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Digitally-Assisted Analog Self-Interference Cancellation for STAR System
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作者 Pan Wensheng Shi Chengzhe +2 位作者 Li Tong Shen Ying Shao Shihai 《China Communications》 2025年第3期36-53,共18页
To enable simultaneous transmit and receive(STAR)on the same frequency in a densely deployed space with multi-interference sources,this work proposes a digitally-assisted analog selfinterference cancellation method,wh... To enable simultaneous transmit and receive(STAR)on the same frequency in a densely deployed space with multi-interference sources,this work proposes a digitally-assisted analog selfinterference cancellation method,which can acquire reference signals through flexible wired/wireless switching access.Based on this method,the Minimum Mean Square Error algorithm with known channel state information is derived in detail,determining the upper limit of the cancellation performance,and the Adaptive Dithered Linear Search algorithm for real-time engineering cancellation is given.The correctness of theoretical analysis is verified by the practical self-interference channel measured by a vector network analyzer.Furthermore,we have designed and implemented the corresponding multiinterference cancellation prototype with the digitallyassisted structure,capable of handling multiple interferences(up to three)and supporting a large receive bandwidth of 100 MHz as well as a wide frequency coverage from 30 MHz to 3000 MHz.Prototype test results demonstrate that in the presence of three interferences,when the single interference bandwidth is 0.2/2/20 MHz(corresponding to the receive bandwidth of 2/20/100 MHz),the cancellation performance can reach 46/32/22 dB or more. 展开更多
关键词 analog self-interference cancellation channel measurement digitally-assisted multiinterference prototype design simultaneous transmit and receive
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Immune Recognition Method Based on Analogy Reasoning in Intrusion Detection System 被引量:1
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作者 ZHANG Changyou CAO Yuanda +2 位作者 YANG Minghua YU Jiong ZHU Dongfeng 《Wuhan University Journal of Natural Sciences》 CAS 2006年第6期1839-1843,共5页
In this paper, we propose an analogy based immune recognition method that focuses on the implement of the clone selection process and the negative selection process by means of analogy similarity. This method is appli... In this paper, we propose an analogy based immune recognition method that focuses on the implement of the clone selection process and the negative selection process by means of analogy similarity. This method is applied in an IDS (Intrusion Detection System) following several steps. Firstly, the initial abnormal behaviours sample set is optimized through the combining of the AIS (Artificial Immune System) and the genetic algorithm. Then, the abnormity probability algorithm is raised considering the two sides of abnormality and normality. Finally, an intrusion detection system model is established based on the above algorithms and models. 展开更多
关键词 immune recognition analogy reasoning SIMILARITY genetic algorithm intrusion detection system
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Energy-Efficient Large-Scale Antenna Systems with Hybrid Digital-Analog Beamforming Structure 被引量:1
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作者 Shuangfeng Han Chih-Lin I +2 位作者 Zhikun Xu Qi Sun Haibin Li 《ZTE Communications》 2015年第1期28-34,共7页
A largescale antenna system (LSAS) with digital beamforming is expected to significantly increase energy efficiency (EE) and spectral efficiency (SE) in a wireless communication system. However, there are many c... A largescale antenna system (LSAS) with digital beamforming is expected to significantly increase energy efficiency (EE) and spectral efficiency (SE) in a wireless communication system. However, there are many challenging issues related to calibration, energy consumption, and cost in implementing a digital beamforming structure in an LSAS. In a practical LSAS deployment, hybrid digitalanalog beamforming structures with active antennas can be used. In this paper, we investigate the optimal antenna configuration in an N &#215; M beamforming structure, where N is the number of transceivers, M is the number of active antennas per transceiver, where analog beamforming is introduced for individual transceivers and digital beamforming is introduced across all N transceivers. We analyze the green point, which is the point of maximum EE on the EESE curve, and show that the logscale EE scales linearly with SE along a slope of lg2/N. We investigate the effect of M on EE for a given SE value in the case of fixed NM and independent N and M. In both cases, there is a unique optimal M that results in optimal EE. In the case of independent N and M, there is no optimal (N, M) combination for optimizing EE. The results of numerical simulations are provided, and these results support our analysis. 展开更多
关键词 digital beamfornling analog beamforming hybrid beamlorming energy efficiency spectral efficiency
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Geological Analogy Expert System of Oil-Generating Depressions
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作者 Ye Jiaren Lu Mingde Wang FeiqiaoChina University of Geosciences , Wuhan 430074 《Journal of Earth Science》 SCIE CAS CSCD 1993年第1期94-99,共6页
The geologic analogy expert system of oil-generating depressions (GAESOD) constructed on IBM 386 by using GCLISP language is a tool-type expert system for geologic analogy .GAESOD consists of eight parts: (1) illustra... The geologic analogy expert system of oil-generating depressions (GAESOD) constructed on IBM 386 by using GCLISP language is a tool-type expert system for geologic analogy .GAESOD consists of eight parts: (1) illustrating module of system; (2) general controlling module; (3) knowledge base; (4 (reasoning module; (5 )data base; (6)explanation module; (7)gaining and managing module of knowledge; (8) managing module of data base .There are 36 known models of oil-generating depressions of the eastern part and the continental shelf of China in the knowledge base .Three values,such as resemblance coefficient ,certainty factor and fine-poor coefficient ,will be acquired if this system is applied to any two on-generating depressions .Finally,GAESOD are applied to the analysis of some data from Xichang depression ,Hepu basin and the conclusions from this system are consistent with the results from geologic experts. 展开更多
关键词 geologic analogy expert system knowledge oil-generating depressions .reasoning .
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Signal modulating noise effect in bistable stochastic resonance systems and its analog simulation
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作者 肖方红 闫桂荣 谢世成 《Journal of Central South University of Technology》 EI 2006年第5期595-597,共3页
The effect of signal modulating noise in bistable stochastic resonance systems was studied theoretically and experimentally. A mathematical analysis was made on the bistable stochastic resonance model with small syste... The effect of signal modulating noise in bistable stochastic resonance systems was studied theoretically and experimentally. A mathematical analysis was made on the bistable stochastic resonance model with small system parameters. An analogue circuit was designed to perform the effect. The effect of signal modulating noise was shown in the analog simulation experiment. The analog experiment was conducted for two sinusoidal signals with different frequencies. The results show that there are a sinusoidal component corresponding to the input sinusoidal signal and a noise component presented as a Wiener process corresponding to the input white noise in the system output. By properly selecting system parameters, the effect of signal modulating noise can be manifested in the system output. 展开更多
关键词 signal modulating noise effect bistable system stochastic resonance analog simulation
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The Continuous Analogy of Newton’s Method for Solving a System of Linear Algebraic Equations
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作者 Tugal Zhanlav Ochbadrakh Chuluunbaatar Gantumur Ankhbayar 《Applied Mathematics》 2013年第1期210-216,共7页
We propose a continuous analogy of Newton’s method with inner iteration for solving a system of linear algebraic equations. Implementation of inner iterations is carried out in two ways. The former is to fix the numb... We propose a continuous analogy of Newton’s method with inner iteration for solving a system of linear algebraic equations. Implementation of inner iterations is carried out in two ways. The former is to fix the number of inner iterations in advance. The latter is to use the inexact Newton method for solution of the linear system of equations that arises at each stage of outer iterations. We give some new choices of iteration parameter and of forcing term, that ensure the convergence of iterations. The performance and efficiency of the proposed iteration is illustrated by numerical examples that represent a wide range of typical systems. 展开更多
关键词 CONTINUOUS analogY of Newton’s Method SOLVING the system of Linear ALGEBRAIC Equations Convergence CHOICE of ITERATION Parameter
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Root Analogous Solid Waste Management System (RA-MSW for Biocells)
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作者 Ahmad Qasaimeh 《Journal of Environmental Protection》 2012年第8期760-766,共7页
Root Analogous Municipal Solid Waste System “RA-MSW” is a novel management system that manages waste, biogas, and leachate in bioreactor landfill. Different than conventional disposal at landfills, waste is penetrat... Root Analogous Municipal Solid Waste System “RA-MSW” is a novel management system that manages waste, biogas, and leachate in bioreactor landfill. Different than conventional disposal at landfills, waste is penetrated by synthetic roots that serve dual mission for biogas collection and leachate recirculation. RA-MSW roots are permeable hydropho- bic polymer material that are formed on-place or prefabricated at factory from recyclable material available on the dumping area. Since the material is hydrophobic, it does not contain water in the voids providing more space for gas transport and collection. The roots are also interchangeably used for leachate recirculation where the parameters of wa- ter content, nutrients, pH, and temperature are optimized to enhance biogas production simultaneously with leachate treatment. RA-MSW provides new approach of waste management and control;it has new virtues of landfill operation;new material medium for biogas collection;new biocell design configuration;new manipulation for leachate and biogas. The approach adds new merits for solid waste management, bio-energy utilization, and the concept of 5 R’s cycle for MSW management. 展开更多
关键词 ROOT analogY RA Municipal Solid Waste Management Biogas LEACHATE Biocell 5 R’s Cycle
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The Analogy between the Immune System and Human Life
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作者 Gassem Gohal 《Open Journal of Immunology》 2024年第3期47-59,共13页
The immune system operates as a complex organization with distinct roles and functions. Excitingly we recognized the similarities between the cellular dynamics of the immune system and our lives, activities, and behav... The immune system operates as a complex organization with distinct roles and functions. Excitingly we recognized the similarities between the cellular dynamics of the immune system and our lives, activities, and behaviors. Observing the immune system can guide how to respond to various daily situations, including when to react, tolerate, or ignore. Recognizing this analogy between our lives and the immune system should motivate us to adopt a wisdom-based approach when investigating the mechanisms and future discoveries related to this system and to deepen our understanding of this complex system with newfound respect. In this context, the present review examines several integral biological processes of the immune system by drawing parallels between them and human life, activities, and behaviors to learn how we must behave based on the insights offered by this complex organization. The literature search was conducted in international databases such as PubMed/MEDLINE and Google Scholar search engine using English equivalent keywords from 1998 up to April 2023. The search strategy used the following subject heading terms: Immune system, analogy, human life, cellular dynamics, memory, tolerance, and ignorance. In conclusion, the immune system is a complex organization comprising various cells interacting within specific sites and networks, communicating, drawing experiences, and learning how to tolerate certain conditions that make it share certain similarities with human life. 展开更多
关键词 Immune system analogY MEMORY TOLERANCE IGNORANCE
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Reconfigurable Ultrasonic Testing System Development Using Programmable Analog Front-End and Reconfigurable System-on-Chip Hardware
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作者 Pramod Govindan Vidya Vasudevan +1 位作者 Thomas Gonnot Jafar Saniie 《Circuits and Systems》 2015年第7期161-171,共11页
Ultrasonic testing systems have been extensively used in medical imaging and non-destructive testing applications. Generally, these systems aim at a particular application or target material. To make these systems por... Ultrasonic testing systems have been extensively used in medical imaging and non-destructive testing applications. Generally, these systems aim at a particular application or target material. To make these systems portable and more adaptable to the test environments, this study presents a reconfigurable ultrasonic testing system (RUTS), which possesses dynamic reconfiguration capabilities. RUTS consists a fully programmable Analog Front-End (AFE), which facilitates beamforming and signal conditioning for variety of applications. RUTS AFE supports up to 8 transducers for phased-array implementation. Xilinx Zynq System-on-Chip (SoC) based Zedboard provides the back-end processing of RUTS. The powerful ARM embedded processor available within Zynq SoC manages the ultrasonic data acquisition/processing and overall system control, which makes RUTS a unique platform for the ultrasonic researchers to experiment and evaluate a wide range of real-time ultrasonic signal processing applications. This Linux-based system is utilized for ultra-sonic data compression implementation providing a versatile environment for further development of ultrasonic imaging and testing system. Furthermore, this study demonstrates the capabilities of RUTS by performing ultrasonic data acquisition and data compression in real-time. Thus, this reconfigurable system enables ultrasonic designers and researchers to efficiently prototype different experiments and to incorporate and analyze high performance ultrasonic signal and image processing algorithms. 展开更多
关键词 Dynamic RECONFIGURATION system-ON-CHIP analog FRONT-END Ultrasonic Imaging
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Application of Legal Texts in the Migration from Analog to Digital Television in the Republic of Guinea
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作者 M’mahawa Bangoura Alsény Bangoura Mamadou Sanoussi Camara 《Journal of Energy and Power Engineering》 2025年第2期54-58,共5页
The application of legal texts in the context of digital television is a process that relies on several normative instruments,ranging from international treaties,such as those of the ITU(International Telecommunicatio... The application of legal texts in the context of digital television is a process that relies on several normative instruments,ranging from international treaties,such as those of the ITU(International Telecommunications Union),to national regulations defining the obligations of audiovisual operators and the modalities of consumer support.Many countries have introduced specific laws and regulations to organize the gradual switch-off of analog broadcasting and encourage the adoption of new digital standards.Consequently,the digitization of Guinea’s broadcasting network cannot be carried out without taking into account the legal framework:allocation of resources and broadcasting players.Analog and digital broadcasting,according to regulatory texts,shows the relationships between the different communication management structures.As for digital broadcasting,we note the appearance of a new service,multiplex. 展开更多
关键词 APPLICATION TEXTS legal MIGRATION television analog digital Republic Guinea
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Selective and effective removal of cesium ions using Prussian blue analog@γ-alumina core-shell pellets
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作者 Jiajia Song Ying Liu +7 位作者 Baojian Liu Yifeng Cao Jinxiong Lin Fuxing Shen Qiwei Yang Zhiguo Zhang Qilong Ren Zongbi Bao 《Chinese Journal of Chemical Engineering》 2025年第1期30-41,共12页
The removal of cesium-137(^(137)Cs)from nuclear wastewater remains crucial due to its radioactivity and high solubility in water,which pose serious risk to human health and the environment.Aiming at selective capture ... The removal of cesium-137(^(137)Cs)from nuclear wastewater remains crucial due to its radioactivity and high solubility in water,which pose serious risk to human health and the environment.Aiming at selective capture of Cs^(+) from wastewater,a core-shell adsorbent,Prussian blue analog@y-alumina(PBA@Al_(2)O_(3))pellets were synthesized using the hydrothermal-stepwise deposition method.The coreshell PBA@Al_(2)O_(3)pellets showcased a PBA loading of 25%and demonstrated a maximum adsorption capacity of 15.65 mg·g^(-1).The adsorption data was consistent with the pseudo-second-order kinetic model and the Langmuir isotherm model.It effectively reduced bulk Cs^(+) concentrations from an initial 6.62 mg·L^(-1)to 2 μg·L^(-1),achieving a removal efficiency of 99.97%and distribution coefficient(Kd)of 1.265×10^(6)ml·g^(-1),surpassing the performance of other PBA-based materials.The material also indicated good mechanical properties and cesium ion removal rates of 99.7%across a wide pH range(1.82 to 11.12).Furthermore,PBA@Al_(2)O_(3)exhibited consistent removal rate of over 99%and good selectivity(SF=50-1600)towards Cs^(+) even in the presence of interfering ions such as Na^(+),K^(+),Mg^(2+),and Ca^(2+)ions.The Kd(Cs^(+))for PBA@Al2O3 in simulated seawater and groundwater were 9.92×10^(3)and 2.23×10^(4)ml·g^(-1),where the removal rates reached 96.1%and 98.2%,respectively.XPS confirms that the adsorption mechanism is the ion exchange between Cs^(+) and K^(+)ions.This study underscores the significant potential of inorganic core-shell pellets adsorbents as promising agents for the selective capture of Cs^(+) from wastewater. 展开更多
关键词 ADSORPTION Cesium removal Prussian blue analog Nuclear wastewater CORE-SHELL
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Phase reconstruction via metasurfaceintegrated quantum analog operation
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作者 Qiuying Li Minggui Liang +4 位作者 Shuoqing Liu Jiawei Liu Shizhen Chen Shuangchun Wen Hailu Luo 《Opto-Electronic Advances》 2025年第4期42-50,共9页
Phase reconstruction plays a pivotal role in biology, medical imaging, and wavefront sensing. However, multiple measurements and adjustments are usually required for conventional schemes, which inevitably reduces the ... Phase reconstruction plays a pivotal role in biology, medical imaging, and wavefront sensing. However, multiple measurements and adjustments are usually required for conventional schemes, which inevitably reduces the quality of phase imaging. Here, based on multi-channel metasurface and quantum entanglement source, a simple and integrated quantum analog operation system is proposed to realize quantitative phase reconstruction with a high signal-to-noise ratio (SNR) under a low signal photon level. Without additional measurements and adjustments, four differential images necessary for the phase reconstruction are captured simultaneously. The non-local correlation of entangled photon pairs enables to remotely manipulate working modes of the system. Besides, the consistency of entangled photon pairs in time domain makes it possible to achieve a high SNR imaging by trigger detection. The results may potentially empower the application of metasurfaces in optical chip, wave function reconstruction, and label-free biology imaging. 展开更多
关键词 phase reconstruction metasurface polarization entanglement optical analog operation
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Exploration of the Teaching Reform of Integrating Marine Knowledge and Basic Analog Electronic Technology Course Based on BOPPPS
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作者 Tianzhao Li Xiaodong Zhang Linlin Zhang 《Journal of Contemporary Educational Research》 2025年第10期14-22,共9页
This paper focuses on the problems existing in the teaching of analog electronic technology courses,and puts forward the teaching reform idea of combining marine knowledge with the course content.Based on the BOPPPS t... This paper focuses on the problems existing in the teaching of analog electronic technology courses,and puts forward the teaching reform idea of combining marine knowledge with the course content.Based on the BOPPPS teaching model,specific teaching links are designed,and the teaching practice is carried out as an example of a low-power,high-precision microprocessor development project.The practical results show that the teaching reform improves students’learning interest and participation,cultivates students’engineering practice and innovation abilities,and provides a useful reference for the teaching reform of related courses. 展开更多
关键词 Marine knowledge analog electronic technology Teaching reform BOPPPS
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Photophysical property of fluorescent guanine analogs for selectively recognizing acetylated cytosine: A theoretical study
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作者 Xiaolin Chen Xixi Cui +3 位作者 Yongkang Lyu Chenyang Zhang Changzhe Zhang Qingtian Meng 《Chinese Physics B》 2025年第5期339-345,共7页
The photophysical properties of fluorescent nucleobase analogs play a crucial role in nucleic acids detection and the investigation of their structural and functional characteristics.In this study,we computationally d... The photophysical properties of fluorescent nucleobase analogs play a crucial role in nucleic acids detection and the investigation of their structural and functional characteristics.In this study,we computationally designed a series of quasiintrinsic fluorescent probes according to natural guanine(G)for selectively identifying covalent N^(4)-acetylcytosine(4acC),a base that is highly correlated with active transcription and gene expression.This work aims to gain insight into the role of 4acC in biological regulation with minimal perturbation to the native DNA structure.The results indicate that these Ganalogs possess extended π-conjugation in comparison with the natural guanine,which could yield efficient fluorescence emission and red-shifted absorption.Especially,the 8-thienyl-2’-deoxyguanosine(ThG)exhibits the highest fluorescence intensity and avoids self-absorption on account of the large Stokes shifts(>67 nm).What is more,the fluorescence of ThG is unaffected to base pairing with natural cytosine,while the obvious fluorescence quenching is observed by virtue of the excited state intermolecular charge transfer after pairing with 4acC,so it is supposed as a promising biosensor for monitoring the fluorescence changes in the absence or presence of the 4acC.Additionally,the impact of binding deoxyribose on photophysical properties is explored to guarantee the biological applicability of the bright G-analogs in real environment. 展开更多
关键词 guanine analog base modification fluorescence probe density functional theory
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Flexible artificial vision computing system based on FeOx optomemristor for speech recognition
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作者 Jie Li Yue Xin +6 位作者 Bai Sun Dengshun Gu Changrong Liao Xiaofang Hu Lidan Wang Shukai Duan Guangdong Zhou 《Journal of Semiconductors》 2025年第1期225-232,共8页
With the advancement of artificial intelligence,optic in-sensing reservoir computing based on emerging semiconductor devices is high desirable for real-time analog signal processing.Here,we disclose a flexible optomem... With the advancement of artificial intelligence,optic in-sensing reservoir computing based on emerging semiconductor devices is high desirable for real-time analog signal processing.Here,we disclose a flexible optomemristor based on C_(27)H_(30)O_(15)/FeOx heterostructure that presents a highly sensitive to the light stimuli and artificial optic synaptic features such as short-and long-term plasticity(STP and LTP),enabling the developed optomemristor to implement complex analogy signal processing through building a real-physical dynamic-based in-sensing reservoir computing algorithm and yielding an accuracy of 94.88%for speech recognition.The charge trapping and detrapping mediated by the optic active layer of C_(27)H_(30)O_(15) that is extracted from the lotus flower is response for the positive photoconductance memory in the prepared optomemristor.This work provides a feasible organic−inorganic heterostructure as well as an optic in-sensing vision computing for an advanced optic computing system in future complex signal processing. 展开更多
关键词 reservoir computing flexible optomemristor analogy signal processing optic computing
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Manipulating Heterogeneous Surface/Interface Reconstruction of Nickel Molybdate Nanofiber by In Situ Prussian Blue Analogs Etching Strategy for Oxygen Evolution
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作者 Xinyao Ding Lirong Zhang +2 位作者 Peng Yu Ruibai Cang Mingyi Zhang 《Energy & Environmental Materials》 2025年第3期199-207,共9页
Bimetallic oxides are promising electrocatalysts due to their rich composition,facile synthesis,and favorable stability under oxidizing conditions.This paper innovatively proposes a strategy aimed at constructing a on... Bimetallic oxides are promising electrocatalysts due to their rich composition,facile synthesis,and favorable stability under oxidizing conditions.This paper innovatively proposes a strategy aimed at constructing a one-dimensional heterostructure(Fe–NiO/NiMoO_(4) nanoparticles/nanofibers).The strategy commences with the meticulous treatment of NiMoO_(4) nanofibers,utilizing in situ etching techniques to induce the formation of Prussian Blue Analog compounds.In this process,[Fe(CN)_(6)]^(3-)anions react with the NiMoO_(4) host layer to form a steady NiFe PBA.Subsequently,the surface/interface reconstituted NiMoO_(4) nanofibers undergo direct oxidation,leading to a reconfiguration of the surface structure and the formation of a unique Fe–NiO/NiMoO_(4) one-dimensional heterostructure.The catalyst showed markedly enhanced electrocatalytic performance for the oxygen evolution reaction.Density functional theory results reveal that the incorporation of Fe as a dopant dramatically reduces the Gibbs free energy associated with the rate-determining step in the oxygen evolution reaction pathway.This pivotal transformation directly lowers the activation energy barrier,thereby significantly enhancing electron transfer efficiency. 展开更多
关键词 in situ etching NANOFIBER NiMoO_(4) OER Prussian Blue analog
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Dual therapy with nucleos(t)ide analogues in the prevention of hepatitis B virus recurrence after liver transplantation:Two case reports
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作者 Nicolás Ortiz-López Maximiliano Acevedo +4 位作者 Tamara Vergara Juan Pablo Roblero Álvaro Urzúa Máximo Cattaneo Jaime Poniachik 《World Journal of Hepatology》 2025年第4期144-150,共7页
BACKGROUND Infection by the hepatitis B virus(HBV)represents a significant global sociosanitary burden.While liver transplantation(LT)is an important therapeutic option,treatments that prevent HBV reinfection are nece... BACKGROUND Infection by the hepatitis B virus(HBV)represents a significant global sociosanitary burden.While liver transplantation(LT)is an important therapeutic option,treatments that prevent HBV reinfection are necessary.The combination of anti-hepatitis B immunoglobulin(HBIG)and nucleoside/nucleotide analogs(NA)is the standard post-transplant treatment;however,there are limitations in using HBIG,particularly its cost.We present two illustrative clinical cases as examples of post-transplant management using dual NA therapy,unaccompanied by HBIG.CASE SUMMARY The first case involves a 42-year-old man with HBV-related cirrhosis,who,in the context of a diagnosis of hepatocellular carcinoma and hepatopulmonary syndrome,underwent LT without viremia at the time of transplantation.A lack of availability of HBIG led to the combined use of two NAs,entecavir,and tenofovir alafenamide—resulting in the negativization of hepatitis B surface antigen(HBsAg)and maintenance of a negative viral load in the post-transplant period.In the second case,a 63-year-old woman presented with acute hepatic failure due to HBV with viremia during transplantation.Combined therapy with entecavir and tenofovir alafenamide,again due to the unavailability of HBIG,ultimately led to the negativization of HBsAg and viral load.CONCLUSION These cases suggest the efficacy of dual NA therapy in post-transplant HBV management,emphasizing the need to reconsider traditional treatment approaches. 展开更多
关键词 Antiviral drug Liver transplant Hepatitis B virus Viral recurrence Nucleoside analog Case report
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Recent progress of Prussian blue analogues as cathode materials for metal ion secondary batteries
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作者 Xin-Yuan Fu Lu-Lu Zhang +2 位作者 Cheng-Cheng Wang Hua-Bin Sun Xue-Lin Yang 《Rare Metals》 2025年第1期34-59,共26页
With the rapid development of new energy and the high proportion of new energy connected to the grid,energy storage has become the leading technology driving significant adjustments in the global energy landscape.Elec... With the rapid development of new energy and the high proportion of new energy connected to the grid,energy storage has become the leading technology driving significant adjustments in the global energy landscape.Electrochemical energy storage,as the most popular and promising energy storage method,has received extensive attention.Currently,the most widely used energy storage method is metal-ion secondary batteries,whose performance mainly depends on the cathode material.Prussian blue analogues(PBAs)have a unique open framework structures that allow quick and reversible insertion/extraction of metal ions such as Na^(+),K^(+),Zn^(2+),Li^(+)etc.,thus attracting widespread attention.The advantages of simple synthesis process,abundant resources,and low cost also distinguish it from its counterparts.Unfortunately,the crystal water and structural defects in the PBAs lattice that is generated during the synthesis process,as well as the low Na content,significantly affect their electrochemical performance.This paper focuses on PBAs’synthesis methods,crystal structure,modification strategies,and their potential applications as cathode materials for various metal ion secondary batteries and looks forward to their future development direction. 展开更多
关键词 Prussian blue analogs Cathode material Metal-ion secondary batteries Synthesis method Modification strategy
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Entropy Engineering Activates Cu-Fe Inertia Center From Prussian Blue Analogs With Micro-Strains for Oxygen Electrocatalysis in Zn-Air Batteries
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作者 Han Man Guanyu Chen +5 位作者 Fengmei Wang Jiafeng Ruan Yihao Liu Yang Liu Fang Fang Renchao Che 《Carbon Energy》 2025年第5期126-135,共10页
By the random distribution of metals in a single phase,entropy engineering is applied to construct dense neighboring active centers with diverse electronic and geometric structures,realizing the continuous optimizatio... By the random distribution of metals in a single phase,entropy engineering is applied to construct dense neighboring active centers with diverse electronic and geometric structures,realizing the continuous optimization of multiple primary reactions for oxygen reduction reaction(ORR)and oxygen evolution reaction(OER).Many catalysts developed through entropy engineering have been built in nearly equimolar ratios to pursue high entropy,hindering the identification of the active sites and potentially diluting the concentration of real active sites while weakening their electronic interactions with reaction intermediates.Herein,this work proposes an entropy-engineering strategy in metal nanoparticle-embedded nitrogen carbon electrocatalysts,implemented by entropy-engineered Prussian blue analogs(PBA)as precursors to enhance the catalytic activity of primary Cu-Fe active sites.Through the introduction of the micro-strains driven by entropy engineering,density functional theory(DFT)calculations and geometric phase analysis(GPA)using Lorentz electron microscopy further elucidate the optimization of the adsorption/desorption of intermediates.Furthermore,the multi-dimensional morphology and the size diminishment of the nanocrystals serve to expand the electrochemical area,maximizing the catalytic activity for both ORR and OER.Notably,the Zn-air battery assembled with CuFeCoNiZn-NC operated for over 1300 h with negligible decay.This work presents a paradigm for the design of low-cost electrocatalysts with entropy engineering for multi-step reactions. 展开更多
关键词 Prussian blue analog STRAINS transition metal-based catalyst zinc-air battery
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Unraveling key factors that influence and shape fluid flow dynamics in Brazilian salt Lagoon stromatolites: A case study in pre-salt analogues
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作者 Herson Oliveira da Rocha Roseane Marchezi Missagia +5 位作者 Marco Antonio Rodrigues de Ceia Andre Oliveira Martins Rafaella Rocha Baggieri Irineu de Azevedo Lima Neto Victor Hugo Santos Lucas Cesar Oliveira 《Petroleum Science》 2025年第3期1080-1097,共18页
This study analyzes Brazilian stromatolites in Lagoa Salgada,serving as analogs for pre-salt rocks in the Santos and Campos basins.Despite their excellent petrophysical properties,such as high porosity and permeabilit... This study analyzes Brazilian stromatolites in Lagoa Salgada,serving as analogs for pre-salt rocks in the Santos and Campos basins.Despite their excellent petrophysical properties,such as high porosity and permeability,these reservoirs present challenges in fluid flow modeling and simulation.The research investigates various factors influencing the development of carbonate reservoirs,including diagenetic processes employing several techniques,such as microcomputed tomography(micro-CT)and digital rock physics(DRP),to study petrophysical and geological characteristics.Additionally,through numerical simulations,the properties of fluid flow in different microfacies of stromatolites are estimated,with particular emphasis on understanding and highlighting changes in the direction of fluid flow in the three characterized microfacies.These findings offer crucial insights into optimizing oil and gas exploration and production techniques in carbonate reservoirs,providing a comprehensive understanding of the dynamics of fluid transport in porous media,especially in terms of directional changes within stromatolites. 展开更多
关键词 Fluid dynamics in stromatolites Carbonate reservoirs Numerical simulation Pre-salt analogs
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