The study is interested in chemical quality of water of the one of the five aquifers, unconfined water AQ1, (other free groundwaters AQ2, AQ3, AQ4 and AQ5 being captive) in the area of Pointe-Noire. A series of physic...The study is interested in chemical quality of water of the one of the five aquifers, unconfined water AQ1, (other free groundwaters AQ2, AQ3, AQ4 and AQ5 being captive) in the area of Pointe-Noire. A series of physicochemical analysis was carried out on the samples of water of the zone. The results of these analyses were treated starting from a chemical-hydro method which uses the diagrams of Piper, Stabler, Schoeller Berkaloff, Stiff, Wilcox and the statistical methods classic. These chemical-hydro results made it possible to highlight the prevalence of sodic and potassic facies chlorinated in groundwaters of the unconfined water of the area of Pointe-Noire. In this area, the groundwaters of the unconfined water gather in three principal-hydro facies: sodic and potassic chlorinated waters are the most important (66.7%) in the studied water;calcic and magnesian bicarbonated water (16.65%) and bicarbonated sodic and potassic ones (16.65%). This study reveals that the groundwaters of the area of Pointe-Noire undergo an intrusion saltworks. As a whole, these groundwaters require in certain cases, a specific treatment before consumption.展开更多
Solar-driven energy conversion is a promising technology for a sustainable energy future and environmental remediation, and an efficient catalyst is a key factor. Recently, metal halide perovskites(MHPs) have emerged ...Solar-driven energy conversion is a promising technology for a sustainable energy future and environmental remediation, and an efficient catalyst is a key factor. Recently, metal halide perovskites(MHPs) have emerged as promising photocatalysts due to their exceptional photoelectronic properties and low-cost solution processing, enabling successful applications in H_(2) evolution, CO_(2) reduction, organic synthesis, and pollutant degradation. Despite these successes, the practical applications of MHPs are limited by their water instability. In this review, the recently developed strategies driving MHPcatalyzed reactions in aqueous media are outlined. We first articulate the structures and properties of MHPs, followed by elaborating on the origin of instability in MHPs. Then, we highlight the advances in solar-driven MHPbased catalytic systems in aqueous solutions, focusing on developing external protection strategies and intrinsically water-stable MHP materials. With each approach offering peculiar sets of advantages and challenges, we conclude by outlining potentially promising opportunities and directions for MHP-based photocatalysis research in aqueous conditions moving forward. We anticipate that this timely review will provide some inspiration for the design of MHPbased photocatalysts, manifestly stimulating their applications in aqueous environments for solar-to-chemical energy conversion.展开更多
文摘The study is interested in chemical quality of water of the one of the five aquifers, unconfined water AQ1, (other free groundwaters AQ2, AQ3, AQ4 and AQ5 being captive) in the area of Pointe-Noire. A series of physicochemical analysis was carried out on the samples of water of the zone. The results of these analyses were treated starting from a chemical-hydro method which uses the diagrams of Piper, Stabler, Schoeller Berkaloff, Stiff, Wilcox and the statistical methods classic. These chemical-hydro results made it possible to highlight the prevalence of sodic and potassic facies chlorinated in groundwaters of the unconfined water of the area of Pointe-Noire. In this area, the groundwaters of the unconfined water gather in three principal-hydro facies: sodic and potassic chlorinated waters are the most important (66.7%) in the studied water;calcic and magnesian bicarbonated water (16.65%) and bicarbonated sodic and potassic ones (16.65%). This study reveals that the groundwaters of the area of Pointe-Noire undergo an intrusion saltworks. As a whole, these groundwaters require in certain cases, a specific treatment before consumption.
基金City University of Hong Kong,Grant/Award Number:SIRG 7020022Hong Kong Research Grant Council(RGC),Grant/A ward Numbers:GRFCityU 11305419,GRF CityU 11306920,GRF CityU 11308721,GRF CityU11316522。
文摘Solar-driven energy conversion is a promising technology for a sustainable energy future and environmental remediation, and an efficient catalyst is a key factor. Recently, metal halide perovskites(MHPs) have emerged as promising photocatalysts due to their exceptional photoelectronic properties and low-cost solution processing, enabling successful applications in H_(2) evolution, CO_(2) reduction, organic synthesis, and pollutant degradation. Despite these successes, the practical applications of MHPs are limited by their water instability. In this review, the recently developed strategies driving MHPcatalyzed reactions in aqueous media are outlined. We first articulate the structures and properties of MHPs, followed by elaborating on the origin of instability in MHPs. Then, we highlight the advances in solar-driven MHPbased catalytic systems in aqueous solutions, focusing on developing external protection strategies and intrinsically water-stable MHP materials. With each approach offering peculiar sets of advantages and challenges, we conclude by outlining potentially promising opportunities and directions for MHP-based photocatalysis research in aqueous conditions moving forward. We anticipate that this timely review will provide some inspiration for the design of MHPbased photocatalysts, manifestly stimulating their applications in aqueous environments for solar-to-chemical energy conversion.
