Friction stir lap welding(FSLW)was adopted to join successfully dissimilar AZ31B Mg alloy and TC4 Ti alloy with Sn foil addition of 30μm thickness.Interfacial microstructure,tensile shear performances and bonding mec...Friction stir lap welding(FSLW)was adopted to join successfully dissimilar AZ31B Mg alloy and TC4 Ti alloy with Sn foil addition of 30μm thickness.Interfacial microstructure,tensile shear performances and bonding mechanism of the joints obtained using three different rotation speeds were studied.High-performance FSLW Mg/Ti dissimilar joints with maximum tensile shear strength of 593.3 N/mm were produced at 1180 r/min,and which was mainly attributed to ultrastrong reaction interlayer consisting of 125.9 nm thick(Mg_(2)Sn+Mg)transition layer and discontinuous(Ti_(6)Sn_(5)+Ti_(3)Al)IMCs layer with 6.58 nm thickness at the interface.The formation of the reaction interlayer was beneficial for high interfacial strength,resulting in significantly improving the joint strength.The fracture of all FSLW joints located on AZ31B Mg stirred zone adjacent to(Mg_(2)Sn+Mg)transition layer or along the crack propagation direction of the AZ31B/TC4 interface with different fracture mechanisms,and which could be consistent with interfacial microstructure.展开更多
This study aims to investigate the influence of Sn addition on microstructure and corrosion properties of AS21 magnesium alloys. The AS21 alloys with 0, 0.5, 1 and 2 wt.% Sn additions were produced by low pressure die...This study aims to investigate the influence of Sn addition on microstructure and corrosion properties of AS21 magnesium alloys. The AS21 alloys with 0, 0.5, 1 and 2 wt.% Sn additions were produced by low pressure die casting method. Microstructure characterizations were performed by optical and scanning electron microscopy. Corrosion properties of the alloys were examined by immersion and electrochemical corrosion tests in 3.5% NaCl solution. The microscopic results showed that AS21 alloy consisted of α-Mg, isolated β-Mg17Al12 and Chinese script type Mg2Si intermetallic phases. With increasing amount of Sn, the distribution of Mg2Si phase became more discrete and denser. After 2 wt.% Sn addition, a Sn-rich network structure formed throughout the microstructure and islands of Chinese script shape were made of shorter rods of Mg2Si phase. The constant immersion corrosion tests revealed that increasing Sn addition led to a continual decrease in the degradation of AS21 alloys, in which the corrosion rate of AS21 alloy was decreased by approximately 65% with 2 wt.% Sn addition. The electrochemical corrosion tests also showed that the corrosion resistance of AS21 alloy was gradually improved with increasing Sn content.展开更多
In this work,the beneficial effect of Sn addition on the corrosion resistance mechanism of Cr-Mo low alloy steel was studied.Results demonstrated that Sn improves the corrosion resistance of the steel matrix mainly by...In this work,the beneficial effect of Sn addition on the corrosion resistance mechanism of Cr-Mo low alloy steel was studied.Results demonstrated that Sn improves the corrosion resistance of the steel matrix mainly by influencing the microstructural transformation.Sn addition and the synergistic effect of Sn,Cr,and Mo promote the formation of α-FeOOH,SnO_(2),SnO,Cr(OH)_(3),and molybdates,lead to the improved protection and stability of the rust layer.This synergistic effect also endows the inner rust layer with cation selectivity,preventing the further penetration of Cl-and inhibiting the localized corrosion of steel.展开更多
The effects of trace elements Cd and Sn on precipitation process of Al-Si-Cu-Mg cast alloys were investigated in the present research.It is shown that the addition of Cd and Sn not only increases remarkably the aging ...The effects of trace elements Cd and Sn on precipitation process of Al-Si-Cu-Mg cast alloys were investigated in the present research.It is shown that the addition of Cd and Sn not only increases remarkably the aging peak hardness and reduces the time to reach aging peak,but also eliminates the double-aging-peak phenomenon which appears in Al-Si-Cu-Mg alloys.In Al-Si-Cu-Mg alloys the first aging peak corresponds to GP zones(especially GPⅡ) ,and the second one is caused by metastable phases.The obvious time interval of transition from GPⅡ to metastable phases associates with the double-aging-peak phenomenon.The results of DSC and TEM show that Cd/Sn elements suppress the formation of GPⅠzone,stimulate the formation of θ",θ' and θ phases,and then shorten remarkably the temperature intervals of each exothermic peak.Because the transition interval between GPⅡzone and metastable phases is shortened by Cd/Sn in Al-Si-Cu-Mg cast alloys,θ' phase coexists with θ" phase in matrix of ageing peak condition,which causes effective hardening on the alloys,and at the same time,eliminates the double-aging-peak phenomenon.展开更多
Catalytic dehydrogenation represents one of the most effective methods for converting low-carbon hydrocarbons into monoolefins and hydrogen with identical carbon numbers.In this study,microporous(HZSMi)and meso-microp...Catalytic dehydrogenation represents one of the most effective methods for converting low-carbon hydrocarbons into monoolefins and hydrogen with identical carbon numbers.In this study,microporous(HZSMi)and meso-microporous molecular sieves(HZSMu)with a Si/Al atomic ratio of 150,synthesized in the laboratory,were prepared via hydrothermal synthesis.These supports were impregnated with 2.4%Co using the incipient wetness impregnation method and subsequently modified by introducing the metal additives Zr and Sn.Notably,the Co-Sn/HZSMu catalyst exhibited the highest stability,achieving a propylene selectivity of 95.3% within 400 min while maintaining robust activity.A series of characterization analyses reveal that the HZSMu molecular sieve possesses distinctive weaving properties.The synergistic effect between mesopores facilitates the adsorption and activation of reactants while preventing pore blockage,thus promoting the rapid diffusion of reactants on its surface.The incorporation of the metal additive Sn promotes the uniform dispersion of Co,mitigating the occurrence of side reactions and enhancing the catalytic performance and reaction stability of the catalyst.展开更多
基金supported by the National Natural Science Foundation of China(NSFC)(Nos.52005240,52164045)Young Talent Program of Major Disciplines of Academic and Technical Leaders in Jiangxi Province(No.20212BCJ23028)Outstanding Youth Foundation in Jiangxi Province(No.20224ACB214012).
文摘Friction stir lap welding(FSLW)was adopted to join successfully dissimilar AZ31B Mg alloy and TC4 Ti alloy with Sn foil addition of 30μm thickness.Interfacial microstructure,tensile shear performances and bonding mechanism of the joints obtained using three different rotation speeds were studied.High-performance FSLW Mg/Ti dissimilar joints with maximum tensile shear strength of 593.3 N/mm were produced at 1180 r/min,and which was mainly attributed to ultrastrong reaction interlayer consisting of 125.9 nm thick(Mg_(2)Sn+Mg)transition layer and discontinuous(Ti_(6)Sn_(5)+Ti_(3)Al)IMCs layer with 6.58 nm thickness at the interface.The formation of the reaction interlayer was beneficial for high interfacial strength,resulting in significantly improving the joint strength.The fracture of all FSLW joints located on AZ31B Mg stirred zone adjacent to(Mg_(2)Sn+Mg)transition layer or along the crack propagation direction of the AZ31B/TC4 interface with different fracture mechanisms,and which could be consistent with interfacial microstructure.
基金supported by the Scientific Research Projects of Karabuk University (BAP) with Project No. KBUBAP-18-DS-008
文摘This study aims to investigate the influence of Sn addition on microstructure and corrosion properties of AS21 magnesium alloys. The AS21 alloys with 0, 0.5, 1 and 2 wt.% Sn additions were produced by low pressure die casting method. Microstructure characterizations were performed by optical and scanning electron microscopy. Corrosion properties of the alloys were examined by immersion and electrochemical corrosion tests in 3.5% NaCl solution. The microscopic results showed that AS21 alloy consisted of α-Mg, isolated β-Mg17Al12 and Chinese script type Mg2Si intermetallic phases. With increasing amount of Sn, the distribution of Mg2Si phase became more discrete and denser. After 2 wt.% Sn addition, a Sn-rich network structure formed throughout the microstructure and islands of Chinese script shape were made of shorter rods of Mg2Si phase. The constant immersion corrosion tests revealed that increasing Sn addition led to a continual decrease in the degradation of AS21 alloys, in which the corrosion rate of AS21 alloy was decreased by approximately 65% with 2 wt.% Sn addition. The electrochemical corrosion tests also showed that the corrosion resistance of AS21 alloy was gradually improved with increasing Sn content.
基金This work was supported by National Key R&D Program of China(2017YFB0702100)the Fundamental Research Funds for the Central Universities(No.FRF-MP-18-002)。
文摘In this work,the beneficial effect of Sn addition on the corrosion resistance mechanism of Cr-Mo low alloy steel was studied.Results demonstrated that Sn improves the corrosion resistance of the steel matrix mainly by influencing the microstructural transformation.Sn addition and the synergistic effect of Sn,Cr,and Mo promote the formation of α-FeOOH,SnO_(2),SnO,Cr(OH)_(3),and molybdates,lead to the improved protection and stability of the rust layer.This synergistic effect also endows the inner rust layer with cation selectivity,preventing the further penetration of Cl-and inhibiting the localized corrosion of steel.
文摘The effects of trace elements Cd and Sn on precipitation process of Al-Si-Cu-Mg cast alloys were investigated in the present research.It is shown that the addition of Cd and Sn not only increases remarkably the aging peak hardness and reduces the time to reach aging peak,but also eliminates the double-aging-peak phenomenon which appears in Al-Si-Cu-Mg alloys.In Al-Si-Cu-Mg alloys the first aging peak corresponds to GP zones(especially GPⅡ) ,and the second one is caused by metastable phases.The obvious time interval of transition from GPⅡ to metastable phases associates with the double-aging-peak phenomenon.The results of DSC and TEM show that Cd/Sn elements suppress the formation of GPⅠzone,stimulate the formation of θ",θ' and θ phases,and then shorten remarkably the temperature intervals of each exothermic peak.Because the transition interval between GPⅡzone and metastable phases is shortened by Cd/Sn in Al-Si-Cu-Mg cast alloys,θ' phase coexists with θ" phase in matrix of ageing peak condition,which causes effective hardening on the alloys,and at the same time,eliminates the double-aging-peak phenomenon.
基金supported by the National Natural Science Foundation of China(Grant No.21968034).
文摘Catalytic dehydrogenation represents one of the most effective methods for converting low-carbon hydrocarbons into monoolefins and hydrogen with identical carbon numbers.In this study,microporous(HZSMi)and meso-microporous molecular sieves(HZSMu)with a Si/Al atomic ratio of 150,synthesized in the laboratory,were prepared via hydrothermal synthesis.These supports were impregnated with 2.4%Co using the incipient wetness impregnation method and subsequently modified by introducing the metal additives Zr and Sn.Notably,the Co-Sn/HZSMu catalyst exhibited the highest stability,achieving a propylene selectivity of 95.3% within 400 min while maintaining robust activity.A series of characterization analyses reveal that the HZSMu molecular sieve possesses distinctive weaving properties.The synergistic effect between mesopores facilitates the adsorption and activation of reactants while preventing pore blockage,thus promoting the rapid diffusion of reactants on its surface.The incorporation of the metal additive Sn promotes the uniform dispersion of Co,mitigating the occurrence of side reactions and enhancing the catalytic performance and reaction stability of the catalyst.
