Given that a large amount of crude oil remains on the surface of rocks and is difficult to produce after conventional waterflooding,a new superwetting oil displacement system incorporating the synergy between a hydrox...Given that a large amount of crude oil remains on the surface of rocks and is difficult to produce after conventional waterflooding,a new superwetting oil displacement system incorporating the synergy between a hydroxyl anion compound(1OH-1C)and an extended surfactant(S-C_(13)PO_(13)S)was designed.The interfacial tension,contact angle and emulsification performance of the system were measured.The oil displacement effects and improved oil recovery(IOR)mechanisms of 1OH-1C,S-C_(13)PO_(13)S and their compound system were investigated by microscopic visualization oil displacement experiments and core displacement experiments.The results show that 1OH-1C creates a superwetting interface and electrostatic separation pressure on the solid surface,which destroys the strong interactions between crude oil and quartz to peel off the oil film.S-C_(13)PO_(13)S has low interfacial tension,which can promote the flow of remaining oil and emulsify it into oil-in-water emulsions.The compound system of 1OH-1C and S-C_(13)PO_(13)S has both superwettability and low IFT,which can effectively improve oil recovery through a synergistic effect.The oil displacement experiment of low-permeability natural core shows that the compound solution can increase the oil recovery by 16.4 percentage points after waterflooding.This new high-efficiency system is promising for greatly improving oil recovery in low-permeability reservoirs.展开更多
A series of CoS_(2-x)Se_(x)(x=0.05,0.1,0.2,0.3,and 2)composite catalysts were synthesized on carbon fiber paper via the hydrothermal method with Se doping.By precisely controlling the reaction temperature and Se dopin...A series of CoS_(2-x)Se_(x)(x=0.05,0.1,0.2,0.3,and 2)composite catalysts were synthesized on carbon fiber paper via the hydrothermal method with Se doping.By precisely controlling the reaction temperature and Se doping level,a hollow spherical catalyst structure composed of CoSSe was successfully synthesized,which exhibited exceptional activity for hydrogen evolution in acidic solutions.The influences of Se doping on the microstructure and catalytic mechanism of hydrogen evolution reaction(HER)of these composites were systematically investigated.The experimental results reveal that the hollow spherical sample displays an overpotential value of 143 mV along with a Tafel slope value of 69.8 mV·dec^(-1)at a current density of 10 mA·cm^(-2)in an acid aqueous solution.Furthermore,it demonstrates remarkable cycling stability after undergoing 3000 cycles.The comprehensive analysis indicates that Se doping optimizes the electronic structure and enhances conductivity,meanwhile the unique hollow spherical architecture increases active sites for HER and significantly improves overall electrocatalytic performance.展开更多
B and N mixed anions co-doped titania with various crystal phases such as anatase,brookite,and rutile were successfully synthesized by a hydrothermal synthesis followed by heat treatment in an ammonia gas atmosphere a...B and N mixed anions co-doped titania with various crystal phases such as anatase,brookite,and rutile were successfully synthesized by a hydrothermal synthesis followed by heat treatment in an ammonia gas atmosphere at 550-650℃(denoted as BN-Ana_x,BN-Bro_x,and BN-Rut_x,x is the treatment temperature).The colors of as-prepared BN-Ana,BN-Bro,and BN-Rut are red,yellow-green,and cyangreen,respectively.The color changing mechanism of titania was related to their various band gap structure and the existence of B-N bonding.The nitridation temperature exhibits effective color changing compared to that of nitridation time.The different phases of the mixed anion codoped titania possess different photocatalytic deNO_(x) activity.The BN-Ana and BN-Rut show poor photocatalytic deNO_(x) activity,while the BN-Bro shows excellent photocatalytic deNO_(x) activity,better than that of standard titania photocatalyst Degussa P25.The colorful titania with low-photocatalytic activity is heavy metal elements free,indicating their possible applications as nontoxic color pigments or novel cosmetic raw materials.展开更多
Hybrid materials constructed from a visible-light-absorbing semiconductor and a functional metal complex have attracted attention as efficient photocatalysts for CO_(2) reduction with high selectivity to a desired pro...Hybrid materials constructed from a visible-light-absorbing semiconductor and a functional metal complex have attracted attention as efficient photocatalysts for CO_(2) reduction with high selectivity to a desired product.In this work,defect fluorite-type Ln-Ta oxynitrides LnTaO_(x)N_(y)(Ln=Nd,Sm,Gd,Tb,Dy and Ho)were examined as the semiconductor component in a hybrid photocatalyst system combined with known Ag nanoparticle promoter and binuclear ruthenium(Ⅱ)complex(RuRu’).Among the LnTaO_(x)N_(y) examined,TbTaO_(x)N_(y) gave the highest performance for CO_(2) reduction under visible light(k>400 nm),with a Ru Ru0-based turnover number of 18 and high selectivity to formate(>99%).Physicochemical analyses indicated that high crystallinity and more negative conduction band potential of Ln Ta O_(x)N_(y)with the absence of Ln-4 f states in the band gap structure contributed to higher activity of the hybrid photocatalyst.展开更多
基金Supported by the National Key R&D Program of China(2019YFA0708700,2023YFF0614100)CNPC Major Science and Technology Project(2021ZZ01,2023ZZ04).
文摘Given that a large amount of crude oil remains on the surface of rocks and is difficult to produce after conventional waterflooding,a new superwetting oil displacement system incorporating the synergy between a hydroxyl anion compound(1OH-1C)and an extended surfactant(S-C_(13)PO_(13)S)was designed.The interfacial tension,contact angle and emulsification performance of the system were measured.The oil displacement effects and improved oil recovery(IOR)mechanisms of 1OH-1C,S-C_(13)PO_(13)S and their compound system were investigated by microscopic visualization oil displacement experiments and core displacement experiments.The results show that 1OH-1C creates a superwetting interface and electrostatic separation pressure on the solid surface,which destroys the strong interactions between crude oil and quartz to peel off the oil film.S-C_(13)PO_(13)S has low interfacial tension,which can promote the flow of remaining oil and emulsify it into oil-in-water emulsions.The compound system of 1OH-1C and S-C_(13)PO_(13)S has both superwettability and low IFT,which can effectively improve oil recovery through a synergistic effect.The oil displacement experiment of low-permeability natural core shows that the compound solution can increase the oil recovery by 16.4 percentage points after waterflooding.This new high-efficiency system is promising for greatly improving oil recovery in low-permeability reservoirs.
基金Funded by the Breeding Project of Anhui Polytechnic University(No.2019YQQ027)the Scientific Research Foundation of Anhui Polytechnic University(No.xjky2022016)+1 种基金the Open Research Found of Anhui Key Laboratory of High-performance Non-ferrous Metal Materials(No.YSJS-2023-07)the Innovative Entrepreneurship Training Program for College Students in Anhui Province(No.S202210363391)。
文摘A series of CoS_(2-x)Se_(x)(x=0.05,0.1,0.2,0.3,and 2)composite catalysts were synthesized on carbon fiber paper via the hydrothermal method with Se doping.By precisely controlling the reaction temperature and Se doping level,a hollow spherical catalyst structure composed of CoSSe was successfully synthesized,which exhibited exceptional activity for hydrogen evolution in acidic solutions.The influences of Se doping on the microstructure and catalytic mechanism of hydrogen evolution reaction(HER)of these composites were systematically investigated.The experimental results reveal that the hollow spherical sample displays an overpotential value of 143 mV along with a Tafel slope value of 69.8 mV·dec^(-1)at a current density of 10 mA·cm^(-2)in an acid aqueous solution.Furthermore,it demonstrates remarkable cycling stability after undergoing 3000 cycles.The comprehensive analysis indicates that Se doping optimizes the electronic structure and enhances conductivity,meanwhile the unique hollow spherical architecture increases active sites for HER and significantly improves overall electrocatalytic performance.
基金supported by the KOSéCosmetology Research Foundationthe Japan Society funded the present work for the Promotion of Science (JSPS)Grant-in-Aid for Scientific Research (Nos.16H06439 and 20H00297)。
文摘B and N mixed anions co-doped titania with various crystal phases such as anatase,brookite,and rutile were successfully synthesized by a hydrothermal synthesis followed by heat treatment in an ammonia gas atmosphere at 550-650℃(denoted as BN-Ana_x,BN-Bro_x,and BN-Rut_x,x is the treatment temperature).The colors of as-prepared BN-Ana,BN-Bro,and BN-Rut are red,yellow-green,and cyangreen,respectively.The color changing mechanism of titania was related to their various band gap structure and the existence of B-N bonding.The nitridation temperature exhibits effective color changing compared to that of nitridation time.The different phases of the mixed anion codoped titania possess different photocatalytic deNO_(x) activity.The BN-Ana and BN-Rut show poor photocatalytic deNO_(x) activity,while the BN-Bro shows excellent photocatalytic deNO_(x) activity,better than that of standard titania photocatalyst Degussa P25.The colorful titania with low-photocatalytic activity is heavy metal elements free,indicating their possible applications as nontoxic color pigments or novel cosmetic raw materials.
基金supported by a Grant-in-Aid for Scientific Research on Innovative Area “Mixed Anion(Projects JP16K21724 and JP16H06441)”from the Japan Society for the Promotion of Science(JSPS)a CREST program(Project JPMJCR13L1)from the Japan Science and Technology Agency(JST)a JSPS Fellowship for Young Scientists(Project JP17J06914)。
文摘Hybrid materials constructed from a visible-light-absorbing semiconductor and a functional metal complex have attracted attention as efficient photocatalysts for CO_(2) reduction with high selectivity to a desired product.In this work,defect fluorite-type Ln-Ta oxynitrides LnTaO_(x)N_(y)(Ln=Nd,Sm,Gd,Tb,Dy and Ho)were examined as the semiconductor component in a hybrid photocatalyst system combined with known Ag nanoparticle promoter and binuclear ruthenium(Ⅱ)complex(RuRu’).Among the LnTaO_(x)N_(y) examined,TbTaO_(x)N_(y) gave the highest performance for CO_(2) reduction under visible light(k>400 nm),with a Ru Ru0-based turnover number of 18 and high selectivity to formate(>99%).Physicochemical analyses indicated that high crystallinity and more negative conduction band potential of Ln Ta O_(x)N_(y)with the absence of Ln-4 f states in the band gap structure contributed to higher activity of the hybrid photocatalyst.
