为了更系统地研究分散剂对无氰电沉积Ag/C复合层耐蚀性的影响,在以KI为配位剂的无氰电沉积Ag/C镀液中加入石墨粉和自制含羧基分散剂,在铜片表面电镀Ag/C复合层。利用扫描电镜和能谱仪分析了Ag/C复合镀层的表面形貌及成分;通过抗硫化变...为了更系统地研究分散剂对无氰电沉积Ag/C复合层耐蚀性的影响,在以KI为配位剂的无氰电沉积Ag/C镀液中加入石墨粉和自制含羧基分散剂,在铜片表面电镀Ag/C复合层。利用扫描电镜和能谱仪分析了Ag/C复合镀层的表面形貌及成分;通过抗硫化变色性能试验、Tafel极化曲线等研究了分散剂用量对复合镀层在SO2,H2S气体及Na2S,K2SO4溶液中腐蚀特性的影响。结果表明:分散剂最佳用量为5 m L/L,此时石墨在镀液及镀层中分散效果最好,所得镀层也最均匀、细致;镀液中含分散剂时所得Ag/C复合层在H2S,SO2气氛中及Na2S和K2SO4溶液中的抗硫化变色能力均较强。展开更多
The uncontrolled dendrite growth and shuttle effect of polysulfides have hindered the practical application of lith-ium-sulfur(Li-S)batteries.Herein,a metal-organic framework-derived Ag/C core-shell composite integrat...The uncontrolled dendrite growth and shuttle effect of polysulfides have hindered the practical application of lith-ium-sulfur(Li-S)batteries.Herein,a metal-organic framework-derived Ag/C core-shell composite integrated with a carbon nanofiber film(Ag/C@CNF)is developed to address these issues in Li-S batteries.The Ag/C core-shell structure design endows the CNF skeleton with enhanced electrical conductivity,electrocatalysis performance toward polysulfides conversion,and lithium nucleation.When served as a freestanding bifunctional host in Li-S batteries,the Ag/C@CNF composite regulates the Li and sulfur electrochemical processes by guiding the uniform Li deposition with mitigated dendrite growth and at the same time accelerating the polysulfides conversion.The assembled Li-S full battery delivers a considerable capacity of 650 mAh g^(-1),an ultralong cyclability with an attenuation rate as low as 0.02%per cycle for 1000 cycles at 5 C,and excellent rate performances at increased sulfur loading up to 7.6 mg cm^(-2)under lean electrolyte condition.展开更多
文摘为了更系统地研究分散剂对无氰电沉积Ag/C复合层耐蚀性的影响,在以KI为配位剂的无氰电沉积Ag/C镀液中加入石墨粉和自制含羧基分散剂,在铜片表面电镀Ag/C复合层。利用扫描电镜和能谱仪分析了Ag/C复合镀层的表面形貌及成分;通过抗硫化变色性能试验、Tafel极化曲线等研究了分散剂用量对复合镀层在SO2,H2S气体及Na2S,K2SO4溶液中腐蚀特性的影响。结果表明:分散剂最佳用量为5 m L/L,此时石墨在镀液及镀层中分散效果最好,所得镀层也最均匀、细致;镀液中含分散剂时所得Ag/C复合层在H2S,SO2气氛中及Na2S和K2SO4溶液中的抗硫化变色能力均较强。
基金sponsorship from Outstanding Young Talents Project of Hebei High Education Institutions(BJ2021020)National Natural Science Foundation of China(No.22278109).
文摘The uncontrolled dendrite growth and shuttle effect of polysulfides have hindered the practical application of lith-ium-sulfur(Li-S)batteries.Herein,a metal-organic framework-derived Ag/C core-shell composite integrated with a carbon nanofiber film(Ag/C@CNF)is developed to address these issues in Li-S batteries.The Ag/C core-shell structure design endows the CNF skeleton with enhanced electrical conductivity,electrocatalysis performance toward polysulfides conversion,and lithium nucleation.When served as a freestanding bifunctional host in Li-S batteries,the Ag/C@CNF composite regulates the Li and sulfur electrochemical processes by guiding the uniform Li deposition with mitigated dendrite growth and at the same time accelerating the polysulfides conversion.The assembled Li-S full battery delivers a considerable capacity of 650 mAh g^(-1),an ultralong cyclability with an attenuation rate as low as 0.02%per cycle for 1000 cycles at 5 C,and excellent rate performances at increased sulfur loading up to 7.6 mg cm^(-2)under lean electrolyte condition.
