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Effects of Additive AlCl_3 on Crystal Phase, Particle Size and Microstructural Parameters of Nanocrystalline TiO_2 Prepared by HF-PCVD 被引量:2
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作者 HaipingXU YanpingSUN XinmouCHEN 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2004年第6期641-643,共3页
Nanocrystalline TiO2 was prepared by high frequency plasma chemical vapor deposition (HF-PCVD). The effects of additive AlCl3 on crystal phase, particle size and microstructurai parameters of TiO2 nanocrystallites wer... Nanocrystalline TiO2 was prepared by high frequency plasma chemical vapor deposition (HF-PCVD). The effects of additive AlCl3 on crystal phase, particle size and microstructurai parameters of TiO2 nanocrystallites were investigated by X-ray diffraction(XRD) and transmission electron microscopy (TEM). The nanocrystallites obtained experimentally are mixture of anatase and rutile, the uniform diameters of particles are about 30 nm. The phase transformation from anatase to rutile was accelerated by AlCl3, and rutile content is increased from 26.7 wt pct to 53.6 wt pct with increasing of addition of AlCl3 from 0.0 wt pct to 5.0 wt pct. The particle size is reduced and the size distribution becomes very narrow. The crystal lattice constants have the trend to decrease, and celi volumes appear as shrinkable. 展开更多
关键词 additive AlCl_3 Nanocrystalline TiO_2 Crystal phase Particle size Microstructural parameters
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Additive manufacturing-by-design for support structures:a critical review
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作者 Jinlong Su Yang Mo +3 位作者 Peijie Shangguan Chinnapat Panwisawas Fulin Jiang Swee Leong Sing 《International Journal of Extreme Manufacturing》 2025年第5期52-80,共29页
Support structure,a critical component in the design for additive manufacturing(DfAM),has been largely overlooked by additive manufacturing(AM)communities.The support structure stabilises overhanging sections,aids in ... Support structure,a critical component in the design for additive manufacturing(DfAM),has been largely overlooked by additive manufacturing(AM)communities.The support structure stabilises overhanging sections,aids in heat dissipation,and reduces the risk of thermal warping,residual stress,and distortion,particularly in the fabrication of complex geometries that challenge traditional manufacturing methods.Despite the importance of support structures in AM,a systematic review covering all aspects of the design,optimisation,and removal of support structures remains lacking.This review provides an overview of various support structure types—contact and non-contact,as well as identical and dissimilar material configurations—and outlines optimisation methods,including geometric,topology,simulation-driven,data-driven,and multi-objective approaches.Additionally,the mechanisms of support removal,such as mechanical milling and chemical dissolution,and innovations like dissolvable supports and sensitised interfaces,are discussed.Future research directions are outlined,emphasising artificial intelligence(AI)-driven intelligent design,multi-material supports,sustainable support materials,support-free AM techniques,and innovative support removal methods,all of which are essential for advancing AM technology.Overall,this review aims to serve as a foundational reference for the design and optimisation of the support structure in AM. 展开更多
关键词 additive manufacturing support structure design and optimisation SIMULATION SUSTAINABILITY 3D printing
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Realizing dendrite-free Zn anode using an efficient sulfone-based electrolyte additive for high-performance aqueous zinc-ion batteries
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作者 Hongda Cui Wenxin Li +2 位作者 Hongming Chen Zijin Liu Dan Zhou 《Journal of Energy Chemistry》 2025年第10期455-465,共11页
Aqueous zinc-ion batteries(AZIBs)have emerged as a promising next-generation energy storage solution due to their high energy density,abundant resources,low cost,and high safety.However,unstable zinc anode caused by s... Aqueous zinc-ion batteries(AZIBs)have emerged as a promising next-generation energy storage solution due to their high energy density,abundant resources,low cost,and high safety.However,unstable zinc anode caused by side reactions and dendritic growth always severely worsens the long-term operation of AZIBs.Herein,a novel 3-cyclobutene sulfone(CS)additive was employed in the aqueous electrolyte to achieve a highly reversible Zn anode.The CS additive can offer strong electronegativity and high binding energy for the coordination with Zn^(2+),which enables its entry into the solvent sheath structure of Zn^(2+)and eliminates the free H_(2)O molecules from the solvated{Zn^(2+)-SO_(4)^(2-)-(H_(2)O)_(5)}.Thus,the occurrence of side reactions and dendritic growth can be effectively inhibited.Accordingly,the Zn anode achieves long cycle-life(1400 h at 1 m A cm^(-2),1 m Ah cm^(-2),and 400 h at 5 m A cm^(-2),5 m Ah cm^(-2))and high average coulombic efficiency(99.5% over 500 cycles at 10 m A cm^(-2),1 m Ah cm^(-2)).Besides,the assembled Zn||NH_(4)V_(4)O_(10)full cell suggests enhanced cycling reversibility(123.8 m Ah g^(-1)over 500 cycles at 2 A g^(-1),84.9 m Ah g^(-1)over 800 cycles at 5 A g^(-1))and improved rate capability(139.1 m Ah g^(-1)at 5 A g^(-1)).This work may exhibit the creative design and deep understanding of sulfone-based electrolyte additives for the achievement of high-performance AZIBs. 展开更多
关键词 AZIBs 3-Cyclobutene sulfone Electrolyte additive Highly reversible Zn anode
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Sparse-view irradiation processing volumetric additive manufacturing
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作者 Huiyuan Wang Fangyuan Gao +6 位作者 Yu Shi Kai Wang Xinbo Wei Chunyang Ma Xiewen Wen Xueli Chen Jiebo Li 《International Journal of Extreme Manufacturing》 2025年第6期376-388,共13页
Volumetric additive manufacturing(VAM) transforms traditional 2D light pattern projection into spatial light field energy superposition,maximizing the utilization of radiated light and allowing for ultra-fast,support-... Volumetric additive manufacturing(VAM) transforms traditional 2D light pattern projection into spatial light field energy superposition,maximizing the utilization of radiated light and allowing for ultra-fast,support-free printing,which has specific applications in fields such as life sciences and optics.However,traditional VAM processes require numerous projections and extensive computational preparation,limiting practical applications due to low projection efficiency and prolonged calculation times.In this study,we developed sparse-view irradiation processing VAM(SVIP-VAM),employing an optimized odd-even(OE) irradiation strategy inspired by sparse-view computed tomography.Theoretically,we demonstrated structural contour reconstruction feasibility with as few as 8 projections.Using this sparse-view approach,we achieved high-quality fabrication with only 15 projections,enhancing each projection efficiency by over 60 times and reducing projection set computational time by nearly 10-fold.Ultimately,this efficient sparse-view method significantly expands VAM applications into fields requiring rapid manufacturing,such as tissue engineering,medical implants,and aerospace manufacturing. 展开更多
关键词 volumetric additive manufacturing 3D printing sparse view odd-even irradiation
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A comprehensive review and future perspectives of simulation approaches in wire arc additive manufacturing(WAAM)
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作者 Zhonghao Chen Lei Yuan +4 位作者 Zengxi Pan Hongtao Zhu Ninshu Ma Donghong Ding Huijun Li 《International Journal of Extreme Manufacturing》 2025年第2期588-628,共41页
Wire arc additive manufacturing(WAAM)has emerged as a promising technique for producing large-scale metal components,favoured by high deposition rates,flexibility and low cost.Despite its potential,the complexity of W... Wire arc additive manufacturing(WAAM)has emerged as a promising technique for producing large-scale metal components,favoured by high deposition rates,flexibility and low cost.Despite its potential,the complexity of WAAM processes,which involves intricate thermal dynamics,phase transitions,and metallurgical,mechanical,and chemical interactions,presents considerable challenges in final product qualities.Simulation technologies in WAAM have proven invaluable,providing accurate predictions in key areas such as material properties,defect identification,deposit morphology,and residual stress.These predictions play a critical role in optimising manufacturing strategies for the final product.This paper provides a comprehensive review of the simulation techniques applied in WAAM,tracing developments from 2013 to 2023.Initially,it analyses the current challenges faced by simulation methods in three main areas.Subsequently,the review explores the current modelling approaches and the applications of these simulations.Following this,the paper discusses the present state of WAAM simulation,identifying specific issues inherent to WAAM simulation itself.Finally,through a thorough review of existing literature and related analysis,the paper offers future perspectives on potential advancements in WAAM simulation strategies. 展开更多
关键词 wire arc additive manufacturing SIMULATION machine learning computational fluid dynamics finite element method 3D printing
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钕铁硼在AlCl_3-EMIC离子液体中电沉积铝层的耐腐蚀性能 被引量:10
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作者 陈静 凌国平 《材料保护》 CAS CSCD 北大核心 2011年第11期1-4,12,共5页
在钕铁硼(NdFeB)表面电沉积铝可提高其耐蚀性,而铝的电沉积只能在无水体系中进行。在摩尔比为2:1的AlCl_3-EMIC(氯化1-甲基-3-乙基咪唑)离子液体中对NdFeB表面电沉积铝,利用扫描电镜(SEM)、能谱、刻划剥离及热震试验对铝镀层的表面形貌... 在钕铁硼(NdFeB)表面电沉积铝可提高其耐蚀性,而铝的电沉积只能在无水体系中进行。在摩尔比为2:1的AlCl_3-EMIC(氯化1-甲基-3-乙基咪唑)离子液体中对NdFeB表面电沉积铝,利用扫描电镜(SEM)、能谱、刻划剥离及热震试验对铝镀层的表面形貌、成分及其与基体的结合情况进行了分析,采用中性盐雾试验、极化曲线和交流阻抗谱研究了镀层的耐蚀性能。结果表明:以2.5 A/dm^2电流密度对NdFeB阳极活化20 min后,其表面氧化膜被有效去除,电沉积后得到致密、结合优良的铝层;NdFeB在离子液体中镀铝后耐蚀性得到显著提高,自腐蚀电流密度减小2个数量级,阻抗值增加2个数量级,中性盐雾腐蚀200 h后镀层完好无损。 展开更多
关键词 电沉积铝 NDFEB AlCl_3-EMIC离子液体 阳极活化 耐蚀性
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氯化铝-盐酸体系下冰晶石的浸出动力学和机理
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作者 许恩乐 覃仁国 +4 位作者 郝天祥 苗真勇 赵杉 王宏雷 宋志浩 《化工进展》 北大核心 2026年第2期1190-1201,共12页
为解决前期工作中硫酸铝浸出液中可溶性AlF_(3)(aq)占比过高以及浸出过程各影响因素作用大小未明确等问题,有必要开展Na_(3)AlF_(6)在AlCl_(3)酸性溶液中浸出动力学与机理研究。本文通过单因素和正交实验,分析不同操作条件对浸出率的影... 为解决前期工作中硫酸铝浸出液中可溶性AlF_(3)(aq)占比过高以及浸出过程各影响因素作用大小未明确等问题,有必要开展Na_(3)AlF_(6)在AlCl_(3)酸性溶液中浸出动力学与机理研究。本文通过单因素和正交实验,分析不同操作条件对浸出率的影响,结果显示影响程度依次为:AlCl_(3)浓度>液固比>浸出时间>温度>HCl浓度。在优化条件下:AlCl_(3)浓度1mol/L、液固比25mL/g、浸出时间5min、HCl浓度0.1mol/L、温度358K,Na_(3)AlF_(6)和废铝电解质浸出率分别达91.3%和89.4%。动力学分析表明,Avrami方程[-ln(1-X)=ktn]能很好拟合Na_(3)AlF_(6)浸出过程。308~323K时,浸出受化学反应和固体产物层扩散共同控制,表观活化能为53.08kJ/mol;323~358K时,仅由固体产物层扩散控制,表观活化能为32.27kJ/mol。经热力学模拟、FTIR和XRD分析,反应机理为:HCl与AlF_(6)^(3-)反应生成Na_(5)Al_(3)F_(14),促使Na_(3)AlF_(6)转变为Na_(5)Al_(3)F_(14);AlCl_(3)经两步反应将固态Na_(3)AlF_(6)转化为AlF_(2)^(+)、AlF^(2+)等,且浸出液中基本无AlF_(3)(aq)。因Na_(3)AlF_(6)溶解解离微弱,浸出时AlCl_(3)起主要作用,HCl起辅助作用。本研究为工业化处理废铝电解质工艺参数选择提供了指导。 展开更多
关键词 反应动力学 废铝电解质 冰晶石 AlCl_(3)-HCl 机理
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酸性焙烧-水浸回收废旧LiNi_(1/3)Co_(1/3)Mn_(1/3)O_(2)过程中添加剂的影响及其机理研究
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作者 宋晓龙 王大辉 +2 位作者 陈怀敬 李彦强 彭小平 《矿冶工程》 北大核心 2026年第1期114-119,共6页
为促进废旧锂离子电池资源化回收利用,提出“酸性焙烧-水浸”的新型工艺,以LiNi_(1/3)Co_(1/3)Mn_(1/3)O_(2)材料为原料,研究了焙烧过程中添加剂对有价金属元素回收效果的影响。结果表明:LiNi_(1/3)Co_(1/3)Mn_(1/3)O_(2)与添加剂NaHSO_... 为促进废旧锂离子电池资源化回收利用,提出“酸性焙烧-水浸”的新型工艺,以LiNi_(1/3)Co_(1/3)Mn_(1/3)O_(2)材料为原料,研究了焙烧过程中添加剂对有价金属元素回收效果的影响。结果表明:LiNi_(1/3)Co_(1/3)Mn_(1/3)O_(2)与添加剂NaHSO_(4)·H_(2)O、KHSO_(4)、Na_(2)S_(2)O_(7)、K_(2)S_(2)O_(7)分别按物质的量比1∶3、1∶3、1∶1.5、1∶1.5混合后焙烧,有明显的失重与吸热行为;在添加剂存在的情况下,焙烧后LiNi_(1/3)Co_(1/3)Mn_(1/3)O_(2)中的Li、Ni、Co、Mn分别以相应的硫酸盐形式存在,焙烧产物为块状和致密结构;LiNi_(1/3)Co_(1/3)Mn_(1/3)O_(2)与添加剂的混合物经600℃、0.5 h焙烧后再经水浸,添加剂NaHSO_(4)·H_(2)O、KHSO_(4)、Na_(2)S_(2)O_(7)、K_(2)S_(2)O_(7)对应的金属元素浸出率分别为99.99%、98.97%、99.89%、98.86%。 展开更多
关键词 废旧锂离子电池 LiNi_(1/3)Co_(1/3)Mn_(1/3)O_(2) 金属回收 酸性焙烧 添加剂 水浸
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纳米TiO_(2)对Al_(2)O_(3)陶瓷烧结特性的影响
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作者 陈友梅 李镒成 +5 位作者 何婷 刘应寿 黎阳 肖汉宁 袁谋云 张伟群 《硅酸盐通报》 北大核心 2026年第1期256-263,共8页
以煅烧α-Al_(2)O_(3)粉体为原料、纳米TiO_(2)为烧结助剂、羧甲基纤维素为成型黏结剂,采用模压成型-常压烧结制备了Al_(2)O_(3)陶瓷,研究了烧结温度及纳米TiO_(2)添加量对Al_(2)O_(3)陶瓷微观形貌、线收缩率、物相结构、体积密度、孔... 以煅烧α-Al_(2)O_(3)粉体为原料、纳米TiO_(2)为烧结助剂、羧甲基纤维素为成型黏结剂,采用模压成型-常压烧结制备了Al_(2)O_(3)陶瓷,研究了烧结温度及纳米TiO_(2)添加量对Al_(2)O_(3)陶瓷微观形貌、线收缩率、物相结构、体积密度、孔隙率、抗折强度和白度的影响,评估了烧结特性。结果表明,添加适量纳米TiO_(2)能够显著提高Al_(2)O_(3)陶瓷的烧结性能,而过量纳米TiO_(2)会造成Al_(2)O_(3)晶粒异常长大,进而导致收缩率和体积密度降低、孔隙率增大。当纳米TiO_(2)添加量为0.7%(质量分数)、烧结温度为1 500℃时,Al_(2)O_(3)陶瓷性能较为优异,其抗折强度达到最大值,为(188.89±5.87) MPa,体积密度、孔隙率和白度分别为3.45 g·cm^(-3)、7.78%和76.6。 展开更多
关键词 Al_(2)O_(3)陶瓷 纳米TiO_(2) 模压成型 烧结温度 烧结助剂
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不同氮源对温带森林土壤活性有机碳、环境因子的影响及其相互作用
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作者 赵涵 左甜 +4 位作者 刁静文 苗梦雨 张晓慧 高哲 郭鹏 《环境科学》 北大核心 2026年第1期573-580,共8页
活性有机碳[易氧化有机碳(EOC)和可溶性有机碳(DOC)]作为土壤总有机碳(TOC)中最活跃的组分,对土壤环境因子的变化极为敏感.大量研究已证实,大气氮沉降的加剧显著影响了活性有机碳的含量.然而,不同类型的氮源化学性质差异明显,导致其对... 活性有机碳[易氧化有机碳(EOC)和可溶性有机碳(DOC)]作为土壤总有机碳(TOC)中最活跃的组分,对土壤环境因子的变化极为敏感.大量研究已证实,大气氮沉降的加剧显著影响了活性有机碳的含量.然而,不同类型的氮源化学性质差异明显,导致其对活性有机碳的影响可能存在差异.以典型温带森林土壤为研究对象,开展连续4 a氮沉降模拟实验[施氮量均为10g·(m^(2)·a)^(-1)],比较施加硝酸钠(NaNO_(3))、硝酸铵(NH_(4)NO_(3))、氯化铵(NH_(4)Cl)及尿素[CO(NH_(2))_(2)]后土壤活性有机碳、理化性质及胞外酶活性等的变化.结果表明,施氮后EOC和DOC的含量以及在TOC中的占比均显著降低(P<0.05).其中,施加氯化铵的效应最为明显(EOC/TOC和DOC/TOC降幅分别为-80.0%和-69.8%),硝酸钠次之,而施加硝酸铵和尿素后活性有机碳变化相对较小.随机森林模型表明,土壤理化性质(pH和总氮)和活性有机碳降解酶(转化酶和β-葡萄糖苷酶)活性是驱动活性有机碳分配比例变化的关键因子.施加氯化铵后,pH降低0.8个单位,土壤转化酶和β-葡萄糖苷酶活性分别增加22.3%和69.1%,进而加速对活性有机碳组分的分解,导致其分配比例降低.硝态氮易淋失,对有效氮含量影响较小.施加尿素后土壤酸化程度较弱,导致其对土壤酶活性的影响有限.综上所述,施氮会影响活性有机碳分配比例,但其对不同氮源的响应并不完全一致.因此,在精确评估、预测和分析氮沉降对土壤活性有机碳含量的影响时,应考虑氮源类型的影响. 展开更多
关键词 施氮 活性有机碳 铵态氮(NH_(4)^(+)-N) 硝态氮(NO_(3)^(-)-N) 土壤理化性质 土壤酶活性
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INFLUENCE OF Li_2CO_3-SiO_2 ADDITIVE ON THE PROPERTIES AND PROCESSING OF DOUBLE-FUNCTION SrTiO_3-BASED LOW VOLTAGE VARISTOR CERAMICS
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作者 季惠明 梁辉 郝俊杰 《Transactions of Tianjin University》 EI CAS 2001年第2期127-131,共5页
Semiconducting SrTiO 3 based voltage sensing and dielectric ceramics were prepared by single step sintering with Li 2CO 3 SiO 2 as liquid phase additives.The effects of the content of liquid phase,the ratio o... Semiconducting SrTiO 3 based voltage sensing and dielectric ceramics were prepared by single step sintering with Li 2CO 3 SiO 2 as liquid phase additives.The effects of the content of liquid phase,the ratio of Li/Si and the sintering temperatures on properties were discussed in terms of electrical properties and microstructures of materials.The results showed thatSrTiO 3 based varistor ceramics,with 0.6 mol% Li 2CO 3 SiO 2(Li/Si=3/2) and sintered at 1 380 ℃ in graphite and N 2 reducing atomosphere,had excellent current volatage sensing and dielectric characteristics. 展开更多
关键词 SrTiO 3 VARISTOR liquid phase additive PROPERTY
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AlCl_(3)-EMIC离子液体电沉积Al-Ti合金及耐蚀性研究
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作者 钟海霞 钟庆东 +3 位作者 杨健 章书剑 王雪妹 范佳宝 《材料导报》 北大核心 2026年第2期129-135,共7页
本研究旨在通过优化Al-Ti合金镀层的电沉积工艺,调控Ti含量并提升耐腐蚀性能,以满足高性能防护镀层的应用需求。采用恒电流法在铜基体上制备Al-Ti合金镀层,电解液由物质的量比2∶1的AlCl_(3)与1-乙基-3-甲基咪唑(EMIC)离子液体组成,并... 本研究旨在通过优化Al-Ti合金镀层的电沉积工艺,调控Ti含量并提升耐腐蚀性能,以满足高性能防护镀层的应用需求。采用恒电流法在铜基体上制备Al-Ti合金镀层,电解液由物质的量比2∶1的AlCl_(3)与1-乙基-3-甲基咪唑(EMIC)离子液体组成,并以氟钛酸钾(K_(2)TiF_(6))作为Ti源,通过调控电流密度(10~20 mA/cm^(2))和电沉积时间(45~120 min),系统研究了其对镀层形貌、成分及耐腐蚀性能的影响。实验结果表明,随着电流密度的增加,镀层中的Ti含量显著提高,且在较高电流密度下镀层致密性增强。当电流密度为20 mA/cm^(2)、电镀时间为60 min时,镀层中的Ti含量达到最大值(20.43%,质量分数)。电化学测试结果表面,随着电流密度的增加,自腐蚀电流密度从56.520μA/cm^(2)显著降低至1.068μA/cm^(2)。在15 mA/cm^(2)条件下镀层表现出明显的钝化现象,表现为阳极极化曲线的平台区域。此外,随着电沉积时间的延长,镀层的电荷转移阻抗和膜电阻增加,当电镀时间为90 min时,镀层致密性进一步增强,电化学反应速率减慢,防护性能显著增强。综合分析表明电流密度为15 mA/cm^(2)和电镀时间为90 min时,镀层均表现出最佳的耐腐蚀性能。 展开更多
关键词 离子液体 EMIC 铝钛合金 氯化铝 耐腐蚀性
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Annular Microfluidic Meta-Atom Fusion-Enabled Broadband Metamaterial Absorber
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作者 Jinpeng Peng Yi Zhang +7 位作者 Zihao Chen Qiye Wen Shaomeng Wang Yaoyao Li Aiwu Zhou Zhengnan Sun Xiaohui Mu Xiaosheng Zhang 《Nano-Micro Letters》 2026年第5期729-745,共17页
Electromagnetic(EM)metamaterial absorbers(MMAs)with broadband absorption are of growing interest for applications such as stealth and EM interference mitigation.In this work,we present a novel 3D-printed MMA based on ... Electromagnetic(EM)metamaterial absorbers(MMAs)with broadband absorption are of growing interest for applications such as stealth and EM interference mitigation.In this work,we present a novel 3D-printed MMA based on a fused annular microfluidic metaatom(FAMMA)architecture,designed for W-band absorption.The FAMMA structure features three kinds of orthogonally fused annual meta-atoms,forming a complex 3D microfluidic meta-atom with intricate architecture.Fabricated via high-precision micro 3D printing technology,the FAMMA-based MMA exploits the synergistic solid-liquid coupling effect of the unique three-dimensional orthogonal structure to achieve strong broadband absorption.Three representative FAMMAs with different geometric dimensions have achieved ultra-low reflection loss(RL of-42.1 dB),ultra-broadband effective absorption bandwidth(EAB of 31.3 GHz),and dual-band absorption(in 76.0-85.3 and 99.1-105.6 GHz),respectively.The underlying absorption mechanisms are elucidated by impedance matching theory and electromagnetic field distribution analyses.Application demonstrations show that the FAMMA-based MMA significantly suppresses radar echo power and renders metallic targets undetectable to both radar detector and radar imaging systems,highlighting its potential in stealth technology.Overall,this work establishes a new design concept for high-performance broadband millimeter wave MMAs,opening new avenue for future applications such as high-speed communication,through-wall sensing,and drone detection. 展开更多
关键词 Metamaterial absorber MMA 3D printing additive manufacturing Radar stealth
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INFLUENCE OF Li2CO3-SiO2 ADDITIVE ON THE PROPERTIES AND PROCESSING OF DOUBLE-FUNCTION SrTiO3-BASED LOW VOLTAGE VARISTOR CERAMICS
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作者 季惠明 梁辉 郝俊杰 《Transactions of Tianjin University》 EI CAS 2001年第2期127-131,共页
Semiconducting SrTiO 3 based voltage sensing and dielectric ceramics were prepared by single step sintering with Li 2CO 3 SiO 2 as liquid phase additives.The effects of the content of liquid phase,the ratio o... Semiconducting SrTiO 3 based voltage sensing and dielectric ceramics were prepared by single step sintering with Li 2CO 3 SiO 2 as liquid phase additives.The effects of the content of liquid phase,the ratio of Li/Si and the sintering temperatures on properties were discussed in terms of electrical properties and microstructures of materials.The results showed thatSrTiO 3 based varistor ceramics,with 0.6 mol% Li 2CO 3 SiO 2(Li/Si=3/2) and sintered at 1 380 ℃ in graphite and N 2 reducing atomosphere,had excellent current volatage sensing and dielectric characteristics. 展开更多
关键词 SrTiO 3 VARISTOR liquid phase additive PROPERTY
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Development Trends in Additive Manufacturing and 3D Printing 被引量:64
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作者 Bingheng Lu Dichen Li Xiaoyong Tian 《Engineering》 SCIE EI 2015年第1期85-89,共5页
Additive manufacturing and 3D printing tech-nology have been developing rapidly in the last 30 years, and indicate great potential for future development. The promising future of this technology makes its impact on tr... Additive manufacturing and 3D printing tech-nology have been developing rapidly in the last 30 years, and indicate great potential for future development. The promising future of this technology makes its impact on traditional industry unpredictable. 3D printing will propel the revolution of fabrication modes forward, and bring in a new era for customized fabrication by realizing the five "any"s: use of almost any material to fabricate any part, in any quantity and any location, for any industrial field. Innovations in material, design, and fabrication processes will be inspired by the merging of 3D-printing technology and processes with traditional manufacturing processes. Finally, 3D printing will become as valuable for manufacturing industries as equivalent and subtractive manufacturing processes. 展开更多
关键词 additive manufacturing 3D printing fabricationmodes customized fabrication innovative design
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Applying Neural-Network-Based Machine Learning to Additive Manufacturing:Current Applications,Challenges,and Future Perspectives 被引量:26
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作者 Xinbo Qi Guofeng Chen +2 位作者 Yong Li Xuan Cheng Changpeng Li 《Engineering》 SCIE EI 2019年第4期721-729,共9页
Additive manufacturing(AM),also known as three-dimensional printing,is gaining increasing attention from academia and industry due to the unique advantages it has in comparison with traditional subtractive manufacturi... Additive manufacturing(AM),also known as three-dimensional printing,is gaining increasing attention from academia and industry due to the unique advantages it has in comparison with traditional subtractive manufacturing.However,AM processing parameters are difficult to tune,since they can exert a huge impact on the printed microstructure and on the performance of the subsequent products.It is a difficult task to build a process-structure-property-performance(PSPP)relationship for AM using traditional numerical and analytical models.Today,the machine learning(ML)method has been demonstrated to be a valid way to perform complex pattern recognition and regression analysis without an explicit need to construct and solve the underlying physical models.Among ML algorithms,the neural network(NN)is the most widely used model due to the large dataset that is currently available,strong computational power,and sophisticated algorithm architecture.This paper overviews the progress of applying the NN algorithm to several aspects of the AM whole chain,including model design,in situ monitoring,and quality evaluation.Current challenges in applying NNs to AM and potential solutions for these problems are then outlined.Finally,future trends are proposed in order to provide an overall discussion of this interdisciplinary area. 展开更多
关键词 additive manufacturing 3D PRINTING NEURAL network MACHINE learning Algorithm
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Recent progress and perspectives in additive manufacturing of magnesium alloys 被引量:27
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作者 Zhuoran Zeng Mojtaba Salehi +3 位作者 Alexander Kopp Shiwei Xu Marco Esmaily Nick Birbilis 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2022年第6期1511-1541,共31页
Magnesium alloys remain critical in the context of light-weighting and advanced devices. The increased utilisation of magnesium(Mg)each year reveals growing demand for its Mg-based alloys. Additive manufacturing(AM) p... Magnesium alloys remain critical in the context of light-weighting and advanced devices. The increased utilisation of magnesium(Mg)each year reveals growing demand for its Mg-based alloys. Additive manufacturing(AM) provides the possibility to directly manufacture components in net-shape, providing new possibilities and applications for the use of Mg-alloys, and new prospects in the utilisation of novel physical structures made possible from ‘3D printing’. The review herein seeks to holistically explore the additive manufacturing of Mg-alloys to date, including a synopsis of processes used and properties measured(with a comparison to conventionally prepared Mg-alloys). The challenges and possibilities of AM Mg-alloys are critically elaborated for the field of mechanical metallurgy. 展开更多
关键词 MAGNESIUM additive manufacturing MICROSTRUCTURE 3D printing Mechanical properties Electrochemical properties
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3DPMD-Arc-based additive manufacturing with titanium powder as raw material 被引量:13
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作者 Hoefer Kevin Mayr Peter 《China Welding》 EI CAS 2019年第1期11-15,共5页
The study aims to demonstrate the suitability of the 3DPMD for the production of titanium components with and without reinforcing particles in layer-by-layer design. Various demonstrators are prepared and analyzed. Th... The study aims to demonstrate the suitability of the 3DPMD for the production of titanium components with and without reinforcing particles in layer-by-layer design. Various demonstrators are prepared and analyzed. The microstructure, the porosity and the hardness values of the different structures are compared with each other through metallographic cross-sections. The uniform distribution of the carbides and the interaction with the matrix was analyzed by SEM and EDX.The miller-test method(ASTM G75-07) was used to determine data for the relative abrasivity of the structures. In summary, 3DPMD offers the possibility to produce titanium structures with and without reinforced particles. Using automated routines, it is possible to generate metal structures using welding robots directly from the CAD drawings. Microstructures and properties are directly related to the process and therefore material-process-property relationships are discussed within this work. 展开更多
关键词 additive manufacturing PLASMA TITANIUM 3D PLASMA metal DEPOSITION REINFORCED PARTICLES
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Interfacial Bonding Mechanism and Mechanical Performance of Continuous Fiber Reinforced Composites in Additive Manufacturing 被引量:10
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作者 Congze Fan Zhongde Shan +2 位作者 Guisheng Zou Li Zhan Dongdong Yan 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2021年第1期131-141,共11页
The additive manufacturing of continuous fiber composites has the advantage of a high-precision and efficient forming process,which can realize the lightweight and integrated manufacturing of complex structures.Howeve... The additive manufacturing of continuous fiber composites has the advantage of a high-precision and efficient forming process,which can realize the lightweight and integrated manufacturing of complex structures.However,many void defects exist between layers in the printing process of additive manufacturing;consequently,the bonding performance between layers is poor.The bonding neck is considered a key parameter for representing the quality of interfacial bonding.In this study,the formation mechanism of the bonding neck was comprehensively analyzed.First,the influence of the nozzle and basement temperatures on the printing performance and bonding neck size was measured.Second,CT scanning was used to realize the quantitative characterization of bonding neck parameters,and the reason behind the deviation of actual measurements from theoretical calculations was analyzed.When the nozzle temperature increased from 180 to 220℃,CT measurement showed that the bonding neck diameter increased from 0.29 to 0.34 mm,and the cross-sectional porosity reduced from 5.48%to 3.22%.Finally,the fracture mechanism was studied,and the influence of the interfacial bonding quality on the destruction process of the materials was determined.In conclusion,this study can assist in optimizing the process parameters,which improves the precision of the printing parts and performance between the layers. 展开更多
关键词 3D printing Thermoplastic resin Continuous fiber additive manufacturing
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Additive Manufacture of Ceramics Components by Inkjet Printing 被引量:19
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作者 Brian Derby 《Engineering》 SCIE EI 2015年第1期113-123,共11页
In order to build a ceramic component by inkjet printing, the object must be fabricated through the interaction and solidification of drops, typically in the range of 10–100 p L. In order to achieve this goal, stable... In order to build a ceramic component by inkjet printing, the object must be fabricated through the interaction and solidification of drops, typically in the range of 10–100 p L. In order to achieve this goal, stable ceramic inks must be developed. These inks should satisfy specific rheological conditions that can be illustrated within a parameter space defined by the Reynolds and Weber numbers. Printed drops initially deform on impact with a surface by dynamic dissipative processes, but then spread to an equilibrium shape defined by capillarity. We can identify the processes by which these drops interact to form linear features during printing, but there is a poorer level of understanding as to how 2D and 3D structures form. The stability of 2D sheets of ink appears to be possible over a more limited range of process conditions that is seen with the formation of lines. In most cases, the ink solidifies through evaporation and there is a need to control the drying process to eliminate the "coffee ring" defect. Despite these uncertainties, there have been a large number of reports on the successful use of inkjet printing for the manufacture of small ceramic components from a number of different ceramics. This technique offers good prospects as a future manufacturing technique. This review identifies potential areas for future research to improve our understanding of this manufacturing method. 展开更多
关键词 additive manufacture 3D printing inkjet printing ceramic components
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