To assess the performances of state-of-the-art global climate models on simulating the Arctic clouds and surface radiation balance,the 2001–2014 Arctic Basin surface radiation budget,clouds,and the cloud radiative ef...To assess the performances of state-of-the-art global climate models on simulating the Arctic clouds and surface radiation balance,the 2001–2014 Arctic Basin surface radiation budget,clouds,and the cloud radiative effects(CREs)in 22 coupled model intercomparison project 6(CMIP6)models are evaluated against satellite observations.For the results from CMIP6 multi-model mean,cloud fraction(CF)peaks in autumn and is lowest in winter and spring,consistent with that from three satellite observation products(Cloud Sat-CALIPSO,CERESMODIS,and APP-x).Simulated CF also shows consistent spatial patterns with those in observations.However,almost all models overestimate the CF amount throughout the year when compared to CERES-MODIS and APP-x.On average,clouds warm the surface of the Arctic Basin mainly via the longwave(LW)radiation cloud warming effect in winter.Simulated surface energy loss of LW is less than that in CERES-EBAF observation,while the net surface shortwave(SW)flux is underestimated.The biases may result from the stronger cloud LW warming effect and SW cooling effect from the overestimated CF by the models.These two biases compensate each other,yielding similar net surface radiation flux between model output(3.0 W/m2)and CERES-EBAF observation(6.1 W/m2).During 2001–2014,significant increasing trend of spring CF is found in the multi-model mean,consistent with previous studies based on surface and satellite observations.Although most of the 22 CMIP6 models show common seasonal cycles of CF and liquid water path/ice water path(LWP/IWP),large inter-model spreads exist in the amounts of CF and LWP/IWP throughout the year,indicating the influences of different cloud parameterization schemes used in different models.Cloud Feedback Model Intercomparison Project(CFMIP)observation simulator package(COSP)is a great tool to accurately assess the performance of climate models on simulating clouds.More intuitive and credible evaluation results can be obtained based on the COSP model output.In the future,with the release of more COSP output of CMIP6 models,it is expected that those inter-model spreads and the model-observation biases can be substantially reduced.Longer term active satellite observations are also necessary to evaluate models’cloud simulations and to further explore the role of clouds in the rapid Arctic climate changes.展开更多
Two kinds of commercial ammonium polyphosphate （APP） and three kinds of APP which were prepared in the laboratory were studied by X-ray diffraction （XRD）, Fourier transforms infrared spectroscopy （FTIR）, scannin...Two kinds of commercial ammonium polyphosphate （APP） and three kinds of APP which were prepared in the laboratory were studied by X-ray diffraction （XRD）, Fourier transforms infrared spectroscopy （FTIR）, scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. In identification of the form Ⅱ crystal APP by XRD and FTIR, some discrepancies were discussed. It is pointed out that the absorbance of the FTIR spectra at 682 cm^-1 can exist not only in the form Ⅰ APP, but also in the form Ⅱ APP with the crystal lattice defects. The SEM images indicate that the form Ⅱ APP is of multilayer crystal structure. XRD and TEM can reveal the crystal lattice defects.展开更多
基金The Major State Basic Research Development Program of China under contract No.2016YFA0601804the Global Change Research Program of China under contract No.2015CB953900+1 种基金the National Natural Science Foundation of China under contract Nos 41941007 and 41876220the China Postdoctoral Science Foundation under contract No.2020M681661
文摘To assess the performances of state-of-the-art global climate models on simulating the Arctic clouds and surface radiation balance,the 2001–2014 Arctic Basin surface radiation budget,clouds,and the cloud radiative effects(CREs)in 22 coupled model intercomparison project 6(CMIP6)models are evaluated against satellite observations.For the results from CMIP6 multi-model mean,cloud fraction(CF)peaks in autumn and is lowest in winter and spring,consistent with that from three satellite observation products(Cloud Sat-CALIPSO,CERESMODIS,and APP-x).Simulated CF also shows consistent spatial patterns with those in observations.However,almost all models overestimate the CF amount throughout the year when compared to CERES-MODIS and APP-x.On average,clouds warm the surface of the Arctic Basin mainly via the longwave(LW)radiation cloud warming effect in winter.Simulated surface energy loss of LW is less than that in CERES-EBAF observation,while the net surface shortwave(SW)flux is underestimated.The biases may result from the stronger cloud LW warming effect and SW cooling effect from the overestimated CF by the models.These two biases compensate each other,yielding similar net surface radiation flux between model output(3.0 W/m2)and CERES-EBAF observation(6.1 W/m2).During 2001–2014,significant increasing trend of spring CF is found in the multi-model mean,consistent with previous studies based on surface and satellite observations.Although most of the 22 CMIP6 models show common seasonal cycles of CF and liquid water path/ice water path(LWP/IWP),large inter-model spreads exist in the amounts of CF and LWP/IWP throughout the year,indicating the influences of different cloud parameterization schemes used in different models.Cloud Feedback Model Intercomparison Project(CFMIP)observation simulator package(COSP)is a great tool to accurately assess the performance of climate models on simulating clouds.More intuitive and credible evaluation results can be obtained based on the COSP model output.In the future,with the release of more COSP output of CMIP6 models,it is expected that those inter-model spreads and the model-observation biases can be substantially reduced.Longer term active satellite observations are also necessary to evaluate models’cloud simulations and to further explore the role of clouds in the rapid Arctic climate changes.
基金Sponsored by the National Key Technology R&D Program(2006BAE03B05-2)
文摘Two kinds of commercial ammonium polyphosphate （APP） and three kinds of APP which were prepared in the laboratory were studied by X-ray diffraction （XRD）, Fourier transforms infrared spectroscopy （FTIR）, scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. In identification of the form Ⅱ crystal APP by XRD and FTIR, some discrepancies were discussed. It is pointed out that the absorbance of the FTIR spectra at 682 cm^-1 can exist not only in the form Ⅰ APP, but also in the form Ⅱ APP with the crystal lattice defects. The SEM images indicate that the form Ⅱ APP is of multilayer crystal structure. XRD and TEM can reveal the crystal lattice defects.
