In order to investigate the electromagnetic shielding effectiveness （SE） and absorbing properties of fiber reinforced concrete, steel fiber, carbon fiber and synthetic polyvinyl alcohol （PVA） fiber reinforced conc...In order to investigate the electromagnetic shielding effectiveness （SE） and absorbing properties of fiber reinforced concrete, steel fiber, carbon fiber and synthetic polyvinyl alcohol （PVA） fiber reinforced concrete were researched. The results show that with the increase of fiber Volume fraction, the SE and trend of frequency change of corresponding fiber reinforced concrete are enhanced. When the volume content of steel fiber is 3%, the SE of concrete is above 50 dB and its frequency is above 1.8 GHz. Moreover, in the range of 8-18 GHz, steel fiber, carbon fiber and PVA fiber all can improve the microwave absorption properties of concrete. The concrete with 0.5% carbon fiber can achieve the best absorbing property, the minimum reflectivity is about -7 dB; while steel fiber optimal volume fraction is 2%. The reflectivity curve of PVA fiber reinforced concrete fluctuates with the frequency, and the minimum value of the reflectivity is below -10 dB. The results show that fiber reinforced concrete could be used as EMI（electromagnetic interference） prevention buildings by attenuating and reflecting electromagnetic wave energy.展开更多
Spatial and temporal variability of the absorption properties of colored dissolved organic matter （CDOM） in the Taiwan Strait was investigated in summer （July to August of 2006） and winter （from December 2006 to ...Spatial and temporal variability of the absorption properties of colored dissolved organic matter （CDOM） in the Taiwan Strait was investigated in summer （July to August of 2006） and winter （from December 2006 to January of 2007） seasons. The CDOM absorption coefficient at 280 nm （a 280 ） showed a decreasing trend from nearshore to offshore areas while the spectral slope coefficient parameter calculated between wavelengths 275–295 nm （S 275 295 ） showed an increase, indicative of decreasing aromaticity and molecular weight of the CDOM. The average a 280 in winter （1.47 ± 0.50 m ^-1 ） was significantly higher than in summer （1.10 ± 0.41 m ^-1 ）, while the average S 275 295 in winter （26.7 ± 5.2 μm^- 1 ） was significantly lower than in summer （30.6 ± 5.5 μm^- 1 ）, demonstrating clear seasonal variation in CDOM abundance and properties in the Taiwan Strait. A three-end- member conservative mixing model showed that local terrestrial CDOM inputs from several rivers along the western coast were small （〈5%）. However, the distribution of CDOM in the Taiwan Strait is mainly controlled by water mass movement [i.e., the Zhe-min Coastal Current （ZCC） and the Kuroshio Branch Current （KBC） in winter and the South China Sea Water （SCSW） in summer]. Biological activity was also an important factor affecting the distribution of CDOM in the offshore region in summer months.展开更多
Foam structure materials are well known for their lightweight,efficient,and broadband microwave absorption properties compared to bulk material.However,little has been understood about the effect of a foam structure o...Foam structure materials are well known for their lightweight,efficient,and broadband microwave absorption properties compared to bulk material.However,little has been understood about the effect of a foam structure on the absorption performance of the foam material.In this study,the role of foam structure properties of the silicon carbide/carbon(SiC/C)foam material on microwave absorption is explored using experiment and simulation.We find that the foam structure of SiC/C foam material causes diffraction,multiple reflections,improves the interfacial polarization,and compatibilization.The absorption performance of SiC/C foam material is also studied.The-10 dB effective absorption bandwidth can be adjusted from 4.0 GHz to 18 GHz by tuning SiC/C foam material thickness to 3-7 mm.Therefore,the foam structure design is an effective way to improve the absorption performance of the SiC/C foam material.展开更多
Objective: To determine the in vitro and in vivo absorption properties of active ingredients of the Chinese medicine, baicalein, to enrich mechanistic understanding of oral drug absorption.Methods: The Biopharmaceutic...Objective: To determine the in vitro and in vivo absorption properties of active ingredients of the Chinese medicine, baicalein, to enrich mechanistic understanding of oral drug absorption.Methods: The Biopharmaceutic Classification System(BCS) category was determined using equilibrium solubility, intrinsic dissolution rate, and intestinal permeability to evaluate intestinal absorption mechanisms of baicalein in rats in vitro. Physiologically based pharmacokinetic(PBPK) model commercial software GastroPlus~(TM) was used to predict oral absorption of baicalein in vivo.Results: Based on equilibrium solubility, intrinsic dissolution rate, and permeability values of main absorptive segments in the duodenum, jejunum, and ileum, baicalein was classified as a drug with low solubility and high permeability. Intestinal perfusion with venous sampling(IPVS) revealed that baicalein was extensively metabolized in the body, which corresponded to the low bioavailability predicted by the PBPK model. Further, the PBPK model predicted the key indicators of BCS, leading to reclassification as BCS-II. Predicted values of peak plasma concentration of the drug(C_(max)) and area under the curve(AUC)fell within two times of the error of the measured results, highlighting the superior prediction of absorption of baicalein in rats, beagles, and humans. The PBPK model supported in vitro and in vivo evidence and provided excellent prediction for this BCS class II drug.Conclusion: BCS and PBPK are complementary methods that enable comprehensive research of BCS parameters, intestinal absorption rate, metabolism, prediction of human absorption fraction and bioavailability, simulation of PK, and drug absorption in various intestinal segments across species. This combined approach may facilitate a more comprehensive and accurate analysis of the absorption characteristics of active ingredients of Chinese medicine from in vitro and in vivo perspectives.展开更多
Superfine powders of nano-lithium ferrite doped with different kinds and amount of rare earth element were prepared by sol-gel method. Their photograph was taken by transmission electron microscopy. From it, we can se...Superfine powders of nano-lithium ferrite doped with different kinds and amount of rare earth element were prepared by sol-gel method. Their photograph was taken by transmission electron microscopy. From it, we can see most of particles are less than 100 nm and average diameter of superfine powders is 50 nm. Then their microwave absorption properties are measured by power ratio method. The result indicates that microwave absorption properties of nano-lithium ferrite doped with rare earth element change obviously. Different kinds and amount of rare earth element make different influences. Magnetic hysteresis loop is surveyed by vibrating sample magnetometer. We find that there are some relationships between magnetism and microwave absorption properties.展开更多
Carbonaceous nanomaterials such as carbon nanotubes （CNTs）, magnetic metal nanomaterials and semicon- ductor nanomaterials are superior candidates for microwave absorbers. Taking full advantage of the features of CN...Carbonaceous nanomaterials such as carbon nanotubes （CNTs）, magnetic metal nanomaterials and semicon- ductor nanomaterials are superior candidates for microwave absorbers. Taking full advantage of the features of CNTs, nanophase cobalt and nanophase zinc oxide, whose main microwave absorption mechanisms are based on resistance loss, magnetic loss and dielectric loss, we fabricate CNT/Co and CNT/ZnO heterostructure nanocom- posites, respectively. By using the CNTs, CNT/Co nanocomposites and CNT/ZnO nanocomposites as nanofillers, composites with polyester as matrix are prepared by in situ polymerization, and their microwave absorption per- formance is studied. It is indicated that the synergetic effects of the physic properties of different components in nano-heterostructures result in greatly enhanced microwave absorption performance in a wide frequency range. The absorption peak is increased, the absorption bandwidth is broadened, and the maximum peak shifts to a lower frequency.展开更多
Amorphous Ti_(0.88)Ni_(1.00) and Ti_(1.69)Ni_(1.00) alloy films are prepared by means of ion beam sputtering using TiNi and Ti_2Ni alloy targets, respectively. Their hydrogen absorption properties are investigated by ...Amorphous Ti_(0.88)Ni_(1.00) and Ti_(1.69)Ni_(1.00) alloy films are prepared by means of ion beam sputtering using TiNi and Ti_2Ni alloy targets, respectively. Their hydrogen absorption properties are investigated by a galvanostatic method. The results show th the discharge capacity of the Ti_(1.69)Ni_(1.00) sample is higher than that of the Ti_(0.88)Ni_(1.00) sample. And the film electrodes have high durability and long cycle life.展开更多
Coaxially dielectric samples consisting of different packing ratios of glass-covered Fe73.5Si13.5B9Nb3Cu1 amorphous wires embedded in a paraffin wax matrix were fabricated, and the influence of short-wire packing rati...Coaxially dielectric samples consisting of different packing ratios of glass-covered Fe73.5Si13.5B9Nb3Cu1 amorphous wires embedded in a paraffin wax matrix were fabricated, and the influence of short-wire packing ratio (3%-9% in mass fraction) and thickness (1-7 mm) on the microwave absorption properties was systematically investigated in microwave frequency range of 2-18 GHz. X-ray diffraction (XRD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM) and scalar network analyzer (SNA) were used for characterizing microstructure and evaluating microwave absorption properties. Experimental results show the significant frequency (6-18 GHz) dependence of the complex relative permeability and permittivity. The reflection loss (RL) with different thickness and short-wire packing ratio reveals that the composite sample containing 7% exhibits better microwave absorption behavior with its minimum value of RL reaching-34 dB in thickness of 3 mm at 14 GHz. Therefore, it is significantly useful to develop microwire-dielectric materials with much wider absorption band for microwave absorption applications.展开更多
Microwave absorption properties of spherical NiO particles and Co0.2Ni0.4Zn0.4Fe2O4（CNZF） ferrites with single-layer and double-layer absorbers were studied in the frequency range of 2–18 GHz. The spherical NiO par...Microwave absorption properties of spherical NiO particles and Co0.2Ni0.4Zn0.4Fe2O4（CNZF） ferrites with single-layer and double-layer absorbers were studied in the frequency range of 2–18 GHz. The spherical NiO particles were synthesized by using a hydrothermal process, while the CNZF powders were prepared by using a sol–gel autoignition method. The double-layer absorbers, composed of 30 wt% NiO as matching layer and 30 wt% CNZF as absorption layer,with a total thickness of 3.2 mm, exhibited a maximum reflection loss（RL） of –67.0 d B at 9.2 GHz and an effective absorbing bandwidth below –10 d B to be 3.9 GHz from 7.0 to 10.9 GHz. The excellent microwave absorption performance of the double-layer absorbers should be ascribed to the high impedance matching ratio, the great microwave attenuation capability, and well-coupled layer.展开更多
In this work,novel carbon nanotube(CNT)/CoSi/SiOC nanocomposite ceramics with in-situ formed multi-walled CNTs and core-shell structured CoSi@C nanoparticles were successfully prepared via a single-source-precursor de...In this work,novel carbon nanotube(CNT)/CoSi/SiOC nanocomposite ceramics with in-situ formed multi-walled CNTs and core-shell structured CoSi@C nanoparticles were successfully prepared via a single-source-precursor derived ceramic approach.Ppolymericprecursor characterization as well as phase evolution,microstructure,and electromagnetic wave(EMW)absorption properties of the ceramics were investigated in detail.The results show that the in-situ formed CNTs and magnetic CoSi@C nanoparticles provide a synergistic effect on both dielectric loss(tand:)and magnetic loss,leading to outstanding EMW absorption properties of the ceramics annealed at only 1100 C.(i)For the Co feeding of 6.25 wt%,the minimum reflection loss(RLmin)is-53.1 dB,and the effective absorption bandwidth(EAB)is 4.96 GHz(7.12-12.08 GHz)with a ceramic-paraffin hybrid sample thickness of 3.10 mm,achieving full X-band coverage;(i)for the Co feeding of 9.09 wt%,the RLmin value of-66.4 dB and the EAB value of 3.04 GHz(8.40-11.44 GHz)were achieved with a thickness of only 2.27 mm.Therefore,the present CNT/CoSi/SiOC nanocomposite ceramics have potential applications for thin,lightweight,and efficient EMW absorption in harsh environments.展开更多
This work presents the saturable absorption(SA) properties of CsPbBr_3 perovskite quantum dots(QDs). The perovskite QDs show excellent SA performance with a nonlinear absorption coefficient of-35 × 10^(-2) cm∕GW...This work presents the saturable absorption(SA) properties of CsPbBr_3 perovskite quantum dots(QDs). The perovskite QDs show excellent SA performance with a nonlinear absorption coefficient of-35 × 10^(-2) cm∕GW and a figure of merit of 3.7 × 10^(-14) esu cm. Further, their use as saturable absorbers in a passively Q-switched visible solid-state laser for the generation of soliton pulses is demonstrated. These results demonstrate thepotential for the perovskite QDs to act as saturable absorbers.展开更多
Ni1-xZnxFe2O4(0≤x≤1,in steps of 0.1) nanocrystallines were synthesized by sol-gel route.The doping effects of zinc on structural,magnetic and microwave absorption properties were investigated in detail.X-ray diffrac...Ni1-xZnxFe2O4(0≤x≤1,in steps of 0.1) nanocrystallines were synthesized by sol-gel route.The doping effects of zinc on structural,magnetic and microwave absorption properties were investigated in detail.X-ray diffraction(XRD) results show that all the samples are single-phase spinel structure.The magnetic and microwave absorption properties are strongly dependent on the zinc content,which can be understood in terms of the cations redistribution in spinel tetrahedral and octahedral sites with the increase of zinc content.The magnetic measurement shows the antiferromagnetic nature of the samples for x=0.9 and x=1.0.The saturation magnetization reaches the maximum of 3.35μB/f.u.at x=0.5.The optimal reflection loss(RL) of-29.6 dB is found at 6.5 GHz for an absorber thickness of 5 mm.The RL values exceeding 10 dB are obtained for the absorber in the range of 3.9-8.9 GHz.These Ni1-xZnxFe2O4 nanocrystallines may be attractive candidates for electromagnetic wave absorption materials.展开更多
Acoustic structure study always is the academic research interest. Diffusion ab？sorbing structure（DiflFsorber） has good research value because it has both diflFusion property and sound absorption property. Quadrati...Acoustic structure study always is the academic research interest. Diffusion ab？sorbing structure（DiflFsorber） has good research value because it has both diflFusion property and sound absorption property. Quadratic residue diffusers（QRD） structure which had good diffusion property was combined with the perforated panel which had good sound absorption property in this study. According to standard AES-4id-2001, the diffusion experiments were carried out to study QRD structure and ones composited with perforated-panels which had1 mm-thickness and perforated percentage of 3%, 5%, 8% respectively. The polar coordinate diagrams of different structure were analyzed to derive the diffusion coefficients. Results showed that the composite structure still had good diffusion performance in the frequency range from100 Hz to 800 Hz. The reflection sound energy of composite structure reduced obviously in the perforated panel resonance frequency range where there was about 2 dB reduction averagely.The study result can provide the reference for the design and development of diifsorber.展开更多
The structural,morphological,optical,and nonlinear optical properties of a lead sulfde(PbS) thin film grown by chemical bath deposition(CBD) are investigated by X-ray difraction(XRD),scanning electron microscope(SEM),...The structural,morphological,optical,and nonlinear optical properties of a lead sulfde(PbS) thin film grown by chemical bath deposition(CBD) are investigated by X-ray difraction(XRD),scanning electron microscope(SEM),ultraviolet-visible(UV-Vis),and open aperture Z-scan experiments.The band gap energy of the PbS nanocrystalline film is 1.82 eV,higher than that of bulk PbS at 300 K.The nonlinear absorption properties of the film are investigated using the open aperture Z-scan technique at 1064 nm and pulse durations of 4 ns and 65 ps.Intensity-dependent switching of the film from nonlinear absorption to saturable absorption is observed.The nonlinear absorption coefficient increases monotonically with increasing pulse duration from 65 ps to 4 ns.展开更多
The structural, electronic, and optical absorption properties of TiO2 nanotube （TiO2NT） with Cun clusters （n =1-4） adsorbed on its surface have been investigated based on density functional theory calculations. Th...The structural, electronic, and optical absorption properties of TiO2 nanotube （TiO2NT） with Cun clusters （n =1-4） adsorbed on its surface have been investigated based on density functional theory calculations. The TiO2NT is constructed by rolling up a （101） sheet of anatase TiO2 around the [ 1-01 ] direction; the ground states of Cun/TiOzNT systems are determined by analyzing the average adsorption energies. Calculation results show that odd-even oscillations occur for the average adsorption energy, the Cu-O bond length, and the amount of transferred electrons, with the increase in Cu. cluster size; and the Cun/TiO2NTs with odd n＇s demonstrate stronger interaction between the Cu. cluster and the TiO2NT. Also, the impurity states introduced by the Cun cluster to the band gap of TiOzNT cause an obvious redshift of the optical absorption spectrum toward the visible light region, especially for the even n cases.展开更多
In the research,three kinds composite materials of biomimetic laminated boards made from cross-linking starch/maize stalk fiber-the single layer jute fiber reinforced maize stalk fiber boards,the dual layer jute fiber...In the research,three kinds composite materials of biomimetic laminated boards made from cross-linking starch/maize stalk fiber-the single layer jute fiber reinforced maize stalk fiber boards,the dual layer jute fiber reinforced maize stalk fiber boards,the jute fiber hybrid reinforced maize stalk fiber boards were obtained according to the formulation of cross-linking maize starch adhesive and the preparation process of composite materials.The hygroscopicity variation of the biomimetic laminated boards made from cross-linking starch/maize stalk fiber was investigated under different relative humidity conditions.The moisture absorption rate and the variation velocity were used as important evaluation indexes to evaluate the moisture absorption properties of the straw fiber composites.The mathematical models of the moisture absorption rate and the variation velocity were established.The hygroscopicity variation curves of three kinds of composite materials were measured under the five different relative humidity conditions.The results showed that the three kinds composites had low moisture absorption rate compared with other stalk fiber composites which were good at water resistance and the waterproof property of the three kinds stalk fibers were excellent under the experimental conditions.The research provides a useful reference to improve the water resistance of fiber composites and a new idea on the development and application of the biodegradable composites,especially the straw fiber reinforced composites.展开更多
PEG (Polyethylene glycol average molecular weight 300) is used as absorbent of NO2. The absorption efficiency is found to reach up to 97%. The absorbing product, PEG NO2, can be used to cleave benzyl ethers mildly a...PEG (Polyethylene glycol average molecular weight 300) is used as absorbent of NO2. The absorption efficiency is found to reach up to 97%. The absorbing product, PEG NO2, can be used to cleave benzyl ethers mildly and selectively to benzaldehyde and corresponding fatty alcohols, showing that PEG is a valuable oxidizing agent of benzyl ethers. As a carrier of NO2.PEG can be recovered and utilized repeatedly after the oxidation.展开更多
At present,developing high-efficiency microwave absorption materials with properties including lightweight,thin thickness,strong absorbing intensity and broad bandwidth is an urgent demand to solve the electromagnetic...At present,developing high-efficiency microwave absorption materials with properties including lightweight,thin thickness,strong absorbing intensity and broad bandwidth is an urgent demand to solve the electromagnetic pollution issues.An ideal microwave absorber should have excellent dielectric and magnetic loss capabilities,thereby inducing attenuation and absorption of incident electromagnetic radiation.Recently,various carbon/magnetic metal composites have been developed and expected to become promising candidates for high-performance microwave absorbers.In this review,we introduce the mechanisms of microwave absorption and summarize the recent advances in carbon/magnetic metal composites.Preparation methods and microwave absorption properties of carbon/magnetic metal composites with different components,morphologies and microstructures are discussed in detail.Finally,the challenges and future prospects of carbon/magnetic metal absorbing materials are also proposed,which will be useful to develop high-performance microwave absorption materials.展开更多
Previous results revealed that the defect and/or interface had a great impact on the electromagnetic pa-rameters of materials.In order to understand the main physical mechanisms and effectively utilize these strategie...Previous results revealed that the defect and/or interface had a great impact on the electromagnetic pa-rameters of materials.In order to understand the main physical mechanisms and effectively utilize these strategies,in this study,M Fe_(2)O_(4)and flower-like core@shell M Fe_(2)O_(4)@MoS_(2)(M=Mn,Ni,and Zn)sam-ples with different categories were elaborately designed and selectively produced in large scale through a simple two-step hydrothermal reaction.We conducted the systematical investigation on their microstruc-tures,electromagnetic parameters and microwave absorption performances(MAPs).The obtained results revealed that the large radius of M^(2+)cation could effectively boost the concentration of oxygen vacancy in the M Fe_(2)O_(4)and M Fe_(2)O_(4)@MoS_(2)samples,which resulted in the improvement of dielectric loss capabil-ities and MAPs.Furthermore,the introduction of MoS_(2)nanosheets greatly improved the interfacial effect and enhanced the polarization loss capabilities,which also boosted the MAPs.By taking full advantage of the defect and interface,the designed M Fe_(2)O_(4)@MoS_(2)samples displayed tunable and excellent com-prehensive MAPs including strong absorption capability,wide absorption bandwidth and thin matching thicknesses.Therefore,the clear understanding of defect and interface engineering made these strategies well elaborately designed and applicable to improving MAPs.展开更多
Ultra-light carboxylic functionalized multi-walled carbon nanotubes(CNTs-COOH) and Ti3C2 MXene hybrids modified sodium alginate(CNTs/Ti3C2-SA) based composite foams were prepared through ice-templated freeze-drying me...Ultra-light carboxylic functionalized multi-walled carbon nanotubes(CNTs-COOH) and Ti3C2 MXene hybrids modified sodium alginate(CNTs/Ti3C2-SA) based composite foams were prepared through ice-templated freeze-drying method. The microstructure of the synthesized CNTs/Ti3C2 hybrids and CNTs/Ti3C2-SA foams is characterized by the presence of CNTs inserted between MXene layers which prevents their restacking. The resultant CNTs/Ti3C2 hybrids exhibit a unique sandwich-like hierarchical structure. Scanning electron microscopy(SEM) images show that the CNTs/Ti3C2-SA foam exhibits a heterogeneous anisotropic microstructure and CNTs/Ti3C2 hybrids are homogeneously dispersed in the skeleton of the porous foam. In case that the content of the hybrids amounts 40 mg/cm^3, the CNTs/Ti3C2-SA foam possesses excellent electromagnetic(EM) absorption performance with a minimum reflection coefficient(RCmin) as low as-40.0 dB. In case of a sample thickness of 3.95 mm, the RCminreaches-24.4 dB and the effective absorption bandwidth covers the whole X band from 8.2 to 12.4 GHz. A control test shows that, with the same absorbent content, the CNTs/Ti3C2-SA foam exhibits a far better EM performance than that of CNT-free Ti3C2-SA foam.展开更多
基金Chinese Government for Scientific Researches (No. A1420060186)Doctoral Fundation of University of Jinan(No. XBS1026)
文摘In order to investigate the electromagnetic shielding effectiveness （SE） and absorbing properties of fiber reinforced concrete, steel fiber, carbon fiber and synthetic polyvinyl alcohol （PVA） fiber reinforced concrete were researched. The results show that with the increase of fiber Volume fraction, the SE and trend of frequency change of corresponding fiber reinforced concrete are enhanced. When the volume content of steel fiber is 3%, the SE of concrete is above 50 dB and its frequency is above 1.8 GHz. Moreover, in the range of 8-18 GHz, steel fiber, carbon fiber and PVA fiber all can improve the microwave absorption properties of concrete. The concrete with 0.5% carbon fiber can achieve the best absorbing property, the minimum reflectivity is about -7 dB; while steel fiber optimal volume fraction is 2%. The reflectivity curve of PVA fiber reinforced concrete fluctuates with the frequency, and the minimum value of the reflectivity is below -10 dB. The results show that fiber reinforced concrete could be used as EMI（electromagnetic interference） prevention buildings by attenuating and reflecting electromagnetic wave energy.
基金Scientific Research Foundation of Third Institute of Oceanography, State Oceanic Administration under contract No. TIO 2009007the National Natural Science Foundation of China under contract No. 41276064+3 种基金Fujian Provincial Surveys of Marine Chemistry in Coastal Waters and Harbours under contract No. FJ908-04-07River Basin-Estuary Ecological Security Assessment and Management Strategy under contract No. 200805064the National 908 Surveys of Marine Chemistry in Coastal Waters under contract No. 908-ZC-I-03the Fujian Provincial 908 Project under contract No. FJ-01-01-HS(chemistry)
文摘Spatial and temporal variability of the absorption properties of colored dissolved organic matter （CDOM） in the Taiwan Strait was investigated in summer （July to August of 2006） and winter （from December 2006 to January of 2007） seasons. The CDOM absorption coefficient at 280 nm （a 280 ） showed a decreasing trend from nearshore to offshore areas while the spectral slope coefficient parameter calculated between wavelengths 275–295 nm （S 275 295 ） showed an increase, indicative of decreasing aromaticity and molecular weight of the CDOM. The average a 280 in winter （1.47 ± 0.50 m ^-1 ） was significantly higher than in summer （1.10 ± 0.41 m ^-1 ）, while the average S 275 295 in winter （26.7 ± 5.2 μm^- 1 ） was significantly lower than in summer （30.6 ± 5.5 μm^- 1 ）, demonstrating clear seasonal variation in CDOM abundance and properties in the Taiwan Strait. A three-end- member conservative mixing model showed that local terrestrial CDOM inputs from several rivers along the western coast were small （〈5%）. However, the distribution of CDOM in the Taiwan Strait is mainly controlled by water mass movement [i.e., the Zhe-min Coastal Current （ZCC） and the Kuroshio Branch Current （KBC） in winter and the South China Sea Water （SCSW） in summer]. Biological activity was also an important factor affecting the distribution of CDOM in the offshore region in summer months.
文摘Foam structure materials are well known for their lightweight,efficient,and broadband microwave absorption properties compared to bulk material.However,little has been understood about the effect of a foam structure on the absorption performance of the foam material.In this study,the role of foam structure properties of the silicon carbide/carbon(SiC/C)foam material on microwave absorption is explored using experiment and simulation.We find that the foam structure of SiC/C foam material causes diffraction,multiple reflections,improves the interfacial polarization,and compatibilization.The absorption performance of SiC/C foam material is also studied.The-10 dB effective absorption bandwidth can be adjusted from 4.0 GHz to 18 GHz by tuning SiC/C foam material thickness to 3-7 mm.Therefore,the foam structure design is an effective way to improve the absorption performance of the SiC/C foam material.
基金supported by the National Natural Science Foundation of China (81473362)。
文摘Objective: To determine the in vitro and in vivo absorption properties of active ingredients of the Chinese medicine, baicalein, to enrich mechanistic understanding of oral drug absorption.Methods: The Biopharmaceutic Classification System(BCS) category was determined using equilibrium solubility, intrinsic dissolution rate, and intestinal permeability to evaluate intestinal absorption mechanisms of baicalein in rats in vitro. Physiologically based pharmacokinetic(PBPK) model commercial software GastroPlus~(TM) was used to predict oral absorption of baicalein in vivo.Results: Based on equilibrium solubility, intrinsic dissolution rate, and permeability values of main absorptive segments in the duodenum, jejunum, and ileum, baicalein was classified as a drug with low solubility and high permeability. Intestinal perfusion with venous sampling(IPVS) revealed that baicalein was extensively metabolized in the body, which corresponded to the low bioavailability predicted by the PBPK model. Further, the PBPK model predicted the key indicators of BCS, leading to reclassification as BCS-II. Predicted values of peak plasma concentration of the drug(C_(max)) and area under the curve(AUC)fell within two times of the error of the measured results, highlighting the superior prediction of absorption of baicalein in rats, beagles, and humans. The PBPK model supported in vitro and in vivo evidence and provided excellent prediction for this BCS class II drug.Conclusion: BCS and PBPK are complementary methods that enable comprehensive research of BCS parameters, intestinal absorption rate, metabolism, prediction of human absorption fraction and bioavailability, simulation of PK, and drug absorption in various intestinal segments across species. This combined approach may facilitate a more comprehensive and accurate analysis of the absorption characteristics of active ingredients of Chinese medicine from in vitro and in vivo perspectives.
文摘Superfine powders of nano-lithium ferrite doped with different kinds and amount of rare earth element were prepared by sol-gel method. Their photograph was taken by transmission electron microscopy. From it, we can see most of particles are less than 100 nm and average diameter of superfine powders is 50 nm. Then their microwave absorption properties are measured by power ratio method. The result indicates that microwave absorption properties of nano-lithium ferrite doped with rare earth element change obviously. Different kinds and amount of rare earth element make different influences. Magnetic hysteresis loop is surveyed by vibrating sample magnetometer. We find that there are some relationships between magnetism and microwave absorption properties.
基金Supported by the National Natural Science Foundation of China under Grant No 10332020
文摘Carbonaceous nanomaterials such as carbon nanotubes （CNTs）, magnetic metal nanomaterials and semicon- ductor nanomaterials are superior candidates for microwave absorbers. Taking full advantage of the features of CNTs, nanophase cobalt and nanophase zinc oxide, whose main microwave absorption mechanisms are based on resistance loss, magnetic loss and dielectric loss, we fabricate CNT/Co and CNT/ZnO heterostructure nanocom- posites, respectively. By using the CNTs, CNT/Co nanocomposites and CNT/ZnO nanocomposites as nanofillers, composites with polyester as matrix are prepared by in situ polymerization, and their microwave absorption per- formance is studied. It is indicated that the synergetic effects of the physic properties of different components in nano-heterostructures result in greatly enhanced microwave absorption performance in a wide frequency range. The absorption peak is increased, the absorption bandwidth is broadened, and the maximum peak shifts to a lower frequency.
文摘Amorphous Ti_(0.88)Ni_(1.00) and Ti_(1.69)Ni_(1.00) alloy films are prepared by means of ion beam sputtering using TiNi and Ti_2Ni alloy targets, respectively. Their hydrogen absorption properties are investigated by a galvanostatic method. The results show th the discharge capacity of the Ti_(1.69)Ni_(1.00) sample is higher than that of the Ti_(0.88)Ni_(1.00) sample. And the film electrodes have high durability and long cycle life.
基金Project(51371067)supported by the National Natural Science Foundation of China
文摘Coaxially dielectric samples consisting of different packing ratios of glass-covered Fe73.5Si13.5B9Nb3Cu1 amorphous wires embedded in a paraffin wax matrix were fabricated, and the influence of short-wire packing ratio (3%-9% in mass fraction) and thickness (1-7 mm) on the microwave absorption properties was systematically investigated in microwave frequency range of 2-18 GHz. X-ray diffraction (XRD), differential scanning calorimetry (DSC), scanning electron microscopy (SEM) and scalar network analyzer (SNA) were used for characterizing microstructure and evaluating microwave absorption properties. Experimental results show the significant frequency (6-18 GHz) dependence of the complex relative permeability and permittivity. The reflection loss (RL) with different thickness and short-wire packing ratio reveals that the composite sample containing 7% exhibits better microwave absorption behavior with its minimum value of RL reaching-34 dB in thickness of 3 mm at 14 GHz. Therefore, it is significantly useful to develop microwire-dielectric materials with much wider absorption band for microwave absorption applications.
基金financially supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)the Opening Project of Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology (ASMA201405)+1 种基金the National Natural Science Foundation of China (51672129)Singapore MOE AcRF Tier 1 Project (Research ID 477)
文摘Microwave absorption properties of spherical NiO particles and Co0.2Ni0.4Zn0.4Fe2O4（CNZF） ferrites with single-layer and double-layer absorbers were studied in the frequency range of 2–18 GHz. The spherical NiO particles were synthesized by using a hydrothermal process, while the CNZF powders were prepared by using a sol–gel autoignition method. The double-layer absorbers, composed of 30 wt% NiO as matching layer and 30 wt% CNZF as absorption layer,with a total thickness of 3.2 mm, exhibited a maximum reflection loss（RL） of –67.0 d B at 9.2 GHz and an effective absorbing bandwidth below –10 d B to be 3.9 GHz from 7.0 to 10.9 GHz. The excellent microwave absorption performance of the double-layer absorbers should be ascribed to the high impedance matching ratio, the great microwave attenuation capability, and well-coupled layer.
基金the National Natural Science Foundation of China(Nos.51872246 and 52061135102)for financial support.
文摘In this work,novel carbon nanotube(CNT)/CoSi/SiOC nanocomposite ceramics with in-situ formed multi-walled CNTs and core-shell structured CoSi@C nanoparticles were successfully prepared via a single-source-precursor derived ceramic approach.Ppolymericprecursor characterization as well as phase evolution,microstructure,and electromagnetic wave(EMW)absorption properties of the ceramics were investigated in detail.The results show that the in-situ formed CNTs and magnetic CoSi@C nanoparticles provide a synergistic effect on both dielectric loss(tand:)and magnetic loss,leading to outstanding EMW absorption properties of the ceramics annealed at only 1100 C.(i)For the Co feeding of 6.25 wt%,the minimum reflection loss(RLmin)is-53.1 dB,and the effective absorption bandwidth(EAB)is 4.96 GHz(7.12-12.08 GHz)with a ceramic-paraffin hybrid sample thickness of 3.10 mm,achieving full X-band coverage;(i)for the Co feeding of 9.09 wt%,the RLmin value of-66.4 dB and the EAB value of 3.04 GHz(8.40-11.44 GHz)were achieved with a thickness of only 2.27 mm.Therefore,the present CNT/CoSi/SiOC nanocomposite ceramics have potential applications for thin,lightweight,and efficient EMW absorption in harsh environments.
基金National Natural Science Foundation of China(NSFC)(61378074,61475173)Youth Innovation Promotion Association Chinese Academy of Sciences(CAS)
文摘This work presents the saturable absorption(SA) properties of CsPbBr_3 perovskite quantum dots(QDs). The perovskite QDs show excellent SA performance with a nonlinear absorption coefficient of-35 × 10^(-2) cm∕GW and a figure of merit of 3.7 × 10^(-14) esu cm. Further, their use as saturable absorbers in a passively Q-switched visible solid-state laser for the generation of soliton pulses is demonstrated. These results demonstrate thepotential for the perovskite QDs to act as saturable absorbers.
基金supported by the National Natural Science Foundation of China (Grant Nos.10874051,51002156,and 11104098)the Natural Science Major Foundation of Anhui Provincial Higher Education Institutions of China (Grant No. KJ2012ZD14)
文摘Ni1-xZnxFe2O4(0≤x≤1,in steps of 0.1) nanocrystallines were synthesized by sol-gel route.The doping effects of zinc on structural,magnetic and microwave absorption properties were investigated in detail.X-ray diffraction(XRD) results show that all the samples are single-phase spinel structure.The magnetic and microwave absorption properties are strongly dependent on the zinc content,which can be understood in terms of the cations redistribution in spinel tetrahedral and octahedral sites with the increase of zinc content.The magnetic measurement shows the antiferromagnetic nature of the samples for x=0.9 and x=1.0.The saturation magnetization reaches the maximum of 3.35μB/f.u.at x=0.5.The optimal reflection loss(RL) of-29.6 dB is found at 6.5 GHz for an absorber thickness of 5 mm.The RL values exceeding 10 dB are obtained for the absorber in the range of 3.9-8.9 GHz.These Ni1-xZnxFe2O4 nanocrystallines may be attractive candidates for electromagnetic wave absorption materials.
基金supported by the National Natural Science Foundation of China(11004133)open project of China communication and transportation industry key laboratory of environmental technology
文摘Acoustic structure study always is the academic research interest. Diffusion ab？sorbing structure（DiflFsorber） has good research value because it has both diflFusion property and sound absorption property. Quadratic residue diffusers（QRD） structure which had good diffusion property was combined with the perforated panel which had good sound absorption property in this study. According to standard AES-4id-2001, the diffusion experiments were carried out to study QRD structure and ones composited with perforated-panels which had1 mm-thickness and perforated percentage of 3%, 5%, 8% respectively. The polar coordinate diagrams of different structure were analyzed to derive the diffusion coefficients. Results showed that the composite structure still had good diffusion performance in the frequency range from100 Hz to 800 Hz. The reflection sound energy of composite structure reduced obviously in the perforated panel resonance frequency range where there was about 2 dB reduction averagely.The study result can provide the reference for the design and development of diifsorber.
文摘The structural,morphological,optical,and nonlinear optical properties of a lead sulfde(PbS) thin film grown by chemical bath deposition(CBD) are investigated by X-ray difraction(XRD),scanning electron microscope(SEM),ultraviolet-visible(UV-Vis),and open aperture Z-scan experiments.The band gap energy of the PbS nanocrystalline film is 1.82 eV,higher than that of bulk PbS at 300 K.The nonlinear absorption properties of the film are investigated using the open aperture Z-scan technique at 1064 nm and pulse durations of 4 ns and 65 ps.Intensity-dependent switching of the film from nonlinear absorption to saturable absorption is observed.The nonlinear absorption coefficient increases monotonically with increasing pulse duration from 65 ps to 4 ns.
基金supported by the National Natural Science Foundation of China(Grant No.11104199)the Natural Science Foundation of Shanxi Province,China(Grant No.2012011021-3)
文摘The structural, electronic, and optical absorption properties of TiO2 nanotube （TiO2NT） with Cun clusters （n =1-4） adsorbed on its surface have been investigated based on density functional theory calculations. The TiO2NT is constructed by rolling up a （101） sheet of anatase TiO2 around the [ 1-01 ] direction; the ground states of Cun/TiOzNT systems are determined by analyzing the average adsorption energies. Calculation results show that odd-even oscillations occur for the average adsorption energy, the Cu-O bond length, and the amount of transferred electrons, with the increase in Cu. cluster size; and the Cun/TiO2NTs with odd n＇s demonstrate stronger interaction between the Cu. cluster and the TiO2NT. Also, the impurity states introduced by the Cun cluster to the band gap of TiOzNT cause an obvious redshift of the optical absorption spectrum toward the visible light region, especially for the even n cases.
基金supported by National Science Fund for Distinguished Young Scho lars of China(Grant No.50025516)National Natural Science Foundation of China(Grant No.50675087,50673037,5030600131)+1 种基金"985 Project"of Jilin University,Natural Science Foundation of Henan Educational Committee(Grant No.2009B210006)Innovation Ability Foundation of Natural Science(Grant No.2013ZCX002)of Henan University of Science and Technology.
文摘In the research,three kinds composite materials of biomimetic laminated boards made from cross-linking starch/maize stalk fiber-the single layer jute fiber reinforced maize stalk fiber boards,the dual layer jute fiber reinforced maize stalk fiber boards,the jute fiber hybrid reinforced maize stalk fiber boards were obtained according to the formulation of cross-linking maize starch adhesive and the preparation process of composite materials.The hygroscopicity variation of the biomimetic laminated boards made from cross-linking starch/maize stalk fiber was investigated under different relative humidity conditions.The moisture absorption rate and the variation velocity were used as important evaluation indexes to evaluate the moisture absorption properties of the straw fiber composites.The mathematical models of the moisture absorption rate and the variation velocity were established.The hygroscopicity variation curves of three kinds of composite materials were measured under the five different relative humidity conditions.The results showed that the three kinds composites had low moisture absorption rate compared with other stalk fiber composites which were good at water resistance and the waterproof property of the three kinds stalk fibers were excellent under the experimental conditions.The research provides a useful reference to improve the water resistance of fiber composites and a new idea on the development and application of the biodegradable composites,especially the straw fiber reinforced composites.
文摘PEG (Polyethylene glycol average molecular weight 300) is used as absorbent of NO2. The absorption efficiency is found to reach up to 97%. The absorbing product, PEG NO2, can be used to cleave benzyl ethers mildly and selectively to benzaldehyde and corresponding fatty alcohols, showing that PEG is a valuable oxidizing agent of benzyl ethers. As a carrier of NO2.PEG can be recovered and utilized repeatedly after the oxidation.
基金financially supported by the National Science and Technology Major Project(No.2017-VI-0008-0078)the Joint Fund of the National Natural Science Foundation of China and Baosteel Group Corporation(No.U1560106)+1 种基金the Aeronautical Science Foundation of China(No.2016ZF51050)the Scientific Research Foundation for the Returned Overseas Chinese Scholars(State Education Ministry)。
文摘At present,developing high-efficiency microwave absorption materials with properties including lightweight,thin thickness,strong absorbing intensity and broad bandwidth is an urgent demand to solve the electromagnetic pollution issues.An ideal microwave absorber should have excellent dielectric and magnetic loss capabilities,thereby inducing attenuation and absorption of incident electromagnetic radiation.Recently,various carbon/magnetic metal composites have been developed and expected to become promising candidates for high-performance microwave absorbers.In this review,we introduce the mechanisms of microwave absorption and summarize the recent advances in carbon/magnetic metal composites.Preparation methods and microwave absorption properties of carbon/magnetic metal composites with different components,morphologies and microstructures are discussed in detail.Finally,the challenges and future prospects of carbon/magnetic metal absorbing materials are also proposed,which will be useful to develop high-performance microwave absorption materials.
基金This work was supported by the Fund of Fok Ying Tung Edu-cation Foundation,the Major Research Project of Innovative Group of Guizhou province(No.2018-013)Open Fund from Henan Uni-versity of Science and Technology,the National Science Foundation of China(Nos.11964006 and 11774156)the Foundation of the National Key Project for Basic Research(No.2012CB932304)for fi-nancial support。
文摘Previous results revealed that the defect and/or interface had a great impact on the electromagnetic pa-rameters of materials.In order to understand the main physical mechanisms and effectively utilize these strategies,in this study,M Fe_(2)O_(4)and flower-like core@shell M Fe_(2)O_(4)@MoS_(2)(M=Mn,Ni,and Zn)sam-ples with different categories were elaborately designed and selectively produced in large scale through a simple two-step hydrothermal reaction.We conducted the systematical investigation on their microstruc-tures,electromagnetic parameters and microwave absorption performances(MAPs).The obtained results revealed that the large radius of M^(2+)cation could effectively boost the concentration of oxygen vacancy in the M Fe_(2)O_(4)and M Fe_(2)O_(4)@MoS_(2)samples,which resulted in the improvement of dielectric loss capabil-ities and MAPs.Furthermore,the introduction of MoS_(2)nanosheets greatly improved the interfacial effect and enhanced the polarization loss capabilities,which also boosted the MAPs.By taking full advantage of the defect and interface,the designed M Fe_(2)O_(4)@MoS_(2)samples displayed tunable and excellent com-prehensive MAPs including strong absorption capability,wide absorption bandwidth and thin matching thicknesses.Therefore,the clear understanding of defect and interface engineering made these strategies well elaborately designed and applicable to improving MAPs.
文摘Ultra-light carboxylic functionalized multi-walled carbon nanotubes(CNTs-COOH) and Ti3C2 MXene hybrids modified sodium alginate(CNTs/Ti3C2-SA) based composite foams were prepared through ice-templated freeze-drying method. The microstructure of the synthesized CNTs/Ti3C2 hybrids and CNTs/Ti3C2-SA foams is characterized by the presence of CNTs inserted between MXene layers which prevents their restacking. The resultant CNTs/Ti3C2 hybrids exhibit a unique sandwich-like hierarchical structure. Scanning electron microscopy(SEM) images show that the CNTs/Ti3C2-SA foam exhibits a heterogeneous anisotropic microstructure and CNTs/Ti3C2 hybrids are homogeneously dispersed in the skeleton of the porous foam. In case that the content of the hybrids amounts 40 mg/cm^3, the CNTs/Ti3C2-SA foam possesses excellent electromagnetic(EM) absorption performance with a minimum reflection coefficient(RCmin) as low as-40.0 dB. In case of a sample thickness of 3.95 mm, the RCminreaches-24.4 dB and the effective absorption bandwidth covers the whole X band from 8.2 to 12.4 GHz. A control test shows that, with the same absorbent content, the CNTs/Ti3C2-SA foam exhibits a far better EM performance than that of CNT-free Ti3C2-SA foam.
