运用CALPHAD技术,基于多组元多相复杂平衡体系的吉布斯自由能最小化原理,用大型集成数据库F A C T系统,考察了铝和氧化铁经典反应体系的热力学规律。针对材料的反应合成技术,计算了化学计量铝和氧化铁体系以及各种产物中物种的相变情况...运用CALPHAD技术,基于多组元多相复杂平衡体系的吉布斯自由能最小化原理,用大型集成数据库F A C T系统,考察了铝和氧化铁经典反应体系的热力学规律。针对材料的反应合成技术,计算了化学计量铝和氧化铁体系以及各种产物中物种的相变情况;分析了原料初始温度、配料比和SiO2含量对绝热温度和平衡组成的影响。展开更多
Using a liquid-solid phase inversion method, a hybrid matrix poly（vinylidene fluoride）（PVDF） membrane was prepared with alumina（Al2O3） nanoparticle addition. Pd/Fe nanoparticles（NPs） were successfully immobili...Using a liquid-solid phase inversion method, a hybrid matrix poly（vinylidene fluoride）（PVDF） membrane was prepared with alumina（Al2O3） nanoparticle addition. Pd/Fe nanoparticles（NPs） were successfully immobilized on the Al2O3/PVDF membrane, which was characterized by Scanning Electron Microscopy（SEM） and Transmission Electron Microscopy（TEM）. The micrographs showed that the Pd/Fe NPs were dispersed homogeneously. Several important experimental parameters were optimized, including the mechanical properties, contact angle and surface area of Al2O3/PVDF composite membranes with different Al2O3 contents. At the same time, the ferrous ion concentration and the effect of hydrophilization were studied. The results showed that the modified Al2O3/PVDF membrane functioned well as a support. The Al2O3/PVDF membrane with immobilized Pd/Fe NPs exhibited high efficiency in terms of dichloroacetic acid（DCAA） dechlorination. Additionally, a reaction pathway for DCAA dechlorination by Pd/Fe NPs immobilized on the Al2O3/PVDF membrane system was proposed.展开更多
文摘运用CALPHAD技术,基于多组元多相复杂平衡体系的吉布斯自由能最小化原理,用大型集成数据库F A C T系统,考察了铝和氧化铁经典反应体系的热力学规律。针对材料的反应合成技术,计算了化学计量铝和氧化铁体系以及各种产物中物种的相变情况;分析了原料初始温度、配料比和SiO2含量对绝热温度和平衡组成的影响。
基金supported by the Nature Science Foundation of Heilongjiang Province (No. B201410)the Postdoctoral Foundation Project of Heilongjiang Province (No. LBH-Z13128)+3 种基金the Science and Technology Research Program of Education Bureau of Heilongjiang Province (No. 12531206)the Special Scientific Research Projects of Harbin Normal University (12XQXG02)the National Nature Science Foundation of China (No. 41030743)the National Nature Science Foundation of China (No. 42171217)
文摘Using a liquid-solid phase inversion method, a hybrid matrix poly（vinylidene fluoride）（PVDF） membrane was prepared with alumina（Al2O3） nanoparticle addition. Pd/Fe nanoparticles（NPs） were successfully immobilized on the Al2O3/PVDF membrane, which was characterized by Scanning Electron Microscopy（SEM） and Transmission Electron Microscopy（TEM）. The micrographs showed that the Pd/Fe NPs were dispersed homogeneously. Several important experimental parameters were optimized, including the mechanical properties, contact angle and surface area of Al2O3/PVDF composite membranes with different Al2O3 contents. At the same time, the ferrous ion concentration and the effect of hydrophilization were studied. The results showed that the modified Al2O3/PVDF membrane functioned well as a support. The Al2O3/PVDF membrane with immobilized Pd/Fe NPs exhibited high efficiency in terms of dichloroacetic acid（DCAA） dechlorination. Additionally, a reaction pathway for DCAA dechlorination by Pd/Fe NPs immobilized on the Al2O3/PVDF membrane system was proposed.
