Five cadmium naphthalene-diphosphonates,formulated as[Cd_(1.5)(1,4-ndpaH_(2))2(4,4'-bpyH)(4,4'-bpy)0.5(H_(2)O)_(2)]2(1),[Cd(1,4-ndpaH_(2))(1,4-bib)0.5(H_(2)O)](2),[Cd(1,4-ndpaH3)2(1,2-dpe)(H_(2)O)]·(1,2-d...Five cadmium naphthalene-diphosphonates,formulated as[Cd_(1.5)(1,4-ndpaH_(2))2(4,4'-bpyH)(4,4'-bpy)0.5(H_(2)O)_(2)]2(1),[Cd(1,4-ndpaH_(2))(1,4-bib)0.5(H_(2)O)](2),[Cd(1,4-ndpaH3)2(1,2-dpe)(H_(2)O)]·(1,2-dpe)·7H_(2)O(3),(1,2-bixH)[Cd3(1,4-ndpaH)(1,4-ndpaH_(2))2(H_(2)O)_(2)](4),and[Cd(1,4-ndpaH_(2))(H_(2)O)]·H_(2)O(5),have been synthesized from the selfassembly reactions of 1,4-naphthalenediphosphonic acid(1,4-ndpaH4)with Cd(NO3)2·4H_(2)O by introducing auxiliary ligands with variation of rigidity,such as 4,4'-bipyridine(4,4'-bpy),1,4-bis(1-imidazolyl)benzene(1,4-bib),1,2-di(4-pyridyl)ethylene(1,2-dpe),1,3-di(4-pyridyl)propane(1,3-dpp),and bis(imidazol-1-ylmethyl)benzene(1,2-bix),respectively.Structure resolution by single-crystal X-ray diffraction reveals that compound 1 possesses a layered framework,in which the{Cd3(PO2)2}trimers made up of corner-sharing two{CdO4N2}and one{CdO6}octahedra are connected by phosphonate groups,forming a ribbon,which are cross-linked by 4,4'-bipy ligands,forming a 2D layer.Compound 2 shows a 3D open-framework structure,where chains of corner-sharing{CdO4N}trigonal bipyramids and{PO3C}tetrahedra are cross-linked by 1,4-bib and/or phosphonate groups.A 1D ladder-like chain structure is found in compound 3,where the ladder-like chains made up of corner-sharing{CdO5N}octahedra and{PO3C}tetra hedra are connected by 1,4-ndpaH_(2)^(2-).Both compounds 4 and 5 obtained by the introduction of flexible ligands during the synthesis show a 2D layered structure,which is formed by ligand crosslinking double metal chains.Interestingly,In 4,flexible 1,2-bix was singly protonated,as vip molecules,filled between layer and layer,while flexible ligand 1,3-dpp is absent in 5.Photophysical measurements indicate that compounds 1-5 show ligand-centered emissions.展开更多
Piezocomposites with both flexibility and electromechanical conversion characteristics have been widely applied in various fields,including sensors,energy harvesting,catalysis,and biomedical treatment.In the compositi...Piezocomposites with both flexibility and electromechanical conversion characteristics have been widely applied in various fields,including sensors,energy harvesting,catalysis,and biomedical treatment.In the composition of piezocomposites or their preparation process,a category of materials is commonly employed that do not possess piezoelectric properties themselves but play a crucial role in performance enhancement.In this review,the concept of auxiliary phase is first proposed to define these materials,aiming to provide a new perspective for designing high-performance piezocomposites.Three different categories of modulation forms of auxiliary phase in piezocomposites are systematically summarized,including the modification of piezo-matrix,the modification of piezo-fillers,and the construction of special structures.Each category emphasizes the role of the auxiliary phase and systematically discusses the latest advancements and the physical mechanisms of the auxiliary phase enhanced flexible piezocomposites.Finally,a summary and future outlook of piezocomposites based on the auxiliary phase are provided.展开更多
Climate downscaling is used to transform large-scale meteorological data into small-scale data with enhanced detail,which finds wide applications in climate modeling,numerical weather forecasting,and renewable energy....Climate downscaling is used to transform large-scale meteorological data into small-scale data with enhanced detail,which finds wide applications in climate modeling,numerical weather forecasting,and renewable energy.Although deeplearning-based downscaling methods effectively capture the complex nonlinear mapping between meteorological data of varying scales,the supervised deep-learning-based downscaling methods suffer from insufficient high-resolution data in practice,and unsupervised methods struggle with accurately inferring small-scale specifics from limited large-scale inputs due to small-scale uncertainty.This article presents DualDS,a dual-learning framework utilizing a Generative Adversarial Network–based neural network and subgrid-scale auxiliary information for climate downscaling.Such a learning method is unified in a two-stream framework through up-and downsamplers,where the downsampler is used to simulate the information loss process during the upscaling,and the upsampler is used to reconstruct lost details and correct errors incurred during the upscaling.This dual learning strategy can eliminate the dependence on high-resolution ground truth data in the training process and refine the downscaling results by constraining the mapping process.Experimental findings demonstrate that DualDS is comparable to several state-of-the-art deep learning downscaling approaches,both qualitatively and quantitatively.Specifically,for a single surface-temperature data downscaling task,our method is comparable with other unsupervised algorithms with the same dataset,and we can achieve a 0.469 dB higher peak signal-to-noise ratio,0.017 higher structural similarity,0.08 lower RMSE,and the best correlation coefficient.In summary,this paper presents a novel approach to addressing small-scale uncertainty issues in unsupervised downscaling processes.展开更多
In wideband noncooperative interference cancellation,the reference signals obtained through auxiliary antennas are weighted to cancel with the interference signal.The correlation between the reference signal and the i...In wideband noncooperative interference cancellation,the reference signals obtained through auxiliary antennas are weighted to cancel with the interference signal.The correlation between the reference signal and the interference signal determines interference cancellation performance,while the auxiliary antenna array affects the correlation by influencing the amplitude and phase of the reference signals.This paper analyzes the effect of auxiliary antenna array on multiple performances of wideband noncooperative interference cancellation.Firstly,the array received signal model of wideband interference is established,and the weight vector coupled with the auxiliary antennas array manifold is solved by spectral analysis and eigen-subspace decomposition.Then,multiple performances which include cancellation resolution,grating null,wideband interference cancellation ratio(ICR),and convergence rate are quantitatively characterized with the auxiliary antenna array.It is obtained through analysis that the performances mutually restrict the auxiliary antenna array.Higher cancellation resolution requires larger array aperture,but when the number of auxiliary antennas is fixed,larger array aperture results in more grating nulls.When the auxiliary antennas are closer to the main antenna,the wideband ICR is improved,but the convergence rate is reduced.The conclusions are verified through simulation of one-dimensional uniform array and two-dimensional nonuniform array.The experiments of three arrays are compared,and the results conform well with simulation and support the theoretical analysis.展开更多
Following votes by the Valanginian Working Group,the International Subcommission on Cretaceous Stratigraphy and the International Commission on Stratigraphy,the Executive Committee of the International Union of Geolog...Following votes by the Valanginian Working Group,the International Subcommission on Cretaceous Stratigraphy and the International Commission on Stratigraphy,the Executive Committee of the International Union of Geological Sciences unanimously approved in December 2024 the Global Stratotype Section and Point(GSSP)for the Valanginian Stage(Cretaceous System).展开更多
An efficient and accurate scalar auxiliary variable(SAV)scheme for numerically solving nonlinear parabolic integro-differential equation(PIDE)is developed in this paper.The original equation is first transformed into ...An efficient and accurate scalar auxiliary variable(SAV)scheme for numerically solving nonlinear parabolic integro-differential equation(PIDE)is developed in this paper.The original equation is first transformed into an equivalent system,and the k-order backward differentiation formula(BDF k)and central difference formula are used to discretize the temporal and spatial derivatives,respectively.Different from the traditional discrete method that adopts full implicit or full explicit for the nonlinear integral terms,the proposed scheme is based on the SAV idea and can be treated semi-implicitly,taking into account both accuracy and effectiveness.Numerical results are presented to demonstrate the high-order convergence(up to fourth-order)of the developed schemes and it is computationally efficient in long-time computations.展开更多
Constrained multi-objective optimization problems(CMOPs) include the optimization of objective functions and the satisfaction of constraint conditions, which challenge the solvers.To solve CMOPs, constrained multi-obj...Constrained multi-objective optimization problems(CMOPs) include the optimization of objective functions and the satisfaction of constraint conditions, which challenge the solvers.To solve CMOPs, constrained multi-objective evolutionary algorithms(CMOEAs) have been developed. However, most of them tend to converge into local areas due to the loss of diversity. Evolutionary multitasking(EMT) is new model of solving complex optimization problems, through the knowledge transfer between the source task and other related tasks. Inspired by EMT, this paper develops a new EMT-based CMOEA to solve CMOPs, in which the main task, a global auxiliary task, and a local auxiliary task are created and optimized by one specific population respectively. The main task focuses on finding the feasible Pareto front(PF), and global and local auxiliary tasks are used to respectively enhance global and local diversity. Moreover, the global auxiliary task is used to implement the global search by ignoring constraints, so as to help the population of the main task pass through infeasible obstacles. The local auxiliary task is used to provide local diversity around the population of the main task, so as to exploit promising regions. Through the knowledge transfer among the three tasks, the search ability of the population of the main task will be significantly improved. Compared with other state-of-the-art CMOEAs, the experimental results on three benchmark test suites demonstrate the superior or competitive performance of the proposed CMOEA.展开更多
The Global Stratotype Section and Point(GSSP)of the base-Wuchiapingian Stage was formally ratified at the Penglaitan section in South China in 2005.However,the riverside GSSP section at Penglaitan and its auxiliary se...The Global Stratotype Section and Point(GSSP)of the base-Wuchiapingian Stage was formally ratified at the Penglaitan section in South China in 2005.However,the riverside GSSP section at Penglaitan and its auxiliary section at Tieqiao have been permanently flooded since 2020.We herein designate an excavated section at Penglaitan as the new GSSP and the Fengshan section as a new Standard Auxiliary Boundary Stratotype(SABS).In addition,we revised the original definition based on a detailed restudy of the conodont succession from the two sections.We define the GSSP of the base-Wuchiapingian by the First Appearance Datum(FAD)of Clarkina postbitteri within the lineage Jinogondolella granti→Clarkina postbitteri→C.dukouensis.It represents a major evolutionary turnover in conodonts from Jinogondolella to Clarkina and marks the end-Guadalupian extinction event.The U-Pb date of 259.51±0.21 Ma from the uppermost part of the Emeishan basalt is adopted for the GLB age.δ13Ccarb chemostratigraphy at the SABS exhibits several excursions between 3‰and 5‰across the GLB interval.Carbonate 87Sr/86Sr ratio is 0.707244 at the GLB.Remarkably,the SABS contains six normal and six reverse geomagnetic polarity zones in the uppermost Capitanian and three in the lowest Wuchiapingian.展开更多
In this paper, an efficient approximated method based upon the method of auxiliary sources （MAS） is proposed to solve the two-dimensional scattering problem of large, infinite dielectric cylinder. To reduce the size...In this paper, an efficient approximated method based upon the method of auxiliary sources （MAS） is proposed to solve the two-dimensional scattering problem of large, infinite dielectric cylinder. To reduce the size of the total computational cost, the formulation of the MAS is modified by minimizing the number of auxiliary sources considered to implement the solution. It is shown that the standard formulation of the method of auxiliary sources, based on placing a finite number of auxiliary sources in an interior cylinder and the same number in the exterior cylinder surrounding the physical boundary, can be replaced by a finite number of strips placed on the same interior and exterior cylinder. These strips, containing auxiliary sources, are separated by a constant angle. Thus, compared with the standard MAS, the number of auxiliary sources of the new approximated method is reduced; also the proposed method can greatly reduce the computational complexity and the memory requirement. The numerical results obtained in this paper reveal the validity of the proposed approximated method.展开更多
The Ideale section(IS)at Montalbano Jonico,Italy,has been approved as a Standard Auxiliary Boundary Stratotype(SABS)for the Global boundary Stratotype Section and Point(GSSP)of the Middle Pleistocene Subseries/Subepoc...The Ideale section(IS)at Montalbano Jonico,Italy,has been approved as a Standard Auxiliary Boundary Stratotype(SABS)for the Global boundary Stratotype Section and Point(GSSP)of the Middle Pleistocene Subseries/Subepoch and Chibanian Stage/Age at the Chiba section,Japan.The proposal was submitted to the voting members of the International Commission on Stratigraphy’s Subcommission on Quaternary Stratigraphy(SQS)on May 4,2023,and following discussions was approved on July 8,2023.The 74 m thick IS continuously spans the Marine Isotope Stage(MIS)20–18 interval,and is part of the longer Montalbano Jonico succession(Basilicata,southern Italy in the Mediterranean region)encompassing MIS 37 to early MIS 16.The IS provides a detailed record based on multiple chronologically well constrained marine and terrestrial proxies,which are particularly useful for outlining the paleoclimatic evolution through the Lower–Middle Pleistocene transition.The high-resolution carbon and oxygen isotope stratigraphy outlines glacial–interglacial and stadial–interstadial phases as well as the sub-millennialscale features of Termination IX and the onset of MIS 19c.The sapropel layer equivalent to insolation cycle 74(784 ka)occurs in early MIS 19c.A prominent peak in the 10Be/9Be record at the MIS 19c–19b transition identifies the low geomagnetic dipole moment associated with the Matuyama–Brunhes boundary interval.Two tephra layers(V3 and V4)relevant to boundary interval are 40Ar/39Ar dated.The V4 layer,occurring at the MIS 19c–b transition and in the middle of the 10Be/9Be peak,has an age of 774.1±0.9 ka,corresponding to the age of the Middle Pleistocene GSSP.A high-resolution alkenone sea-surface temperature and several paleobiological records complement the rich chronological and paleoenvironmental dataset from MIS 20 to the inception of MIS 18.The GSSP boundary interval in the IS is represented from 35.50 to 39.50 m,which corresponds to the interval of the highest values of the 10Be/9Be ratio(~776.35–771.87 ka)and includes the V4 tephra layer and the MIS 19c–MIS 19b transition.This SABS extends the correlation potential of the Middle Pleistocene Subseries/Subepoch GSSP interval to the Mediterranean region.展开更多
The reliability of the on-wing aircraft Auxiliary Power Unit(APU)decides the cost and the comfort of flight to a large degree.The most important function of APU is to help start main engines by providing compressed ai...The reliability of the on-wing aircraft Auxiliary Power Unit(APU)decides the cost and the comfort of flight to a large degree.The most important function of APU is to help start main engines by providing compressed air.Especially on the condition of sudden shutdown in the air,APU can offer additional thrust for landing.Therefore,its condition monitoring has drawn much attention from the academic and industrial field.Among the on-wing sensing data which can reflect its condition,Exhaust Gas Temperature(EGT)is one of the most important parameters.To ensure the reliability of EGT,one kind of data-driven anomaly detection framework for EGT sensing data is proposed based on the Gaussian Process Regression and Kernel Principal Component Analysis.The situations of one-dimensional and two-dimensional input data for EGT anomaly detection are considered,respectively.The cross-validation experiments are carried out by utilizing the real condition data of APU,which are provided by China Southern Airlines Company Limited Shenyang Maintenance Base.The anomalous stuck condition of EGT sensing data is also detected.Experimental results show that the proposed EGT sensing data anomaly detection method can achieve better performance of false positive ratio,false negative ratio and accuracy.展开更多
Only in the presence of sidelobe jamming （SLJ）, can the conventional adaptive monopulse technique null the jamming effectively and maintain the monopulse angle estimation accuracy simultaneously. While mainlobe jamm...Only in the presence of sidelobe jamming （SLJ）, can the conventional adaptive monopulse technique null the jamming effectively and maintain the monopulse angle estimation accuracy simultaneously. While mainlobe jamming （MLJ） exists, the mainlobe of adaptive pattern will subject to serious distortion, which results in a failure of detecting and tracking targets by monopulse technique. Therefore, a monopulse angle estimation algorithm based on combining sum-difference beam and auxiliary beam is presented. This algorithm utilizes both high gain difference beams and high gain auxiliary beams for cancelling the mainlobe jammer and multiple sidelobe jammers （SLJs） while keeping an adap- tive monopulse ratio. Theoretical analysis and simulation results indicate that the serious invalidation of monopulse technique in MLJ and SLJs scenarios is resolved well, which improves the monopulse angle accuracy greatly. Furthermore, the proposed algorithm is of simple implementation and low computational complexity.展开更多
A new procedure for the highly diastereoselective synthesis of （1S）-trans-cyclopropane derivatives using a fructose derivative as the chiral auxiliary was developed. Chloroacetylated 1,2;4,5-di-O-isopropylidene-D-fr...A new procedure for the highly diastereoselective synthesis of （1S）-trans-cyclopropane derivatives using a fructose derivative as the chiral auxiliary was developed. Chloroacetylated 1,2;4,5-di-O-isopropylidene-D-fructopyranose was reacted with a tertiary amine to form the ammonium salt, which was treated with cesium carbonate to give the cyclopropane derivative through ylide intermediate. The described procedure provides an efficient method to synthesize optically pure dior poly-substituded cyclopropanes.展开更多
A new hybrid welding process was successfully used to join aluminum alloy and stainless steel. In the MIG welding-brazing process, the lower thermal conductivity of steel can cause dramatic change of temperature gradi...A new hybrid welding process was successfully used to join aluminum alloy and stainless steel. In the MIG welding-brazing process, the lower thermal conductivity of steel can cause dramatic change of temperature gradient on steel surface, while the auxiliary TIG arc can change this phenomenon by heating the steel side. The auxiliary TIG improved the wettability of molten metal, resulting in the molten metal spreading fully on upper surfaces, front and back surface of steel, forming a sound brazing joint; the content of Cr and Ni elements in IMCs layer was increased, which can enhance the quality of the layer; and the microstructure of IMCs layer also was improved, increasing the bonding strength with the weld seam. The average tensile strength of the joint obtained with auxiliary TIG arc（146.7 MPa） was higher than that without auxiliary TIG arc（96.7 MPa）.展开更多
A novel DLC film deposition method was proposed to realize the deposition of DLC film on the surface of complex shaped workpiece.Meanwhile,Si-DLC film was deposited on the surface of M2 high-speed steel(HSS M2)and 304...A novel DLC film deposition method was proposed to realize the deposition of DLC film on the surface of complex shaped workpiece.Meanwhile,Si-DLC film was deposited on the surface of M2 high-speed steel(HSS M2)and 304 stainless steel(304SS),and the microstructure,surface roughness,mechanical properties,corrosion resistance and tribological properties of Si-DLC films were characterized in detail.Results show that Si-DLC film at different axial positions of the auxiliary cathode possesses similar microstructure,film thickness and surface roughness,and the as-deposited Si-DLC film shows the low intrinsic stress of<0.3 GPa.Compared with the 304SS substrate,the Si-DLC film presents more noble corrosion potential,lower corrosion current density and higher polarization resistance,exhibiting higher corrosion resistance.Moreover,the Si-DLC film exhibits higher hardness,elastic factor and plastic factor than HSS M2 substrate and the corresponding adhesive strength is more than 10 N.The Si-DLC film sliding against GCr15 steel ball shows a lower friction coefficient than that of HSS M2 substrate and the wear rate of GCr15 steel ball sliding against the Si-DLC is lower than that of HSS M2 substrate.In addition,this novel method was used to deposit Si-DLC film on gears,drills and bearings without rotating sample racks.As a consequence,this method possesses great potential and can be generalized for the deposition of DLC film on the surface of complex shape workpiece.展开更多
An adaptive stable observer with output current online identification strategy for the auxiliary inverters applied in advanced electric trains, such as high speed railway, urban rail, subway and maglev trains, is prop...An adaptive stable observer with output current online identification strategy for the auxiliary inverters applied in advanced electric trains, such as high speed railway, urban rail, subway and maglev trains, is proposed. The designed observer is used to estimate the state variables, i.e. controllable duty ratio and current components in d-q-o rotary reference frame. The convergence of the observer estimation error is analyzed with consideration of uncertain level variation of input voltage at direct current(DC) side and sufficient conditions are given to prove its practical stability. Experimental results are shown to confirm the effectiveness of the proposed observer.展开更多
In this paper, we propose a simulative experimental system in wind tunnel conditions lbr the separation of auxiliary fuel tanks from an aircraft. The experimental system consists of a simulative release mechanism, a s...In this paper, we propose a simulative experimental system in wind tunnel conditions lbr the separation of auxiliary fuel tanks from an aircraft. The experimental system consists of a simulative release mechanism, a scaled model and a pose measuring system. A new release mechanism was designed to ensure stability of the separation. Scaled models of the auxiliary fuel tank were designed and their moment of inertia was adjusted by installing counterweights inside the model. Pose param- eters of the scaled model were measured and calculated by a binocular vision system. Additionally, in order to achieve high brightness and high signal-to-noise ratio of the images in the dark enclosed wind tunnel, a new high-speed image acquisition method based on miniature self-emitting units was pre- sented. Accuracy of the pose measurement system and repeatability of the separation mechanism were verified in the laboratory. Results show that the position precision of the pose measurement system can reach 0.1 mm, the precision of the pitch and yaw angles is less than 0.1° and that of the roll angle can be up to 0.3°. Besides, repeatability errors of models＂ velocity and angular velocity controlled by the release mechanism remain small, satisfying the measurement requirements. Finally, experiments for the separation of auxiliary fuel tanks were conducted in the laboratory.展开更多
This paper applies an extended auxiliary equation method to obtain exact solutions of the KdV equation with variable coefficients. As a result, solitary wave solutions, trigonometric function solutions, rational funct...This paper applies an extended auxiliary equation method to obtain exact solutions of the KdV equation with variable coefficients. As a result, solitary wave solutions, trigonometric function solutions, rational function solutions, Jacobi elliptic doubly periodic wave solutions, and nonsymmetrical kink solution are obtained. It is shown that the extended auxiliary equation method, with the help of a computer symbolic computation system, is reliable and effective in finding exact solutions of variable coefficient nonlinear evolution equations in mathematical physics.展开更多
To track the nonlinear,non-Gaussian bearings-only maneuvering target accurately online,the constrained auxiliary particle filtering(CAPF)algorithm is presented.To restrict the samples into the feasible area,the soft m...To track the nonlinear,non-Gaussian bearings-only maneuvering target accurately online,the constrained auxiliary particle filtering(CAPF)algorithm is presented.To restrict the samples into the feasible area,the soft measurement constraints are implemented into the update routine via the1 regularization.Meanwhile,to enhance the sampling diversity and efficiency,the target kinetic features and the latest observations are involved into the evolution.To take advantage of the past and the current measurement information simultaneously,the sub-optimal importance distribution is constructed as a Gaussian mixture consisting of the original and modified priors with the fuzzy weighted factors.As a result,the corresponding weights are more evenly distributed,and the posterior distribution of interest is approximated well with a heavier tailor.Simulation results demonstrate the validity and superiority of the CAPF algorithm in terms of efficiency and robustness.展开更多
文摘Five cadmium naphthalene-diphosphonates,formulated as[Cd_(1.5)(1,4-ndpaH_(2))2(4,4'-bpyH)(4,4'-bpy)0.5(H_(2)O)_(2)]2(1),[Cd(1,4-ndpaH_(2))(1,4-bib)0.5(H_(2)O)](2),[Cd(1,4-ndpaH3)2(1,2-dpe)(H_(2)O)]·(1,2-dpe)·7H_(2)O(3),(1,2-bixH)[Cd3(1,4-ndpaH)(1,4-ndpaH_(2))2(H_(2)O)_(2)](4),and[Cd(1,4-ndpaH_(2))(H_(2)O)]·H_(2)O(5),have been synthesized from the selfassembly reactions of 1,4-naphthalenediphosphonic acid(1,4-ndpaH4)with Cd(NO3)2·4H_(2)O by introducing auxiliary ligands with variation of rigidity,such as 4,4'-bipyridine(4,4'-bpy),1,4-bis(1-imidazolyl)benzene(1,4-bib),1,2-di(4-pyridyl)ethylene(1,2-dpe),1,3-di(4-pyridyl)propane(1,3-dpp),and bis(imidazol-1-ylmethyl)benzene(1,2-bix),respectively.Structure resolution by single-crystal X-ray diffraction reveals that compound 1 possesses a layered framework,in which the{Cd3(PO2)2}trimers made up of corner-sharing two{CdO4N2}and one{CdO6}octahedra are connected by phosphonate groups,forming a ribbon,which are cross-linked by 4,4'-bipy ligands,forming a 2D layer.Compound 2 shows a 3D open-framework structure,where chains of corner-sharing{CdO4N}trigonal bipyramids and{PO3C}tetrahedra are cross-linked by 1,4-bib and/or phosphonate groups.A 1D ladder-like chain structure is found in compound 3,where the ladder-like chains made up of corner-sharing{CdO5N}octahedra and{PO3C}tetra hedra are connected by 1,4-ndpaH_(2)^(2-).Both compounds 4 and 5 obtained by the introduction of flexible ligands during the synthesis show a 2D layered structure,which is formed by ligand crosslinking double metal chains.Interestingly,In 4,flexible 1,2-bix was singly protonated,as vip molecules,filled between layer and layer,while flexible ligand 1,3-dpp is absent in 5.Photophysical measurements indicate that compounds 1-5 show ligand-centered emissions.
基金supported by the Beijing Natural Science Foundation(Grant No.JL23004)the National Natural Science Foundation of China(Grant Nos.52473120,52472117,52072010,51972005 and 52325204).
文摘Piezocomposites with both flexibility and electromechanical conversion characteristics have been widely applied in various fields,including sensors,energy harvesting,catalysis,and biomedical treatment.In the composition of piezocomposites or their preparation process,a category of materials is commonly employed that do not possess piezoelectric properties themselves but play a crucial role in performance enhancement.In this review,the concept of auxiliary phase is first proposed to define these materials,aiming to provide a new perspective for designing high-performance piezocomposites.Three different categories of modulation forms of auxiliary phase in piezocomposites are systematically summarized,including the modification of piezo-matrix,the modification of piezo-fillers,and the construction of special structures.Each category emphasizes the role of the auxiliary phase and systematically discusses the latest advancements and the physical mechanisms of the auxiliary phase enhanced flexible piezocomposites.Finally,a summary and future outlook of piezocomposites based on the auxiliary phase are provided.
基金supported by the following funding bodies:the National Key Research and Development Program of China(Grant No.2020YFA0608000)National Science Foundation of China(Grant Nos.42075142,42375148,42125503+2 种基金42130608)FY-APP-2022.0609,Sichuan Province Key Tech nology Research and Development project(Grant Nos.2024ZHCG0168,2024ZHCG0176,2023YFG0305,2023YFG-0124,and 23ZDYF0091)the CUIT Science and Technology Innovation Capacity Enhancement Program project(Grant No.KYQN202305)。
文摘Climate downscaling is used to transform large-scale meteorological data into small-scale data with enhanced detail,which finds wide applications in climate modeling,numerical weather forecasting,and renewable energy.Although deeplearning-based downscaling methods effectively capture the complex nonlinear mapping between meteorological data of varying scales,the supervised deep-learning-based downscaling methods suffer from insufficient high-resolution data in practice,and unsupervised methods struggle with accurately inferring small-scale specifics from limited large-scale inputs due to small-scale uncertainty.This article presents DualDS,a dual-learning framework utilizing a Generative Adversarial Network–based neural network and subgrid-scale auxiliary information for climate downscaling.Such a learning method is unified in a two-stream framework through up-and downsamplers,where the downsampler is used to simulate the information loss process during the upscaling,and the upsampler is used to reconstruct lost details and correct errors incurred during the upscaling.This dual learning strategy can eliminate the dependence on high-resolution ground truth data in the training process and refine the downscaling results by constraining the mapping process.Experimental findings demonstrate that DualDS is comparable to several state-of-the-art deep learning downscaling approaches,both qualitatively and quantitatively.Specifically,for a single surface-temperature data downscaling task,our method is comparable with other unsupervised algorithms with the same dataset,and we can achieve a 0.469 dB higher peak signal-to-noise ratio,0.017 higher structural similarity,0.08 lower RMSE,and the best correlation coefficient.In summary,this paper presents a novel approach to addressing small-scale uncertainty issues in unsupervised downscaling processes.
基金supported by the National Fund for Distinguished Young Scholars(52025072)the National Natural Science Foundation of China(52177012)the Foundation of National Key Laboratory of Science and Technology(614221722051301).
文摘In wideband noncooperative interference cancellation,the reference signals obtained through auxiliary antennas are weighted to cancel with the interference signal.The correlation between the reference signal and the interference signal determines interference cancellation performance,while the auxiliary antenna array affects the correlation by influencing the amplitude and phase of the reference signals.This paper analyzes the effect of auxiliary antenna array on multiple performances of wideband noncooperative interference cancellation.Firstly,the array received signal model of wideband interference is established,and the weight vector coupled with the auxiliary antennas array manifold is solved by spectral analysis and eigen-subspace decomposition.Then,multiple performances which include cancellation resolution,grating null,wideband interference cancellation ratio(ICR),and convergence rate are quantitatively characterized with the auxiliary antenna array.It is obtained through analysis that the performances mutually restrict the auxiliary antenna array.Higher cancellation resolution requires larger array aperture,but when the number of auxiliary antennas is fixed,larger array aperture results in more grating nulls.When the auxiliary antennas are closer to the main antenna,the wideband ICR is improved,but the convergence rate is reduced.The conclusions are verified through simulation of one-dimensional uniform array and two-dimensional nonuniform array.The experiments of three arrays are compared,and the results conform well with simulation and support the theoretical analysis.
基金support of a project(2021-2023)funded by the Polish and French Ministries of foreign affairs(Partenariat Hubert Curien,cf.the current palaeomagnetic study that also includes the contribution of Chmielewski Andrezj,Iwanczuk Jolanta and Ploch Izabela from the Polish Geological Institute of Warsaw,colleagues who are hereby thanked)the CNRS SYSTER program(WOAW SYSTER French project,with the contribution of two students Lea Baubant and Durel Franchevel who are acknowledged),Project APVV-20-0079(Slovakian National Grant Agency,thanks to Diana Olveczka)and various grants from the Laboratoire de Geologie de Lyon.
文摘Following votes by the Valanginian Working Group,the International Subcommission on Cretaceous Stratigraphy and the International Commission on Stratigraphy,the Executive Committee of the International Union of Geological Sciences unanimously approved in December 2024 the Global Stratotype Section and Point(GSSP)for the Valanginian Stage(Cretaceous System).
基金Supported by the National Natural Science Foundation of China(Grant Nos.12001210 and 12261103)the Natural Science Foundation of Henan(Grant No.252300420308)the Yunnan Fundamental Research Projects(Grant No.202301AT070117).
文摘An efficient and accurate scalar auxiliary variable(SAV)scheme for numerically solving nonlinear parabolic integro-differential equation(PIDE)is developed in this paper.The original equation is first transformed into an equivalent system,and the k-order backward differentiation formula(BDF k)and central difference formula are used to discretize the temporal and spatial derivatives,respectively.Different from the traditional discrete method that adopts full implicit or full explicit for the nonlinear integral terms,the proposed scheme is based on the SAV idea and can be treated semi-implicitly,taking into account both accuracy and effectiveness.Numerical results are presented to demonstrate the high-order convergence(up to fourth-order)of the developed schemes and it is computationally efficient in long-time computations.
基金supported in part by the National Natural Science Fund for Outstanding Young Scholars of China (61922072)the National Natural Science Foundation of China (62176238, 61806179, 61876169, 61976237)+2 种基金China Postdoctoral Science Foundation (2020M682347)the Training Program of Young Backbone Teachers in Colleges and Universities in Henan Province (2020GGJS006)Henan Provincial Young Talents Lifting Project (2021HYTP007)。
文摘Constrained multi-objective optimization problems(CMOPs) include the optimization of objective functions and the satisfaction of constraint conditions, which challenge the solvers.To solve CMOPs, constrained multi-objective evolutionary algorithms(CMOEAs) have been developed. However, most of them tend to converge into local areas due to the loss of diversity. Evolutionary multitasking(EMT) is new model of solving complex optimization problems, through the knowledge transfer between the source task and other related tasks. Inspired by EMT, this paper develops a new EMT-based CMOEA to solve CMOPs, in which the main task, a global auxiliary task, and a local auxiliary task are created and optimized by one specific population respectively. The main task focuses on finding the feasible Pareto front(PF), and global and local auxiliary tasks are used to respectively enhance global and local diversity. Moreover, the global auxiliary task is used to implement the global search by ignoring constraints, so as to help the population of the main task pass through infeasible obstacles. The local auxiliary task is used to provide local diversity around the population of the main task, so as to exploit promising regions. Through the knowledge transfer among the three tasks, the search ability of the population of the main task will be significantly improved. Compared with other state-of-the-art CMOEAs, the experimental results on three benchmark test suites demonstrate the superior or competitive performance of the proposed CMOEA.
基金supported by the National Natural Science Foundation of China(42293280,42272031,42250104,42261144668)Strategic Priority Research Program(B)of the Chinese Academy of Sciences(XDB26000000).
文摘The Global Stratotype Section and Point(GSSP)of the base-Wuchiapingian Stage was formally ratified at the Penglaitan section in South China in 2005.However,the riverside GSSP section at Penglaitan and its auxiliary section at Tieqiao have been permanently flooded since 2020.We herein designate an excavated section at Penglaitan as the new GSSP and the Fengshan section as a new Standard Auxiliary Boundary Stratotype(SABS).In addition,we revised the original definition based on a detailed restudy of the conodont succession from the two sections.We define the GSSP of the base-Wuchiapingian by the First Appearance Datum(FAD)of Clarkina postbitteri within the lineage Jinogondolella granti→Clarkina postbitteri→C.dukouensis.It represents a major evolutionary turnover in conodonts from Jinogondolella to Clarkina and marks the end-Guadalupian extinction event.The U-Pb date of 259.51±0.21 Ma from the uppermost part of the Emeishan basalt is adopted for the GLB age.δ13Ccarb chemostratigraphy at the SABS exhibits several excursions between 3‰and 5‰across the GLB interval.Carbonate 87Sr/86Sr ratio is 0.707244 at the GLB.Remarkably,the SABS contains six normal and six reverse geomagnetic polarity zones in the uppermost Capitanian and three in the lowest Wuchiapingian.
文摘In this paper, an efficient approximated method based upon the method of auxiliary sources （MAS） is proposed to solve the two-dimensional scattering problem of large, infinite dielectric cylinder. To reduce the size of the total computational cost, the formulation of the MAS is modified by minimizing the number of auxiliary sources considered to implement the solution. It is shown that the standard formulation of the method of auxiliary sources, based on placing a finite number of auxiliary sources in an interior cylinder and the same number in the exterior cylinder surrounding the physical boundary, can be replaced by a finite number of strips placed on the same interior and exterior cylinder. These strips, containing auxiliary sources, are separated by a constant angle. Thus, compared with the standard MAS, the number of auxiliary sources of the new approximated method is reduced; also the proposed method can greatly reduce the computational complexity and the memory requirement. The numerical results obtained in this paper reveal the validity of the proposed approximated method.
文摘The Ideale section(IS)at Montalbano Jonico,Italy,has been approved as a Standard Auxiliary Boundary Stratotype(SABS)for the Global boundary Stratotype Section and Point(GSSP)of the Middle Pleistocene Subseries/Subepoch and Chibanian Stage/Age at the Chiba section,Japan.The proposal was submitted to the voting members of the International Commission on Stratigraphy’s Subcommission on Quaternary Stratigraphy(SQS)on May 4,2023,and following discussions was approved on July 8,2023.The 74 m thick IS continuously spans the Marine Isotope Stage(MIS)20–18 interval,and is part of the longer Montalbano Jonico succession(Basilicata,southern Italy in the Mediterranean region)encompassing MIS 37 to early MIS 16.The IS provides a detailed record based on multiple chronologically well constrained marine and terrestrial proxies,which are particularly useful for outlining the paleoclimatic evolution through the Lower–Middle Pleistocene transition.The high-resolution carbon and oxygen isotope stratigraphy outlines glacial–interglacial and stadial–interstadial phases as well as the sub-millennialscale features of Termination IX and the onset of MIS 19c.The sapropel layer equivalent to insolation cycle 74(784 ka)occurs in early MIS 19c.A prominent peak in the 10Be/9Be record at the MIS 19c–19b transition identifies the low geomagnetic dipole moment associated with the Matuyama–Brunhes boundary interval.Two tephra layers(V3 and V4)relevant to boundary interval are 40Ar/39Ar dated.The V4 layer,occurring at the MIS 19c–b transition and in the middle of the 10Be/9Be peak,has an age of 774.1±0.9 ka,corresponding to the age of the Middle Pleistocene GSSP.A high-resolution alkenone sea-surface temperature and several paleobiological records complement the rich chronological and paleoenvironmental dataset from MIS 20 to the inception of MIS 18.The GSSP boundary interval in the IS is represented from 35.50 to 39.50 m,which corresponds to the interval of the highest values of the 10Be/9Be ratio(~776.35–771.87 ka)and includes the V4 tephra layer and the MIS 19c–MIS 19b transition.This SABS extends the correlation potential of the Middle Pleistocene Subseries/Subepoch GSSP interval to the Mediterranean region.
基金partially supported by the National Natural Science Foundation of China(No.61803121)China Postdoctoral Science Foundation(No.2019M651277).
文摘The reliability of the on-wing aircraft Auxiliary Power Unit(APU)decides the cost and the comfort of flight to a large degree.The most important function of APU is to help start main engines by providing compressed air.Especially on the condition of sudden shutdown in the air,APU can offer additional thrust for landing.Therefore,its condition monitoring has drawn much attention from the academic and industrial field.Among the on-wing sensing data which can reflect its condition,Exhaust Gas Temperature(EGT)is one of the most important parameters.To ensure the reliability of EGT,one kind of data-driven anomaly detection framework for EGT sensing data is proposed based on the Gaussian Process Regression and Kernel Principal Component Analysis.The situations of one-dimensional and two-dimensional input data for EGT anomaly detection are considered,respectively.The cross-validation experiments are carried out by utilizing the real condition data of APU,which are provided by China Southern Airlines Company Limited Shenyang Maintenance Base.The anomalous stuck condition of EGT sensing data is also detected.Experimental results show that the proposed EGT sensing data anomaly detection method can achieve better performance of false positive ratio,false negative ratio and accuracy.
基金supported by the National Natural Science Foundation of China(60925005)
文摘Only in the presence of sidelobe jamming （SLJ）, can the conventional adaptive monopulse technique null the jamming effectively and maintain the monopulse angle estimation accuracy simultaneously. While mainlobe jamming （MLJ） exists, the mainlobe of adaptive pattern will subject to serious distortion, which results in a failure of detecting and tracking targets by monopulse technique. Therefore, a monopulse angle estimation algorithm based on combining sum-difference beam and auxiliary beam is presented. This algorithm utilizes both high gain difference beams and high gain auxiliary beams for cancelling the mainlobe jammer and multiple sidelobe jammers （SLJs） while keeping an adap- tive monopulse ratio. Theoretical analysis and simulation results indicate that the serious invalidation of monopulse technique in MLJ and SLJs scenarios is resolved well, which improves the monopulse angle accuracy greatly. Furthermore, the proposed algorithm is of simple implementation and low computational complexity.
基金National Natural Science Foundation of China (Grant No. 20602001)
文摘A new procedure for the highly diastereoselective synthesis of （1S）-trans-cyclopropane derivatives using a fructose derivative as the chiral auxiliary was developed. Chloroacetylated 1,2;4,5-di-O-isopropylidene-D-fructopyranose was reacted with a tertiary amine to form the ammonium salt, which was treated with cesium carbonate to give the cyclopropane derivative through ylide intermediate. The described procedure provides an efficient method to synthesize optically pure dior poly-substituded cyclopropanes.
文摘A new hybrid welding process was successfully used to join aluminum alloy and stainless steel. In the MIG welding-brazing process, the lower thermal conductivity of steel can cause dramatic change of temperature gradient on steel surface, while the auxiliary TIG arc can change this phenomenon by heating the steel side. The auxiliary TIG improved the wettability of molten metal, resulting in the molten metal spreading fully on upper surfaces, front and back surface of steel, forming a sound brazing joint; the content of Cr and Ni elements in IMCs layer was increased, which can enhance the quality of the layer; and the microstructure of IMCs layer also was improved, increasing the bonding strength with the weld seam. The average tensile strength of the joint obtained with auxiliary TIG arc（146.7 MPa） was higher than that without auxiliary TIG arc（96.7 MPa）.
基金financially supported by the National Key R&D Program of China(No.2018YFB0703801)the Sichuan Science and Technology Program(No.2019YFSY0012)the CAS"Light of West China"Program。
文摘A novel DLC film deposition method was proposed to realize the deposition of DLC film on the surface of complex shaped workpiece.Meanwhile,Si-DLC film was deposited on the surface of M2 high-speed steel(HSS M2)and 304 stainless steel(304SS),and the microstructure,surface roughness,mechanical properties,corrosion resistance and tribological properties of Si-DLC films were characterized in detail.Results show that Si-DLC film at different axial positions of the auxiliary cathode possesses similar microstructure,film thickness and surface roughness,and the as-deposited Si-DLC film shows the low intrinsic stress of<0.3 GPa.Compared with the 304SS substrate,the Si-DLC film presents more noble corrosion potential,lower corrosion current density and higher polarization resistance,exhibiting higher corrosion resistance.Moreover,the Si-DLC film exhibits higher hardness,elastic factor and plastic factor than HSS M2 substrate and the corresponding adhesive strength is more than 10 N.The Si-DLC film sliding against GCr15 steel ball shows a lower friction coefficient than that of HSS M2 substrate and the wear rate of GCr15 steel ball sliding against the Si-DLC is lower than that of HSS M2 substrate.In addition,this novel method was used to deposit Si-DLC film on gears,drills and bearings without rotating sample racks.As a consequence,this method possesses great potential and can be generalized for the deposition of DLC film on the surface of complex shape workpiece.
基金Project(61273158)supported by the National Natural Science Foundation of China
文摘An adaptive stable observer with output current online identification strategy for the auxiliary inverters applied in advanced electric trains, such as high speed railway, urban rail, subway and maglev trains, is proposed. The designed observer is used to estimate the state variables, i.e. controllable duty ratio and current components in d-q-o rotary reference frame. The convergence of the observer estimation error is analyzed with consideration of uncertain level variation of input voltage at direct current(DC) side and sufficient conditions are given to prove its practical stability. Experimental results are shown to confirm the effectiveness of the proposed observer.
基金co-supported by the National Natural Science Foundation of China(Nos.51375075,51227004)the Special Funds of the National Natural Science Foundation of China(No.51227004)+2 种基金the National Basic Research Program of China(No.2014CB046504)the Fundamental Research Funds for the Central Universities of Chinathe Science Fund for Creative Research Groups of China(No.51321004)
文摘In this paper, we propose a simulative experimental system in wind tunnel conditions lbr the separation of auxiliary fuel tanks from an aircraft. The experimental system consists of a simulative release mechanism, a scaled model and a pose measuring system. A new release mechanism was designed to ensure stability of the separation. Scaled models of the auxiliary fuel tank were designed and their moment of inertia was adjusted by installing counterweights inside the model. Pose param- eters of the scaled model were measured and calculated by a binocular vision system. Additionally, in order to achieve high brightness and high signal-to-noise ratio of the images in the dark enclosed wind tunnel, a new high-speed image acquisition method based on miniature self-emitting units was pre- sented. Accuracy of the pose measurement system and repeatability of the separation mechanism were verified in the laboratory. Results show that the position precision of the pose measurement system can reach 0.1 mm, the precision of the pitch and yaw angles is less than 0.1° and that of the roll angle can be up to 0.3°. Besides, repeatability errors of models＂ velocity and angular velocity controlled by the release mechanism remain small, satisfying the measurement requirements. Finally, experiments for the separation of auxiliary fuel tanks were conducted in the laboratory.
基金Project supported by the Fundamental Research Funds for the Central Universities （Grant No. 2010B17914） and the National Natural Science Foundation of China （Grant No. 10926162）.
文摘This paper applies an extended auxiliary equation method to obtain exact solutions of the KdV equation with variable coefficients. As a result, solitary wave solutions, trigonometric function solutions, rational function solutions, Jacobi elliptic doubly periodic wave solutions, and nonsymmetrical kink solution are obtained. It is shown that the extended auxiliary equation method, with the help of a computer symbolic computation system, is reliable and effective in finding exact solutions of variable coefficient nonlinear evolution equations in mathematical physics.
基金supported by the National Natural Science Foundation of China(61773267)the Shenzhen Fundamental Research Project(JCYJ2017030214551952420170818102503604)
文摘To track the nonlinear,non-Gaussian bearings-only maneuvering target accurately online,the constrained auxiliary particle filtering(CAPF)algorithm is presented.To restrict the samples into the feasible area,the soft measurement constraints are implemented into the update routine via the1 regularization.Meanwhile,to enhance the sampling diversity and efficiency,the target kinetic features and the latest observations are involved into the evolution.To take advantage of the past and the current measurement information simultaneously,the sub-optimal importance distribution is constructed as a Gaussian mixture consisting of the original and modified priors with the fuzzy weighted factors.As a result,the corresponding weights are more evenly distributed,and the posterior distribution of interest is approximated well with a heavier tailor.Simulation results demonstrate the validity and superiority of the CAPF algorithm in terms of efficiency and robustness.
