The UV photooxidation with Fe（Ⅲ） and H2O2 was employed to treat a naval derusting wastewater, which contains the high COD （chemical oxygen demand） and various metal concentrations exceptionally with high concentr...The UV photooxidation with Fe（Ⅲ） and H2O2 was employed to treat a naval derusting wastewater, which contains the high COD （chemical oxygen demand） and various metal concentrations exceptionally with high concentrations of citric acid and iron. Because of its iron containment, the Fenton-like reaction automatically took place with the added amount of H2O2. The decomposition rate was found in a sequence of： UV/HEOE/Fe（Ⅲ） 〉 UV/H2O2 〉 Fe（Ⅱ）/H2O2. Two H2O2 injection methods, single and multiple points, were evaluated. The multiple-point H2O2 injection was more efficient to decompose the citric acid. The decomposition of the synthetic citric acid and the real derusting citric acid wastewater was also compared. The 93% COD reduction of the derusting wastewater was achieved using the UV/HEOE/Fe（Ⅲ） treatment.展开更多
The highly-dispersed iron element decorated Ni foam was prepared by simple immersion in a ferric nitrate solution at room temperature without using acid etching, and characterized by X-ray powder diffraction(XRD), sca...The highly-dispersed iron element decorated Ni foam was prepared by simple immersion in a ferric nitrate solution at room temperature without using acid etching, and characterized by X-ray powder diffraction(XRD), scanning electron microscopy(SEM), EDAX spectrum(EDAX mapping) and Raman spectroscopy. The EDAX spectrum illustrated that iron element was highly-dispersed over the entire surface of nickel foam, and the Raman spectroscopy revealed that both Ni-O and Fe-O bonds were formed on the surface of the as-prepared electrode. Moreover, the iron element decorated Ni foam electrode can be used as non-enzymatic glucose sensor and it exhibits not only an ultra-wide linear concentration range of 1-18 mmol/L with an outstanding sensitivity of 1.0388 m A·mmol/(L·cm2), but also an excellent ability of stability and selectivity. Therefore, this work presents a simple yet effective approach to successfully modify Ni foam as non-enzymatic glucose sensor.展开更多
The formation of a rust layer on iron and steels surfaces accelerates their degradation and eventually causes material failure.In addition to fabricating a protective layer or using a sacrificial anode, repairing or r...The formation of a rust layer on iron and steels surfaces accelerates their degradation and eventually causes material failure.In addition to fabricating a protective layer or using a sacrificial anode, repairing or removing the rust layer is another way to reduce the corrosion rate and extend the lifespans of iron and steels.Herein, an electrochemical healing approach was employed to repair the rust layer in molten Na_(2)CO_(3)-K_(2)CO_(3).The rusty layers on iron rods and screws were electrochemically converted to iron in only several minutes and a metallic luster appeared.Scanning electron microscopy(SEM) and energy dispersive X-ray spectroscopy(EDS) analyses showed that the structures of the rust layer after healing were slightly porous and the oxygen content reached a very low level.Thus, high-temperature molten-salt electrolysis may be an effective way to metalize iron rust of various shapes and structures in a short time, and could be used in the repair of cultural relics and even preparing a three-dimensional porous structures for other applications.展开更多
The structure, working principles, and main technological parameters of the premajet derusting machine are introduced. Experiments were made to test the relationship among such jet parameters as working pressure, rate...The structure, working principles, and main technological parameters of the premajet derusting machine are introduced. Experiments were made to test the relationship among such jet parameters as working pressure, rate of water flow, abrasive weight consistency and derusting efficiency. Reasonable parameters were decided. Results prove that the derusting machine is characterized by its high derusting efficiency (as high as 20m 2/h), good derusting quality (as good as ISO8501 1 Sa 2.5), and low specific power consumption (about 0.3kW·h/m 2). Therefore it is a new type of high efficiency derusting machine.展开更多
Rapid dynamics and remarkable proton conduction induced by confined water in nanospaces have attracted much attentions from researchers,which is crucial for advancing the development of innovative proton conductors an...Rapid dynamics and remarkable proton conduction induced by confined water in nanospaces have attracted much attentions from researchers,which is crucial for advancing the development of innovative proton conductors and deepening comprehension of proton and water transport mechanisms within biological systems.In this aspect,carbon nanotubes(CNTs)are frequently employed as a research platform.However,they possess certain limitations,such as their inherent electronic conductivity and extreme hydrophobicity,which can impede the accurate assessment and precise regulation of proton conduction.We herein prepared two 2D COFs with different hydrophilic fragment,and obtained maximum acid-free proton conductivity of 3.04×10^(–4) S·cm^(–1) at 70℃ and 100%RH with Grotthuss type activation energy of 0.14 eV.This is mainly due to that the water molecules in the center of channel form strong hydrogen bonds,enhancing proton dissociation and guiding fast directional diffusion.展开更多
文摘The UV photooxidation with Fe（Ⅲ） and H2O2 was employed to treat a naval derusting wastewater, which contains the high COD （chemical oxygen demand） and various metal concentrations exceptionally with high concentrations of citric acid and iron. Because of its iron containment, the Fenton-like reaction automatically took place with the added amount of H2O2. The decomposition rate was found in a sequence of： UV/HEOE/Fe（Ⅲ） 〉 UV/H2O2 〉 Fe（Ⅱ）/H2O2. Two H2O2 injection methods, single and multiple points, were evaluated. The multiple-point H2O2 injection was more efficient to decompose the citric acid. The decomposition of the synthetic citric acid and the real derusting citric acid wastewater was also compared. The 93% COD reduction of the derusting wastewater was achieved using the UV/HEOE/Fe（Ⅲ） treatment.
基金Project(2019zzts684)supported by the Fundamental Research Funds for the Central Universities,China。
文摘The highly-dispersed iron element decorated Ni foam was prepared by simple immersion in a ferric nitrate solution at room temperature without using acid etching, and characterized by X-ray powder diffraction(XRD), scanning electron microscopy(SEM), EDAX spectrum(EDAX mapping) and Raman spectroscopy. The EDAX spectrum illustrated that iron element was highly-dispersed over the entire surface of nickel foam, and the Raman spectroscopy revealed that both Ni-O and Fe-O bonds were formed on the surface of the as-prepared electrode. Moreover, the iron element decorated Ni foam electrode can be used as non-enzymatic glucose sensor and it exhibits not only an ultra-wide linear concentration range of 1-18 mmol/L with an outstanding sensitivity of 1.0388 m A·mmol/(L·cm2), but also an excellent ability of stability and selectivity. Therefore, this work presents a simple yet effective approach to successfully modify Ni foam as non-enzymatic glucose sensor.
基金financially supported by the Fundamental Research Funds for the Central Universities (No.N172505002)the National Natural Science Foundation of China (No.51704060)+1 种基金the National Thousand Youth Talent Program of Chinathe 111 Project (No.B16009)。
文摘The formation of a rust layer on iron and steels surfaces accelerates their degradation and eventually causes material failure.In addition to fabricating a protective layer or using a sacrificial anode, repairing or removing the rust layer is another way to reduce the corrosion rate and extend the lifespans of iron and steels.Herein, an electrochemical healing approach was employed to repair the rust layer in molten Na_(2)CO_(3)-K_(2)CO_(3).The rusty layers on iron rods and screws were electrochemically converted to iron in only several minutes and a metallic luster appeared.Scanning electron microscopy(SEM) and energy dispersive X-ray spectroscopy(EDS) analyses showed that the structures of the rust layer after healing were slightly porous and the oxygen content reached a very low level.Thus, high-temperature molten-salt electrolysis may be an effective way to metalize iron rust of various shapes and structures in a short time, and could be used in the repair of cultural relics and even preparing a three-dimensional porous structures for other applications.
文摘The structure, working principles, and main technological parameters of the premajet derusting machine are introduced. Experiments were made to test the relationship among such jet parameters as working pressure, rate of water flow, abrasive weight consistency and derusting efficiency. Reasonable parameters were decided. Results prove that the derusting machine is characterized by its high derusting efficiency (as high as 20m 2/h), good derusting quality (as good as ISO8501 1 Sa 2.5), and low specific power consumption (about 0.3kW·h/m 2). Therefore it is a new type of high efficiency derusting machine.
基金supported by National Natural Science Foundation of China(52207238)China Postdoctoral Science Foundation(2023M731361)Jiangsu University Senior Talent Launch Fund.
文摘Rapid dynamics and remarkable proton conduction induced by confined water in nanospaces have attracted much attentions from researchers,which is crucial for advancing the development of innovative proton conductors and deepening comprehension of proton and water transport mechanisms within biological systems.In this aspect,carbon nanotubes(CNTs)are frequently employed as a research platform.However,they possess certain limitations,such as their inherent electronic conductivity and extreme hydrophobicity,which can impede the accurate assessment and precise regulation of proton conduction.We herein prepared two 2D COFs with different hydrophilic fragment,and obtained maximum acid-free proton conductivity of 3.04×10^(–4) S·cm^(–1) at 70℃ and 100%RH with Grotthuss type activation energy of 0.14 eV.This is mainly due to that the water molecules in the center of channel form strong hydrogen bonds,enhancing proton dissociation and guiding fast directional diffusion.
