Diatomic metasurfaces designed for interferometric mechanisms possess significant potential for the multidimensional manipulation of electromagnetic waves,including control over amplitude,phase,frequency,and polarizat...Diatomic metasurfaces designed for interferometric mechanisms possess significant potential for the multidimensional manipulation of electromagnetic waves,including control over amplitude,phase,frequency,and polarization.Geometric phase profiles with spin-selective properties are commonly associated with wavefront modulation,allowing the implementation of conjugate strategies within orthogonal circularly polarized channels.Simultaneous control of these characteristics in a single-layered diatomic metasurface will be an apparent technological extension.Here,spin-selective modulation of terahertz(THz)beams is realized by assembling a pair of meta-atoms with birefringent effects.The distinct modulation functions arise from geometric phase profiles characterized by multiple rotational properties,which introduce independent parametric factors that elucidate their physical significance.By arranging the key parameters,the proposed design strategy can be employed to realize independent amplitude and phase manipulation.A series of THz metasurface samples with specific modulation functions are characterized,experimentally demonstrating the accuracy of on-demand manipulation.This research paves the way for all-silicon meta-optics that may have great potential in imaging,sensing and detection.展开更多
Difficulty in extracting nonlinear sparse impulse features due to variable speed conditions and redundant noise interference leads to challenges in diagnosing variable speed faults.Therefore,an improved spectral amplit...Difficulty in extracting nonlinear sparse impulse features due to variable speed conditions and redundant noise interference leads to challenges in diagnosing variable speed faults.Therefore,an improved spectral amplitude modulation(ISAM)based on sparse feature adaptive convolution(SFAC)is proposed to enhance the fault features under variable speed conditions.First,an optimal bi-damped wavelet construction method is proposed to learn signal impulse features,which selects the optimal bi-damped wavelet parameters with correlation criterion and particle swarm optimization.Second,a convolutional basis pursuit denoising model based on an optimal bi-damped wavelet is proposed for resolving sparse impulses.A model regularization parameter selection method based on weighted fault characteristic amplitude ratio assistance is proposed.Then,an ISAM method based on kurtosis threshold is proposed to further enhance the fault information of sparse signal.Finally,the type of variable speed faults is determined by order spectrum analysis.Various experimental results,such as spectral amplitude modulation and Morlet wavelet matching,verify the effectiveness and advantages of the ISAM-SFAC method.展开更多
The Rydberg atom-based receiver, as a novel type of antenna, demonstrates broad application prospects in the field of microwave communications. However, since Rydberg atomic receivers are nonlinear systems, mismatches...The Rydberg atom-based receiver, as a novel type of antenna, demonstrates broad application prospects in the field of microwave communications. However, since Rydberg atomic receivers are nonlinear systems, mismatches between the parameters of the received amplitude modulation(AM) signals and the system's linear workspace and demodulation operating points can cause severe distortion in the demodulated signals. To address this, the article proposes a method for determining the operational parameters based on the mean square error(MSE) and total harmonic distortion(THD) assessments and presents strategies for optimizing the system's operational parameters focusing on linear response characteristics(LRC) and linear dynamic range(LDR). Specifically, we employ a method that minimizes the MSE to define the system's linear workspace, thereby ensuring the system has a good LRC while maximizing the LDR. To ensure that the signal always operates within the linear workspace, an appropriate carrier amplitude is set as the demodulation operating point. By calculating the THD at different operating points, the LRC performance within different regions of the linear workspace is evaluated, and corresponding optimization strategies based on the range of signal strengths are proposed. Moreover, to more accurately restore the baseband signal, we establish a mapping relationship between the carrier Rabi frequency and the transmitted power of the probe light, and optimize the slope of the linear demodulation function to reduce the MSE to less than 0.8×10^(-4). Finally, based on these methods for determining the operational parameters, we explore the effects of different laser Rabi frequencies on the system performance, and provide optimization recommendations. This research provides robust support for the design of high-performance Rydberg atom-based AM receivers.展开更多
This paper designs a high-frequency stable wireless amplitude modulation(AM)system based on a Pierce circuit.The system utilizes an oscillator and comparator to generate a 20 kHz square wave with an adjustable duty cy...This paper designs a high-frequency stable wireless amplitude modulation(AM)system based on a Pierce circuit.The system utilizes an oscillator and comparator to generate a 20 kHz square wave with an adjustable duty cycle,combined with a 41 MHz carrier wave produced by a passive crystal oscillator Pierce circuit.A 100% modulation index amplitude modulation is achieved through the AD835 multiplier.The modulated signal is amplified by a power amplifier circuit and transmitted wirelessly via the transmitter antenna.Upon reception,the signal undergoes two-stage highfrequency amplification before passing through a Schottky diode envelope detector.The NE5532 shaping circuit then restores the square wave.Experimental results demonstrate reliable 11-meter transmission with carrier frequency deviation<0.75% and demodulation error<1%.展开更多
We have theoretically and experimentally studied the dispersive signal of the Rydberg atomic electromagneticallyinduced transparency(EIT)Autler–Townes(AT)splitting spectra obtained using amplitude modulation of the m...We have theoretically and experimentally studied the dispersive signal of the Rydberg atomic electromagneticallyinduced transparency(EIT)Autler–Townes(AT)splitting spectra obtained using amplitude modulation of the microwave(MW)electric field.In addition to the two zero-crossing points interval△f_(zeros),the dispersion signal has two positive maxima with an interval defined as the shoulder interval△f_(sho),which is theoretically expected to be used to measure a much weaker MW electric field.The relationship of the MW field strength E_(MW)and△f_(sho)is experimentally studied at the MW frequencies of 31.6 GHz and 9.2 GHz respectively.The results show that△f_(sho)can be used to characterize the much weaker E_(MW)than that of△f_(zeros)and the traditional EIT–AT splitting interval△f_(m);the minimum E_(MW)measured by△f_(sho)is about 30 times smaller than that by△f_(m).As an example,the minimum E_(MW)at 9.2 GHz that can be characterized by△f_(sho)is 0.056 mV/cm,which is the minimum value characterized by the frequency interval using a vapor cell without adding any auxiliary fields.The proposed method can improve the weak limit and sensitivity of E_(MW)measured by the spectral frequency interval,which is important in the direct measurement of weak E_(MW).展开更多
High temperature piezoelectric energy harvester(HTPEH)is an important solution to replace chemical battery to achieve independent power supply of HT wireless sensors.However,simultaneously excellent performances,inclu...High temperature piezoelectric energy harvester(HTPEH)is an important solution to replace chemical battery to achieve independent power supply of HT wireless sensors.However,simultaneously excellent performances,including high figure of merit(FOM),insulation resistivity(ρ)and depolarization temperature(Td)are indispensable but hard to achieve in lead-free piezoceramics,especially operating at 250°C has not been reported before.Herein,well-balanced performances are achieved in BiFeO3–BaTiO3 ceramics via innovative defect engineering with respect to delicate manganese doping.Due to the synergistic effect of enhancing electrostrictive coefficient by polarization configuration optimization,regulating iron ion oxidation state by high valence manganese ion and stabilizing domain orientation by defect dipole,comprehensive excellent electrical performances(Td=340°C,ρ250°C>10^(7)Ωcm and FOM_(250°C)=4905×10^(–15)m^(2)N^(−1))are realized at the solid solubility limit of manganese ions.The HT-PEHs assembled using the rationally designed piezoceramic can allow for fast charging of commercial electrolytic capacitor at 250°C with high energy conversion efficiency(η=11.43%).These characteristics demonstrate that defect engineering tailored BF-BT can satisfy high-end HT-PEHs requirements,paving a new way in developing selfpowered wireless sensors working in HT environments.展开更多
As a cluster overlap amplitude,the reduced-width amplitude is an important physical quantity for analyzing clustering in the nucleus depending on specified channels and has been calculated and widely applied in nuclea...As a cluster overlap amplitude,the reduced-width amplitude is an important physical quantity for analyzing clustering in the nucleus depending on specified channels and has been calculated and widely applied in nuclear cluster physics.In this review,we briefly revisit the theoretical framework for calculating the reduced-width amplitude,as well as the outlines of cluster models to obtain microscopic or semi-microscopic cluster wave functions.We also introduce the recent progress related to cluster overlap amplitudes,including the implementation of cross-section estimation and extension to three-body clustering analysis.Comprehensive examples are provided to demonstrate the application of the reduced-width amplitude in analyzing clustering structures.展开更多
This work aims to reveal the mechanical responses and energy evolution characteristics of skarn rock under constant amplitude-varied frequency loading paths.Testing results show that the fatigue lifetime,stress−strain...This work aims to reveal the mechanical responses and energy evolution characteristics of skarn rock under constant amplitude-varied frequency loading paths.Testing results show that the fatigue lifetime,stress−strain responses,deformation,energy dissipation and fracture morphology are all impacted by the loading rate.A pronounced influence of the loading rate on rock deformation is found,with slower loading rate eliciting enhanced strain development,alongside augmented energy absorption and dissipation.In addition,it is revealed that the loading rate and cyclic loading amplitude jointly influence the phase shift distribution,with accelerated rates leading to a narrower phase shift duration.It is suggested that lower loading rate leads to more significant energy dissipation.Finally,the tensile or shear failure modes were intrinsically linked to loading strategy,with cyclic loading predominantly instigating shear damage,as manifest in the increased presence of pulverized grain particles.This work would give new insights into the fortification of mining structures and the optimization of mining methodologies.展开更多
The control of adiabatic dynamics is essential for quantum manipulation.We investigate the effects of both periodic modulating field and linear sweeping field on adiabatic dynamics based on a non-reciprocal Landau-Zen...The control of adiabatic dynamics is essential for quantum manipulation.We investigate the effects of both periodic modulating field and linear sweeping field on adiabatic dynamics based on a non-reciprocal Landau-Zener model with periodic modulation.We obtain adiabatic phase diagrams in the(ω,δ)parameter space,where the adiabatic region is bounded by the modulating frequencyωgreater than a critical valueω_(c) and the non-reciprocal parameterδless than one.The results show that the adiabaticity of the system is not sensitive to the modulating amplitude.We find that the critical modulating frequency can be expressed as a power function of the modulating period number or the sweeping rate.Our findings suggest that one can change the adiabatic region or improve the adiabaticity by adjusting the parameters of both the modulating and the sweeping fields,which provides an effective means to flexibly control the adiabatic dynamics of non-reciprocal systems.展开更多
Single-wavelength interferometry achieves high resolution for smooth surfaces but struggles with rough industrially relevant ones due to limited unambiguous measuring range and speckle effects.Multiwavelength interfer...Single-wavelength interferometry achieves high resolution for smooth surfaces but struggles with rough industrially relevant ones due to limited unambiguous measuring range and speckle effects.Multiwavelength interferometry addresses these challenges using synthetic wavelengths,enabling a balance between extended measurement range and resolution by combining several synthetic wavelengths.This approach holds immense potential for diverse industrial applications,yet it remains largely untapped due to the lack of suitable light sources.Existing solutions are constrained by limited flexibility in synthetic-wavelength generation and slow switching speeds.We demonstrate a light source for multiwavelength interferometry based on electro-optic single-sideband modulation.It reliably generates synthetic wavelengths with arbitrary values from centimeters to meters and switching time below 30 ms.This breakthrough paves the way for dynamic reconfigurable multiwavelength interferometry capable of adapting to complex surfaces and operating efficiently even outside laboratory settings.These capabilities unlock the full potential of multiwavelength interferometry,offering unprecedented flexibility and speed for industrial and technological applications.展开更多
To reveal the effects of environmental and loading conditions, as well as asphalt properties on the nonlinear rheological behavior of asphalt, the large amplitude oscillation shear(LAOS) test was introduced, and the F...To reveal the effects of environmental and loading conditions, as well as asphalt properties on the nonlinear rheological behavior of asphalt, the large amplitude oscillation shear(LAOS) test was introduced, and the Fourier transform rheology, Lissajous curve method, and the LAOS fatigue test have been applied to investigate the nonlinear rheological behavior of asphalt binders. The research results indicate that a decrease in temperature, an increase in shear frequency and strain level, the introduction of polymer modifiers, and the aging effect of asphalt can significantly increase the nonlinearity of asphalt, manifested by the higher relative magnitude of the third harmonic and zero-strain nonlinear coefficient. For the two polymer modifiers selected in this study, the 4%polyurethane modifier exhibits a higher nonlinear lifting effect than the 4% styrene-butadiene-styrene(SBS). The impact of long-term aging on nonlinear viscoelasticity is observably greater than that of short-term aging. The zero-strain nonlinear coefficient estimated based on the average value method can accurately characterize the nonlinear viscoelasticity of asphalt, which can serve as an effective supplement to the relative magnitude of the third harmonic. All asphalts exhibit shear thinning behavior under the test temperature of 24℃, and the decrease in test temperature, the increase in shear rate and strain level, the introduction of modifiers, and the aging effect of asphalt all exacerbate the shear thinning behavior of asphalt. In addition, the fatigue failure process of asphalt materials is accompanied by an increasing degree of nonlinearity.展开更多
Low sidelobe waveform can reduce mutual masking between targets and increase the detection probability of weak targets.A low sidelobe waveform design method based on complementary amplitude coding(CAC)is proposed in t...Low sidelobe waveform can reduce mutual masking between targets and increase the detection probability of weak targets.A low sidelobe waveform design method based on complementary amplitude coding(CAC)is proposed in this paper,which can be used to reduce the sidelobe level of multiple waveforms.First,the CAC model is constructed.Then,the waveform design problem is transformed into a nonlinear optimization problem by constructing an objective function using the two indicators of peak-to-sidelobe ratio(PSLR)and integrated sidelobe ratio(ISLR).Finally,genetic algorithm(GA)is used to solve the optimization problem to get the best CAC waveforms.Simulations and experiments are conducted to verify the effectiveness of the proposed method.展开更多
Background:The nuclear receptor coactivator(NCOA)family,including NCOA1,NCOA2,and NCOA3,is critical in regulating gene expression through interactions with nuclear receptors and other transcription factors.These coact...Background:The nuclear receptor coactivator(NCOA)family,including NCOA1,NCOA2,and NCOA3,is critical in regulating gene expression through interactions with nuclear receptors and other transcription factors.These coactivators are implicated in various cancers,but their comprehensive roles across different cancer types remain poorly understood.Methods:We performed a pan-cancer bioinformatics analysis using data from The Cancer Genome Atlas and the Genotype-Tissue Expression project.We assessed the differential expression,copy number variations,mutations,methylation status,tumor mutation burden,microsatellite instability,and immune cell infiltration associated with NCOA family members across various cancers.Differential expression analysis was conducted using the DESeq2 package.Methylation data were analyzed using the ChAMP package,and immune cell infiltration was estimated using the CIBERSORT algorithm.Results:NCOA1 and NCOA2 were predominantly downregulated in multiple cancers,suggesting potential tumor suppressor roles,whereas NCOA3 was largely upregulated,indicating a consistent oncogenic function.These expression patterns significantly correlated with patient prognosis.Frequent copy number variations,particularly gains,and high mutation rates were observed in NCOA2.NCOA3 demonstrated consistent hypomethylation in tumors,which was associated with increased gene expression.Significant correlations were found between NCOA expression and tumor mutation burden,microsatellite instability,and immune cell infiltration,indicating their involvement in genomic instability and immune modulation.Conclusion:This comprehensive analysis reveals significant alterations in the expression,genomic,and epigenetic profiles of NCOA family members across various cancers.The findings highlight the multifaceted roles of NCOA1,NCOA2,and NCOA3 in tumorigenesis and their potential as biomarkers and therapeutic targets.Future research should focus on elucidating the mechanisms underlying the associations between NCOA expression,genomic alterations,and immune modulation to develop targeted cancer therapies.展开更多
This paper establishes an amplitude modulation heating model, simulating the far-field radiation of ELF/VLF signals generated by modulation heating, as well as the specific location and longitudinal extent of the radi...This paper establishes an amplitude modulation heating model, simulating the far-field radiation of ELF/VLF signals generated by modulation heating, as well as the specific location and longitudinal extent of the radiation source. We consider various modulation waveforms and find that square-wave modulation has the highest excitation efficiency for ELF/VLF signals, and that square-wave modulation with a smaller duty cycle(<50%) exhibits higher excitation efficiency for ELF/VLF signals, while the sin^(2)t waveform modulation yields the lowest proportion of harmonic energy in the generated signals. The amplitude of the second harmonic generated by the sin^(2)t waveform is less than one-tenth that of the fundamental frequency, and the energy of higher-frequency harmonics can be negligibly small compared with those of the fundamental wave. It is a challenging task to achieve a balance between enhancing the excitation efficiency of ELF/VLF signals and also suppressing harmonics generated by the modulated heating process. This is because the harmonics are correspondingly enhanced as the excitation efficiency of the signals is increased. However, we find that under conditions of varying effective radiant power and modulation frequency, as long as the modulation waveform is unchanged, the energy ratio between the fundamental frequency signal generated by modulated heating and each harmonic is relatively fixed, with changes only in signal intensity and the location of the radiation source zone. This implies that one can first select modulation waveforms that make the signal less prone to distortion, then increase the effective radiated power to enhance the signal strength, without concern for harmonic interference of the fundamental signal.展开更多
A designed visual geometry group(VGG)-based convolutional neural network(CNN)model with small computational cost and high accuracy is utilized to monitor pulse amplitude modulation-based intensity modulation and direc...A designed visual geometry group(VGG)-based convolutional neural network(CNN)model with small computational cost and high accuracy is utilized to monitor pulse amplitude modulation-based intensity modulation and direct detection channel performance using eye diagram measurements.Experimental results show that the proposed technique can achieve a high accuracy in jointly monitoring modulation format,probabilistic shaping,roll-off factor,baud rate,optical signal-to-noise ratio,and chromatic dispersion.The designed VGG-based CNN model outperforms the other four traditional machine-learning methods in different scenarios.Furthermore,the multitask learning model combined with MobileNet CNN is designed to improve the flexibility of the network.Compared with the designed VGG-based CNN,the MobileNet-based MTL does not need to train all the classes,and it can simultaneously monitor single parameter or multiple parameters without sacrificing accuracy,indicating great potential in various monitoring scenarios.展开更多
Large-angle stimulated Raman scattering(LA-SRS)in a longitudinally inhomogeneous plasma with a transverse density modulation is studied using a three-wave coupled model and numerical simulations.The simulations show t...Large-angle stimulated Raman scattering(LA-SRS)in a longitudinally inhomogeneous plasma with a transverse density modulation is studied using a three-wave coupled model and numerical simulations.The simulations show that the scattering angle of SRS in a longitudinally inhomogeneous plasma can be significantly affected by transverse density modulation.Under transverse density modulation conditions,the laser focuses into underdense regions,owing to the transversely modulated refractive index.The angle of LA-SRS,neither a purely 90° angle side scattering nor purely backscattering,is almost consistent with the specific angle at which the density inhomogeneity vanishes.In modulated plasmas,the nonuniform distribution of laser intensity shifts the regions of scattering and gain compared with those in uniform plasmas,ultimately affecting the laser transmission.SRS is suppressed in weakly modulated regimes,whereas it is enhanced under strong modulation conditions,and a theoretical criterion distinguishing between strong and weak modulation is established.展开更多
The development of solid frustrated Lewis pairs(FLPs)catalysts with porous structures is a promising strategy for advancing green hydrogenation technologies and has garnered significant attention.Leveraging the divers...The development of solid frustrated Lewis pairs(FLPs)catalysts with porous structures is a promising strategy for advancing green hydrogenation technologies and has garnered significant attention.Leveraging the diverse oxidation states and structural tunability of cerium-based metal-organic frameworks(Ce-MOFs),this study employed a competitive coordination strategy utilizing a single carboxylate functional group ligand to construct a series of MOF-808-X(X=-NH_(2),-OH,-Br,and-NO_(2))featuring rich solid-state FLPs for hydrogenation of unsaturated olefins.The-X functional group serves as a microenvironment,enhancing hydrogenation activity by modulating the electronic properties and acid-base characteristics of the FLP sites.The unique redox properties of elemental cerium facilitate the exposure of unsaturated Ce sites(Ce-CUS,Lewis acid(LA))and adjacent Ce-OH(Lewis base(LB))sites within the MOFs,generating abundant solid-state FLP(Ce-CUS/Ce-OH)sites.Experimental results demonstrate that Ce-CUS and Ce-OH interact with theσandσ^(*)orbitals of H-H,and this"push-pull"synergy promotes heterolytic cleavage of the H-H bond.The lone pair electrons of the electron-donating functional group are transmitted through the molecular backbone to the LB site,thereby increasing its strength and reducing the activation energy required for H_(2)heterolytic cleavage.Notably,at 100℃and 2 MPa H_(2),MOF-808-NH_(2)achieves complete conversion of styrene and dicyclopentadiene,significantly outperforming MOF-808.Based on in-situ analysis and density functional theory calculations,a plausible reaction mechanism is proposed.This research enriches the theoretical framework for unsaturated olefin hydrogenation catalysts and contributes to the development of efficient catalytic systems.展开更多
The dynamics of network power response play a crucial role in system stability.However,the integration of power electronic equipment leads to amplitude and angular frequency(abbreviated as"frequency")time-va...The dynamics of network power response play a crucial role in system stability.However,the integration of power electronic equipment leads to amplitude and angular frequency(abbreviated as"frequency")time-varying characteristics of the node voltage during dynamic processes.As a result,traditional calcu-lation methods for and characteristics of the power response of the network based on phasor and impe-dance lose their validity.Therefore,this paper undertakes mathematical calculations to reveal the power response of a network under excitation by voltage with time-varying amplitude and frequency(TVAF),relying on the original mathematical relationships and superimposed step response.Then,the multi-timescale characteristics of both the active and reactive power of the network are explored physically.Additionally,this paper reveals a new phenomenon of storing and releasing the active and reactive power of the network.To meet practical engineering requirements,a simplified power expression is presented.Finally,the theoretical analysis is validated through time-domain simulations.展开更多
Neuromorphic devices,inspired by the intricate architecture of the human brain,have garnered recognition for their prodigious computational speed and sophisticated parallel computing capabilities.Vision,the primary mo...Neuromorphic devices,inspired by the intricate architecture of the human brain,have garnered recognition for their prodigious computational speed and sophisticated parallel computing capabilities.Vision,the primary mode of external information acquisition in living organisms,has garnered substantial scholarly interest.Notwithstanding numerous studies simulating the retina through optical synapses,their applications remain circumscribed to single-mode perception.Moreover,the pivotal role of temperature,a fundamental regulator of biological activities,has regrettably been relegated to the periphery.To address these limitations,we proffer a neuromorphic device endowed with multimodal perception,grounded in the principles of light-modulated semiconductors.This device seamlessly accomplishes dynamic hybrid visual and thermal multimodal perception,featuring temperature-dependent paired pulse facilitation properties and adaptive storage.Crucially,our meticulous examination of transfer curves,capacitance–voltage(C–V)tests,and noise measurements provides insights into interface and bulk defects,elucidating the physical mechanisms underlying adaptive storage and other functionalities.Additionally,the device demonstrates a variety of synaptic functionalities,including filtering properties,Ebbinghaus curves,and memory applications in image recognition.Surprisingly,the digital recognition rate achieves a remarkable value of 98.8%.展开更多
The steps of NO_(3)^(-)adsorption,deoxygenation,nitrogen species hydrogenation and ammonia desorption are vital for electrocatalytic nitrate reduction(NO_(3)^(-)RR)to ammonia,and lowering their Gibbs free energy chan...The steps of NO_(3)^(-)adsorption,deoxygenation,nitrogen species hydrogenation and ammonia desorption are vital for electrocatalytic nitrate reduction(NO_(3)^(-)RR)to ammonia,and lowering their Gibbs free energy change(ΔG)is the essential approach for improving NO_(3)^(-)RR.The copper-based alloys are considered as the outstanding catalysts thanks to the tunable d-band center,reconstruction and synergistic effect of multiple metal atoms in the past decades.Here,we synthesized a single-phase coppernickel alloy by electrodeposition and optimized itsΔG during NO_(3)^(-)RR through tuning the electrodeposition potential to regulate the metal component ratio.The atomic ratio of Ni/Cu in CuNi alloys is gradually increased as the negative shift of deposition potential from-1.0 to-1.2 V versus SCE,thus achieving the fast modulation of intermediate adsorption energy for NO_(3)^(-)RR.According to density functional theory,profited by a strong NO_(3)^(-)adsorption and a weak NH_(3)desorption energy barrier,the optimized CuNi alloy(Cu_(3)Ni_(1)/CF)exhibits an ideal ammonia yield of 364.1μmol cm^(-2)h^(-1)and Faradaic efficiency of 92.25%at-0.23 V versus RHE.Further applying Cu_(3)Ni_(1)/CF as the cathode material,a novel Znnitrate battery exhibits a maximum power density of5.85 mW cm^(-2)with a NH_(3)yield of 92.50μmol cm^(-2)h^(-1)and Faradaic efficiency of 99.15%at 20 mA cm^(-2)for NH_(3)production.This work not only offers a rational design concept with clear guidance for efficient modulation of intermediate adsorption free energy on alloy catalysts prepared by electrodeposition,but also provides the further understanding for efficient developments of NO_(3)^(-)RR and Zn-based batteries.展开更多
基金supports from National Key Research and Development Program of China(2021YFB2800703)Sichuan Province Science and Technology Support Program(25QNJJ2419)+1 种基金National Natural Science Foundation of China(U22A2008,12404484)Laoshan Laboratory Science and Technology Innovation Project(LSKJ202200801).
文摘Diatomic metasurfaces designed for interferometric mechanisms possess significant potential for the multidimensional manipulation of electromagnetic waves,including control over amplitude,phase,frequency,and polarization.Geometric phase profiles with spin-selective properties are commonly associated with wavefront modulation,allowing the implementation of conjugate strategies within orthogonal circularly polarized channels.Simultaneous control of these characteristics in a single-layered diatomic metasurface will be an apparent technological extension.Here,spin-selective modulation of terahertz(THz)beams is realized by assembling a pair of meta-atoms with birefringent effects.The distinct modulation functions arise from geometric phase profiles characterized by multiple rotational properties,which introduce independent parametric factors that elucidate their physical significance.By arranging the key parameters,the proposed design strategy can be employed to realize independent amplitude and phase manipulation.A series of THz metasurface samples with specific modulation functions are characterized,experimentally demonstrating the accuracy of on-demand manipulation.This research paves the way for all-silicon meta-optics that may have great potential in imaging,sensing and detection.
基金funded by the National Natural Science Foundation of China(grant nos.52475084 and 52375076)the Postdoctoral Fellowship Program of CPSF(grant no.GZC20230202).
文摘Difficulty in extracting nonlinear sparse impulse features due to variable speed conditions and redundant noise interference leads to challenges in diagnosing variable speed faults.Therefore,an improved spectral amplitude modulation(ISAM)based on sparse feature adaptive convolution(SFAC)is proposed to enhance the fault features under variable speed conditions.First,an optimal bi-damped wavelet construction method is proposed to learn signal impulse features,which selects the optimal bi-damped wavelet parameters with correlation criterion and particle swarm optimization.Second,a convolutional basis pursuit denoising model based on an optimal bi-damped wavelet is proposed for resolving sparse impulses.A model regularization parameter selection method based on weighted fault characteristic amplitude ratio assistance is proposed.Then,an ISAM method based on kurtosis threshold is proposed to further enhance the fault information of sparse signal.Finally,the type of variable speed faults is determined by order spectrum analysis.Various experimental results,such as spectral amplitude modulation and Morlet wavelet matching,verify the effectiveness and advantages of the ISAM-SFAC method.
基金Project supported by the National Natural Science Foundation of China (Grant No. U22B2095)the Civil Aerospace Technology Research Project (Grant No. D010103)。
文摘The Rydberg atom-based receiver, as a novel type of antenna, demonstrates broad application prospects in the field of microwave communications. However, since Rydberg atomic receivers are nonlinear systems, mismatches between the parameters of the received amplitude modulation(AM) signals and the system's linear workspace and demodulation operating points can cause severe distortion in the demodulated signals. To address this, the article proposes a method for determining the operational parameters based on the mean square error(MSE) and total harmonic distortion(THD) assessments and presents strategies for optimizing the system's operational parameters focusing on linear response characteristics(LRC) and linear dynamic range(LDR). Specifically, we employ a method that minimizes the MSE to define the system's linear workspace, thereby ensuring the system has a good LRC while maximizing the LDR. To ensure that the signal always operates within the linear workspace, an appropriate carrier amplitude is set as the demodulation operating point. By calculating the THD at different operating points, the LRC performance within different regions of the linear workspace is evaluated, and corresponding optimization strategies based on the range of signal strengths are proposed. Moreover, to more accurately restore the baseband signal, we establish a mapping relationship between the carrier Rabi frequency and the transmitted power of the probe light, and optimize the slope of the linear demodulation function to reduce the MSE to less than 0.8×10^(-4). Finally, based on these methods for determining the operational parameters, we explore the effects of different laser Rabi frequencies on the system performance, and provide optimization recommendations. This research provides robust support for the design of high-performance Rydberg atom-based AM receivers.
文摘This paper designs a high-frequency stable wireless amplitude modulation(AM)system based on a Pierce circuit.The system utilizes an oscillator and comparator to generate a 20 kHz square wave with an adjustable duty cycle,combined with a 41 MHz carrier wave produced by a passive crystal oscillator Pierce circuit.A 100% modulation index amplitude modulation is achieved through the AD835 multiplier.The modulated signal is amplified by a power amplifier circuit and transmitted wirelessly via the transmitter antenna.Upon reception,the signal undergoes two-stage highfrequency amplification before passing through a Schottky diode envelope detector.The NE5532 shaping circuit then restores the square wave.Experimental results demonstrate reliable 11-meter transmission with carrier frequency deviation<0.75% and demodulation error<1%.
基金Project supported by Beijing Natural Science Foundation(Grant No.1212014)the National Key Research and Development Program of China(Grant Nos.2017YFA0304900 and 2017YFA0402300)+4 种基金the National Natural Science Foundation of China(Grant Nos.11604334,11604177,and U2031125)the Key Research Program of the Chinese Academy of Sciences(Grant No.XDPB08-3)the Open Research Fund Program of the State Key Laboratory of Low-Dimensional Quantum Physics(Grant No.KF201807)the Fundamental Research Funds for the Central UniversitiesYouth Innovation Promotion Association CAS。
文摘We have theoretically and experimentally studied the dispersive signal of the Rydberg atomic electromagneticallyinduced transparency(EIT)Autler–Townes(AT)splitting spectra obtained using amplitude modulation of the microwave(MW)electric field.In addition to the two zero-crossing points interval△f_(zeros),the dispersion signal has two positive maxima with an interval defined as the shoulder interval△f_(sho),which is theoretically expected to be used to measure a much weaker MW electric field.The relationship of the MW field strength E_(MW)and△f_(sho)is experimentally studied at the MW frequencies of 31.6 GHz and 9.2 GHz respectively.The results show that△f_(sho)can be used to characterize the much weaker E_(MW)than that of△f_(zeros)and the traditional EIT–AT splitting interval△f_(m);the minimum E_(MW)measured by△f_(sho)is about 30 times smaller than that by△f_(m).As an example,the minimum E_(MW)at 9.2 GHz that can be characterized by△f_(sho)is 0.056 mV/cm,which is the minimum value characterized by the frequency interval using a vapor cell without adding any auxiliary fields.The proposed method can improve the weak limit and sensitivity of E_(MW)measured by the spectral frequency interval,which is important in the direct measurement of weak E_(MW).
基金supported by the National Natural Science Foundation of China(Grant Nos.52272103 and 52072010)Beijing Natural Science Foundation(Grant Nos.2242029 and JL23004).
文摘High temperature piezoelectric energy harvester(HTPEH)is an important solution to replace chemical battery to achieve independent power supply of HT wireless sensors.However,simultaneously excellent performances,including high figure of merit(FOM),insulation resistivity(ρ)and depolarization temperature(Td)are indispensable but hard to achieve in lead-free piezoceramics,especially operating at 250°C has not been reported before.Herein,well-balanced performances are achieved in BiFeO3–BaTiO3 ceramics via innovative defect engineering with respect to delicate manganese doping.Due to the synergistic effect of enhancing electrostrictive coefficient by polarization configuration optimization,regulating iron ion oxidation state by high valence manganese ion and stabilizing domain orientation by defect dipole,comprehensive excellent electrical performances(Td=340°C,ρ250°C>10^(7)Ωcm and FOM_(250°C)=4905×10^(–15)m^(2)N^(−1))are realized at the solid solubility limit of manganese ions.The HT-PEHs assembled using the rationally designed piezoceramic can allow for fast charging of commercial electrolytic capacitor at 250°C with high energy conversion efficiency(η=11.43%).These characteristics demonstrate that defect engineering tailored BF-BT can satisfy high-end HT-PEHs requirements,paving a new way in developing selfpowered wireless sensors working in HT environments.
基金supported by the National Key R&D Program of China(No.2023YFA1606701)the National Natural Science Foundation of China(Nos.12175042 and 12147101)。
文摘As a cluster overlap amplitude,the reduced-width amplitude is an important physical quantity for analyzing clustering in the nucleus depending on specified channels and has been calculated and widely applied in nuclear cluster physics.In this review,we briefly revisit the theoretical framework for calculating the reduced-width amplitude,as well as the outlines of cluster models to obtain microscopic or semi-microscopic cluster wave functions.We also introduce the recent progress related to cluster overlap amplitudes,including the implementation of cross-section estimation and extension to three-body clustering analysis.Comprehensive examples are provided to demonstrate the application of the reduced-width amplitude in analyzing clustering structures.
基金Project(52174069) supported by the National Natural Science Foundation of ChinaProject(8202033) supported by the Beijing Natural Science Foundation,ChinaProject(KCF2203) supported by the Henan Key Laboratory for Green and Efficient Mining&Comprehensive Utilization of Mineral Resources (Henan Polytechnic University),China。
文摘This work aims to reveal the mechanical responses and energy evolution characteristics of skarn rock under constant amplitude-varied frequency loading paths.Testing results show that the fatigue lifetime,stress−strain responses,deformation,energy dissipation and fracture morphology are all impacted by the loading rate.A pronounced influence of the loading rate on rock deformation is found,with slower loading rate eliciting enhanced strain development,alongside augmented energy absorption and dissipation.In addition,it is revealed that the loading rate and cyclic loading amplitude jointly influence the phase shift distribution,with accelerated rates leading to a narrower phase shift duration.It is suggested that lower loading rate leads to more significant energy dissipation.Finally,the tensile or shear failure modes were intrinsically linked to loading strategy,with cyclic loading predominantly instigating shear damage,as manifest in the increased presence of pulverized grain particles.This work would give new insights into the fortification of mining structures and the optimization of mining methodologies.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12375019 and 11974273)。
文摘The control of adiabatic dynamics is essential for quantum manipulation.We investigate the effects of both periodic modulating field and linear sweeping field on adiabatic dynamics based on a non-reciprocal Landau-Zener model with periodic modulation.We obtain adiabatic phase diagrams in the(ω,δ)parameter space,where the adiabatic region is bounded by the modulating frequencyωgreater than a critical valueω_(c) and the non-reciprocal parameterδless than one.The results show that the adiabaticity of the system is not sensitive to the modulating amplitude.We find that the critical modulating frequency can be expressed as a power function of the modulating period number or the sweeping rate.Our findings suggest that one can change the adiabatic region or improve the adiabaticity by adjusting the parameters of both the modulating and the sweeping fields,which provides an effective means to flexibly control the adiabatic dynamics of non-reciprocal systems.
基金supported by the German Federal Ministry of Education and Research,Research Program Quantum Systems(Grant No.13N16774).
文摘Single-wavelength interferometry achieves high resolution for smooth surfaces but struggles with rough industrially relevant ones due to limited unambiguous measuring range and speckle effects.Multiwavelength interferometry addresses these challenges using synthetic wavelengths,enabling a balance between extended measurement range and resolution by combining several synthetic wavelengths.This approach holds immense potential for diverse industrial applications,yet it remains largely untapped due to the lack of suitable light sources.Existing solutions are constrained by limited flexibility in synthetic-wavelength generation and slow switching speeds.We demonstrate a light source for multiwavelength interferometry based on electro-optic single-sideband modulation.It reliably generates synthetic wavelengths with arbitrary values from centimeters to meters and switching time below 30 ms.This breakthrough paves the way for dynamic reconfigurable multiwavelength interferometry capable of adapting to complex surfaces and operating efficiently even outside laboratory settings.These capabilities unlock the full potential of multiwavelength interferometry,offering unprecedented flexibility and speed for industrial and technological applications.
基金supported by the National Key Research and Development Program of China(2023YFB2603500).
文摘To reveal the effects of environmental and loading conditions, as well as asphalt properties on the nonlinear rheological behavior of asphalt, the large amplitude oscillation shear(LAOS) test was introduced, and the Fourier transform rheology, Lissajous curve method, and the LAOS fatigue test have been applied to investigate the nonlinear rheological behavior of asphalt binders. The research results indicate that a decrease in temperature, an increase in shear frequency and strain level, the introduction of polymer modifiers, and the aging effect of asphalt can significantly increase the nonlinearity of asphalt, manifested by the higher relative magnitude of the third harmonic and zero-strain nonlinear coefficient. For the two polymer modifiers selected in this study, the 4%polyurethane modifier exhibits a higher nonlinear lifting effect than the 4% styrene-butadiene-styrene(SBS). The impact of long-term aging on nonlinear viscoelasticity is observably greater than that of short-term aging. The zero-strain nonlinear coefficient estimated based on the average value method can accurately characterize the nonlinear viscoelasticity of asphalt, which can serve as an effective supplement to the relative magnitude of the third harmonic. All asphalts exhibit shear thinning behavior under the test temperature of 24℃, and the decrease in test temperature, the increase in shear rate and strain level, the introduction of modifiers, and the aging effect of asphalt all exacerbate the shear thinning behavior of asphalt. In addition, the fatigue failure process of asphalt materials is accompanied by an increasing degree of nonlinearity.
基金supported by the National Natural Science Foundation of China(62001481,61890542)the Natural Science Foundation of Hunan Province(2021JJ40686).
文摘Low sidelobe waveform can reduce mutual masking between targets and increase the detection probability of weak targets.A low sidelobe waveform design method based on complementary amplitude coding(CAC)is proposed in this paper,which can be used to reduce the sidelobe level of multiple waveforms.First,the CAC model is constructed.Then,the waveform design problem is transformed into a nonlinear optimization problem by constructing an objective function using the two indicators of peak-to-sidelobe ratio(PSLR)and integrated sidelobe ratio(ISLR).Finally,genetic algorithm(GA)is used to solve the optimization problem to get the best CAC waveforms.Simulations and experiments are conducted to verify the effectiveness of the proposed method.
基金supported by grants from the Tianjin Health Technology Project(Grant No.2022QN106).
文摘Background:The nuclear receptor coactivator(NCOA)family,including NCOA1,NCOA2,and NCOA3,is critical in regulating gene expression through interactions with nuclear receptors and other transcription factors.These coactivators are implicated in various cancers,but their comprehensive roles across different cancer types remain poorly understood.Methods:We performed a pan-cancer bioinformatics analysis using data from The Cancer Genome Atlas and the Genotype-Tissue Expression project.We assessed the differential expression,copy number variations,mutations,methylation status,tumor mutation burden,microsatellite instability,and immune cell infiltration associated with NCOA family members across various cancers.Differential expression analysis was conducted using the DESeq2 package.Methylation data were analyzed using the ChAMP package,and immune cell infiltration was estimated using the CIBERSORT algorithm.Results:NCOA1 and NCOA2 were predominantly downregulated in multiple cancers,suggesting potential tumor suppressor roles,whereas NCOA3 was largely upregulated,indicating a consistent oncogenic function.These expression patterns significantly correlated with patient prognosis.Frequent copy number variations,particularly gains,and high mutation rates were observed in NCOA2.NCOA3 demonstrated consistent hypomethylation in tumors,which was associated with increased gene expression.Significant correlations were found between NCOA expression and tumor mutation burden,microsatellite instability,and immune cell infiltration,indicating their involvement in genomic instability and immune modulation.Conclusion:This comprehensive analysis reveals significant alterations in the expression,genomic,and epigenetic profiles of NCOA family members across various cancers.The findings highlight the multifaceted roles of NCOA1,NCOA2,and NCOA3 in tumorigenesis and their potential as biomarkers and therapeutic targets.Future research should focus on elucidating the mechanisms underlying the associations between NCOA expression,genomic alterations,and immune modulation to develop targeted cancer therapies.
基金supported by the National Key R&D Program of China (No. 2022YFE0204100)the National Natural Science Foundation of China (12205067 and 12375199)the Fundamental Research Funds for the Central Universities (Grant No. HIT.OCEF. 2022036)。
文摘This paper establishes an amplitude modulation heating model, simulating the far-field radiation of ELF/VLF signals generated by modulation heating, as well as the specific location and longitudinal extent of the radiation source. We consider various modulation waveforms and find that square-wave modulation has the highest excitation efficiency for ELF/VLF signals, and that square-wave modulation with a smaller duty cycle(<50%) exhibits higher excitation efficiency for ELF/VLF signals, while the sin^(2)t waveform modulation yields the lowest proportion of harmonic energy in the generated signals. The amplitude of the second harmonic generated by the sin^(2)t waveform is less than one-tenth that of the fundamental frequency, and the energy of higher-frequency harmonics can be negligibly small compared with those of the fundamental wave. It is a challenging task to achieve a balance between enhancing the excitation efficiency of ELF/VLF signals and also suppressing harmonics generated by the modulated heating process. This is because the harmonics are correspondingly enhanced as the excitation efficiency of the signals is increased. However, we find that under conditions of varying effective radiant power and modulation frequency, as long as the modulation waveform is unchanged, the energy ratio between the fundamental frequency signal generated by modulated heating and each harmonic is relatively fixed, with changes only in signal intensity and the location of the radiation source zone. This implies that one can first select modulation waveforms that make the signal less prone to distortion, then increase the effective radiated power to enhance the signal strength, without concern for harmonic interference of the fundamental signal.
基金supported by the National Key Research and Development Program of China (Grant No.2019YFB1803700)the Key Technologies Research and Development Program of Tianjin (Grant No.20YFZCGX00440).
文摘A designed visual geometry group(VGG)-based convolutional neural network(CNN)model with small computational cost and high accuracy is utilized to monitor pulse amplitude modulation-based intensity modulation and direct detection channel performance using eye diagram measurements.Experimental results show that the proposed technique can achieve a high accuracy in jointly monitoring modulation format,probabilistic shaping,roll-off factor,baud rate,optical signal-to-noise ratio,and chromatic dispersion.The designed VGG-based CNN model outperforms the other four traditional machine-learning methods in different scenarios.Furthermore,the multitask learning model combined with MobileNet CNN is designed to improve the flexibility of the network.Compared with the designed VGG-based CNN,the MobileNet-based MTL does not need to train all the classes,and it can simultaneously monitor single parameter or multiple parameters without sacrificing accuracy,indicating great potential in various monitoring scenarios.
基金supported by the National Natural Science Foundation of China under Grant Nos.U2430207,12035002,and 12305258by the CAEP Foundation under Grant No.YZJJZQ2023020.
文摘Large-angle stimulated Raman scattering(LA-SRS)in a longitudinally inhomogeneous plasma with a transverse density modulation is studied using a three-wave coupled model and numerical simulations.The simulations show that the scattering angle of SRS in a longitudinally inhomogeneous plasma can be significantly affected by transverse density modulation.Under transverse density modulation conditions,the laser focuses into underdense regions,owing to the transversely modulated refractive index.The angle of LA-SRS,neither a purely 90° angle side scattering nor purely backscattering,is almost consistent with the specific angle at which the density inhomogeneity vanishes.In modulated plasmas,the nonuniform distribution of laser intensity shifts the regions of scattering and gain compared with those in uniform plasmas,ultimately affecting the laser transmission.SRS is suppressed in weakly modulated regimes,whereas it is enhanced under strong modulation conditions,and a theoretical criterion distinguishing between strong and weak modulation is established.
文摘The development of solid frustrated Lewis pairs(FLPs)catalysts with porous structures is a promising strategy for advancing green hydrogenation technologies and has garnered significant attention.Leveraging the diverse oxidation states and structural tunability of cerium-based metal-organic frameworks(Ce-MOFs),this study employed a competitive coordination strategy utilizing a single carboxylate functional group ligand to construct a series of MOF-808-X(X=-NH_(2),-OH,-Br,and-NO_(2))featuring rich solid-state FLPs for hydrogenation of unsaturated olefins.The-X functional group serves as a microenvironment,enhancing hydrogenation activity by modulating the electronic properties and acid-base characteristics of the FLP sites.The unique redox properties of elemental cerium facilitate the exposure of unsaturated Ce sites(Ce-CUS,Lewis acid(LA))and adjacent Ce-OH(Lewis base(LB))sites within the MOFs,generating abundant solid-state FLP(Ce-CUS/Ce-OH)sites.Experimental results demonstrate that Ce-CUS and Ce-OH interact with theσandσ^(*)orbitals of H-H,and this"push-pull"synergy promotes heterolytic cleavage of the H-H bond.The lone pair electrons of the electron-donating functional group are transmitted through the molecular backbone to the LB site,thereby increasing its strength and reducing the activation energy required for H_(2)heterolytic cleavage.Notably,at 100℃and 2 MPa H_(2),MOF-808-NH_(2)achieves complete conversion of styrene and dicyclopentadiene,significantly outperforming MOF-808.Based on in-situ analysis and density functional theory calculations,a plausible reaction mechanism is proposed.This research enriches the theoretical framework for unsaturated olefin hydrogenation catalysts and contributes to the development of efficient catalytic systems.
基金supported in part by the National Natural Science Fundation of China(52225704 and 52107096).
文摘The dynamics of network power response play a crucial role in system stability.However,the integration of power electronic equipment leads to amplitude and angular frequency(abbreviated as"frequency")time-varying characteristics of the node voltage during dynamic processes.As a result,traditional calcu-lation methods for and characteristics of the power response of the network based on phasor and impe-dance lose their validity.Therefore,this paper undertakes mathematical calculations to reveal the power response of a network under excitation by voltage with time-varying amplitude and frequency(TVAF),relying on the original mathematical relationships and superimposed step response.Then,the multi-timescale characteristics of both the active and reactive power of the network are explored physically.Additionally,this paper reveals a new phenomenon of storing and releasing the active and reactive power of the network.To meet practical engineering requirements,a simplified power expression is presented.Finally,the theoretical analysis is validated through time-domain simulations.
基金the financial support given by National Natural Science Foundation of China(52227808,62202285)the National Science Foundation for Distinguished Young Scholars of China(51725505)+1 种基金the Development Fund for Shanghai Talents(No.2021003)Shanghai Collaborative Innovation Center of Intelligent Perception Chip Technology。
文摘Neuromorphic devices,inspired by the intricate architecture of the human brain,have garnered recognition for their prodigious computational speed and sophisticated parallel computing capabilities.Vision,the primary mode of external information acquisition in living organisms,has garnered substantial scholarly interest.Notwithstanding numerous studies simulating the retina through optical synapses,their applications remain circumscribed to single-mode perception.Moreover,the pivotal role of temperature,a fundamental regulator of biological activities,has regrettably been relegated to the periphery.To address these limitations,we proffer a neuromorphic device endowed with multimodal perception,grounded in the principles of light-modulated semiconductors.This device seamlessly accomplishes dynamic hybrid visual and thermal multimodal perception,featuring temperature-dependent paired pulse facilitation properties and adaptive storage.Crucially,our meticulous examination of transfer curves,capacitance–voltage(C–V)tests,and noise measurements provides insights into interface and bulk defects,elucidating the physical mechanisms underlying adaptive storage and other functionalities.Additionally,the device demonstrates a variety of synaptic functionalities,including filtering properties,Ebbinghaus curves,and memory applications in image recognition.Surprisingly,the digital recognition rate achieves a remarkable value of 98.8%.
基金financially supported by the National Natural Science Foundation of China(No.U22A20253)High-level Talent Doctoral Scientific Research Foundation of Zhoukou Normal University(No.ZKNUC2023027)Young and Middle-Aged Backbone Teachers of Zhoukou Normal University
文摘The steps of NO_(3)^(-)adsorption,deoxygenation,nitrogen species hydrogenation and ammonia desorption are vital for electrocatalytic nitrate reduction(NO_(3)^(-)RR)to ammonia,and lowering their Gibbs free energy change(ΔG)is the essential approach for improving NO_(3)^(-)RR.The copper-based alloys are considered as the outstanding catalysts thanks to the tunable d-band center,reconstruction and synergistic effect of multiple metal atoms in the past decades.Here,we synthesized a single-phase coppernickel alloy by electrodeposition and optimized itsΔG during NO_(3)^(-)RR through tuning the electrodeposition potential to regulate the metal component ratio.The atomic ratio of Ni/Cu in CuNi alloys is gradually increased as the negative shift of deposition potential from-1.0 to-1.2 V versus SCE,thus achieving the fast modulation of intermediate adsorption energy for NO_(3)^(-)RR.According to density functional theory,profited by a strong NO_(3)^(-)adsorption and a weak NH_(3)desorption energy barrier,the optimized CuNi alloy(Cu_(3)Ni_(1)/CF)exhibits an ideal ammonia yield of 364.1μmol cm^(-2)h^(-1)and Faradaic efficiency of 92.25%at-0.23 V versus RHE.Further applying Cu_(3)Ni_(1)/CF as the cathode material,a novel Znnitrate battery exhibits a maximum power density of5.85 mW cm^(-2)with a NH_(3)yield of 92.50μmol cm^(-2)h^(-1)and Faradaic efficiency of 99.15%at 20 mA cm^(-2)for NH_(3)production.This work not only offers a rational design concept with clear guidance for efficient modulation of intermediate adsorption free energy on alloy catalysts prepared by electrodeposition,but also provides the further understanding for efficient developments of NO_(3)^(-)RR and Zn-based batteries.
