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Performance analysis of ammonia-water absorption/compression combined refrigeration cycle 被引量:1
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作者 鲍帅阳 杜垲 +2 位作者 蔡星辰 牛晓峰 武云龙 《Journal of Southeast University(English Edition)》 EI CAS 2014年第1期60-67,共8页
In view of different compressor adding ways in the ammonia-water absorption/compression combined refrigeration AWA /CCR cycle combining the Schulz state equation of the ammonia-water solution the theoretical analysis ... In view of different compressor adding ways in the ammonia-water absorption/compression combined refrigeration AWA /CCR cycle combining the Schulz state equation of the ammonia-water solution the theoretical analysis and calculations on two combination ways by adding the compressor in the high-pressure area and in the low-pressure area are conducted respectively.The effects of several factors including the evaporation temperature Te heat-source temperature Th as well as the cooling water temperature Tw on the equivalent heat consumption in compression qCW heat consumption in absorption qG and the system coefficient of performance COP are analyzed under the two combination configurations.The results show that the effect of the equivalent heat consumption in compression on the COP is less than that of the heat consumption in absorption.Besides the compressor set in the high-pressure area uses more energy than that in the low-pressure area. Moreover the compressor in the low-pressure area is superior to that in the high-pressure area with respect to the COP. Under the given intermediate pressure there is an optimum heat-source temperature corresponding to the maximum COP of the AWA/CCR cycle. 展开更多
关键词 ammonia-water ABSORPTION compression refrigeration combined refrigeration cycle coefficient of performance COP
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Thermodynamic analysis of simplified dual-pressure ammonia-water absorption power cycle 被引量:5
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作者 华君叶 陈亚平 +1 位作者 刘化瑾 吴嘉峰 《Journal of Central South University》 SCIE EI CAS 2012年第3期797-802,共6页
A simplified dual-pressure ammonia-water absorption power cycle(DPAPC-a) using low grade energy resources is presented and analyzed.This cycle uses turbine exhaust heat to distill the basic solution for desorption.The... A simplified dual-pressure ammonia-water absorption power cycle(DPAPC-a) using low grade energy resources is presented and analyzed.This cycle uses turbine exhaust heat to distill the basic solution for desorption.The structure of the cycle is simple which comprises evaporator,turbine,regenerator(desorber),absorber,pump and throttle valves for both diluted solution and vapor.And it is of high efficiency,because the working medium has large temperature difference in evaporation and small temperature difference in absorptive condensation,which can match the sensible exothermal heat resource and the cooling water simultaneously.Orthogonal calculation was made to investigate the influence of the working concentration,the basic concentration and the circulation multiple on the cycle performance,with 85-110 ℃ heat resource and 20-32 ℃ cooling water.An optimum scheme was given in the condition of 110 ℃ sensitive heat resource and 20 ℃ cooling water,with the working concentration of 0.6,basic concentration of 0.385,and circulation multiple of 5.The thermal efficiency and the power recovery efficiency are 8.06 % and 6.66%,respectively.The power recovery efficiency of the DPAPC-a is 28.8% higher than that of the steam Rankine cycle(SRC) and 12.7% higher than that of ORC(R134a) under the optimized situation. 展开更多
关键词 absorption power cycle ammonia-water circulation multiple ammonia concentration Kalina cycle
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Influence factors on thermal conductivity of ammonia-water nanofluids 被引量:4
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作者 杨柳 杜垲 张小松 《Journal of Central South University》 SCIE EI CAS 2012年第6期1622-1628,共7页
In order to investigate the mechanism of nanoparticles enhancing the heat and mass transfer of the ammonia-water absorption process,several types of binary nanofluids were prepared by mixing Al2O3 nanoparticles with p... In order to investigate the mechanism of nanoparticles enhancing the heat and mass transfer of the ammonia-water absorption process,several types of binary nanofluids were prepared by mixing Al2O3 nanoparticles with polyacrylic acid(PAA),TiO2 with polyethylene glycol(PEG 1000),and TiN,SiC,hydroxyapatite(noodle-like) with PEG 10000 to ammonia-water solution,respectively.The thermal conductivities were measured by using a KD2 Pro thermal properties analyzer.The influences of surfactant and ammonia on the dispersion stabilities of the binary nanofluids were investigated by the light absorbency ratio index methods.The results show that the type,content and size of nanoparticles,the temperature as well as the dispersion stability are the key parameters that affect the thermal conductivity of nanofluids.For the given nanoparticle material and the base fluid,the thermal conductivity ratio of the nanofluid to the ammonia-water liquid increases as the nanoparticle content and the temperature are increased,and the diameter of nanoparticle is decreased.Furthermore,the thermal conductivity ratio increases significantly by improving the stabilities of nanofluids,which is achieved by adding surfactants or performing the proper ammonia content in the fluid. 展开更多
关键词 binary nanofluids ammonia-water thermal conductivity size effect dispersion stability
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Thermodynamic and Experimental Analysis of an Ammonia-Water Absorption Chiller 被引量:1
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作者 Dingfeng Kong Jianhua Liu +2 位作者 Liang Zhang Hang He Zhiyun Fang 《Energy and Power Engineering》 2010年第4期298-305,共8页
A single stage ammonia-water absorption chiller with complete condensation is designed, built and tested. The apparatus is designed for a cooling capacity of 2814 W, which is obtained using electric heater as heating ... A single stage ammonia-water absorption chiller with complete condensation is designed, built and tested. The apparatus is designed for a cooling capacity of 2814 W, which is obtained using electric heater as heating source. The thermodynamic models have been derived using the First and Second Laws. Calculated results are compared with experimental data. The results show that the cooling capacity of experimental apparatus is found between 1900 and 2200 W with the actual coefficient of performance (COP) between 0.32 and 0.36. The contribution of the components to internal entropy production is analyzed. It shows that the larger irreversibility is caused by spanning the largest temperature and dissipated thermal energy by heat transfer losses at the generator and evaporator. In the experimentation, the low pressure is lower than the designed value. This is a consequence of a large capacity in the falling film absorber which performs as expected. This decreases the evaporation pressure, and the evaporating temperature could be reduced to the designed value. 展开更多
关键词 ABSORPTION CHILLER ammonia-water THERMODYNAMIC MODELING EXPERIMENTAL Performance
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Magnetic Field Enhancement in Ammonia-Water Absorption Refrigeration Systems
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作者 Moradeyo K. Odunfa Richard O. Fagbenle +1 位作者 Olanrewaju M. Oyewola Olayinka S. Ohunakin 《Energy and Power Engineering》 2014年第4期54-68,共15页
Absorption enhancement has been considered as an effective way of improving coefficient of performance (COP) of refrigeration systems and magnetic enhancement is one of these methods. A model of magnetic field enhance... Absorption enhancement has been considered as an effective way of improving coefficient of performance (COP) of refrigeration systems and magnetic enhancement is one of these methods. A model of magnetic field enhancement in ammonia-water absorption systems is presented in this paper. A numerical model using finite difference scheme was developed based on the conservation equations and mass transport relationship. Macroscopic magnetic field force was introduced in the momentum equation. The model was validated using data obtained from the literature. Changes in the physical properties of ammonia solution while absorbing both in the direction of falling film and across its thickness were investigated. The magnetic field was found to have some positive effect on the ammonia-water falling film absorption. The results indicate that absorption performance enhancement increased with magnetic intensity. The COP of simple ammonia solution absorption refrigeration system increased by 1.9% and 3.6% for magnetic induction of 1.4 and 3.0 Tesla respectively. 展开更多
关键词 ammonia-water Absorption REFRIGERATION Magnetic Field Force AMMONIA SOLUTION Concentration COEFFICIENT of Performance Finite DIFFERENCE Scheme Numerical SOLUTION
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Computer Simulation of an Ammonia-Water Absorption Cycle for Refrigeration: Using a Distillation Tower to Replace the Generator
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作者 You-Im Chang Lin-Chia Wu +1 位作者 Cherng-Chiao Wu Larry K. Jang 《Energy and Power Engineering》 2020年第6期237-256,共20页
<div style="text-align:justify;"> <span style="font-family:Verdana;">By using a distillation tower as the regenerator, the coefficient of performance (COP) of the ammonia-water absorpti... <div style="text-align:justify;"> <span style="font-family:Verdana;">By using a distillation tower as the regenerator, the coefficient of performance (COP) of the ammonia-water absorption refrigeration cycle is calculated in </span><span style="font-family:Verdana;">this work. Two types of distillation towers, namely an equilibrium-stage</span><span style="font-family:Verdana;"> tower with a total condenser and a packed-bed tower with a partial condenser, are used in the cycle. From the simulation results, it is found that both types of distillation towers can successfully increase the COP of the cycle due to increased ammonia concentration in the vapor phase of the ammonia-water refrigerant. It was also found that the tower equipped with a partial condenser provides higher COP than that of the tower equipped with a total condenser. The value of COP can be further increased when the generator is replaced by the packed-bed tower in this water-ammonia absorption cycle. The effects of the mass flow rate ratio of NH</span><sub><span style="font-family:Verdana;">3</span></sub><span style="font-family:Verdana;">/H</span><sub><span style="font-family:Verdana;">2</span></sub><span style="font-family:Verdana;">O, stage number, reflux ratio and energy duty of the tower on the COP of the cycle are also studied in the present paper.</span> </div> 展开更多
关键词 Simulation ammonia-water ABSORPTION REFRIGERATION
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Thermodynamic Modelling of a 10-kW Ammonia-Water Absorption Machine
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作者 Fatimata Dione Ababacar Thiam +1 位作者 Djicknoum Diouf Amadou-Seidou Maiga 《Journal of Energy and Power Engineering》 2022年第5期213-221,共9页
Absorption chillers are cooling units usually powered by renewable energy or waste heat.Their performance generally depends on the temperatures of the heat source,the ambient and the medium to be cooled.The present wo... Absorption chillers are cooling units usually powered by renewable energy or waste heat.Their performance generally depends on the temperatures of the heat source,the ambient and the medium to be cooled.The present work deals with the thermodynamic study of a 10 kW NH3/H2O absorption machine in order to find the COP(coefficient of performance).The first and second laws of thermodynamics were used for the operating conditions.The thermodynamic properties of the NH3/H2O mixture were determined using the EES(Engineering Equation Solver)software.The results of the simulation of the machine were validated with the results of the literature.After validation,the program was used to simulate a 10-kW NH3/H2O absorption machine for milk conservation/cold storage in northern Senegal.The simulation results of the 10-kW ammonia-water absorption machine give an acceptable COP of 0.521 with a milk storage temperature of 4°C. 展开更多
关键词 ABSORPTION ammonia-water COP EES
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Numerical investigation of falling film generation outside vertical tube with ammonia-water nanofluid
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作者 Yanjun Li Weixue Jiang +4 位作者 Jinwei Song Zuo Xu Xinyu Tang Shuhong Li Kai Du 《Energy and Built Environment》 2025年第2期362-377,共16页
This paper constructed a mathematical model of ammonia-water nanofluid falling film generation outside the vertical tube,which considers the change of the film thickness of the falling film solution,the thermal convec... This paper constructed a mathematical model of ammonia-water nanofluid falling film generation outside the vertical tube,which considers the change of the film thickness of the falling film solution,the thermal convection along the film thickness direction and the physical properties of the solution.By solving the mathematical model,the temperature field and other elements of the liquid film were determined.The influence of the properties of the working fluid on the heat and mass transfer in the falling film process is investigated.According to the calculation results,a method of adding nanoparticles in the process of ammonia falling film generation is proposed.The simulation results showed that the heat efficiency of entire falling film process can be enhanced by adding an appropriate amount of Al_(2)O_(3) nanoparticles.When the added Al_(2)O_(3) nanoparticles are 1 vol.%,the coefficient of the heat transfer is increased by about 4%,and the mass transfer effect is also improved by about 12%.In brief,the establishment of this model aims to improve heat and mass transfer efficiency and promote the application and integration of low-grade waste heat or renewable energy technologies in built environment. 展开更多
关键词 Numerical model NANOFLUID ammonia-water Falling film generation
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Theoretical and experimental investigation on a liquid-gas ejector power cycle using ammonia-water 被引量:10
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作者 YUAN Han MEI Ning +3 位作者 LI Yan YANG Shuai HU SiYuan HAN YiFang 《Science China(Technological Sciences)》 SCIE EI CAS 2013年第9期2289-2298,共10页
The purpose of this paper is to investigate a novel power cycle using low-temperature heat sources such as oceanic-thermal, biomass as well as industrial waste heat. Both a reheater and a liquid-gas ejector are used i... The purpose of this paper is to investigate a novel power cycle using low-temperature heat sources such as oceanic-thermal, biomass as well as industrial waste heat. Both a reheater and a liquid-gas ejector are used in this ammonia-water based cycle. Energy analysis and parametric analysis are performed to guide the theoretical performance and experimental investigation is done to verify the theoretical results. The results show that the generator pressure, heating source temperature and turbine outlet depressurization made by the ejector can affect the cycle performances. Besides, the experimental thermal efficiency is much lower than the theoretical one on account of the heat losses and irreversibility. Moreover, the performance of liquid-gas ejector is affected by primary flow pressure and temperature. 展开更多
关键词 ammonia-water power cycle EJECTOR EFFICIENCY
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Transportation of low-grade thermal energy over long distance by ammonia-water absorption 被引量:2
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作者 MA Qiang WANG RuZhu +2 位作者 LUO LinGai XIA ZaiZhong LIN Peng 《Chinese Science Bulletin》 SCIE EI CAS 2009年第6期948-957,共10页
This paper presents the importance and the cycle choice for long-distance transportation of low-grade thermal energy, and the thermodynamic and hydrodynamic feasibility of single-effect ammonia-water absorption system... This paper presents the importance and the cycle choice for long-distance transportation of low-grade thermal energy, and the thermodynamic and hydrodynamic feasibility of single-effect ammonia-water absorption system for heat or cold transportation over long distance are also involved. A model of a long-distance thermal energy transportation system is built and analyzed, which shows satisfactory and attractive results. When a steam heat source at 120℃ is available, the user site can get hot water output at about 55℃ with the thermal COP of about 0.6 and the electric COP of about 100 in winter, and cold water output at about 10℃ with the thermal COP of about 0.5 and the electric COP of 50 in summer. A small-size prototype is built to verify the performance analysis. Basically the experimental data show good accordance with the analysis results. The ammonia-water absorption system is a potential pro-spective solution for the heat or cold transportation over long distance. 展开更多
关键词 氨水吸收式 低品位热能 远距离 交通 长途运输 吸收系统 流体力学 运输系统
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膜分离-流动分析-分光光度法自动分析复杂基质工业废水中的氨氮
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作者 胡骏 华燕莉 +1 位作者 黄瑞 林坤德 《分析测试学报》 北大核心 2026年第1期177-183,共7页
基于膨体聚四氟乙烯(ePTFE)中空纤维膜分离技术,结合流动分析和溴百里酚蓝分光光度法,开发了一种简便、高效自动分析复杂基质工业废水中氨氮的方法。探究了基质pH值、盐度和有机氮对氨氮测定的影响,结果表明,以上因素均不会干扰该方法... 基于膨体聚四氟乙烯(ePTFE)中空纤维膜分离技术,结合流动分析和溴百里酚蓝分光光度法,开发了一种简便、高效自动分析复杂基质工业废水中氨氮的方法。探究了基质pH值、盐度和有机氮对氨氮测定的影响,结果表明,以上因素均不会干扰该方法分析氨氮。在优化条件下,方法的检出限为0.16 mg/L,线性范围为0.57~30 mg/L,具有良好的精密度(RSD≤3.0%),分析速度快(样品通量为15 h^(-1))。将该方法应用于工业废水中的氨氮检测,结果与蒸馏-中和滴定法(HJ 537-2009)测定结果基本相近,且基底加标回收率为94.1%~99.0%,显著优于标准方法的加标回收率(47.7%~68.5%)。该方法为复杂基质废水的氨氮检测提供了一种成本较低、自动化程度高和抗干扰能力强的可靠方法,在水质检测领域展现出良好的应用前景。 展开更多
关键词 膜分离 氨氮 复杂基质工业废水 流动分析 水质检测
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磁性沸石加载混凝处理黑臭水体除污效能与机制 被引量:1
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作者 方华 周琼 +2 位作者 李璇 赵金宇 徐林 《环境工程学报》 北大核心 2025年第9期2118-2126,共9页
磁混凝技术在黑臭水体治理应用中,存在着对溶解态污染物、特别是氨氮去除效果差的局限。在制备磁性沸石的基础上,开展磁加载与吸附耦合强化混凝工艺对黑臭水体中污染物的去除效能和机制研究。结果表明,采用共沉淀法可使纳米Fe_(3)O_(4)... 磁混凝技术在黑臭水体治理应用中,存在着对溶解态污染物、特别是氨氮去除效果差的局限。在制备磁性沸石的基础上,开展磁加载与吸附耦合强化混凝工艺对黑臭水体中污染物的去除效能和机制研究。结果表明,采用共沉淀法可使纳米Fe_(3)O_(4)磁种成功负载于沸石上制得磁性沸石。磁性沸石加载强化混凝(磁沸混凝)处理黑臭水体具备了磁混凝除浊效果好、絮体沉降快的技术优势。同时,磁沸混凝还可分别利用离子交换作用和吸附作用大幅提升对氨氮和COD的去除效能,并通过化学除磷作用强化除磷效果。磁沸混凝优先去除DOM中的芳构化和腐殖化程度高、分子质量大的部分;相较于类富里酸,磁沸混凝更易于去除类腐殖酸有机物。随磁性沸石回用次数增加,磁沸混凝对氨氮去除能力快速下降,但对总磷的去除影响较小。磁性沸石脱附再生可恢复对氨氮的去除能力,但导致总磷去除效能降低。相较于磁混凝,磁沸混凝可有效去除黑臭水体中溶解态污染物,全面提升出水水质,具有广阔的应用前景。 展开更多
关键词 磁性沸石 加载混凝 磁混凝 黑臭水体 氨氮 溶解性有机物
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除铁锌渣中锌铜浸出条件的优化及浸出液的资源化利用
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作者 党晓娥 阳丹 刘安全 《中南大学学报(自然科学版)》 北大核心 2025年第8期3345-3359,共15页
针对中浸渣草酸除铁过程中产出的锌渣,采用氨水-碳酸铵浸出锌渣—锌粉还原浸出液—还原后液蒸发回收有价金属及C_(2)O_(4)^(2-)的工艺,研究影响铜和锌浸出的因素,确定锌粉还原浸出液中铜、镍和钴的工艺条件,并采用响应面法对铜和锌的浸... 针对中浸渣草酸除铁过程中产出的锌渣,采用氨水-碳酸铵浸出锌渣—锌粉还原浸出液—还原后液蒸发回收有价金属及C_(2)O_(4)^(2-)的工艺,研究影响铜和锌浸出的因素,确定锌粉还原浸出液中铜、镍和钴的工艺条件,并采用响应面法对铜和锌的浸出条件进行优化,研究还原后液中金属及(NH_(4))_(2)C_(2)O_(4)的回收工艺。研究结果表明,液固比和搅拌速度对锌的浸出率影响较小,NH_(3)·H_(2)O与(NH_(4))_(2)CO_(3)物质的量比、(NH_(4)^(+))TOT的过量倍数、浸出温度以及浸出时间对锌的浸出率影响较大。优化后锌的浸出条件如下:n(NH_(3)·H_(2)O)/n(NH_(4))_(2)CO_(3)=0.51/3.49、(NH_(4)^(+))TOT过量2.011倍、浸出温度为28.63℃。在该优化条件下,锌和铜的浸出率实测值分别为99.46%和58.84%,其预测值分别为101.19%和59.41%,浸出渣为铅银渣。采用锌粉还原浸出液中金属的工艺条件如下:锌粉量为0.11 g、还原温度和还原时间分别为16℃和15 min。还原后液连续蒸发产物为碱式碳酸锌和(NH_(4))_(2)C_(2)O_(4)。该技术解决了锌渣中锌、铜、镍和钴的回收以及草酸盐中C_(2)O_(4)^(2-)的回收问题,为全湿法回收中浸渣中铜、锌、镍及钴提供了一条新思路。 展开更多
关键词 锌渣 氨水 碳酸铵 浸出 优化 还原 蒸发
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水泡粪污水除氨氮细菌筛选研究
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作者 李树文 韩先杰 《家畜生态学报》 北大核心 2025年第6期112-118,共7页
猪场氨气主要来源于液体粪污的氨氮,氨氮的高效去除对于粪污氨气的有效处理具有重要意义。本研究以水泡粪污水为研究对象,以氨气和氨氮去除率为测量指标,对10株芽孢杆菌的脱氨效果进行评价。结果表明,10株细菌均具有去除氨氮的作用,其中... 猪场氨气主要来源于液体粪污的氨氮,氨氮的高效去除对于粪污氨气的有效处理具有重要意义。本研究以水泡粪污水为研究对象,以氨气和氨氮去除率为测量指标,对10株芽孢杆菌的脱氨效果进行评价。结果表明,10株细菌均具有去除氨氮的作用,其中5株菌株即Bacillus licheniformis WL、B.mucilaginosus、B.methylotrophicus、B.megateriumde、B.subtilis GY在实验室条件下72 h氨氮去除率达到50%以上,5株菌株复配后的氨氮去除率与单一菌株处理效果基本相同;水泡粪污水处理试验表明,B.megateriumde具有高效的氨气和氨氮去除率,6 h氨气相对去除率为27%,24 h氨氮相对去除率和绝对去除率分别为63%和64%。该研究结果为水泡粪猪场的氨气和粪污氨氮的有效处理提供了理论指导和实践参考。 展开更多
关键词 水泡粪污水 氨氮 细菌 筛选 去除
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羊粪基生物炭对含盐污水中氨氮的吸附性能研究 被引量:1
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作者 陆一新 刘芳颖 +4 位作者 舒铭宇 唐艺 何小春 杨小波 陈佼 《成都工业学院学报》 2025年第2期1-8,19,共9页
选择废弃羊粪球为原材料,在600℃条件下采用限氧热解法制备羊粪基生物炭(SMB600)应用于吸附去除含盐污水中的氨氮污染物,考察了影响氨氮吸附效果的主要因素,并探讨其吸附行为特征和吸附机理。结果表明,在盐度为0.8%、进水氨氮质量浓度为... 选择废弃羊粪球为原材料,在600℃条件下采用限氧热解法制备羊粪基生物炭(SMB600)应用于吸附去除含盐污水中的氨氮污染物,考察了影响氨氮吸附效果的主要因素,并探讨其吸附行为特征和吸附机理。结果表明,在盐度为0.8%、进水氨氮质量浓度为30 mg/L、反应温度为25℃的水溶液中,设置进水pH值为7,SMB600投加量为1.2 g/L,振荡反应300 min后吸附进入平衡阶段,氨氮去除率可达到90%以上。SMB600对含盐污水中氨氮的吸附行为特征更加符合准二级动力学模型和Langmuir等温线模型,是由化学作用主导的有利单分子层吸附,理论最大氨氮吸附量为25.1~26.6 mg/g。该吸附过程属于熵增推动的自发吸热反应。吸附机理涉及静电引力、孔隙填充、氢键作用、阳离子-π键作用等。SMB600再生性能好,可作为含盐污水中氨氮去除的有效吸附材料,推动低成本生物炭材料在含盐污水处理方面的应用。 展开更多
关键词 生物炭 羊粪 氨氮 含盐污水 吸附
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基于高分二号遥感数据的黑臭水体识别和氨氮反演研究 被引量:1
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作者 卢辉雄 李启亮 +4 位作者 薛庆 张策 孙永彬 韩少飞 牛海威 《世界核地质科学》 2025年第2期360-373,共14页
随着政府部门在水污染防治工作上的不断推进,水环境出现了大幅改善,但在工业区、畜禽养殖场等污染源附近的水体仍然容易反黑反臭,如何识别这些因污水排放导致氨氮含量超标的黑臭水体是迫切需要解决的问题。本次研究以收集的30处氨氮超... 随着政府部门在水污染防治工作上的不断推进,水环境出现了大幅改善,但在工业区、畜禽养殖场等污染源附近的水体仍然容易反黑反臭,如何识别这些因污水排放导致氨氮含量超标的黑臭水体是迫切需要解决的问题。本次研究以收集的30处氨氮超标的黑臭水体为样本,提出一种基于高分二号遥感数据的黑臭水体识别和氨氮反演方法,通过组合多种黑臭水体波段比值识别算法和多种阈值分割算法,获得适用于研究区的黑臭水体识别组合算法并对研究区进行黑臭水体识别,分析各波段比值算法因子和氨氮实测值的相关性,对识别的黑臭水体中氨氮含量进行反演,获得氨氮的空间分布图以发现疑似排污点位置。结果表明:1)BOCI、WCI、FUI和e4共4种算法,对黑臭水体和一般水体的可分离度较高,BOCI-OSTU和BOCI-平均值两种算法组合在预测集样本上分割效果最好,BOCI在各阈值算法中发挥最为稳定;2)BOCI-OSTU、BOCI-平均值和WCI-最小值对黑臭水体的识别效果相对较好;3)在识别到黑臭水体后,BOI和G-R算法与实测氨氮值的相关性最高,决定系数分别是0.6和0.58,能较好地解释实测氨氮值的变化,可作为反演氨氮的因子;4)利用BOI算法对研究区内的3条沟渠进行氨氮反演,获得氨氮空间分布图,给出疑似排污位置。因此,该技术可为政府部门提供高效的黑臭水体排查服务,为生态环境监测提供技术支持。 展开更多
关键词 黑臭水体 高分二号遥感数据 氨氮 波段比值 阈值
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基于不同投喂策略的循环水养殖系统氨氮预测模型 被引量:1
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作者 孙雪倩 李丽 +2 位作者 董双林 田相利 张盛坤 《水产学报》 北大核心 2025年第1期135-146,共12页
【目的】实现对循环水养殖系统水体中总氨氮(TAN)浓度的预测,并研究投喂策略对TAN预测模型预测精度的影响。【方法】本研究测定了斑石鲷养殖池内7个水质指标,采用主成分分析(PCA)和Pearson相关性分析法对数据进行前处理并形成三种数据集... 【目的】实现对循环水养殖系统水体中总氨氮(TAN)浓度的预测,并研究投喂策略对TAN预测模型预测精度的影响。【方法】本研究测定了斑石鲷养殖池内7个水质指标,采用主成分分析(PCA)和Pearson相关性分析法对数据进行前处理并形成三种数据集:原始数据集(OD)、Pearson数据集(Pearson D)和PCA数据集(PCAD),结合随机森林(RF)、BP神经网络(BP)、门控循环单元(GRU)、长短期记忆网络(LSTM)这4种模型,对两种投喂策略下养殖水体中的TAN浓度进行预测,并采用均方根误差(RMSE)、均方误差(MSE)、平均绝对误差(MAE)和R方值(R2-score)对模型进行评估。【结果】RF模型的预测效果最差,随着投喂策略的改变,GRU与LSTM模型预测精度较高且稳定,而BP模型预测精度波动较大。不同投喂阶段筛选出的最优预测模型不同,人工和自动化投喂阶段的最优模型分别为Pearson D-BP和Pearson D-GRU模型,在整个实验周期中,PCAD-LSTM模型、Pearson D-LSTM模型和Pearson D-GRU模型预测性能较好。人工投喂阶段与自动化投喂阶段相比,Pearson DLSTM模型的RMSE、MSE和MAE分别降低了0.0072、0.0019和0.0036,R2-score升高了0.1075;Pearson D-GRU模型的RMSE、MSE和MAE分别降低了0.0030、0.0008和0.0030,R2-score升高了0.0826。【结论】投喂策略会影响TAN预测模型的预测精度,结合Pearson分析的GRU或LSTM模型可很好地实现该系统养殖水体中TAN的预测,该结果可为RAS氨氮预测技术的优化提供参考。 展开更多
关键词 斑石鲷 循环水养殖系统 投喂策略 总氨氮 水质预测模型
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ODS-HPLC法测定水中氨氮的方法研究
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作者 高镱萌 《黑龙江环境通报》 2025年第9期4-6,共3页
本研究旨在探讨在线衍生—高效液相色谱法(HPLC)测定水中氨氮的有效方法。采用赛默飞U3000高效液相色谱仪,结合在线衍生系统,通过氯化铵标准溶液的配置和不同衍生液的使用,优化了检测条件。研究中配置了多种标准溶液和显色液,考察了不... 本研究旨在探讨在线衍生—高效液相色谱法(HPLC)测定水中氨氮的有效方法。采用赛默飞U3000高效液相色谱仪,结合在线衍生系统,通过氯化铵标准溶液的配置和不同衍生液的使用,优化了检测条件。研究中配置了多种标准溶液和显色液,考察了不同衍生液比例、流速及反应温度对检测效果的影响。结果表明,氯化铵的标准曲线具有良好的线性关系(R^(2)=0.9995),检出限为0.069 mg/L,定量限为0.207mg/L。温度对峰面积的影响显著,随着温度升高,峰面积逐渐降低。研究通过对衍生试剂比例和流速的优化,确定了最佳反应条件,并进行了重复性检验,结果显示实验重复性良好(RSD为0.384%)。本研究将为水中氨氮的高效检测提供可靠的实验方法。 展开更多
关键词 高效液相色谱法 在线衍生系统 水环境 氨氮
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水-氧-应力联合作用对X80液氨管道应力腐蚀的影响实验 被引量:1
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作者 李加庆 何帅震 +4 位作者 赵子峰 冯智雨 尹鹏博 滕霖 江莉龙 《油气储运》 北大核心 2025年第3期271-279,共9页
【目的】在“双碳”目标下,液氨有望成为高效与安全的储氢载体。但在液氨长距离管输过程中,管材易发生液氨应力腐蚀开裂进而引起液氨泄漏事故,威胁液氨管道运行本质安全。因此,探究管线钢液氨应力腐蚀敏感性规律对保障管道安全意义重大... 【目的】在“双碳”目标下,液氨有望成为高效与安全的储氢载体。但在液氨长距离管输过程中,管材易发生液氨应力腐蚀开裂进而引起液氨泄漏事故,威胁液氨管道运行本质安全。因此,探究管线钢液氨应力腐蚀敏感性规律对保障管道安全意义重大。【方法】为分析管线钢在含杂质液氨环境下的应力腐蚀行为,设计并开展了不同含量的水、氧气及不同应力下的X80管线钢C形环法应力腐蚀实验;采用失重法、控制变量法定量分析杂质及应力联合作用对X80管线钢液氨应力腐蚀行为的影响;基于管线钢的腐蚀速率、腐蚀微观形貌及腐蚀产物3个方面,阐明管线钢的液氨应力腐蚀演化规律及内在机理。【结果】在无水液氨环境下,随着氧含量的增加,管线钢腐蚀速率增大;随着应力的增加,管线钢腐蚀速率迅速增大;当在含氧液氨中加入质量分数为0.20%的水,在所研究的氧浓度范围内,管线钢的腐蚀速率均降低。氧浓度与应力的联合作用会诱发管线钢表面形成腐蚀产物:当施加应力为100%屈服强度时,腐蚀产物呈颗粒状沉积形态,且有裂纹萌生与扩展;随着应力进一步增大至125%屈服强度、150%屈服强度时,管线钢表面萌生出更多裂纹且部分相连,腐蚀形貌呈现胶泥状沉积形态并伴有龟裂纹形成。分别加入质量分数为0.20%与1.00%的水,即使在高应力下,管线钢表面仅出现少量微裂纹与腐蚀产物,表明一定量的水杂质能够抑制管线钢的液氨应力腐蚀开裂倾向。【结论】在液氨管道设计、建设及运行过程中,需要考虑氧气杂质的混入、管材的高应力抗力以及管道施工引起的残余应变等因素对液氨管道应力腐蚀开裂的影响,必要时可添加一定量的水降低液氨腐蚀风险,提升高钢级管道的服役安全。 展开更多
关键词 X80管线钢 液氨 水-氧-应力 应力腐蚀 腐蚀速率
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湖水入渗中氮迁移转化特征与氧化还原分带规律
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作者 苏小四 赵禹尧 +1 位作者 李宁飞 马锋敏 《南水北调与水利科技(中英文)》 北大核心 2025年第3期693-702,734,共11页
基于富营养湖水向地下水的补给极易对湖周地区地下水水质安全造成威胁,以东北平原腹地的查干湖为研究区,在查明该区水文地质条件的基础上,通过湖水、地下水和含水介质样品的采集与测试,研究查干湖湖水入渗补给地下水过程中氮的迁移转化... 基于富营养湖水向地下水的补给极易对湖周地区地下水水质安全造成威胁,以东北平原腹地的查干湖为研究区,在查明该区水文地质条件的基础上,通过湖水、地下水和含水介质样品的采集与测试,研究查干湖湖水入渗补给地下水过程中氮的迁移转化特征与氧化还原分带规律。结果表明:控制湖水补给地下水过程中氮迁移转化的主要水文地球化学作用包括混合作用、吸附–解吸作用、硝化–反硝化作用和矿化作用;湖水入渗过程中发生顺序氧化还原反应,依次形成有氧呼吸作用和硝化作用带、反硝化作用带、锰铁还原溶解作用带、硫酸盐还原作用带。研究结果对于深入理解湖水入渗补给地下水过程中发生的各项生物地球化学过程、保障湖水和地下水的水质安全具有重要的理论意义和实际应用价值。 展开更多
关键词 湖水入渗 氧化还原分带 硝氮 氨氮 迁移转化
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