The penetration of ladle slag into refractory linings is an essential process in service,and the mechanical properties of the refractory castables are affected by the location and content of slag in the refractory cas...The penetration of ladle slag into refractory linings is an essential process in service,and the mechanical properties of the refractory castables are affected by the location and content of slag in the refractory castables.In this work,ladle slag was added into Al_(2)O_(3)-Mgo refractory castables and its influence on the microstructure evolution,mechanical properties and thermal shock resistance of the castables was investigated.The phase composition and contents of the castables during the corrosion process were calculated by FactSage TM(6.2)and studied.The results indicate that the residual strength decreases as the ladle slag addition increases from 0 to 6 mass%.While the hot modulus of rupture of the castable with 6%ladle slag significantly decreases by approximately 80%compared with the one without ladle slag.The elastic modulus and CMOR of the castables decrease with slag-adding,which leads to the increase of liquid phase contents inside the samples.展开更多
The ineluctable introduction of lithium salt to polymer solid-state electrolytes incurs a compromise between strength,ionic conductivity,and thickness.Here,we propose Al_(2)O_(3)-coated polyimide(AO/PI)porous film as ...The ineluctable introduction of lithium salt to polymer solid-state electrolytes incurs a compromise between strength,ionic conductivity,and thickness.Here,we propose Al_(2)O_(3)-coated polyimide(AO/PI)porous film as a high-strength substrate to support fast-ion-conducting polymer-in-salt(PIS)solid-state electrolytes,aiming to suppress lithium dendrite growth and improve full-cell performance.The Al_(2)O_(3)coating layer not only refines the wettability of polyimide porous film to PIS,but also performs as a high modulus protective layer to suppress the growth of lithium dendrites.The resulting PI/AO@PIS exhibits a small thickness of only 35μm with an outstanding tensile strength of 11.3 MPa and Young's modulus of 537.6 MPa.In addition,the PI/AO@PIS delivers a high ionic conductivity of 0.1 m S/cm at 25°C.As a result,the PI/AO@PIS enables symmetric Li cells to achieve exceptional cyclability for over 1000 h at 0.1 m A/cm2without noticeable lithium dendrite formation.Moreover,the PI/AO@PIS-based LiFePO4||Li full cells demonstrate outstanding rate performance(125.7 m Ah/g at 5 C)and impressive cycling stability(96.1%capacity retention at 1 C after 200 cycles).This work highlights the efficacy of enhancing the mechanical properties of polymer matrices and extending cell performance through the incorporation of a dense inorganic interface layer.展开更多
基金Key Project of the National Natural Science Foundation of China(Grant No.U21A2058)China Postdoctoral Science Foundation(2023M740971)State Key Laboratory of Refractories and Metallurgy(Wuhan University of Science and Technology,G202209).
文摘The penetration of ladle slag into refractory linings is an essential process in service,and the mechanical properties of the refractory castables are affected by the location and content of slag in the refractory castables.In this work,ladle slag was added into Al_(2)O_(3)-Mgo refractory castables and its influence on the microstructure evolution,mechanical properties and thermal shock resistance of the castables was investigated.The phase composition and contents of the castables during the corrosion process were calculated by FactSage TM(6.2)and studied.The results indicate that the residual strength decreases as the ladle slag addition increases from 0 to 6 mass%.While the hot modulus of rupture of the castable with 6%ladle slag significantly decreases by approximately 80%compared with the one without ladle slag.The elastic modulus and CMOR of the castables decrease with slag-adding,which leads to the increase of liquid phase contents inside the samples.
基金the financial support from the 261Project of MIIT and Natural Science Foundation of Jiangsu Province(No.BK20240179)。
文摘The ineluctable introduction of lithium salt to polymer solid-state electrolytes incurs a compromise between strength,ionic conductivity,and thickness.Here,we propose Al_(2)O_(3)-coated polyimide(AO/PI)porous film as a high-strength substrate to support fast-ion-conducting polymer-in-salt(PIS)solid-state electrolytes,aiming to suppress lithium dendrite growth and improve full-cell performance.The Al_(2)O_(3)coating layer not only refines the wettability of polyimide porous film to PIS,but also performs as a high modulus protective layer to suppress the growth of lithium dendrites.The resulting PI/AO@PIS exhibits a small thickness of only 35μm with an outstanding tensile strength of 11.3 MPa and Young's modulus of 537.6 MPa.In addition,the PI/AO@PIS delivers a high ionic conductivity of 0.1 m S/cm at 25°C.As a result,the PI/AO@PIS enables symmetric Li cells to achieve exceptional cyclability for over 1000 h at 0.1 m A/cm2without noticeable lithium dendrite formation.Moreover,the PI/AO@PIS-based LiFePO4||Li full cells demonstrate outstanding rate performance(125.7 m Ah/g at 5 C)and impressive cycling stability(96.1%capacity retention at 1 C after 200 cycles).This work highlights the efficacy of enhancing the mechanical properties of polymer matrices and extending cell performance through the incorporation of a dense inorganic interface layer.
