The influences of applied magnetic field on the corrosion behavior of Al-3.0 wt%Mg alloy in 3.5 wt% NaCl solution were investigated by electrochemical measurements,scanning electron microscopy(SEM)and energy-dispers...The influences of applied magnetic field on the corrosion behavior of Al-3.0 wt%Mg alloy in 3.5 wt% NaCl solution were investigated by electrochemical measurements,scanning electron microscopy(SEM)and energy-dispersive spectroscopy(EDS).Stochastic analysis was applied to investigate the influences of applied magnetic field.The results indicate that the application of horizontal magnetic field of 0.4 T would increase the pitting corrosion potential(E_(pit)),decrease the corrosion current density(i_(corr)),prolong the pit initiation time,slow down the pit generation rate and inhibit the growth of pitting of the tested alloys in 3.5 wt% NaCl solution.The applied magnetic field would also change the mechanism of pit initiation of Al-3.0 wt%Mg alloy from A_3 model(without magnetic field)to A_3+A_4 model(with magnetic field).The intermediate product Al_((ad))~+ is the paramagnetic ion that would be influenced by magnetic field sensitively.展开更多
The effect of Li(2.0 wt%)addition on mechanical properties and ageing precipitation behavior of Al-3.0 Mg 0.5 Si was investigated by tensile test,dynamic elasticity modulus test,scanning electron microscopy(SEM),trans...The effect of Li(2.0 wt%)addition on mechanical properties and ageing precipitation behavior of Al-3.0 Mg 0.5 Si was investigated by tensile test,dynamic elasticity modulus test,scanning electron microscopy(SEM),transmission electron microscopy(TEM)and high-resolution transmission electron microscopy(HRTEM)images.The results show that the tensile strength of the Li-containing alloy can be significantly improved;however,the ductility is sharply decreased and the fracture mechanism changes from ductile fracture to intergranular fracture.The elasticity modulus of the Li-containing alloy increases by 11.6%compared with the base alloy.The microstructure observation shows that the Li addition can absolutely change the precipitation behavior of the base alloy,andδ′-Al_(3)Li phase becomes the main precipitates.Besides,β′′-Mg_(2)Si andδ′-Al_(3)Li dual phases precipitation can be visibly observed at 170℃ ageing for 100 h,although the quantity ofδ′-Al_(3)Li phase is more thanβ′′-Mg_(2)Si phase.The width of the precipitate-free zone(PFZ)of the Li-containing alloy is much wider at the over-ageing state than the base alloy,which has a negative impact on the ductile and results in the decrease of elongation.展开更多
The influences of rare earth elements(cerium and lanthanum) on the microstructure and phases of Al-3.0 wt%Mg alloys used for electromagnetic shielding wire were characterized by scanning electron microscopy(SEM), ...The influences of rare earth elements(cerium and lanthanum) on the microstructure and phases of Al-3.0 wt%Mg alloys used for electromagnetic shielding wire were characterized by scanning electron microscopy(SEM), energy-dispersive spectroscopy(EDS), X-ray diffraction(XRD) and differential scanning calorimetry(DSC). The mechanical properties and electrical resistivity were also investigated. The results indicated that a certain content of rare earth could improve the purification of the aluminum molten, enhance the strength, and reduce the electrical resistivity of Al-3.0 wt%Mg alloys. The strength reached the top value when RE content was 0.3 wt% while the alloy with 0.2 wt% RE addition had the smallest electrical resistivity. The elongation varied little when RE addition was no more than 0.2 wt%. But the excessive addition of rare earth would be harmful to the microstructure and properties of Al-3.0 wt%Mg alloys.展开更多
The hot deformation behavior of Ti-3.0Al-3.7Cr-2.0Fe-0.1B (TACFB) titanium alloy was investigated using a Gleeble-1500D thermal simulator in the temperature range of 800-950 °C, at constant strain rate from 0.01 ...The hot deformation behavior of Ti-3.0Al-3.7Cr-2.0Fe-0.1B (TACFB) titanium alloy was investigated using a Gleeble-1500D thermal simulator in the temperature range of 800-950 °C, at constant strain rate from 0.01 s-1 to 10 s-1 and with height reduction of 70%. Flow stress and microstructure evolution during hot compression of TACFB alloy were investigated. The processing map of TACFB alloy was obtained. The results indicate that the hot deformation behavior of TACFB alloy is sensitive to the deformation temperature and strain rate. The peak flow stress decreases with increasing the test temperature and decreasing the strain rate. The constitutive relationship of TACFB alloy was obtained on the base of Arrhenius equations. When the strain rates are higher than 1.0 s-1, the dynamic recrystallization occurs, and the higher the strain rates are, the more the recrystallization is.展开更多
基金financially supported by the National Natural Science Foundation of China(No.51379070)the Fundamental Research Funds for the Central Universities(No.2014B31714)
文摘The influences of applied magnetic field on the corrosion behavior of Al-3.0 wt%Mg alloy in 3.5 wt% NaCl solution were investigated by electrochemical measurements,scanning electron microscopy(SEM)and energy-dispersive spectroscopy(EDS).Stochastic analysis was applied to investigate the influences of applied magnetic field.The results indicate that the application of horizontal magnetic field of 0.4 T would increase the pitting corrosion potential(E_(pit)),decrease the corrosion current density(i_(corr)),prolong the pit initiation time,slow down the pit generation rate and inhibit the growth of pitting of the tested alloys in 3.5 wt% NaCl solution.The applied magnetic field would also change the mechanism of pit initiation of Al-3.0 wt%Mg alloy from A_3 model(without magnetic field)to A_3+A_4 model(with magnetic field).The intermediate product Al_((ad))~+ is the paramagnetic ion that would be influenced by magnetic field sensitively.
基金Project(2016YFB0300802)supported by the National Key Research and Development Program of China。
文摘The effect of Li(2.0 wt%)addition on mechanical properties and ageing precipitation behavior of Al-3.0 Mg 0.5 Si was investigated by tensile test,dynamic elasticity modulus test,scanning electron microscopy(SEM),transmission electron microscopy(TEM)and high-resolution transmission electron microscopy(HRTEM)images.The results show that the tensile strength of the Li-containing alloy can be significantly improved;however,the ductility is sharply decreased and the fracture mechanism changes from ductile fracture to intergranular fracture.The elasticity modulus of the Li-containing alloy increases by 11.6%compared with the base alloy.The microstructure observation shows that the Li addition can absolutely change the precipitation behavior of the base alloy,andδ′-Al_(3)Li phase becomes the main precipitates.Besides,β′′-Mg_(2)Si andδ′-Al_(3)Li dual phases precipitation can be visibly observed at 170℃ ageing for 100 h,although the quantity ofδ′-Al_(3)Li phase is more thanβ′′-Mg_(2)Si phase.The width of the precipitate-free zone(PFZ)of the Li-containing alloy is much wider at the over-ageing state than the base alloy,which has a negative impact on the ductile and results in the decrease of elongation.
基金Funded by the National Natural Science Foundation of China(No.51379070)the Fundamental Research Funds for the Central Universities(No.2017B40314)
文摘The influences of rare earth elements(cerium and lanthanum) on the microstructure and phases of Al-3.0 wt%Mg alloys used for electromagnetic shielding wire were characterized by scanning electron microscopy(SEM), energy-dispersive spectroscopy(EDS), X-ray diffraction(XRD) and differential scanning calorimetry(DSC). The mechanical properties and electrical resistivity were also investigated. The results indicated that a certain content of rare earth could improve the purification of the aluminum molten, enhance the strength, and reduce the electrical resistivity of Al-3.0 wt%Mg alloys. The strength reached the top value when RE content was 0.3 wt% while the alloy with 0.2 wt% RE addition had the smallest electrical resistivity. The elongation varied little when RE addition was no more than 0.2 wt%. But the excessive addition of rare earth would be harmful to the microstructure and properties of Al-3.0 wt%Mg alloys.
基金Project (2010DFA52280) supported by International Science and Technology CooperationProject (20100470260) supported by China Postdoctoral Science Foundation
文摘The hot deformation behavior of Ti-3.0Al-3.7Cr-2.0Fe-0.1B (TACFB) titanium alloy was investigated using a Gleeble-1500D thermal simulator in the temperature range of 800-950 °C, at constant strain rate from 0.01 s-1 to 10 s-1 and with height reduction of 70%. Flow stress and microstructure evolution during hot compression of TACFB alloy were investigated. The processing map of TACFB alloy was obtained. The results indicate that the hot deformation behavior of TACFB alloy is sensitive to the deformation temperature and strain rate. The peak flow stress decreases with increasing the test temperature and decreasing the strain rate. The constitutive relationship of TACFB alloy was obtained on the base of Arrhenius equations. When the strain rates are higher than 1.0 s-1, the dynamic recrystallization occurs, and the higher the strain rates are, the more the recrystallization is.