The use of Al-V alloys as intermediate additives is pivotal for producing high-performance Ti alloys.Traditionally,the synthesis of these alloys relies on high-purity V_(2)O_(5),with sodium metavanadate as an essentia...The use of Al-V alloys as intermediate additives is pivotal for producing high-performance Ti alloys.Traditionally,the synthesis of these alloys relies on high-purity V_(2)O_(5),with sodium metavanadate as an essential intermediate in V_(2)O_(5)production.This study explores an alternative approach utilizing sodium metavanadate directly,offering an aluminothermic process to alleviate the environmental impact and reduce the time required for V_(2)O_(5)preparation.Al-V alloys are synthesized using sodium metavanadate derived from a shale V-rich solution,and the impurity-migration behaviors are comprehensively analyzed,specifically focusing on Fe,Al,and Na.The result sreveal that Al interacts with CaO to form a slag phase that is different from the alloy,whereas Na undergoes a sequence of reductions (NaVO_(3)→Na_(2)V_(2)O_(5)→NaVO_(2)→Na)and volatilizes at 25-1200℃,thereby avoiding incorporation into the alloy.Fe,reduced by Al,enriches the alloy phase and induces a phase transition(Al-V→Al-Fe→Fe-V)in the presence of excess Fe.Sodium metavanadate(Fe≤0.05wt%)derived from the shale V-rich solution enables the production of a uniform AlV65 alloy with 66.56wt%V,33.14wt%Al,0.08wt%Fe,0.07wt%C,0.02wt%N,and 0.12wt%O.These results establish a streamlined,efficient framework for the future preparation of Al-V alloys from shale V-rich solutions.展开更多
基金funded by the National Key R&D Pro-gram of China (No.2023YFC3903903)the Science and Technology Innovation Talent Program of Hubei Province,China (No.2022EJD002).
文摘The use of Al-V alloys as intermediate additives is pivotal for producing high-performance Ti alloys.Traditionally,the synthesis of these alloys relies on high-purity V_(2)O_(5),with sodium metavanadate as an essential intermediate in V_(2)O_(5)production.This study explores an alternative approach utilizing sodium metavanadate directly,offering an aluminothermic process to alleviate the environmental impact and reduce the time required for V_(2)O_(5)preparation.Al-V alloys are synthesized using sodium metavanadate derived from a shale V-rich solution,and the impurity-migration behaviors are comprehensively analyzed,specifically focusing on Fe,Al,and Na.The result sreveal that Al interacts with CaO to form a slag phase that is different from the alloy,whereas Na undergoes a sequence of reductions (NaVO_(3)→Na_(2)V_(2)O_(5)→NaVO_(2)→Na)and volatilizes at 25-1200℃,thereby avoiding incorporation into the alloy.Fe,reduced by Al,enriches the alloy phase and induces a phase transition(Al-V→Al-Fe→Fe-V)in the presence of excess Fe.Sodium metavanadate(Fe≤0.05wt%)derived from the shale V-rich solution enables the production of a uniform AlV65 alloy with 66.56wt%V,33.14wt%Al,0.08wt%Fe,0.07wt%C,0.02wt%N,and 0.12wt%O.These results establish a streamlined,efficient framework for the future preparation of Al-V alloys from shale V-rich solutions.
