1.Introduction The strength-ductility trade-offdilemma has long been a per-sistent challenge in Al matrix composites(AMCs)[1,2].This is-sue primarily arises from the agglomeration of reinforcements at the grain bounda...1.Introduction The strength-ductility trade-offdilemma has long been a per-sistent challenge in Al matrix composites(AMCs)[1,2].This is-sue primarily arises from the agglomeration of reinforcements at the grain boundaries(GBs),which restricts local plastic flow dur-ing the plastic deformation and leads to stress concentration[3,4].Recently,the development of concepts aimed at achieving hetero-geneous grain has emerged as a promising approach for enhanc-ing comprehensive mechanical properties[5,6].展开更多
To improve the wettability of Al metal matrix composites（Al-MMCs） by common filler metals,Al-12Si-xTi（x=0.1,0.5,1,3.0;mass fraction,%） system active ternary filler metals were prepared.It was demonstrated that alt...To improve the wettability of Al metal matrix composites（Al-MMCs） by common filler metals,Al-12Si-xTi（x=0.1,0.5,1,3.0;mass fraction,%） system active ternary filler metals were prepared.It was demonstrated that although the added Ti existed within Ti（Al1-xSix）3（0≤x≤0.15） phase,the shear strength and shear fracture surface of the developed Al-12Si-xTi brazes were quite similar to those of traditional Al-12Si braze due to the presence of similar microstructure of Al-Si eutectic microstructure with large volume fraction.So,small Ti addition（～1%） did not make the active brazes brittle and hard compared with the conventional Al-12Si braze.The measured melting range of each Al-12Si-xTi foil was very similar,i.e.,580-590 ℃,because the composition was close to that of eutectic.For wettability improvement,with increasing Ti content,the interfacial gap between the Al2O3 reinforcement and filler metal（R/M） could be eliminated,and the amount of the remainder of the active fillers on the composite substrate decreased after sessile drop test at 610 ℃ for 30 min.So,the wettability improvement became easy to observe repeatedly with increasing Ti content.Additionally,the amount and size of Ti（AlSi）3 phase were sensitive to the Ti content（before brazing） and Si content（after brazing）.展开更多
Cold spraying(CS),or cold gas dynamic spray(CGDS),is an emerging solid-state powder deposition process,allowing fast and mass production and restoration of metallic components.CS of metal matrix composites(MMCs)has at...Cold spraying(CS),or cold gas dynamic spray(CGDS),is an emerging solid-state powder deposition process,allowing fast and mass production and restoration of metallic components.CS of metal matrix composites(MMCs)has attracted increasing attention from academia and industry over the last decades,especially in the area of Al matrix composites(AMCs),which have demonstrated a high potential for applications in aerospace,automotive,and electronics industries.This article aims to summarize the recent development of CS-processed AMCs in terms of composite powder preparation,deposition processing,microstructure evolution,mechanical and corrosion properties.Furthermore,this review also reports the relevant research progress with the focus on post-treatments of the AMCs for CS additive manufacturing applications including heat treatment,hot rolling,and friction stir processing.Finally,the challenges and perspectives on the fabrication of advanced AMCs by CS are addressed.展开更多
The microstructures and interface structures of basalt particle reinforced 7A04 Al matrix composites (BP/7A04 Al) were analyzed by using OM, TEM, SEM and EDS, and the mechanical properties of 7A04 Al alloy were compar...The microstructures and interface structures of basalt particle reinforced 7A04 Al matrix composites (BP/7A04 Al) were analyzed by using OM, TEM, SEM and EDS, and the mechanical properties of 7A04 Al alloy were compared with those of BP/7A04 Al matrix composites. The results show that the basalt particles are dispersed in the Al matrix and form a strong bonding interface with the Al matrix. SiO2 at the edge of the basalt particles is continuously replaced by Al2O3 formed in the reaction, forming a high-temperature reaction layer with a thickness of several tens of nanometers, and Al2O3 strengthens the bonding interface between basalt particles and Al matrix. The dispersed basalt particles promote the dislocation multiplication, vacancy formation and precipitation of the matrix, and the precipitated phases mainly consist of plate-like η(MgZn2) phase and bright white band-shaped or ellipsoidal T (Al2Mg3Zn3) phase. The bonding interface, high dislocation density and dispersion strengthening phase significantly improve the mechanical properties of the composites. The yield strength and ultimate tensile strength of BP/7A04 Al matrix composites are up to 665 and 699 MPa, which increase by 11.4% and 10.9% respectively compared with 7A04 Al alloy without basalt particles.展开更多
A B_(4)C@amorphous carbon(APC)/Al matrix composite was fabricated by using hydrothermal carbonized deposition on chips(HTCDC)process and solid-state synthesis process.The microstructure and mechanical properties of th...A B_(4)C@amorphous carbon(APC)/Al matrix composite was fabricated by using hydrothermal carbonized deposition on chips(HTCDC)process and solid-state synthesis process.The microstructure and mechanical properties of the B_(4)C@APC/Al matrix composite were investigated.After HTCDC process,nano-B_(4)C particles(50 nm)and micron-sized B_(4)C@APC core-shell spheres with a diameter of 2μm were found in the composites.The microhardness of the micron-sized B_(4)C@APC spheres is 1.66 GPa,which is greater than that of theα-Al matrix(1.06 GPa).Dislocation accumulation is observed around the micron-sized B_(4)C@APC spheres,indicating that the micron-sized B_(4)C@APC spheres have a strengthening effect on theα-Al matrix.Due to the formation of micron-sized B_(4)C@APC spheres,the reinforcement of nano-B_(4)C particles into the composites is transformed from single-sized particle enhancement to bimodal-sized particle enhancement.The strengthening mechanism for B_(4)C@APC/Al matrix composites with bimodalsized particles of nano-B_(4)C and micron-sized B_(4)C@APC spheres were analyzed,which includes thermal mismatch strengthening generated by the mismatch of coefficient of thermal expansion(CTE)between micron-sized B_(4)C@APC core-shell spheres andα-Al matrix,Orowan strengthening produced by nano-B_(4)C particles,Hall-Petch strengthening and load transfer strengthening produced by the bimodal-sized enhancement from nano and microspheres.A relationship model between the yield strength(YS)increment and the conversion rate(x)of micron-sized B_(4)C@APC core-shell spheres was estimated.展开更多
The influences of volume fraction and particle size of SiC particulate reinforcements on the corrosion characteristics of SiCp/2024 Al metal matrix composites in aerated 3.5 wt pct NaCI aqueous solution were investiga...The influences of volume fraction and particle size of SiC particulate reinforcements on the corrosion characteristics of SiCp/2024 Al metal matrix composites in aerated 3.5 wt pct NaCI aqueous solution were investigated. The electrochemical behavior was investigated by potentiodynamic polarization and electrochemical impedance spectroscopy, the general corrosion behavior of the composites was studied further by immersion tests. The results showed that pitting susceptibility was about the same for the composites and the alloy. The corrosion potentials were also independent of SiC phase. The corrosion resistance for the composites decreased as the volume fraction increased or particle size decreased.展开更多
The 2024 Al composites containing W, Ta were fabricated by powder metallurgy for their potential use as shielding material. W, Ta powders and gas-atomized 2024 Al aluminum powders were mixed by a ball mixer. The mixtu...The 2024 Al composites containing W, Ta were fabricated by powder metallurgy for their potential use as shielding material. W, Ta powders and gas-atomized 2024 Al aluminum powders were mixed by a ball mixer. The mixtures were consolidated by cold isostatic pressing (CIP) and then hot-extruded into full-density bars. The extruded bars were heat treated in T6 conditions. The microstructure and its relationship with the mechanical properties were investigated by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results show that the particles of nonuniform size and irregular shape randomly disperse in the 2024 aluminum alloy matrix. The tensile tests show that an increase of tensile strength and decrease of elongation to failure of the heat treated composites compared with the extruded composites.展开更多
The damping properties were improved by preparing Al matrix composites reinforced with glass cenospheres through the pressure infiltration method.Transmission electron microscopy and scanning electron microscopy were ...The damping properties were improved by preparing Al matrix composites reinforced with glass cenospheres through the pressure infiltration method.Transmission electron microscopy and scanning electron microscopy were employed to characterize the microstructure of the composites.The low-frequency damping properties were examined by using a dynamic mechanical thermal analyzer,aiming at exploring the changing trend of damping capacity with strain,temperature,and frequency.The findings demonstrated that the damping value rose as temperature and strain increased,with a maximum value of 0.15.Additionally,the damping value decreased when the frequency increased.Dislocation damping under strain and interfacial damping under temperature served as the two primary damping mechanisms.The increase in the density of dislocation strong pinning points following heat treatment reduced the damping value,which was attributed to the heat treatment enhancement of the interfacial bonding force of the composites.展开更多
Ti-coated SiCp particles were developed by vacuum evaporation with Ti to improve the interfacial bonding of SiCp/Al composites.Ti-coated SiC particles and uncoated SiC particles reinforced Al 2519 matrix composites we...Ti-coated SiCp particles were developed by vacuum evaporation with Ti to improve the interfacial bonding of SiCp/Al composites.Ti-coated SiC particles and uncoated SiC particles reinforced Al 2519 matrix composites were prepared by hot pressing,hot extrusion and heat treatment.The influence of Ti coating on microstructure and mechanical properties of the composites was analyzed by scanning electron microscopy(SEM)and energy dispersive spectroscopy(EDS).The results show that the densely deposited Ti coating reacts with SiC particles to form TiC and Ti5Si3 phases at the interface.Ti-coated SiC particle reinforced composite exhibits uniformity and compactness compared to the composite reinforced with uncoated SiC particles.The microstructure,relative density and mechanical properties of the composite are significantly improved.When the volume fraction is 15%,the hardness,fracture strain and tensile strength of the SiCp reinforced Al 2519 composite after Ti plating are optimized,which are HB 138.5,4.02%and 455 MPa,respectively.展开更多
50%diamond particle （5μm） reinforced 2024 aluminum matrix （diamond/2024 Al） composites were prepared by pressure infiltration method. Diamond particles were distributed uniformly without any particle clustering, ...50%diamond particle （5μm） reinforced 2024 aluminum matrix （diamond/2024 Al） composites were prepared by pressure infiltration method. Diamond particles were distributed uniformly without any particle clustering, and no apparent porosities or significant casting defects were observed in the composites. The diamond-Al interfaces of as-cast and annealed diamond/2024 Al composites were clean, smooth and free from interfacial reaction product. However, a large number of Al2Cu precipitates were found at diamond-Al interface after aging treatment. Moreover, needle-shaped Al2MgCu precipitates in Al matrix were observed after aging treatment. The coefficient of thermal expansion （CTE） of diamond/2024 Al composites was about 8.5×10-6 °C-1 between 20 and 100 °C, which was compatible with that with chip materials. Annealing treatment showed little effect on thermal expansion behavior, and aging treatment could further decrease the CTE of the composites. The thermal conductivity of obtained diamond/2024 Al composites was about 100 W/（m？K）, and it was slightly increased after annealing while decreased after aging treatment.展开更多
Al alloy matrix composites reinforced with copper-coated graphite particle have been prepared by melt stirring process in this work.The effect of the addition of Mg on distribution of the graphite particles has been i...Al alloy matrix composites reinforced with copper-coated graphite particle have been prepared by melt stirring process in this work.The effect of the addition of Mg on distribution of the graphite particles has been investigated.Scanning electron microscopy （SEM） was used to observe the micro-morphology of Al alloy matrix composites reinforced with graphite particles.Meanwhile,the content of graphite was analyzed in the different position of casting by dissolution method and the mechanical properties of the composites were detected.The results show that the content of graphite increase with increasing Mg content;the graphite particles distribute uniformly in the particle reinforced metal matrix composites （PMMC） with 0.6 wt pct Mg;however,the agglomeration of the graphite particles is observed obviously in the matrix when Mg content is more than 1.0 wt pct.In addition,the proper Mg addition amount is beneficial to enhance the mechanical properties of the graphite particles reinforced Al alloy matrix composites and the abrasion resistance of the materials due to a reduce friction coefficient.展开更多
It is showed that there are Ti 3Al, Ti 2Cu and β phase in the interface of Ti/Ti Al composites reinforced with Y 2O 3 Cr composite soft coated Ti fiber, and that interface bonding is intact. Bending strength ...It is showed that there are Ti 3Al, Ti 2Cu and β phase in the interface of Ti/Ti Al composites reinforced with Y 2O 3 Cr composite soft coated Ti fiber, and that interface bonding is intact. Bending strength of the composites can be increased by 26%, to 709 MPa, and bending deflection increased slightly compared with the Ti/Ti Al composites reinforced by Ti fibers coated with Y 2O 3.展开更多
The main Iimitation to the toughening of the α-Al2O3/Ni composite is the poor bonding atthe interface. which causes the nickel particles to be pulled-out during crack propagation with-out obvious plastic deformation....The main Iimitation to the toughening of the α-Al2O3/Ni composite is the poor bonding atthe interface. which causes the nickel particles to be pulled-out during crack propagation with-out obvious plastic deformation. A proper control of oxygen content at the Al2O3-Ni interfacecan promote wetting at the intedece, and produce a mechanically interlocked and chemically strengthened intedece, causing most of the nickel particles to be stretched to failure and to expe-rience severe plastic deformation during crack propagation in the composite. Fracture toughnesstesting using a modified double cantilever beam method with in situ observation of crack prop-agation in a scanning electron microscope shows that the composite with the strengthenedinterface has a more desirable R-curve behaviour and a higher fracture toughness value than thenormal composite.展开更多
This article studies the effects of the CeCl3 concentrations in conversion solutions with and without addition of NaCl, pH-values of conversion solution, drying temperature, time and temperature of immersion on the Ce...This article studies the effects of the CeCl3 concentrations in conversion solutions with and without addition of NaCl, pH-values of conversion solution, drying temperature, time and temperature of immersion on the Ce-conversion coatings for corrosion protection of the SiCp/5A06 Al-MMC and 5A06 Al-alloy in the 3.5% NaCl aqueous solution at room temperature. Potentiodynamic polarization tests reveal that the Ce-conversion treatment could markedly improve the pitting corrosion resistance of the composite and the matrix alloy in chloride containing environment. The best corrosion resistance effects are obtained for the samples treatment in 1% CeCl3.7H2O/3.5% NaCl solution at 45℃ for 60 min, followed by drying at 100 ℃ for 30 min. Examinations by means of scanning electron microscopy （SEM）, energy dispersion spectroscopy （EDS） and X-ray photoelectron spectroscopy （XPS） indicate that this behavior is due to the precipitation of Ce-oxides/hydroxides on the cathodic intermetallics and the Al-oxide film on the rest of the metal matrix.展开更多
The carbon nanotubes(CNTs) reinforced Al-Cu matrix composites were prepared by hot pressing sintering and hot rolling, and the effects of Cu content on the interfacial reaction between Al and CNTs, the precipitation b...The carbon nanotubes(CNTs) reinforced Al-Cu matrix composites were prepared by hot pressing sintering and hot rolling, and the effects of Cu content on the interfacial reaction between Al and CNTs, the precipitation behavior of Cu-containing precipitates, and the resultant mechanical properties of the composites were systematically investigated. The results showed that the increase of Cu content can not only increase the number and size of Cu-containing precipitate generated during the composite fabrication processes, but also promote the interfacial reaction between CNTs and Al matrix, leading to the intensified conversion of CNTs into Al_(4)C_(3). As a result, the composite containing 1 wt.% Cu possesses the highest strength, elastic modulus and hardness among all composites, due to the maintenance of the original structure of CNTs. Moreover, the increase of Cu content can change the dominant strengthening mechanisms for the enhanced strength of the fabricated composites.展开更多
The in situ Al 2O 3p TiC p/Al composite was fabricated by XD (exothermic dispersion) process in TiO 2 Al C system, and the effect of carbon content on the microstructure of the fabricated composite and the reactive te...The in situ Al 2O 3p TiC p/Al composite was fabricated by XD (exothermic dispersion) process in TiO 2 Al C system, and the effect of carbon content on the microstructure of the fabricated composite and the reactive temperature characteristics had been studied. The results show that carbon content affects the microstructure and reactive temperature of Al 2O 3p TiC p/Al composite greatly. The quantity of TiC phases in the fabricated composites increases, while the Al 3Ti phases reduces with increasing carbon content. And when C/TiO 2 molecular ratio is equal to one, the Al 3Ti phase nearly disappears. High temperature metallurgical field caused by strong exothermic reaction influences the synthetic reaction greatly, and higher synthetic temperature was favorable to the synthesis of Al 2O 3p TiC p reinforce particles.展开更多
6061Al matrix composites reinforced by ZnO-coated Al18B4O33 whiskers were fabricated by a semi-solid mechanical stirring technique.The effects of ZnO coating on interfacial reaction between whiskers and matrix and the...6061Al matrix composites reinforced by ZnO-coated Al18B4O33 whiskers were fabricated by a semi-solid mechanical stirring technique.The effects of ZnO coating on interfacial reaction between whiskers and matrix and the tensile properties of the composites were investigated.Tensile tests on composites were performed at room temperature,and microstructures were observed by scanning electron microscopy(SEM).The results show that the surface treatment of whiskers could reduce interfacial reaction effectively,improve the wettability between whiskers and matrix and enhance the tensile properties of the composites obviously.In addition,semi-solid stirring parameters were also under preliminary study.The stirring parameters were determined by the distribution of whiskers in the composites.The composites with homogeneously distributed whiskers were fabricated by semi-solid stirring at 610 ℃ for 30 min.展开更多
Three groups of AlSiTiCrNiCu high entropy alloy(HEA)particles reinforced Al606l composites were fabricated by spark plasma sintering at 520 and 570℃(S520,S570)and by hot-pressed sintering at 570℃(H570).The AlSiTiCrN...Three groups of AlSiTiCrNiCu high entropy alloy(HEA)particles reinforced Al606l composites were fabricated by spark plasma sintering at 520 and 570℃(S520,S570)and by hot-pressed sintering at 570℃(H570).The AlSiTiCrNiCu(AST)particles used as reinforcements were synthesized by mechanical alloying.The influences of the sintering process on the microstructure and mechanical properties of composites were investigated.The results showed that the AST particles had a near-equiatomic composition with a single BCC structure.The sintering temperature and time had a coupling influence on the interfacial microstructure.S520 had hardly reaction products and slight interfacial diffusion,and the AST particles were completely high entropy.Intense interfacial reactions happened on S570 and H570 with the same reaction products.The element diffusion of S570 was focused on the edge of the AST particles with partial loss of high entropy.Complete element diffusion and entire loss of high entropy of AST particles happened on H570.The differences in the microstructure caused by the three preparation methods led to the changes in mechanical properties and fracture mechanisms of composites.展开更多
In the present work, the wire electrical discharge machining（WEDM） process of the 65 vol% SiCp/2024 Al composite prepared by pressure infiltration methods has been investigated. The microstructure of the machined co...In the present work, the wire electrical discharge machining（WEDM） process of the 65 vol% SiCp/2024 Al composite prepared by pressure infiltration methods has been investigated. The microstructure of the machined composite was characterized by scanning electron microscope, the average surface roughness（Ra）, X-ray diffraction, X-ray photoelectron spectroscopy and transmission electron microscopy（TEM） techniques. Three zones from the surface to the interior（melting zone, heat affected zone and un-affected zone） were found in the machined composites, while the face of SiC particles on the surface toward the outside was ‘‘cut＇＇ to be flat. Increase in Al and Si but decrease in C and O were observed in the core areas of the removed particles. Si phase, which was generated due to the decomposition of SiC, was detected after the WEDM process. The irregular and spherical particles were further observed by TEM. Based on the microstructure observation, it is suggested that the machining mechanism of 65 vol% SiCp/2024 Al composite was the combination of the melting of Al matrix and the decomposition of SiC particles.展开更多
Mixed Al-Si and Al-Cu powders were investigated as insert layers to reactive diffusion bond SiCp/6063 metal matrix composite （MMC）. The results show that SiCp/6063 MMC joints bonded by the insert layers of the mixed...Mixed Al-Si and Al-Cu powders were investigated as insert layers to reactive diffusion bond SiCp/6063 metal matrix composite （MMC）. The results show that SiCp/6063 MMC joints bonded by the insert layers of the mixed Al-Si and Al-Cu powders have a dense joining layer of high quality. The mass transfer between the bonded materials and insert layers during bonding leads to the hypoeutectic microstructure of the joining layers bonded by both the mixed Al-Si and Al-Cu powders with eutectic composition. At fixed bonding time （temperature）, the shear strength of the joints by both insert layers of the mixed Al-Si and Al-Cu powders increases with increasing the bonding temperature （time）, but get maxima at bonding temperature 600℃ （time 90 min）.展开更多
基金support by the National Natural Science Foundation of China(Grant Nos.U23A20546 and 52271010)the Chinese National Natural Science Fund for Distinguished Young Scholars(Grant No.52025015)the Natural Science Foundation of Tianjin City(No.21JCZDJC00510).
文摘1.Introduction The strength-ductility trade-offdilemma has long been a per-sistent challenge in Al matrix composites(AMCs)[1,2].This is-sue primarily arises from the agglomeration of reinforcements at the grain boundaries(GBs),which restricts local plastic flow dur-ing the plastic deformation and leads to stress concentration[3,4].Recently,the development of concepts aimed at achieving hetero-geneous grain has emerged as a promising approach for enhanc-ing comprehensive mechanical properties[5,6].
基金Project(50875199) supported by the National Natural Science Foundation of ChinaProject supported by State Key Laboratory of Advanced Welding and Joining,China
文摘To improve the wettability of Al metal matrix composites（Al-MMCs） by common filler metals,Al-12Si-xTi（x=0.1,0.5,1,3.0;mass fraction,%） system active ternary filler metals were prepared.It was demonstrated that although the added Ti existed within Ti（Al1-xSix）3（0≤x≤0.15） phase,the shear strength and shear fracture surface of the developed Al-12Si-xTi brazes were quite similar to those of traditional Al-12Si braze due to the presence of similar microstructure of Al-Si eutectic microstructure with large volume fraction.So,small Ti addition（～1%） did not make the active brazes brittle and hard compared with the conventional Al-12Si braze.The measured melting range of each Al-12Si-xTi foil was very similar,i.e.,580-590 ℃,because the composition was close to that of eutectic.For wettability improvement,with increasing Ti content,the interfacial gap between the Al2O3 reinforcement and filler metal（R/M） could be eliminated,and the amount of the remainder of the active fillers on the composite substrate decreased after sessile drop test at 610 ℃ for 30 min.So,the wettability improvement became easy to observe repeatedly with increasing Ti content.Additionally,the amount and size of Ti（AlSi）3 phase were sensitive to the Ti content（before brazing） and Si content（after brazing）.
基金financial support of the Chinese Scholarship Council(No.201604490100)UniversitéBourgogne-Franche-Comté,and Centre National de la Recherche Scientifique(CNRS)+2 种基金supported by the Conseil Régional du Nord-Pas de Calaisthe European Regional Development Fund(ERDF)financial support from the National Natural Science Foundation of China(No.51875471)。
文摘Cold spraying(CS),or cold gas dynamic spray(CGDS),is an emerging solid-state powder deposition process,allowing fast and mass production and restoration of metallic components.CS of metal matrix composites(MMCs)has attracted increasing attention from academia and industry over the last decades,especially in the area of Al matrix composites(AMCs),which have demonstrated a high potential for applications in aerospace,automotive,and electronics industries.This article aims to summarize the recent development of CS-processed AMCs in terms of composite powder preparation,deposition processing,microstructure evolution,mechanical and corrosion properties.Furthermore,this review also reports the relevant research progress with the focus on post-treatments of the AMCs for CS additive manufacturing applications including heat treatment,hot rolling,and friction stir processing.Finally,the challenges and perspectives on the fabrication of advanced AMCs by CS are addressed.
基金Projects(2019JJ60050,2018JJ3121) supported by the Natural Science Foundation of Hunan Province,ChinaProject(KFBM20170004) supported by the Jiangsu Province Key Laboratory of Materials Surface Science and Technology,China
文摘The microstructures and interface structures of basalt particle reinforced 7A04 Al matrix composites (BP/7A04 Al) were analyzed by using OM, TEM, SEM and EDS, and the mechanical properties of 7A04 Al alloy were compared with those of BP/7A04 Al matrix composites. The results show that the basalt particles are dispersed in the Al matrix and form a strong bonding interface with the Al matrix. SiO2 at the edge of the basalt particles is continuously replaced by Al2O3 formed in the reaction, forming a high-temperature reaction layer with a thickness of several tens of nanometers, and Al2O3 strengthens the bonding interface between basalt particles and Al matrix. The dispersed basalt particles promote the dislocation multiplication, vacancy formation and precipitation of the matrix, and the precipitated phases mainly consist of plate-like η(MgZn2) phase and bright white band-shaped or ellipsoidal T (Al2Mg3Zn3) phase. The bonding interface, high dislocation density and dispersion strengthening phase significantly improve the mechanical properties of the composites. The yield strength and ultimate tensile strength of BP/7A04 Al matrix composites are up to 665 and 699 MPa, which increase by 11.4% and 10.9% respectively compared with 7A04 Al alloy without basalt particles.
基金financially supported by the National Natural Science Foundation of China(No.51704087)the Natural Science Foundation of Heilongjiang Province(No.LH2020E083)。
文摘A B_(4)C@amorphous carbon(APC)/Al matrix composite was fabricated by using hydrothermal carbonized deposition on chips(HTCDC)process and solid-state synthesis process.The microstructure and mechanical properties of the B_(4)C@APC/Al matrix composite were investigated.After HTCDC process,nano-B_(4)C particles(50 nm)and micron-sized B_(4)C@APC core-shell spheres with a diameter of 2μm were found in the composites.The microhardness of the micron-sized B_(4)C@APC spheres is 1.66 GPa,which is greater than that of theα-Al matrix(1.06 GPa).Dislocation accumulation is observed around the micron-sized B_(4)C@APC spheres,indicating that the micron-sized B_(4)C@APC spheres have a strengthening effect on theα-Al matrix.Due to the formation of micron-sized B_(4)C@APC spheres,the reinforcement of nano-B_(4)C particles into the composites is transformed from single-sized particle enhancement to bimodal-sized particle enhancement.The strengthening mechanism for B_(4)C@APC/Al matrix composites with bimodalsized particles of nano-B_(4)C and micron-sized B_(4)C@APC spheres were analyzed,which includes thermal mismatch strengthening generated by the mismatch of coefficient of thermal expansion(CTE)between micron-sized B_(4)C@APC core-shell spheres andα-Al matrix,Orowan strengthening produced by nano-B_(4)C particles,Hall-Petch strengthening and load transfer strengthening produced by the bimodal-sized enhancement from nano and microspheres.A relationship model between the yield strength(YS)increment and the conversion rate(x)of micron-sized B_(4)C@APC core-shell spheres was estimated.
文摘The influences of volume fraction and particle size of SiC particulate reinforcements on the corrosion characteristics of SiCp/2024 Al metal matrix composites in aerated 3.5 wt pct NaCI aqueous solution were investigated. The electrochemical behavior was investigated by potentiodynamic polarization and electrochemical impedance spectroscopy, the general corrosion behavior of the composites was studied further by immersion tests. The results showed that pitting susceptibility was about the same for the composites and the alloy. The corrosion potentials were also independent of SiC phase. The corrosion resistance for the composites decreased as the volume fraction increased or particle size decreased.
文摘The 2024 Al composites containing W, Ta were fabricated by powder metallurgy for their potential use as shielding material. W, Ta powders and gas-atomized 2024 Al aluminum powders were mixed by a ball mixer. The mixtures were consolidated by cold isostatic pressing (CIP) and then hot-extruded into full-density bars. The extruded bars were heat treated in T6 conditions. The microstructure and its relationship with the mechanical properties were investigated by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results show that the particles of nonuniform size and irregular shape randomly disperse in the 2024 aluminum alloy matrix. The tensile tests show that an increase of tensile strength and decrease of elongation to failure of the heat treated composites compared with the extruded composites.
基金financially supported by the National Key Research and Development Program of China(No.2022YFE0121400)the National Natural Science Foundation of China(Nos.52071117,52111530297,51601047)+1 种基金the Heilongjiang Provincial Science Fund for Distinguished Young Scholars,China(No.JQ2021E002)the Guangdong Basic and Applied Basic Research Foundation,China(No.2022B1515120016)。
文摘The damping properties were improved by preparing Al matrix composites reinforced with glass cenospheres through the pressure infiltration method.Transmission electron microscopy and scanning electron microscopy were employed to characterize the microstructure of the composites.The low-frequency damping properties were examined by using a dynamic mechanical thermal analyzer,aiming at exploring the changing trend of damping capacity with strain,temperature,and frequency.The findings demonstrated that the damping value rose as temperature and strain increased,with a maximum value of 0.15.Additionally,the damping value decreased when the frequency increased.Dislocation damping under strain and interfacial damping under temperature served as the two primary damping mechanisms.The increase in the density of dislocation strong pinning points following heat treatment reduced the damping value,which was attributed to the heat treatment enhancement of the interfacial bonding force of the composites.
基金Project(CXZZ20140506150310438)supported by the Science and Technology Program of Shenzhen,ChinaProject(2017GK2261)supported by the Science and Technology Program of Hunan Province,ChinaProject(2017zzts111)supported by the Fundamental Research Funds for the Central Universities of Central South University,China。
文摘Ti-coated SiCp particles were developed by vacuum evaporation with Ti to improve the interfacial bonding of SiCp/Al composites.Ti-coated SiC particles and uncoated SiC particles reinforced Al 2519 matrix composites were prepared by hot pressing,hot extrusion and heat treatment.The influence of Ti coating on microstructure and mechanical properties of the composites was analyzed by scanning electron microscopy(SEM)and energy dispersive spectroscopy(EDS).The results show that the densely deposited Ti coating reacts with SiC particles to form TiC and Ti5Si3 phases at the interface.Ti-coated SiC particle reinforced composite exhibits uniformity and compactness compared to the composite reinforced with uncoated SiC particles.The microstructure,relative density and mechanical properties of the composite are significantly improved.When the volume fraction is 15%,the hardness,fracture strain and tensile strength of the SiCp reinforced Al 2519 composite after Ti plating are optimized,which are HB 138.5,4.02%and 455 MPa,respectively.
基金Project (AWJ-M13-15) supported by the Open Fund of State Key Laboratory of Advanced Welding and Joining,Harbin Institute of Technology,China
文摘50%diamond particle （5μm） reinforced 2024 aluminum matrix （diamond/2024 Al） composites were prepared by pressure infiltration method. Diamond particles were distributed uniformly without any particle clustering, and no apparent porosities or significant casting defects were observed in the composites. The diamond-Al interfaces of as-cast and annealed diamond/2024 Al composites were clean, smooth and free from interfacial reaction product. However, a large number of Al2Cu precipitates were found at diamond-Al interface after aging treatment. Moreover, needle-shaped Al2MgCu precipitates in Al matrix were observed after aging treatment. The coefficient of thermal expansion （CTE） of diamond/2024 Al composites was about 8.5×10-6 °C-1 between 20 and 100 °C, which was compatible with that with chip materials. Annealing treatment showed little effect on thermal expansion behavior, and aging treatment could further decrease the CTE of the composites. The thermal conductivity of obtained diamond/2024 Al composites was about 100 W/（m？K）, and it was slightly increased after annealing while decreased after aging treatment.
基金supported financially by the National Natural Science Foundation of China (No. 50774021)the Ministry of Science and Technology of China (No.2008AA03Z512)
文摘Al alloy matrix composites reinforced with copper-coated graphite particle have been prepared by melt stirring process in this work.The effect of the addition of Mg on distribution of the graphite particles has been investigated.Scanning electron microscopy （SEM） was used to observe the micro-morphology of Al alloy matrix composites reinforced with graphite particles.Meanwhile,the content of graphite was analyzed in the different position of casting by dissolution method and the mechanical properties of the composites were detected.The results show that the content of graphite increase with increasing Mg content;the graphite particles distribute uniformly in the particle reinforced metal matrix composites （PMMC） with 0.6 wt pct Mg;however,the agglomeration of the graphite particles is observed obviously in the matrix when Mg content is more than 1.0 wt pct.In addition,the proper Mg addition amount is beneficial to enhance the mechanical properties of the graphite particles reinforced Al alloy matrix composites and the abrasion resistance of the materials due to a reduce friction coefficient.
文摘It is showed that there are Ti 3Al, Ti 2Cu and β phase in the interface of Ti/Ti Al composites reinforced with Y 2O 3 Cr composite soft coated Ti fiber, and that interface bonding is intact. Bending strength of the composites can be increased by 26%, to 709 MPa, and bending deflection increased slightly compared with the Ti/Ti Al composites reinforced by Ti fibers coated with Y 2O 3.
文摘The main Iimitation to the toughening of the α-Al2O3/Ni composite is the poor bonding atthe interface. which causes the nickel particles to be pulled-out during crack propagation with-out obvious plastic deformation. A proper control of oxygen content at the Al2O3-Ni interfacecan promote wetting at the intedece, and produce a mechanically interlocked and chemically strengthened intedece, causing most of the nickel particles to be stretched to failure and to expe-rience severe plastic deformation during crack propagation in the composite. Fracture toughnesstesting using a modified double cantilever beam method with in situ observation of crack prop-agation in a scanning electron microscope shows that the composite with the strengthenedinterface has a more desirable R-curve behaviour and a higher fracture toughness value than thenormal composite.
文摘This article studies the effects of the CeCl3 concentrations in conversion solutions with and without addition of NaCl, pH-values of conversion solution, drying temperature, time and temperature of immersion on the Ce-conversion coatings for corrosion protection of the SiCp/5A06 Al-MMC and 5A06 Al-alloy in the 3.5% NaCl aqueous solution at room temperature. Potentiodynamic polarization tests reveal that the Ce-conversion treatment could markedly improve the pitting corrosion resistance of the composite and the matrix alloy in chloride containing environment. The best corrosion resistance effects are obtained for the samples treatment in 1% CeCl3.7H2O/3.5% NaCl solution at 45℃ for 60 min, followed by drying at 100 ℃ for 30 min. Examinations by means of scanning electron microscopy （SEM）, energy dispersion spectroscopy （EDS） and X-ray photoelectron spectroscopy （XPS） indicate that this behavior is due to the precipitation of Ce-oxides/hydroxides on the cathodic intermetallics and the Al-oxide film on the rest of the metal matrix.
基金The financial supports from the National Natural Science Foundation of China (Nos. 52004101 and 52071269)the Chinese Postdoctoral Science Foundation (No. 2020T130246)+2 种基金the Fund of the State Key Laboratory of Solidification Processing in NWPU, China (No. SKLSP202121)the Guangdong Basic and Applied Basic Research Foundation, China (No. 2020A1515110621)the Fundamental Research Funds for the Central Universities, China (No. 11620345)。
文摘The carbon nanotubes(CNTs) reinforced Al-Cu matrix composites were prepared by hot pressing sintering and hot rolling, and the effects of Cu content on the interfacial reaction between Al and CNTs, the precipitation behavior of Cu-containing precipitates, and the resultant mechanical properties of the composites were systematically investigated. The results showed that the increase of Cu content can not only increase the number and size of Cu-containing precipitate generated during the composite fabrication processes, but also promote the interfacial reaction between CNTs and Al matrix, leading to the intensified conversion of CNTs into Al_(4)C_(3). As a result, the composite containing 1 wt.% Cu possesses the highest strength, elastic modulus and hardness among all composites, due to the maintenance of the original structure of CNTs. Moreover, the increase of Cu content can change the dominant strengthening mechanisms for the enhanced strength of the fabricated composites.
文摘The in situ Al 2O 3p TiC p/Al composite was fabricated by XD (exothermic dispersion) process in TiO 2 Al C system, and the effect of carbon content on the microstructure of the fabricated composite and the reactive temperature characteristics had been studied. The results show that carbon content affects the microstructure and reactive temperature of Al 2O 3p TiC p/Al composite greatly. The quantity of TiC phases in the fabricated composites increases, while the Al 3Ti phases reduces with increasing carbon content. And when C/TiO 2 molecular ratio is equal to one, the Al 3Ti phase nearly disappears. High temperature metallurgical field caused by strong exothermic reaction influences the synthetic reaction greatly, and higher synthetic temperature was favorable to the synthesis of Al 2O 3p TiC p reinforce particles.
基金Project(2006CB605203-3) supported by the National Basic Research Program of China
文摘6061Al matrix composites reinforced by ZnO-coated Al18B4O33 whiskers were fabricated by a semi-solid mechanical stirring technique.The effects of ZnO coating on interfacial reaction between whiskers and matrix and the tensile properties of the composites were investigated.Tensile tests on composites were performed at room temperature,and microstructures were observed by scanning electron microscopy(SEM).The results show that the surface treatment of whiskers could reduce interfacial reaction effectively,improve the wettability between whiskers and matrix and enhance the tensile properties of the composites obviously.In addition,semi-solid stirring parameters were also under preliminary study.The stirring parameters were determined by the distribution of whiskers in the composites.The composites with homogeneously distributed whiskers were fabricated by semi-solid stirring at 610 ℃ for 30 min.
基金Funded by the National Natural Science Foundation of China(Nos.52071117,51771063)the Heilongjiang Provincial Science Fund for Distinguished Young Scholars(No.JQ2021E002)
文摘Three groups of AlSiTiCrNiCu high entropy alloy(HEA)particles reinforced Al606l composites were fabricated by spark plasma sintering at 520 and 570℃(S520,S570)and by hot-pressed sintering at 570℃(H570).The AlSiTiCrNiCu(AST)particles used as reinforcements were synthesized by mechanical alloying.The influences of the sintering process on the microstructure and mechanical properties of composites were investigated.The results showed that the AST particles had a near-equiatomic composition with a single BCC structure.The sintering temperature and time had a coupling influence on the interfacial microstructure.S520 had hardly reaction products and slight interfacial diffusion,and the AST particles were completely high entropy.Intense interfacial reactions happened on S570 and H570 with the same reaction products.The element diffusion of S570 was focused on the edge of the AST particles with partial loss of high entropy.Complete element diffusion and entire loss of high entropy of AST particles happened on H570.The differences in the microstructure caused by the three preparation methods led to the changes in mechanical properties and fracture mechanisms of composites.
基金supported by the National Natural Science Foundation of China(No.51501047)China Postdoctoral Science Foundation(No.2016M590280)the Fundamental Research Funds for the Central Universities(Nos.HIT.NSRIF.20161,HIT.MKSTISP.201615)
文摘In the present work, the wire electrical discharge machining（WEDM） process of the 65 vol% SiCp/2024 Al composite prepared by pressure infiltration methods has been investigated. The microstructure of the machined composite was characterized by scanning electron microscope, the average surface roughness（Ra）, X-ray diffraction, X-ray photoelectron spectroscopy and transmission electron microscopy（TEM） techniques. Three zones from the surface to the interior（melting zone, heat affected zone and un-affected zone） were found in the machined composites, while the face of SiC particles on the surface toward the outside was ‘‘cut＇＇ to be flat. Increase in Al and Si but decrease in C and O were observed in the core areas of the removed particles. Si phase, which was generated due to the decomposition of SiC, was detected after the WEDM process. The irregular and spherical particles were further observed by TEM. Based on the microstructure observation, it is suggested that the machining mechanism of 65 vol% SiCp/2024 Al composite was the combination of the melting of Al matrix and the decomposition of SiC particles.
基金the National Natural Science Foundation of China under grant No.50175004
文摘Mixed Al-Si and Al-Cu powders were investigated as insert layers to reactive diffusion bond SiCp/6063 metal matrix composite （MMC）. The results show that SiCp/6063 MMC joints bonded by the insert layers of the mixed Al-Si and Al-Cu powders have a dense joining layer of high quality. The mass transfer between the bonded materials and insert layers during bonding leads to the hypoeutectic microstructure of the joining layers bonded by both the mixed Al-Si and Al-Cu powders with eutectic composition. At fixed bonding time （temperature）, the shear strength of the joints by both insert layers of the mixed Al-Si and Al-Cu powders increases with increasing the bonding temperature （time）, but get maxima at bonding temperature 600℃ （time 90 min）.
