3.5 wires show a slight reduction in strength and hardness compared to W and H/4.5 wires but exhibit a significant increase in tensile elongation and electrical conductivity.The tensile strength was 755 MPa,and the electrical conductivity was 47%international-annealed copper standard(IACS).The optimal performance is attributed to the formation of a high-density,ultrafine Fe fiber structure-aligned parallel to the drawing direction,which is achieved through a suitable combination of the drawing process and intermediate annealing.展开更多
The effect of hot band annealing processes—batch annealing and continuous annealing—on the texture evolution and ridging performance of ferritic stainless steel was investigated.The surface and central layers of the...The effect of hot band annealing processes—batch annealing and continuous annealing—on the texture evolution and ridging performance of ferritic stainless steel was investigated.The surface and central layers of the hot band exhibited strong shear and plane deformation textures,respectively.After batch annealing,the texture intensity of the hot-rolled sheet texture significantly decreased,and a weak recrystallization texture appeared,while fully recrystallized grains occurred after continuous annealing.A complete recrystallized{111}texture was obtained after recrystallization annealing.The sheet subjected to continuous annealing exhibited the highest intensity of{111}texture,which was accompanied by a dispersed grain orientation distribution,resulting in the lowest ridging height.展开更多
Herein,an external crosslinker facilitated the hypercrosslinking of ferrocene and a nitrogen heterocyclic compound(either melamine or imidazole)through a direct Friedel-Crafts reaction,which led to the formation of ni...Herein,an external crosslinker facilitated the hypercrosslinking of ferrocene and a nitrogen heterocyclic compound(either melamine or imidazole)through a direct Friedel-Crafts reaction,which led to the formation of nitrogen-containing hypercrosslinked fer-rocene polymer precursors(HCP-FCs).Subsequent carbonization of these precursors results in the production of iron-nitrogen-doped por-ous carbon absorbers(Fe-NPCs).The Fe-NPCs demonstrate a porous structure comprising aggregated nanotubes and nanospheres.The porosity of this structure can be modulated by adjusting the iron and nitrogen contents to optimize impedance matching.The uniform dis-tribution of Fe-N_(x)C,N dipoles,andα-Fe within the carbon matrix can be ensured by using hypercrosslinked ferrocenes in constructing porous carbon,providing the absorber with numerous polarization sites and a conductive network.The electromagnetic wave absorption performance of the specially designed Fe-NPC-M_(2)absorbers is satisfactory,revealing a minimum reflection loss of-55.3 dB at 2.5 mm and an effective absorption bandwidth of 6.00 GHz at 2.0 mm.By utilizing hypercrosslinked polymers(HCPs)as precursors,a novel method for developing highly efficient carbon-based absorbing agents is introduced in this research.展开更多
For a long time,the large loss of the strength and toughness of fusion welded joints for thick nearβtitanium alloys has largely hindered their engineering application,which results from the few precipitations of the ...For a long time,the large loss of the strength and toughness of fusion welded joints for thick nearβtitanium alloys has largely hindered their engineering application,which results from the few precipitations of the strengtheningαphase during welding cooling.In this study,double annealing treatment was designed for electron beam welded joints of 30-mm-thick nearβTi-5Al-5Mo-5V-1Cr-1Fe alloy,with the aim of regulating the proportion of multi-level lamellar microstructures and enhancing the joint properties.Among various annealing temperatures(first annealing at 750–880 ℃+second annealing at 580 ℃),the 750 ℃+580 ℃ annealed joint exhibited simultaneously enhanced strength and toughness,with the increase in tensile strength and impact energy from 844 MPa and 8.8 J for the as-welded joint to 1129 MPa and 14.5 J for annealed joint,respectively,which were superior to those of the joints of Ti5Al-5Mo-5V-1Cr-1Fe alloy as reported.The great increases in the strength and toughness were mainly attributed to the excellent proportion matching of formed multi-level lamellar microstructures(76.1%of primaryα(αp)lamellae and 7.9%of secondaryα(αs)lamellae),among which theαp phase andαs phase mainly affected the joint toughness and strength,respectively.The good coupling ofαp phase andαs phase improved the precipitation strengthening and the resistance to crack propagation.The modified strengthening mechanism models were proposed by introducing the thickness and proportion parameters of the precipitated phase.It was indicated that the theoretical calculation values were in good agreement with the experimental ones,and the solution strengthening and precipitation strengthening provided a large contribution(a sum of about 75%)to the yield strength of the annealed joints.This study provides a novel method via designing proper multi-level lamellar microstructures to simultaneously improve the strength and toughness of nearβtitanium alloy joints.展开更多
Grain-oriented silicon steels were prepared at different heating rates during high temperature annealing,in which the evolution of magnetic properties,grain orientations and precipitates were studied.To illustrate the...Grain-oriented silicon steels were prepared at different heating rates during high temperature annealing,in which the evolution of magnetic properties,grain orientations and precipitates were studied.To illustrate the Zener factor,the diameter and number density of precipitates of interrupted testing samples were statistically calculated.The effect of precipitate ripening on the Goss texture and magnetic property was investigated.Data indicated that the trend of Zener factor was similar under different heating rates,first increasing and then decreasing,and that the precipitate maturing was greatly inhibited as the heating rate increased.Secondary recrystallization was developed at the temperature of 1010℃when a heating rate of 5℃/h was used,resulting in Goss,Brass and{110}<227>oriented grains growing abnormally and a magnetic induction intensity of 1.90T.Furthermore,increasing the heating rate to 20℃/h would inhibit the development of undesirable oriented grains and obtain a sharp Goss texture.However,when the heating rate was extremely fast,such as 40℃/h,poor secondary recrystallization was developed with many island grains,corresponding to a decrease in magnetic induction intensity to 1.87 T.At a suitable heating rate of 20℃/h,the sharpest Goss texture and the highest magnetic induction of 1.94 T with an onset secondary recrystallization temperature of 1020℃were found among the experimental variables in this study.The heating rate affected the initial temperature of secondary recrystallization by controlling the maturation of precipitates,leading to the deviation and dispersion of Goss texture,thereby reducing the magnetic properties.展开更多
基金Supported by the Specialized Research Project of WuhanIron and Steel Corporation (20050038)
文摘A suit of online self-adapting control （OSAC） approach has been developed to predict and optimize annealing craft system. The approach consists of three critical parts including prediction module, self-adapting optimization module, and self-learning amendment module. Firstly, the prediction module and self- adapting optimization module are based on the modeling methods. The self-adapting optimization module consists of two parts including ＂reappearance of annealed process＂ and ＂optimization of subsequent annealing process＂. Secondly, the self-learning amendment module, based on furnace atmosphere, equipment performance, and compensation coefficients, is designed to improve the accuracy of optimization results. The results obtained from the proposed approach, usually finished in about 3 min, are in good agreement with the test values, such as the deviation of temperature for hot-spot and cold-spot are within 10 K, the relative errors are within 1.1%, and the accuracy of annealing for heating period is increased by using self-learning amendment module.
文摘The mathematic model of heating chamber for implementing the prediction of the annealing craft and improving the self adapting with the expansion of the new annealing furnace form, new annealing crafts and new kinds of steel coil has been established. The model developed which including the temperature for gas in heating chamber and the heating cover is based on the characteristics of anneal craft and the situations of locale production run. Firstly, the characteristic of the heating cover which limits the temperature was considered. Secondly, the locale production run condition and dispatching condition were considered. Finally, combining with the models and the simulation system, the numerical simulation research of the anneal process for the high performance hydrogen bell-type annealer as well as the spot experiment test were carried out. The results obtained from the developed models, usually finished less than thirty seconds, are in fair agreement with the test values, such as the relative errors of annealing times were within ±5%, and the quality＇ of the annealed steels were guaranteed.
基金supported by the National Key R&D Program of China (Grant No. 2022YFB3605000)the National Natural Science Foundation of China (Nos. 62004127, 61725403, 62121005, 61922078, 61827813, and 62004196)+1 种基金the Youth Innovation Promotion Association of Chinese Academy of Sciencesthe Youth Talent Promotion Project of the Chinese Institute of Electronics (No. 2020QNRC001)。
文摘High-temperature-annealed Al N(HTA-Al N) templates provide ideal substrates for high-quality Al Ga N epitaxy. However, the significant compressive stress accumulated within the Al Ga N layer makes it challenging to achieve a smooth surface free of hexagonal hillocks on these templates. To address this issue, we investigate the mechanism of compressive stress accumulation during the growth of Al Ga N-based epilayers on HTA-Al N templates using in-situ curvature analysis in this study. To verify the mechanism, a low-Al-content Al Ga N interlayer is introduced between the Al N epilayer and the subsequent Al Ga N epilayer. The larger a-plane lattice constant of this interlayer relative to the Al Ga N epilayer slows the accumulation rate of compressive stress. The hexagonal hillock can be effectively suppressed and the surface of Al Ga N epilayer can be significantly regulated by adopting various low-Al-content Al Ga N interlayers. This work provides a comprehension on the stress accumulation mechanism in Al Ga N epilayers and a feasible method to obtain hillock-free surface of Al Ga N epilayers on HTA-Al N templates,which will be beneficial for fabricating Al Ga N based devices.
基金Funded by Hunan Provincial Natural Science Foundation(No.2023JJ40074)Hunan Provincial Education Department Excellent Youth Project(No.21B0757)Hunan Provincial Engineering Technology Center(No.2022TP2036)。
文摘In this study,multilayer lamination welding was employed to prepare graphene/copper(Gr/Cu)composite billets from graphene-coated copper foils,followed by multi-pass cold drawing to produce Φ1 mm Gr/Cu composite wires.Microstructure and property analyses in both the cold-drawn and annealed states show that the incorporation of graphene significantly improves the ductility and electrical conductivity of the copper wire.After annealing at 350℃ for 30 minutes,the composite wire demonstrates a tensile strength of 270 MPa and an electrical conductivity of 102.74%IACS,both superior to those of pure copper wire under identical conditions.At 150℃,the electrical conductivity of the annealed composite wire reaches 72.60%IACS,notably higher than the 68.19%IACS of pure copper.The results suggest that graphene is uniformly distributed within the composite wire,with minimal impact on conductivity,while effectively refining the copper grain structure to enhance ductility.Moreover,graphene suppresses copper lattice vibrations at elevated temperatures,reducing the rate of conductivity degradation.
基金supported by the State Key Research and Development Program,Special Gravity Wave(Grant No.2023YFC2206003)the Gansu Provincial Science and Technology Program Funding(Grant No.24JRRA499)+1 种基金the Natural Science Foundation of Shandong Province(Grant No.ZR2024QB219)the Lanzhou City Science and Technology Program Project(Grant No.2025-2-47)。
文摘Giant magnetoimpedance(GMI)sensors are increasingly employed in modern magnetic sensing technologies.However,improving the GMI performance of magnetic cores remains challenging due to intrinsic limitations in material properties and structural stability.In this work,we explore the use of Joule heating to enhance the GMI response of Fe_(20)Ni_(80)/Cu composite wires.By applying a current of 1.8 A for 10 min,notable improvements in magnetic domain uniformity and a reduction in domain spacing are observed.Under these conditions,GMI ratios reach 1870% in the non-diagonal mode and1147%in the diagonal mode,respectively,highlighting their potential for applications in high-precision weak magnetic field sensing.
基金the financial support from the National Key R&D Program of China(2021YFF0500500)the National Natural Science Foundation of China(62474131,62274132,and 62204189)。
文摘Ambient-air,moisture-assisted annealing is widely used in fabricating perovskite solar cells(PSCs).However,the inherent sensitivity of perovskite intermediate-phase to moisture—due to fast and spontaneous intermolecular exchange reaction—requires strict control of ambient humidity and immediate thermal annealing treatment,raising manufacturing costs and causing fast nucleation of perovskite films.We report herein a self-buffered molecular migration strategy to slow down the intermolecular exchange reaction by introducing a n-butylammonium bromide shielding layer,which limits moisture diffusion into intermediate-phase film.This further endows the notably wide nucleation time and humidity windows for perovskite crystallization in ambient air.Consequently,the optimized 1.68 e V-bandgap n-i-p structured PSC reaches a record-high reverse-scan(RS)PCE of 22.09%.Furthermore,the versatility and applicability of as-proposed self-buffered molecular migration strategy are certified by employing various shielding materials and 1.53 eV-/1.77 eV-bandgap perovskite materials.The n-i-p structured PSCs based on 1.53 eV-and 1.77 eV-bandgap perovskite films achieve outstanding RS PCEs of 25.23%and 19.09%,respectively,both of which are beyond of the state-of-the-art ambient-air processed PSCs.
基金supported by the National Natural Science Foundation of China(No.52271101)Suzhou Science and Technology Project,China(Nos.SYG202312,SJC2023005,SZS2023023)+1 种基金Nanjing Major Science and Technology Project,China(No.202309015)the Opening Project of Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology,China(No.ASMA202305)。
文摘To investigate the aging mechanisms and elucidate the correlations between unstable microstructure and performance in biodegradable Zn alloys,the accelerated aging experiment was conducted on a high-performance wrought Zn−0.1Mg alloy by annealing at 200℃ for varying durations.The findings reveal that the tensile strength of the alloy rapidly and significantly declines with prolonged annealing time,decreasing from 383 MPa for the as-received alloy to 102 MPa for the alloy subjected to 1440 min of annealing.The primary factors contributing to this considerable reduction in strength are static recrystallization,grain coarsening,and dislocation annihilation.Initially,the ductility of the alloy shows fluctuations,ultimately experiencing a marked decrease after extended annealing.This decline is linked to the grain growth and heightened texture intensity,while the unusual increase in ductility observed between 30 and 120 min of annealing is likely due to the formation of twins.In addition,due to rapid grain growth and an increase in precipitates and twins,the corrosion resistance of the alloy in Hank’s solution has worsened,with the corrosion rate rising from 0.037 to 0.069 mm/a following 300 min of annealing.
基金supported by the National Natural Science Foundation of China(Nos.U22B2067 and 52073176).
文摘350 keV He^(+) ions were injected into laser powder bed fusion(LPBF)-processed 304L stainless steel and traditional rolled 304L stainless steel with a flux of 1×10^(17) ions/cm^(2) at room temperature,followed by annealing at 750℃ for 10,100,and 300 h,respectively.The results showed that material swelling due to helium bubble coarsening was almost not observed in either the LPBF or rolled samples after 10 h of annealing duration.Rapid coarsening and swelling of bubbles occurred in the rolled samples,but only moderate bubble growth occurred in the LPBF sample after annealing for 100 h.After annealing for 300 h,the helium bubbles in both samples tended to grow steadily.For 10 h of annealing,the irradiated samples were in a disequilibrium state,and the apparent activation energy(E^(act))calculated by the Arrhenius model determined that helium atoms tended to diffuse through the displacement mechanism,and helium bubbles grew under the migration and coalescence(MC)mechanism.With annealing times over 100 h,the high-density dislocations and nano-oxide particles in the LPBF sample still had a strong trapping effect on the movement and growth of helium bubbles.After annealing for 300 h,the cellular subgrains in the LPBF sample decomposed,and the nano-oxide particles had no trapping effect on the helium bubbles.At this time,the dislocation structure played a primary role in suppressing the growth of helium bubbles,and the radiation resistance of the LPBF sample remained superior to that of the rolled samples.
基金supported by the National Natural Science Foundation of China(72571094,72271076,71871079)。
文摘Efficient multiple unmanned aerial vehicles(UAVs)path planning is crucial for improving mission completion efficiency in UAV operations.However,during the actual flight of UAVs,the flight time between nodes is always influenced by external factors,making the original path planning solution ineffective.In this paper,the multi-depot multi-UAV path planning problem with uncertain flight time is modeled as a robust optimization model with a budget uncertainty set.Then,the robust optimization model is transformed into a mixed integer linear programming model by the strong duality theorem,which makes the problem easy to solve.To effectively solve large-scale instances,a simulated annealing algorithm with a robust feasibility check(SA-RFC)is developed.The numerical experiment shows that the SA-RFC can find high-quality solutions within a few seconds.Moreover,the effect of the task location distribution,depot counts,and variations in robustness parameters on the robust optimization solution is analyzed by using Monte Carlo experiments.The results demonstrate that the proposed robust model can effectively reduce the risk of the UAV failing to return to the depot without significantly compromising the profit.
基金supported by the National Natural Science Foundation of China (Grant Nos. 62174019, 52302046, L2424216)the Guangdong Basic and Applied Basic Research Foundation (Grant No. 2024A1515012139)+2 种基金the Major Program (JD) of Hubei Province (Grant No. 2023BAA009)the Knowledge Innovation Program of Wuhan-Shuguang Project (Grant No. 2023010201020262)the Basic Research Program of Jiangsu (Grant No. BK20230268)。
文摘The interfacial properties of Schottky contacts crucially affect the performance of power devices. While a few studies have explored the impact of fluorine on Schottky contacts, a comprehensive theoretical explanation supported by experimental evidence remains lacking. This work investigates the effects of fluorine incorporation and electrothermal annealing(ETA) on the current transport process at Ni/β-Ga_(2)O_(3) Schottky contacts. X-ray photoelectron spectroscopy and first-principles calculations confirm the presence of fluorine substitutions for oxygen and oxygen vacancies and their lowering effect on the Schottky barrier heights. Additionally, accurate electrothermal hybrid TCAD simulations validates the extremely short-duration high temperatures(683 K) induced by ETA, which facilitates lattice rearrangement and reduces interface trap states. The interface trap states are quantitatively resolved through frequency-dependent conductance technique, showing the trap density(DT)reduction from(0.88-2.48) × 10^(11) cm^(-2)·eV^(-1) to(0.46-2.09) × 10^(11) cm^(-2)·eV^(-1). This investigation offers critical insights into the β-Ga_(2)O_(3) contacts with the collaborative treatment and solids the promotion of high-performance β-Ga_(2)O_(3) power devices.
基金supported by Yunnan Power Grid Co.,Ltd.Science and Technology Project:Research and application of key technologies for graphical-based power grid accident reconstruction and simulation(YNKJXM20240333).
文摘An optimized volt-ampere reactive(VAR)control framework is proposed for transmission-level power systems to simultaneously mitigate voltage deviations and active-power losses through coordinated control of large-scale wind/solar farms with shunt static var generators(SVGs).The model explicitly represents reactive-power regulation characteristics of doubly-fed wind turbines and PV inverters under real-time meteorological conditions,and quantifies SVG high-speed compensation capability,enabling seamless transition from localized VAR management to a globally coordinated strategy.An enhanced adaptive gain-sharing knowledge optimizer(AGSK-SD)integrates simulated annealing and diversity maintenance to autonomously tune voltage-control actions,renewable source reactive-power set-points,and SVG output.The algorithm adaptively modulates knowledge factors and ratios across search phases,performs SA-based fine-grained local exploitation,and periodically re-injects population diversity to prevent premature convergence.Comprehensive tests on IEEE 9-bus and 39-bus systems demonstrate AGSK-SD’s superiority over NSGA-II and MOPSO in hypervolume(HV),inverse generative distance(IGD),and spread metrics while maintaining acceptable computational burden.The method reduces network losses from 2.7191 to 2.15 MW(20.79%reduction)and from 15.1891 to 11.22 MW(26.16%reduction)in the 9-bus and 39-bus systems respectively.Simultaneously,the cumulative voltage-deviation index decreases from 0.0277 to 3.42×10^(−4) p.u.(98.77%reduction)in the 9-bus system,and from 0.0556 to 0.0107 p.u.(80.76%reduction)in the 39-bus system.These improvements demonstrate significant suppression of line losses and voltage fluctuations.Comparative analysis with traditional heuristic optimization algorithms confirms the superior performance of the proposed approach.
基金supported by the Special Zone Project of National Defense Innovation,the National Natural Science Foundation of China(Nos.61572304 and 61272096)the Key Program of the National Natural Science Foundation of China(No.61332019)+2 种基金the Shanghai Sailing Plan of“Science and Technology Innovation Action Plan”(No.21YF1415100)Fujian Provincial Natural Science Foundation Project(No.2021J01129)Open Research Fund of State Key Laboratory of Cryptology。
文摘Universal quantum computers are far from achieving practical applications.The D-Wave quantum computer is initially designed for combinatorial optimizations.Therefore,exploring the potential applications of the D-Wave device in the field of cryptography is of great importance.First,although we optimize the general quantum Hamiltonian on the basis of the structure of the multiplication table(factor up to 1005973),this study attempts to explore the simplification of Hamiltonian derived from the binary structure of the integers to be factored.A simple factorization on 143 with four qubits is provided to verify the potential of further advancing the integer-factoring ability of the D-Wave device.Second,by using the quantum computing cryptography based on the D-Wave 2000 Q system,this research further constructs a simple version of quantum-classical computing architecture and a Quantum-Inspired Simulated Annealing(QISA)framework.Good functions and a high-performance platform are introduced,and additional balanced Boolean functions with high nonlinearity and optimal algebraic immunity can be found.Further comparison between QISA and Quantum Annealing(QA)on six-variable bent functions not only shows the potential speedup of QA,but also suggests the potential of architecture to be a scalable way of D-Wave annealer toward a practical cryptography design.
基金Key Research and Development Plan of Shaanxi Province(2023-YBGY-493)。
文摘As-forged WSTi6421 titanium alloy billet afterβannealing was investigated.Abnormally coarse grains larger than adjacent grains could be observed in the microstructures,forming abnormal grain structures with uneven size distribution.Through electron backscattered diffraction(EBSD),the forged microstructure at various locations of as-forged WSTi6421 titanium alloy billet was analyzed,revealing that the strength of theβphase cubic texture generated by forging significantly influences the grain size afterβannealing.Heat treatment experiments were conducted within the temperature range from T_(β)−50°C to T_(β)+10°C to observe the macro-and micro-morphologies.Results show that the cubic texture ofβphase caused by forging impacts the texture of the secondaryαphase,which subsequently influences theβphase formed during the post-βannealing process.Moreover,the pinning effect of the residual primaryαphase plays a crucial role in the growth ofβgrains during theβannealing process.EBSD analysis results suggest that the strength ofβphase with cubic texture formed during forging process impacts the orientation distribution differences ofβgrains afterβannealing.Additionally,the development of grains with large orientations within the cubic texture shows a certain degree of selectivity duringβannealing,which is affected by various factors,including the pinning effect of the primaryαphase,the strength of the matrix cubic texture,and the orientation relationship betweenβgrain and matrix.Comprehensively,the stronger the texture in a certain region,the less likely the large misoriented grains suffering secondary growth,thereby aggregating the difference in microstructure and grain orientation distribution across different regions afterβannealing.
基金the National Natural Science Foundation of China(No.21978164,22078189 and 22105120)the Outstanding Youth Science Fund of Shaanxi Province(No.2021JC-046)and the Special Support Program for high level talents of Shaanxi Province+3 种基金the Innovation Support Program of Shaanxi Province(2021JZY-001)the Key Research and Development Program of Shaanxi Province(No.2020GY-243)the Special Research Fund of Education Department of Shaanxi(No.20JK0535)the National High-end Foreign Expert Project(No.GDW20186100428).
文摘Pore structure engineering has been acknowledged as suitable approach to creating active sites and en-hancing ion transport capabilities of hard carbon anodes.However,conventional porous carbon materials exhibit high BET and surface defects.Additionally,the sodium storage mechanism predominantly occurs in the slope region.This contradicts practical application requirements because the capacity of the plateau region is crucial for determining the actual capacity of batteries.In our work,we prepared a novel“core-shell”carbon framework(CNA1200).Introducingclosedporesand carboxylgroupsinto coal-basedcarbon materials to enhance its sodium storage performance.The closed pore structure dominates in the“core”structure,which is attributed to the timely removal of sodium hydroxide(NaOH)to prevent further for-mation of active carbon structure.The presence of closed pores is beneficial for increasing sodium ion storage in the low-voltage plateau region.And the“shell”structure originates from coal tar pitch,it not only uniformly connects hard carbon particles together to improve cycling stability,but is also rich in carboxyl groups to enhance the reversible sodium storage performance in slope region.CNA1200 has ex-cellent electrochemical performance,it exhibits a specific capacity of 335.2 mAh g^(−1)at a current density of 20 mA g^(−1)with ICE=51.53%.In addition,CNA1200 has outstanding cycling stability with a capac-ity retention of 91.8%even when cycling over 200 times.When CNA1200 is used as anode paired with Na_(3)V_(2)(PO_(4))_(3)cathode,it demonstrates a capacity of 109.54 mAh g^(−1)at 0.1 C and capacity retention of 94.64%at 0.5 C.This work provides valuable methods for regulating the structure of sodium-ion battery(SIBs)anode and enhances the potential for commercialization.
基金supported by the National Natural Science Foundation of China(No.52001106)Hebei province(No.E2022202158).
文摘Pre-stretching and annealing treatments were conducted on twin roll cast Mg-2Al-1Zn-1Ca(AZX211,in wt.%)plates with a rare earth-like texture.Varying amounts of deformation were applied along the rolling direction(RD)and transverse direction(TD)of AZX211 alloy in order to modify its mechanical proper-ties at room temperature.The results demonstrate that pre-stretching treatment effectively enhances the yield strength(YS),especially along the RD.The strengthening mechanism is attributed to the production of a large number of dislocations and sub-grain boundaries,but the work-hardening ability of the plate will be greatly weakened.Additionally,annealing treatment substantially improves the plasticity and in-plane anisotropy and restores the work-hardening ability.The notable distinction in the pre-stretching process between different directions lies in the underlying deformation mechanism.In case of RD,de-formation is predominantly governed by the slip mechanism of{0002}{11−20}basal slip and{10−10}{11−20}prismatic slip,while along the TD,deformation is primarily controlled by{0002}{11−20}basal slip without significant twinning deformation.When a 6%pre-stretching is conducted,the initial rare earth-like texture of the sample transforms into a symmetrically distributed double-peak basal texture,accompanied by grain refinement.This texture transformation is chiefly due to the dominance of{0002}{11−20}basal slip-driven deformation.Moreover,the annealed sample maintains a strong basal texture,owing to strain-induced recrystallization.
基金support provided by the National Natural Science Foundation of China(Nos.52405364,and 52171110)the Jiangsu Funding Program for Excellent Postdoctoral Talent.W.Huo acknowledges the support from the European Union Horizon 2020 Research and Innovation Program(No.857470)+1 种基金from the European Regional Development Fund via the Foundation for Polish Science International Research Agenda PLUS Program(No.MAB PLUS/2018/8)The publication was partly created within the framework of the project of the Minister of Science and Higher Education"Support for the activities of Centers of Excellence established in Poland under Horizon 2020"(No.MEiN/2023/DIR/3795).
文摘The effects of drawing strain during intermediate annealing on the microstructure and properties of Cu-20 wt%Fe alloy wires while maintaining constant total deformation were investigated.Intermediate annealing effectively removes work hardening in both the Cu matrix and Fe fibers,restoring their plastic deformation capacity and preserving fiber continuity during subsequent redrawing.The process also refines the Fe phase,leading to a more uniform size distribution and straighter,better-aligned Cu/Fe phase interfaces,thereby enhancing the comprehensive properties of the alloy.The magnitude of drawing strain during intermediate annealing plays a critical role in balancing the mechanical strength and electrical conductivity of redrawn wires.A lower initial drawing strain requires greater redrawing strain,leading to excessive hardening of the Fe fibers,which negatively impacts the electrical conductivity and tensile plasticity.Conversely,a higher initial drawing strain can result in insufficient work hardening during the redrawing deformation process,yielding minimal strength improvements.Among the tested alloys,H/3.5 wires show a slight reduction in strength and hardness compared to W and H/4.5 wires but exhibit a significant increase in tensile elongation and electrical conductivity.The tensile strength was 755 MPa,and the electrical conductivity was 47%international-annealed copper standard(IACS).The optimal performance is attributed to the formation of a high-density,ultrafine Fe fiber structure-aligned parallel to the drawing direction,which is achieved through a suitable combination of the drawing process and intermediate annealing.
文摘The effect of hot band annealing processes—batch annealing and continuous annealing—on the texture evolution and ridging performance of ferritic stainless steel was investigated.The surface and central layers of the hot band exhibited strong shear and plane deformation textures,respectively.After batch annealing,the texture intensity of the hot-rolled sheet texture significantly decreased,and a weak recrystallization texture appeared,while fully recrystallized grains occurred after continuous annealing.A complete recrystallized{111}texture was obtained after recrystallization annealing.The sheet subjected to continuous annealing exhibited the highest intensity of{111}texture,which was accompanied by a dispersed grain orientation distribution,resulting in the lowest ridging height.
基金supported by the National Natural Science Foundation of China(No.51803041)the University and Local Integration Development Project of Yantai,China(No.2022 XDRHXMXK08).
文摘Herein,an external crosslinker facilitated the hypercrosslinking of ferrocene and a nitrogen heterocyclic compound(either melamine or imidazole)through a direct Friedel-Crafts reaction,which led to the formation of nitrogen-containing hypercrosslinked fer-rocene polymer precursors(HCP-FCs).Subsequent carbonization of these precursors results in the production of iron-nitrogen-doped por-ous carbon absorbers(Fe-NPCs).The Fe-NPCs demonstrate a porous structure comprising aggregated nanotubes and nanospheres.The porosity of this structure can be modulated by adjusting the iron and nitrogen contents to optimize impedance matching.The uniform dis-tribution of Fe-N_(x)C,N dipoles,andα-Fe within the carbon matrix can be ensured by using hypercrosslinked ferrocenes in constructing porous carbon,providing the absorber with numerous polarization sites and a conductive network.The electromagnetic wave absorption performance of the specially designed Fe-NPC-M_(2)absorbers is satisfactory,revealing a minimum reflection loss of-55.3 dB at 2.5 mm and an effective absorption bandwidth of 6.00 GHz at 2.0 mm.By utilizing hypercrosslinked polymers(HCPs)as precursors,a novel method for developing highly efficient carbon-based absorbing agents is introduced in this research.
基金supported by the National Key Re-search and Development Program of China(No.2023YFC2810700)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2021193)+2 种基金Liaoning Province Excellent Youth Foundation(No.2024JH3/10200021)the Liaoning Revital-ization Talents Program(No.XLYC2403094)the Scientific In-strument Developing Project of the Chinese Academy of Sciences(No.PTYQ2024YZ0009).
文摘For a long time,the large loss of the strength and toughness of fusion welded joints for thick nearβtitanium alloys has largely hindered their engineering application,which results from the few precipitations of the strengtheningαphase during welding cooling.In this study,double annealing treatment was designed for electron beam welded joints of 30-mm-thick nearβTi-5Al-5Mo-5V-1Cr-1Fe alloy,with the aim of regulating the proportion of multi-level lamellar microstructures and enhancing the joint properties.Among various annealing temperatures(first annealing at 750–880 ℃+second annealing at 580 ℃),the 750 ℃+580 ℃ annealed joint exhibited simultaneously enhanced strength and toughness,with the increase in tensile strength and impact energy from 844 MPa and 8.8 J for the as-welded joint to 1129 MPa and 14.5 J for annealed joint,respectively,which were superior to those of the joints of Ti5Al-5Mo-5V-1Cr-1Fe alloy as reported.The great increases in the strength and toughness were mainly attributed to the excellent proportion matching of formed multi-level lamellar microstructures(76.1%of primaryα(αp)lamellae and 7.9%of secondaryα(αs)lamellae),among which theαp phase andαs phase mainly affected the joint toughness and strength,respectively.The good coupling ofαp phase andαs phase improved the precipitation strengthening and the resistance to crack propagation.The modified strengthening mechanism models were proposed by introducing the thickness and proportion parameters of the precipitated phase.It was indicated that the theoretical calculation values were in good agreement with the experimental ones,and the solution strengthening and precipitation strengthening provided a large contribution(a sum of about 75%)to the yield strength of the annealed joints.This study provides a novel method via designing proper multi-level lamellar microstructures to simultaneously improve the strength and toughness of nearβtitanium alloy joints.
文摘Grain-oriented silicon steels were prepared at different heating rates during high temperature annealing,in which the evolution of magnetic properties,grain orientations and precipitates were studied.To illustrate the Zener factor,the diameter and number density of precipitates of interrupted testing samples were statistically calculated.The effect of precipitate ripening on the Goss texture and magnetic property was investigated.Data indicated that the trend of Zener factor was similar under different heating rates,first increasing and then decreasing,and that the precipitate maturing was greatly inhibited as the heating rate increased.Secondary recrystallization was developed at the temperature of 1010℃when a heating rate of 5℃/h was used,resulting in Goss,Brass and{110}<227>oriented grains growing abnormally and a magnetic induction intensity of 1.90T.Furthermore,increasing the heating rate to 20℃/h would inhibit the development of undesirable oriented grains and obtain a sharp Goss texture.However,when the heating rate was extremely fast,such as 40℃/h,poor secondary recrystallization was developed with many island grains,corresponding to a decrease in magnetic induction intensity to 1.87 T.At a suitable heating rate of 20℃/h,the sharpest Goss texture and the highest magnetic induction of 1.94 T with an onset secondary recrystallization temperature of 1020℃were found among the experimental variables in this study.The heating rate affected the initial temperature of secondary recrystallization by controlling the maturation of precipitates,leading to the deviation and dispersion of Goss texture,thereby reducing the magnetic properties.
