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二价铕离子掺杂碱土金属硫代铝酸盐电子振动耦合参量与发光特性
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作者 张东璞 薛唯 +4 位作者 喻志农 章婷 蒋玉蓉 冷健 孔祥君 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2011年第2期335-339,共5页
为了获得高效的蓝色和绿色的电致发光材料,对Eu2+掺杂的碱土金属硫代铝酸盐电子振动耦合参量与发光特性的关系进行了深入研究。首先简述了用于MⅡAl2S4∶Eu材料发光性能评估的位形坐标模型并引入各评估参量;其次结合材料的晶体结构对MⅡ... 为了获得高效的蓝色和绿色的电致发光材料,对Eu2+掺杂的碱土金属硫代铝酸盐电子振动耦合参量与发光特性的关系进行了深入研究。首先简述了用于MⅡAl2S4∶Eu材料发光性能评估的位形坐标模型并引入各评估参量;其次结合材料的晶体结构对MⅡAl2S4∶Eu材料的光致发光和电致发光性能进行了比较和分析;最后,通过材料的PL光谱曲线计算出材料的特征能量和两个比值因子参量的值,从而得到对MⅡAl2S4∶Eu发光材料的量化比较。根据评估结果和其CIE1931色坐标的比较,可以认为BaAl2S4∶Eu和CaAl2S4∶Eu较适合于作为蓝色和绿色发光材料。由于可以使发射峰发生移动,镁、锶的硫代铝酸盐可以作为复合硫代铝酸盐发光材料使用。 展开更多
关键词 MⅡAl2S4∶Eu 发光特性 晶体结构
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A unified constitutive model for multiphase precipitation and multi-stage creep ageing behavior of Al−Li−S4 alloy 被引量:4
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作者 He LI Li-hua ZHAN +5 位作者 Ming-hui HUANG Xing ZHAO Chang ZHOU Li-bin HU Zheng-gen HU De-bo LIU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2021年第5期1217-1234,共18页
A unified constitutive model is presented to predict the recently observed“multi-stage”creep behavior of Al−Li−S4 alloy.The corresponding microstructural variables related to the yield strength and creep deformation... A unified constitutive model is presented to predict the recently observed“multi-stage”creep behavior of Al−Li−S4 alloy.The corresponding microstructural variables related to the yield strength and creep deformation of the alloy during the creep ageing process,including dislocations and multiple precipitates,have been characterized in detail by X-ray diffraction(XRD)and transmission electron microscopy(TEM).For the yield strength,the model considers the multiphase strengthening behavior of the alloy based on strengthening mechanisms,which includes shearable T1 precipitate strengthening,non-shearable T1 precipitate strengthening andθ′precipitate strengthening.Based on creep deformation mechanism,the“multi-stage”creep behavior of the alloy is predicted by introducing the effects of interacting microstructural variables,including the radius of multiple precipitates,dislocation density and solute concentration,into the creep stress−strain model.It is concluded that the results calculated by the model are in a good agreement with the experimental data,which validates the proposed model. 展开更多
关键词 constitutive modelling Al−Li−S4 alloy creep age forming MICROSTRUCTURES numerical algorithms
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