Al2O3p/Al composite coatings were prepared on the surface of AZ31 magnesium alloy by plasma spraying technology with mixed powders of Al and Al2O3. An orthogonal test containing six factors and five levels was carried...Al2O3p/Al composite coatings were prepared on the surface of AZ31 magnesium alloy by plasma spraying technology with mixed powders of Al and Al2O3. An orthogonal test containing six factors and five levels was carried out to acquire the optimum technical parameters. Mierostruetures and properties of the composite coatings were studied. The results show that the coatings consist of Al2O3 particulates distributed uniformly and Al matrix, and the interface between the particulate and matrix is continuous, compact and clean. With increasing the mass fraction of Al2O3 in the mixed powders, the volume fraction of Al2O3 in the coatings iacreases. The Al2O3p/Al composite coating with 14% Al2O3 volume fraction has more compact microstrueture and more satisfactory properties.展开更多
采用原位反应近液相线铸造方法制备Al2O3P/Al-Cu复合材料,对其进行二次加热,研究晶粒的形貌演变和长大规律。用光学显微镜观察组织结构,应用Image Pro Plus软件测量并统计出平均晶粒尺寸及合金液相体积分数,并与理论计算数值进行比较。...采用原位反应近液相线铸造方法制备Al2O3P/Al-Cu复合材料,对其进行二次加热,研究晶粒的形貌演变和长大规律。用光学显微镜观察组织结构,应用Image Pro Plus软件测量并统计出平均晶粒尺寸及合金液相体积分数,并与理论计算数值进行比较。结果表明,在590℃保温10～60 min后,不含Al2O3颗粒的Al-6.8%Cu基体合金平均晶粒尺寸为89～132μm,液相体积分数为14%～26.8%,而3.6 wt%Al2O3P/Al-6.8%Cu复合材料的平均晶粒尺寸为73-107μm,液相体积分数为11.6%～20.9%。说明Al2O3颗粒在合金的二次加热过程中对晶粒长大行为及液相体积分数的增长均有明显的抑制作用,从而为优化半固态组织提供了一种新思路。展开更多
将Ce添加在Al2O3p/Al复合材料中,采用Axiovert25CA金相显微镜和QUANTA400扫描电镜,研究了Ce含量对Al2O3p/Al复合材料铸态组织的影响。结果表明,Ce的加入可以促进Al2O3颗粒的分散、细化α-Al晶粒、使Al Fe Si由粗大骨骼状变为断续的块状...将Ce添加在Al2O3p/Al复合材料中,采用Axiovert25CA金相显微镜和QUANTA400扫描电镜,研究了Ce含量对Al2O3p/Al复合材料铸态组织的影响。结果表明,Ce的加入可以促进Al2O3颗粒的分散、细化α-Al晶粒、使Al Fe Si由粗大骨骼状变为断续的块状或球状,可以提高复合材料的强度。展开更多
Al2O3p-Al composites were synthesized using an in-situ reaction in the 80%Al-20%CuO （mass fraction） system. The effects of the CuO particle size on the synthesis temperature and microstructure of the composites were...Al2O3p-Al composites were synthesized using an in-situ reaction in the 80%Al-20%CuO （mass fraction） system. The effects of the CuO particle size on the synthesis temperature and microstructure of the composites were investigated by various methods. The results indicate that the CuO particle size has a significant effect on the temperature at which the complete reaction in the Al-CuO system occurs：the temperature is 200 ℃ lower in the Al-CuO system containing CuO particles with sizes less than 6μm than that containing CuO particles with sizes less than 100μm. The interfacial bonding between Al2O3 particles and Al is not complete when the temperature is below a critical value. The morphology of the Al2O3 particles varies from ribbon-like shape to near spherical shape when the temperature is above a critical value. These two critical temperatures are affected by the particle size of CuO, and the critical temperature of the sample containing CuO particles with sizes less than 6μm is 100 ℃ lower than that of the sample containing CuO particles with sizes less than 100μm.展开更多
The microstructural characteristic of 1070AI matrix composites reinforced by 0.15 祄 AI2O3 particles whose volume fraction was 40% was investigated by TEM and HREM. The results showed that the interface between the ma...The microstructural characteristic of 1070AI matrix composites reinforced by 0.15 祄 AI2O3 particles whose volume fraction was 40% was investigated by TEM and HREM. The results showed that the interface between the matrix and reinforcements was clean and bonded well, without any interfacial reaction products. There were some preferential crystallographic orientation relationships between Al matrix and AI2O3 particle because of the lattice imperfection on the surface of Al2O3 particles.展开更多
The interaction between Zn-AI eutectic alloy and Al203p/6061AI composites in the vacuum furnace was investigated. Great attention has been paid to the elements diffusion, the microstructure and formation of the interf...The interaction between Zn-AI eutectic alloy and Al203p/6061AI composites in the vacuum furnace was investigated. Great attention has been paid to the elements diffusion, the microstructure and formation of the interface between Zn-AI eutectic alloy and Al2O3p/6061AI composites. Experimental results show that Zn-AI eutectic alloy has a good wetting ability to Al2O3p/6061 Al composites and the wetting angle decreases with increasing the temperature in vacuum. After the interaction, an interaction layer forms between Zn-AI alloy and Al2O3p/6061 Al composites. The phases in the interaction layer mainly consist of α-AI(Zn), Al2O3 and CuZn5 resulted from the diffusion of elements from the Zn-AI alloy. Several porosities distribute in the region near the interface of the Zn-AI alloy/interaction layer. The amount of shrinkage voids in the interacting layer is relevant to the penetration of Zn element into Al2O3p/6061Al composites which is a function of temperature. So it is necessary to lower heating temperature in order to limit the Zn penetration.展开更多
High-energy ball milling has a great influence on the temperature characters of synthetic reaction in Al-TiO2-C system by changing the size,distribution state and wet ability of reactants.Reaction temperature charact...High-energy ball milling has a great influence on the temperature characters of synthetic reaction in Al-TiO2-C system by changing the size,distribution state and wet ability of reactants.Reaction temperature characters（reaction ignition time,ignition temperature time.the maximum temperature and temperature rising rate）were changed by different milling time.The longer the milling time.the earlier the reaction.the quicker the temperature rise and the higher the maximum temperature.When the milling time exceeded 10 hours,the reactivity of reactants was so high that the synthetic reaction could take place at 850℃ directly without a long time pretreatment at 670℃.The microstructure of synthetic composites became uniform and the reinforced particles（TiC and α-Al2O3）became fine with milling time increasing.展开更多
Two micron SiC particles with angular and spherical shape and the sub-micron Al2O3 particles with spherical shape were introduced to reinforce 6061 aluminium by squeeze casting technology. Microstructures and effect o...Two micron SiC particles with angular and spherical shape and the sub-micron Al2O3 particles with spherical shape were introduced to reinforce 6061 aluminium by squeeze casting technology. Microstructures and effect of thermal-cooling cycle treatment （TCCT） on the thermal expansion behaviors of three composites were investigated. The results show that the composites are free of porosity and SiC/Al2O3 particles are distributed uniformly. Inflections at about 300℃ are observed in coefficient of thermal expansion （CTE） versus temperature curves of two SiCp/Al composites, and this characteristic is not affected by TCCT. The TCCT has significant effect on thermal expansion behavior of SiCp/Al composites and CTE of them after 3 cycles is lower than that of 1 or 5 cycles. However, no inflection is observed in Al2O3p/Al composite, while TCCT has effect on CTE of Al2O3p/Al composite. These results should be due to different relaxation behavior of internal stress in three composites.展开更多
基金This research was supported by Jilin Province Science Foundation （No. 20090552）.
文摘Al2O3p/Al composite coatings were prepared on the surface of AZ31 magnesium alloy by plasma spraying technology with mixed powders of Al and Al2O3. An orthogonal test containing six factors and five levels was carried out to acquire the optimum technical parameters. Mierostruetures and properties of the composite coatings were studied. The results show that the coatings consist of Al2O3 particulates distributed uniformly and Al matrix, and the interface between the particulate and matrix is continuous, compact and clean. With increasing the mass fraction of Al2O3 in the mixed powders, the volume fraction of Al2O3 in the coatings iacreases. The Al2O3p/Al composite coating with 14% Al2O3 volume fraction has more compact microstrueture and more satisfactory properties.
文摘采用原位反应近液相线铸造方法制备Al2O3P/Al-Cu复合材料,对其进行二次加热,研究晶粒的形貌演变和长大规律。用光学显微镜观察组织结构,应用Image Pro Plus软件测量并统计出平均晶粒尺寸及合金液相体积分数,并与理论计算数值进行比较。结果表明,在590℃保温10～60 min后,不含Al2O3颗粒的Al-6.8%Cu基体合金平均晶粒尺寸为89～132μm,液相体积分数为14%～26.8%,而3.6 wt%Al2O3P/Al-6.8%Cu复合材料的平均晶粒尺寸为73-107μm,液相体积分数为11.6%～20.9%。说明Al2O3颗粒在合金的二次加热过程中对晶粒长大行为及液相体积分数的增长均有明显的抑制作用,从而为优化半固态组织提供了一种新思路。
文摘将Ce添加在Al2O3p/Al复合材料中,采用Axiovert25CA金相显微镜和QUANTA400扫描电镜,研究了Ce含量对Al2O3p/Al复合材料铸态组织的影响。结果表明,Ce的加入可以促进Al2O3颗粒的分散、细化α-Al晶粒、使Al Fe Si由粗大骨骼状变为断续的块状或球状,可以提高复合材料的强度。
基金Project(2012MS0801)supported by the Natural Science Foundation of Inner Mongolia,China
文摘Al2O3p-Al composites were synthesized using an in-situ reaction in the 80%Al-20%CuO （mass fraction） system. The effects of the CuO particle size on the synthesis temperature and microstructure of the composites were investigated by various methods. The results indicate that the CuO particle size has a significant effect on the temperature at which the complete reaction in the Al-CuO system occurs：the temperature is 200 ℃ lower in the Al-CuO system containing CuO particles with sizes less than 6μm than that containing CuO particles with sizes less than 100μm. The interfacial bonding between Al2O3 particles and Al is not complete when the temperature is below a critical value. The morphology of the Al2O3 particles varies from ribbon-like shape to near spherical shape when the temperature is above a critical value. These two critical temperatures are affected by the particle size of CuO, and the critical temperature of the sample containing CuO particles with sizes less than 6μm is 100 ℃ lower than that of the sample containing CuO particles with sizes less than 100μm.
基金This research is supported by the National Natural Science Foundation of China (under Grant No.59771014 and No.50071019). The help of the National Advanced Material Open Research Lab of Tsinghua University is gratefully acknowledged.
文摘The microstructural characteristic of 1070AI matrix composites reinforced by 0.15 祄 AI2O3 particles whose volume fraction was 40% was investigated by TEM and HREM. The results showed that the interface between the matrix and reinforcements was clean and bonded well, without any interfacial reaction products. There were some preferential crystallographic orientation relationships between Al matrix and AI2O3 particle because of the lattice imperfection on the surface of Al2O3 particles.
文摘The interaction between Zn-AI eutectic alloy and Al203p/6061AI composites in the vacuum furnace was investigated. Great attention has been paid to the elements diffusion, the microstructure and formation of the interface between Zn-AI eutectic alloy and Al2O3p/6061AI composites. Experimental results show that Zn-AI eutectic alloy has a good wetting ability to Al2O3p/6061 Al composites and the wetting angle decreases with increasing the temperature in vacuum. After the interaction, an interaction layer forms between Zn-AI alloy and Al2O3p/6061 Al composites. The phases in the interaction layer mainly consist of α-AI(Zn), Al2O3 and CuZn5 resulted from the diffusion of elements from the Zn-AI alloy. Several porosities distribute in the region near the interface of the Zn-AI alloy/interaction layer. The amount of shrinkage voids in the interacting layer is relevant to the penetration of Zn element into Al2O3p/6061Al composites which is a function of temperature. So it is necessary to lower heating temperature in order to limit the Zn penetration.
文摘High-energy ball milling has a great influence on the temperature characters of synthetic reaction in Al-TiO2-C system by changing the size,distribution state and wet ability of reactants.Reaction temperature characters（reaction ignition time,ignition temperature time.the maximum temperature and temperature rising rate）were changed by different milling time.The longer the milling time.the earlier the reaction.the quicker the temperature rise and the higher the maximum temperature.When the milling time exceeded 10 hours,the reactivity of reactants was so high that the synthetic reaction could take place at 850℃ directly without a long time pretreatment at 670℃.The microstructure of synthetic composites became uniform and the reinforced particles（TiC and α-Al2O3）became fine with milling time increasing.
基金Project(20080430895) supported by China Postdoctoral Science FoundationProject(2008RFQXG045) supported by Special Fund of Technological Innovation of HarbinProject(HITQNJS.2009.021) supported by Development Program for Outstanding Young Teachers in Harbin Institute of Technology
文摘Two micron SiC particles with angular and spherical shape and the sub-micron Al2O3 particles with spherical shape were introduced to reinforce 6061 aluminium by squeeze casting technology. Microstructures and effect of thermal-cooling cycle treatment （TCCT） on the thermal expansion behaviors of three composites were investigated. The results show that the composites are free of porosity and SiC/Al2O3 particles are distributed uniformly. Inflections at about 300℃ are observed in coefficient of thermal expansion （CTE） versus temperature curves of two SiCp/Al composites, and this characteristic is not affected by TCCT. The TCCT has significant effect on thermal expansion behavior of SiCp/Al composites and CTE of them after 3 cycles is lower than that of 1 or 5 cycles. However, no inflection is observed in Al2O3p/Al composite, while TCCT has effect on CTE of Al2O3p/Al composite. These results should be due to different relaxation behavior of internal stress in three composites.
