The catalytic activity and durability of Rh/ZrO2 catalyst were investigated compared with Rh/Al2O3 catalyst under diverse aging atmospheres, including lean, rich and lean–rich cyclic aging atmospheres, to simulate th...The catalytic activity and durability of Rh/ZrO2 catalyst were investigated compared with Rh/Al2O3 catalyst under diverse aging atmospheres, including lean, rich and lean–rich cyclic aging atmospheres, to simulate the real working conditions of three-way catalyst.Oxidation states and microstructures of rhodium species were investigated to correlate with the catalytic performance of the catalysts. The catalytic performance and durability of the Rh catalyst under diverse aging atmospheres were drastically enhanced by ZrO2 support. ZrO2 support was confirmed to be able to effectively inhibit rhodium sintering even under diverse aging conditions. It can also successfully keep Rh species in an active low-valence state on the surface of the catalyst. The superiority of ZrO2 support compared to Al2O3 was verified by the Rh-based monolith catalyst.展开更多
Bitumen Stabilized Materials (BSMs) are widely recognized as environmentally friendly through significantly reduced energy consumption,reduced emissions and reuse of high percentage of RAP and recycled pavement materi...Bitumen Stabilized Materials (BSMs) are widely recognized as environmentally friendly through significantly reduced energy consumption,reduced emissions and reuse of high percentage of RAP and recycled pavement materials. In order for these materials to be cost effective,their life-cycle performance needs to be proven. Durability of BSMs is a long-term phenomena that requires consideration during mix design. Time is very important variable for performance consideration under field conditions. The factors that influence durability and long-term performance of BSMs include the mineral aggregates,binder and mixture compositions. In this study,the important,but less understood aspects of durability properties of BSMs were investigated. These include wear and tear of mineral aggregates,age-hardening of binder (foamed bitumen and bitumen emulsion) and moisture susceptibility of typical mix composition. The wear and tear was investigated using Durability Mill Index (DMI) test,binder ageing was investigated for short and long-term effect,and moisture susceptibility was investigated by pulsing water pressures using new device i.e. moisture induction simulation test (MIST). The accelerated moisture conditioning simulates field conditions whereafter retained shear properties are evaluated. The results found that durability of mineral aggregates is significantly influences by the type and nature of mineral composition. The ageing of binder occurred in both short and long-term conditions,with short-term effects being dominating the foamed bitumen properties during laboratory production. Moisture susceptibility is significantly influenced by the mix compositions of aggregates blends with and without RAP,with different bitumen binder types (foamed bitumen or bitumen emulsion) and active filler type (cement or lime) and contents. The evaluation and ranking of mixes which are resistant and susceptible to moisture damage was done using retained cohesion (RC) after dry and wet monotonic triaxial testing.展开更多
In this study, we employed a nonthermal atmospheric pressure plasma(NTAPP) jet to evaluate the effect of plasma treatment on the durability of resin–dentin bonding under a thermocycling challenge. Furthermore, we ass...In this study, we employed a nonthermal atmospheric pressure plasma(NTAPP) jet to evaluate the effect of plasma treatment on the durability of resin–dentin bonding under a thermocycling challenge. Furthermore, we assessed the degradation resistance of plasma-treated collagen under a sodium hypochlorite(NaClO) challenge. We assessed the beneficial effect of NTAPP treatment on the acid-etched dentin–bonding interface by testing the micro-tensile bond strength and examining the morphology. We found that the immediate bonding strength of the dentin significantly increased after NTAPP treatment. Compared with the control group, NTAPP resulted in a more prominent effect on the bonding durability of the dentin–adhesive interface after treatment for 5 or 10 s. Simultaneously, the mechanical strength of dentin collagen under the NaClO challenge was improved. Our results indicate that, in optimal conditions, NTAPP could be a promising method to protect dentin collagen and to improve the bonding durability between dentin and etch-and-rinse adhesives.展开更多
Although timber was used extensively as a structural material for traditional buildings in Turkey in the past, usage of structural timber decreased significantly over time and timber has been largely replaced by other...Although timber was used extensively as a structural material for traditional buildings in Turkey in the past, usage of structural timber decreased significantly over time and timber has been largely replaced by other materials. As timber is a natural, durable and sustainable material, it would be desirable to re-introduce timber structural elements to contemporary construction in a form that is appealing to industry. Timber-glass composite structural elements are potentially a good candidate for this purpose. To that end, a series of tests were conducted on load-bearing timber-glass composites in order to understand the long-term structural performance of the composite material under atmospheric conditions;to decrease the recurring cost of repair and maintenance;and to minimize the exhaustion of raw materials and energy. In this paper, the first part of this experimental work is presented, which focuses on the durability of timber-glass composite under the effects of accelerated aging, carried out on small-sized timber-glass composite specimens. Accelerated aging effects were observed under wetting-drying, freezing-thawing, UV effects, resistance to acids and high temperature. The mechanical strength of the timber-glass composite specimens before and after the effect of accelerated aging was measured by adhesion and shear strength tests and a comparative analysis of the results was carried out. The results of the experiments indicate that timber-glass composite is suitable to be used under protection from environmental conditions.展开更多
Inhalation of atmospheric PM_(2.5)can induce the generation of excessive reactive oxygen species(ROS)in human alveoli,triggering local and systemic inflammation,which can directly or indirectly result in respiratory a...Inhalation of atmospheric PM_(2.5)can induce the generation of excessive reactive oxygen species(ROS)in human alveoli,triggering local and systemic inflammation,which can directly or indirectly result in respiratory and cardiovascular diseases.In this study,we assessed the oxidative potential(OP)of fresh and O_(3)-aged PM_(2.5)particles from various urban and rural emission sources using the dithiothreitol(DTT)method.Our results revealed variations in the OP of fresh PM_(2.5)among different emission sources,with biomass burning sources exhibiting the highest OP,followed by industrial areas,vehicular emissions,cooking emissions,and suburban areas,respectively.Water-soluble organics and transition metals might potentially exert significant influence on particle OP.O_(3)aging notably decreased the OP of PM_(2.5)particles,possibly due to the oxidation of highly DTT-active components into low redox-active small molecules.Moreover,the evolution of OP in different PM_(2.5)components,including methanol-soluble and insoluble fractions,exhibited distinct responses to O_(3)aging for source-oriented PM_(2.5).Additionally,differences in chemical composition between fresh and aged PM_(2.5)were further elucidated through measurements of component-dependent hygroscopic behaviors and phase transitions.This study systematically delineates variances in the toxic potential of fresh and O_(3)-aged PM_(2.5)from various anthropogenic sources.The findings highlight the intrinsic compositional dependence of particle OP and provide essential insights for assessing the health effects of source-oriented PM_(2.5),as well as for formulating human health protection policies.展开更多
Polymer nanocomposite coatings(PNCCs)are unprecedented generation of coatings engineered for displaying inexpensive and brilliant functional surface coatings with eminent corrosion guard,mechanical resistance,antimicr...Polymer nanocomposite coatings(PNCCs)are unprecedented generation of coatings engineered for displaying inexpensive and brilliant functional surface coatings with eminent corrosion guard,mechanical resistance,antimicrobial,chemical durability,electrical insulation,and UV aging features.Due to their widely anticipation in petroleum,applications in building,conveyance,aerospace,electronics,automobiles and energy,these multi-functional coatings have a tremendous leverage in human life,all technological and scientific subjects.Numerous applications have been made for multilateral polymers like polyurethane(PU),epoxy(EP),polyaniline(PANI)conductive polymer,polypyrrole(PPy),and etc,on various metallic surfaces especially,carbon steel substrate owing to their excellent resistance properties.Practically,nanomaterials can possess potential in the all-interdisciplinary domains of materials science and engineering,chemical and physical sciences,biological and health sciences.As known,the designed polymer nanocomposite coating paradigm is fundamentally constituted from polymer or resin as a vehicle and inorganic nanofillers(nanoparticles and nanocomposites).Some commercialized and excessively employed nanocontainers in polymer nanocomposite coating formulations,like ZnO,TiO_(2),carbon nanotubes(CNTs),clay,SiO_(2),Al_(2)O_(3),graphene,GO,CeO_(2),ZrO_(2),FeTiO_(3),etc were discussed.The current review covered the chemistry and potential applications of the largest utilized multifunctional polymer nanocomposite coatings such as EP,PU and other considerable PNCCs.Lately,a titanic attention was made for epoxy nanocomposites because of their distinct physicochemical characteristics,which result from the combined qualities of the nanoparticles and polymer material unity.In addition,the author incorporated some of his scientific contributions in this area represented in construction of innovative functional polymer nanocomposites for a variety of uses with high economic,industrial impacts and future orientation.Furthermore,some newly published applications of polymer nanocomposite coatings were incorporated and discussed.展开更多
The contact angle of liquid Ag with solid W and its temperature dependance were examined by sessile drop method under various atmospheres,e.g.vacuum,Ar,H_2 and carcked NH_3.The O_2 partial pressure in the atmosphere i...The contact angle of liquid Ag with solid W and its temperature dependance were examined by sessile drop method under various atmospheres,e.g.vacuum,Ar,H_2 and carcked NH_3.The O_2 partial pressure in the atmosphere is found to be the major factor. An obvious improvement on the wettability may be made by a trace amount of Ni,Cu or Ce added to liquid Ag,The contact angle near M.P.is then narrowed from 69 to about 10—20 deg.展开更多
Dynamic strain aging (DSA) is an important phenomenon in solutehardened metals and seri- ously affects the mechanical properties ofmetals. DSA is generally induced by the interaction between themoving dislocations and...Dynamic strain aging (DSA) is an important phenomenon in solutehardened metals and seri- ously affects the mechanical properties ofmetals. DSA is generally induced by the interaction between themoving dislocations and the mobile solute atoms. In this paper, onlythe interaction between moving disloca- tions and mobile solute atomsin a dislocation core area (core atmosphere) will be taken intoaccount. To es- tablish the constitutive model which can describe theDSA phenomenon, we improved the Zerilli-Armstrongdislocation-mechanics-based thermal viscoplastic constitutiverelation, and added the effect of the interaction between the movingdislocations and core atmosphere.展开更多
The results of atmospheric pressure plasma treatments using diffuse coplanar surface barrier discharge (type of surface dielectric barrier discharge) on chromium surfaces are reported. A significant increase of surfac...The results of atmospheric pressure plasma treatments using diffuse coplanar surface barrier discharge (type of surface dielectric barrier discharge) on chromium surfaces are reported. A significant increase of surface wettability was observed after short plasma exposition. A quantitative value of surface wettability, i.e. the surface free energy, changed from 29 mJ/m2 to over 80 mJ/m2. In time, a hydrophobic recovery of the plasma treated surfaces was observed. Careful study by surface free energy measurements and x-ray photoelectron spectroscopy was performed to be able explaining the effects of plasma treatment. Studied samples were treated in air, oxygen and nitrogen plasma and aged in air and vacuum. Main reasons for increased wettability and aging effect are surface cleaning and transformations in chromium oxide. Additionally, generation of surface nitrate groups was found on the chromium surface as a result of plasma treatment in humid air.展开更多
In this paper, we report the modification of polyethylene(45 μm in thickness) webs through a roll-to-roll dielectric barrier discharge plasma treatment in an open atmospheric environment.Our work differs from the nor...In this paper, we report the modification of polyethylene(45 μm in thickness) webs through a roll-to-roll dielectric barrier discharge plasma treatment in an open atmospheric environment.Our work differs from the normal adopted corona discharge treatment at an atmospheric pressure, in that three monomers: allylamine, acrylic acid, and ethanol, are inlet into the discharge zone by argon(Ar) carrier gas. As a comparison, Ar plasma treatment is also carried out. We focus on the aging properties of treated plastics in the open air. It is found that the modified webs can retain the surface energy as high as 50.0?±?1 mN m^(-1) for more than three months. After characterization of the as-prepared and aged samples by the surface roughness, the wettability, and the chemical structure, the mechanism of retaining high surface energy is then presumed. We think that the initial high surface energy just after plasma treatment is correlated to the grafted functional groups, while the over 50.0 mN m^(-1) remaining surface energy after three month aging is due to the stable concentrations of oxygen-contained and nitrogencontained groups by post-reaction on the surfaces.展开更多
The serratedflow of alloy LC9 with different regimes of heat treatment has been investigated at constant rate of stretching.The critieal strain ε_c at the starting of serrated flow increases with the extension of agi...The serratedflow of alloy LC9 with different regimes of heat treatment has been investigated at constant rate of stretching.The critieal strain ε_c at the starting of serrated flow increases with the extension of aging.The activation energy of the process is 0.63 e V which is consistent with the diffusion activation energy of vacancies in A1.The ε_c decreases while the strain rate ε increases,i.e.,with negative strain rate relation.This relation is contrary to that of the an- nealed samples.It shows that the serrated 17ow of annealed sample is controlled by deformation vaeancies,and that of aged sample is controlled by quenching vacancies.The den- sity and shape of the serration are changed by aging.The mechanism of the above mentioned results is discussed.展开更多
To study the atmospheric aging of acrylic coatings,a two-year aging exposure experiment was conducted in 13 representative climatic environments in China.An atmospheric aging evaluation model of acrylic coatings was d...To study the atmospheric aging of acrylic coatings,a two-year aging exposure experiment was conducted in 13 representative climatic environments in China.An atmospheric aging evaluation model of acrylic coatings was developed based on aging data including11 environmental factors from 567 cities.A hybrid method of random forest and Spearman correlation analysis was used to reduce the redundancy and multicollinearity of the data set by dimensionality reduction.A semi-supervised collaborative trained regression model was developed with the environmental factors as input and the low-frequency impedance modulus values of the electrochemical impedance spectra of acrylic coatings in 3.5wt%NaCl solution as output.The model improves accuracy compared to supervised learning algorithms model(support vector machines model).The model provides a new method for the rapid evaluation of the aging performance of acrylic coatings,and may also serve as a reference to evaluate the aging performance of other organic coatings.展开更多
基金supported by the National Natural Science Foundation of China(No.51202116)the Ministry of Science and Technology of China(No.2015AA034603)
文摘The catalytic activity and durability of Rh/ZrO2 catalyst were investigated compared with Rh/Al2O3 catalyst under diverse aging atmospheres, including lean, rich and lean–rich cyclic aging atmospheres, to simulate the real working conditions of three-way catalyst.Oxidation states and microstructures of rhodium species were investigated to correlate with the catalytic performance of the catalysts. The catalytic performance and durability of the Rh catalyst under diverse aging atmospheres were drastically enhanced by ZrO2 support. ZrO2 support was confirmed to be able to effectively inhibit rhodium sintering even under diverse aging conditions. It can also successfully keep Rh species in an active low-valence state on the surface of the catalyst. The superiority of ZrO2 support compared to Al2O3 was verified by the Rh-based monolith catalyst.
基金financial support from SABITA and GAUTRANS in South Africa.
文摘Bitumen Stabilized Materials (BSMs) are widely recognized as environmentally friendly through significantly reduced energy consumption,reduced emissions and reuse of high percentage of RAP and recycled pavement materials. In order for these materials to be cost effective,their life-cycle performance needs to be proven. Durability of BSMs is a long-term phenomena that requires consideration during mix design. Time is very important variable for performance consideration under field conditions. The factors that influence durability and long-term performance of BSMs include the mineral aggregates,binder and mixture compositions. In this study,the important,but less understood aspects of durability properties of BSMs were investigated. These include wear and tear of mineral aggregates,age-hardening of binder (foamed bitumen and bitumen emulsion) and moisture susceptibility of typical mix composition. The wear and tear was investigated using Durability Mill Index (DMI) test,binder ageing was investigated for short and long-term effect,and moisture susceptibility was investigated by pulsing water pressures using new device i.e. moisture induction simulation test (MIST). The accelerated moisture conditioning simulates field conditions whereafter retained shear properties are evaluated. The results found that durability of mineral aggregates is significantly influences by the type and nature of mineral composition. The ageing of binder occurred in both short and long-term conditions,with short-term effects being dominating the foamed bitumen properties during laboratory production. Moisture susceptibility is significantly influenced by the mix compositions of aggregates blends with and without RAP,with different bitumen binder types (foamed bitumen or bitumen emulsion) and active filler type (cement or lime) and contents. The evaluation and ranking of mixes which are resistant and susceptible to moisture damage was done using retained cohesion (RC) after dry and wet monotonic triaxial testing.
基金supported by grants from National Natural Science Foundation of China(Nos.81701014,81801310,31700076)the Basic Research of Natural Science Project funded by the Department of Science and Technology of Shaanxi Province(No.2017JM8038)the Science and Technology Project funded by the Science and Technology Bureau of Weiyang District,Xi’an city(No.201846)。
文摘In this study, we employed a nonthermal atmospheric pressure plasma(NTAPP) jet to evaluate the effect of plasma treatment on the durability of resin–dentin bonding under a thermocycling challenge. Furthermore, we assessed the degradation resistance of plasma-treated collagen under a sodium hypochlorite(NaClO) challenge. We assessed the beneficial effect of NTAPP treatment on the acid-etched dentin–bonding interface by testing the micro-tensile bond strength and examining the morphology. We found that the immediate bonding strength of the dentin significantly increased after NTAPP treatment. Compared with the control group, NTAPP resulted in a more prominent effect on the bonding durability of the dentin–adhesive interface after treatment for 5 or 10 s. Simultaneously, the mechanical strength of dentin collagen under the NaClO challenge was improved. Our results indicate that, in optimal conditions, NTAPP could be a promising method to protect dentin collagen and to improve the bonding durability between dentin and etch-and-rinse adhesives.
基金the Research Council of Turkey(TUBITAK)for funding the research project“Load Bearing Glass and Timber Composites”(project no:110O950)which is a part of the international research program WoodWisdom-Net.
文摘Although timber was used extensively as a structural material for traditional buildings in Turkey in the past, usage of structural timber decreased significantly over time and timber has been largely replaced by other materials. As timber is a natural, durable and sustainable material, it would be desirable to re-introduce timber structural elements to contemporary construction in a form that is appealing to industry. Timber-glass composite structural elements are potentially a good candidate for this purpose. To that end, a series of tests were conducted on load-bearing timber-glass composites in order to understand the long-term structural performance of the composite material under atmospheric conditions;to decrease the recurring cost of repair and maintenance;and to minimize the exhaustion of raw materials and energy. In this paper, the first part of this experimental work is presented, which focuses on the durability of timber-glass composite under the effects of accelerated aging, carried out on small-sized timber-glass composite specimens. Accelerated aging effects were observed under wetting-drying, freezing-thawing, UV effects, resistance to acids and high temperature. The mechanical strength of the timber-glass composite specimens before and after the effect of accelerated aging was measured by adhesion and shear strength tests and a comparative analysis of the results was carried out. The results of the experiments indicate that timber-glass composite is suitable to be used under protection from environmental conditions.
基金supported by the National Natural Science Foundation of China(No.42305109)Quzhou Municipal Science and Technology Bureau(No.2023K222).
文摘Inhalation of atmospheric PM_(2.5)can induce the generation of excessive reactive oxygen species(ROS)in human alveoli,triggering local and systemic inflammation,which can directly or indirectly result in respiratory and cardiovascular diseases.In this study,we assessed the oxidative potential(OP)of fresh and O_(3)-aged PM_(2.5)particles from various urban and rural emission sources using the dithiothreitol(DTT)method.Our results revealed variations in the OP of fresh PM_(2.5)among different emission sources,with biomass burning sources exhibiting the highest OP,followed by industrial areas,vehicular emissions,cooking emissions,and suburban areas,respectively.Water-soluble organics and transition metals might potentially exert significant influence on particle OP.O_(3)aging notably decreased the OP of PM_(2.5)particles,possibly due to the oxidation of highly DTT-active components into low redox-active small molecules.Moreover,the evolution of OP in different PM_(2.5)components,including methanol-soluble and insoluble fractions,exhibited distinct responses to O_(3)aging for source-oriented PM_(2.5).Additionally,differences in chemical composition between fresh and aged PM_(2.5)were further elucidated through measurements of component-dependent hygroscopic behaviors and phase transitions.This study systematically delineates variances in the toxic potential of fresh and O_(3)-aged PM_(2.5)from various anthropogenic sources.The findings highlight the intrinsic compositional dependence of particle OP and provide essential insights for assessing the health effects of source-oriented PM_(2.5),as well as for formulating human health protection policies.
文摘Polymer nanocomposite coatings(PNCCs)are unprecedented generation of coatings engineered for displaying inexpensive and brilliant functional surface coatings with eminent corrosion guard,mechanical resistance,antimicrobial,chemical durability,electrical insulation,and UV aging features.Due to their widely anticipation in petroleum,applications in building,conveyance,aerospace,electronics,automobiles and energy,these multi-functional coatings have a tremendous leverage in human life,all technological and scientific subjects.Numerous applications have been made for multilateral polymers like polyurethane(PU),epoxy(EP),polyaniline(PANI)conductive polymer,polypyrrole(PPy),and etc,on various metallic surfaces especially,carbon steel substrate owing to their excellent resistance properties.Practically,nanomaterials can possess potential in the all-interdisciplinary domains of materials science and engineering,chemical and physical sciences,biological and health sciences.As known,the designed polymer nanocomposite coating paradigm is fundamentally constituted from polymer or resin as a vehicle and inorganic nanofillers(nanoparticles and nanocomposites).Some commercialized and excessively employed nanocontainers in polymer nanocomposite coating formulations,like ZnO,TiO_(2),carbon nanotubes(CNTs),clay,SiO_(2),Al_(2)O_(3),graphene,GO,CeO_(2),ZrO_(2),FeTiO_(3),etc were discussed.The current review covered the chemistry and potential applications of the largest utilized multifunctional polymer nanocomposite coatings such as EP,PU and other considerable PNCCs.Lately,a titanic attention was made for epoxy nanocomposites because of their distinct physicochemical characteristics,which result from the combined qualities of the nanoparticles and polymer material unity.In addition,the author incorporated some of his scientific contributions in this area represented in construction of innovative functional polymer nanocomposites for a variety of uses with high economic,industrial impacts and future orientation.Furthermore,some newly published applications of polymer nanocomposite coatings were incorporated and discussed.
文摘The contact angle of liquid Ag with solid W and its temperature dependance were examined by sessile drop method under various atmospheres,e.g.vacuum,Ar,H_2 and carcked NH_3.The O_2 partial pressure in the atmosphere is found to be the major factor. An obvious improvement on the wettability may be made by a trace amount of Ni,Cu or Ce added to liquid Ag,The contact angle near M.P.is then narrowed from 69 to about 10—20 deg.
基金the Chinese Academy of Sciences and the High Technical Project.
文摘Dynamic strain aging (DSA) is an important phenomenon in solutehardened metals and seri- ously affects the mechanical properties ofmetals. DSA is generally induced by the interaction between themoving dislocations and the mobile solute atoms. In this paper, onlythe interaction between moving disloca- tions and mobile solute atomsin a dislocation core area (core atmosphere) will be taken intoaccount. To es- tablish the constitutive model which can describe theDSA phenomenon, we improved the Zerilli-Armstrongdislocation-mechanics-based thermal viscoplastic constitutiverelation, and added the effect of the interaction between the movingdislocations and core atmosphere.
文摘The results of atmospheric pressure plasma treatments using diffuse coplanar surface barrier discharge (type of surface dielectric barrier discharge) on chromium surfaces are reported. A significant increase of surface wettability was observed after short plasma exposition. A quantitative value of surface wettability, i.e. the surface free energy, changed from 29 mJ/m2 to over 80 mJ/m2. In time, a hydrophobic recovery of the plasma treated surfaces was observed. Careful study by surface free energy measurements and x-ray photoelectron spectroscopy was performed to be able explaining the effects of plasma treatment. Studied samples were treated in air, oxygen and nitrogen plasma and aged in air and vacuum. Main reasons for increased wettability and aging effect are surface cleaning and transformations in chromium oxide. Additionally, generation of surface nitrate groups was found on the chromium surface as a result of plasma treatment in humid air.
基金Supported by National Natural Science Foundation of China(Nos.11775028,11505013)Beijing Municipal National Science Foundation(Nos.4162024,KM201510015009)the Collaborative Innovation Center of Green Printing&Publishing Technology(No.20160113)
文摘In this paper, we report the modification of polyethylene(45 μm in thickness) webs through a roll-to-roll dielectric barrier discharge plasma treatment in an open atmospheric environment.Our work differs from the normal adopted corona discharge treatment at an atmospheric pressure, in that three monomers: allylamine, acrylic acid, and ethanol, are inlet into the discharge zone by argon(Ar) carrier gas. As a comparison, Ar plasma treatment is also carried out. We focus on the aging properties of treated plastics in the open air. It is found that the modified webs can retain the surface energy as high as 50.0?±?1 mN m^(-1) for more than three months. After characterization of the as-prepared and aged samples by the surface roughness, the wettability, and the chemical structure, the mechanism of retaining high surface energy is then presumed. We think that the initial high surface energy just after plasma treatment is correlated to the grafted functional groups, while the over 50.0 mN m^(-1) remaining surface energy after three month aging is due to the stable concentrations of oxygen-contained and nitrogencontained groups by post-reaction on the surfaces.
文摘The serratedflow of alloy LC9 with different regimes of heat treatment has been investigated at constant rate of stretching.The critieal strain ε_c at the starting of serrated flow increases with the extension of aging.The activation energy of the process is 0.63 e V which is consistent with the diffusion activation energy of vacancies in A1.The ε_c decreases while the strain rate ε increases,i.e.,with negative strain rate relation.This relation is contrary to that of the an- nealed samples.It shows that the serrated 17ow of annealed sample is controlled by deformation vaeancies,and that of aged sample is controlled by quenching vacancies.The den- sity and shape of the serration are changed by aging.The mechanism of the above mentioned results is discussed.
基金the National Key R&D Program of China(2023YFB3812901)the Postdoctoral Fellowship Program of CPSF(No.GZC20230239)+1 种基金the China Postdoctoral Science Foundation(No.2023M740219)the National Natural Science Foundation of China(No.22209094)。
文摘To study the atmospheric aging of acrylic coatings,a two-year aging exposure experiment was conducted in 13 representative climatic environments in China.An atmospheric aging evaluation model of acrylic coatings was developed based on aging data including11 environmental factors from 567 cities.A hybrid method of random forest and Spearman correlation analysis was used to reduce the redundancy and multicollinearity of the data set by dimensionality reduction.A semi-supervised collaborative trained regression model was developed with the environmental factors as input and the low-frequency impedance modulus values of the electrochemical impedance spectra of acrylic coatings in 3.5wt%NaCl solution as output.The model improves accuracy compared to supervised learning algorithms model(support vector machines model).The model provides a new method for the rapid evaluation of the aging performance of acrylic coatings,and may also serve as a reference to evaluate the aging performance of other organic coatings.
