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Numerical Simulation on Thermomechanical Coupling Process in Friction Stir-Assisted Wire Arc Additive Manufacturing
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作者 Li Long Xiao Yichen +2 位作者 Shi Lei Chen Ji Wu Chuansong 《稀有金属材料与工程》 北大核心 2026年第1期1-8,共8页
Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing addit... Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing additive-induced defects,and alleviating residual stress and deformation,all of which are critical for enhancing the mechanical performance of the manufactured parts.Integrating interlayer friction stir processing(FSP)into WAAM significantly enhances the quality of deposited materials.However,numerical simulation research focusing on elucidating the associated thermomechanical coupling mechanisms remains insufficient.A comprehensive numerical model was developed to simulate the thermomechanical coupling behavior in friction stir-assisted WAAM.The influence of post-deposition FSP on the coupled thermomechanical response of the WAAM process was analyzed quantitatively.Moreover,the residual stress distribution and deformation behavior under both single-layer and multilayer deposition conditions were investigated.Thermal analysis of different deposition layers in WAAM and friction stir-assisted WAAM was conducted.Results show that subsequent layer deposition induces partial remelting of the previously solidified layer,whereas FSP does not cause such remelting.Furthermore,thermal stress and deformation analysis confirm that interlayer FSP effectively mitigates residual stresses and distortion in WAAM components,thereby improving their structural integrity and mechanical properties. 展开更多
关键词 friction stir processing wire arc additive manufacturing numerical simulation thermomechanical coupling temperature field DEFORMATION
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F-GEOMETRIC ERGODIC OF CONTINUOUS TIME MARKOV PROCESSES BY COUPLING METHOD
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作者 ZHU Zhi-feng ZHOU Jun-chao 《数学杂志》 2025年第6期493-501,共9页
In this paper,we study the geometric ergodicity of continuous time Markov pro-cesses in general state space.For the geometric ergodic continuous time Markov processes,the condition π(f^(p))<∞,p>1 is added.Usin... In this paper,we study the geometric ergodicity of continuous time Markov pro-cesses in general state space.For the geometric ergodic continuous time Markov processes,the condition π(f^(p))<∞,p>1 is added.Using the coupling method,we obtain the existence of a full absorbing set on which continuous time Markov processes are f-geometric ergodic. 展开更多
关键词 Markov process coupling f-norm geometric ergodicity f-geometric ergodicity
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Towards Production and Energy Coupling System Modeling and Simulation for Energy Optimization in the Process Industry 被引量:1
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作者 戴毅茹 王坚 《Journal of Donghua University(English Edition)》 EI CAS 2011年第2期128-133,共6页
The production and energy coupling system is used to mainly present energy flow, material flow, information flow, and their coupling interaction. Through the modeling and simulation of this system, the performance of ... The production and energy coupling system is used to mainly present energy flow, material flow, information flow, and their coupling interaction. Through the modeling and simulation of this system, the performance of energy flow can be analyzed and optimized in the process industry. In order to study this system, the component based hybrid Petri net methodology (CpnHPN) is proposed, synthesizing a number of extended Petri net methods and using the concept of energy place, material place, and information place. Through the interface place in CpnHPN, the component based encapsulation is established, which enables the production and energy coupling system to be built, analyzed, and optimized on the multi-level framework. Considering the block and brief simulation for hybrid system, the CpnHPN model is simulated with Simulink/Stateflow. To illustrate the use of the proposed methodology, the application of CpnHPN in the energy optimization of chlorine balance system is provided. 展开更多
关键词 process INDUSTRY ENERGY optimization PRODUCTION and ENERGY coupling system PETRI NET modeling simulation
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Numerical simulation of a sheet metal extrusion process by using thermal-mechanical coupling EAS FEM 被引量:2
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作者 ZhanghuaChen T.C.Lee 《Journal of University of Science and Technology Beijing》 CSCD 2002年第5期378-382,共5页
The thermal-mechanical coupling finite element method(FEM)was usedto simulate a non-isothermal sheet metal extrusion process. On thebasis of the finite plasticity consistent with multiplicativedecomposition of the def... The thermal-mechanical coupling finite element method(FEM)was usedto simulate a non-isothermal sheet metal extrusion process. On thebasis of the finite plasticity consistent with multiplicativedecomposition of the deformation gradient, the enhanced as- sumedstrain(EAS)FEM was applied to carry out the numerical simulation. Inorder to make the computation reliable ad avoid hour- glass mode inthe EAS element under large compressive strains, an alterative formof the original enhanced deformation gradient was employed. Inaddition, reduced factors were used in the computation of the elementlocal internal parameters and the enhanced part of elementalstiffness. 展开更多
关键词 enhanced assumed strain element thermal-mechanical coupling process houyrglass mode
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The Mesozoic Basin-Mountain Coupling Process of the Southern East China Sea Shelf Basin and its Adjacent Land Area 被引量:10
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作者 YANG Changqing YANG Yanqiu +2 位作者 LI Gang YANG Chuansheng YANG Jinyu 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第3期1051-1052,共2页
Basin-mountain coupling is a key issue for basin formation and evolution. The analysis of basin-mountain coupling process, as well as quantitative or semiquantitative restoration of prototype basin and the evolution o... Basin-mountain coupling is a key issue for basin formation and evolution. The analysis of basin-mountain coupling process, as well as quantitative or semiquantitative restoration of prototype basin and the evolution of continental margin, can be used to interpret the geological process of basin-range conversion and reconstruct early prototype basins, which is a difficult and leadin~ scientific oroblem of basin research. 展开更多
关键词 The Mesozoic Basin-Mountain coupling process of the Southern East China Sea Shelf Basin and its Adjacent Land Area
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Multi-Objective Trajectory Optimization for Rigid-Flexible Coupling Spray-Painting Robot Integrated with Coating Process Constraints 被引量:1
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作者 Feng Xu Bin Zi +1 位作者 Jingyuan Wang Zhaoyi Yu 《Chinese Journal of Mechanical Engineering》 CSCD 2024年第6期396-413,共18页
Robot-automated spraying is widely used in various fields,such as the automotive,metalworking,furniture,and aero-space industries.Spraying quality is influenced by multiple factors,including robot speed,acceleration,e... Robot-automated spraying is widely used in various fields,such as the automotive,metalworking,furniture,and aero-space industries.Spraying quality is influenced by multiple factors,including robot speed,acceleration,end-effector trajectory,and spraying process constraints.To achieve high-quality spraying under the influence of multiple factors,this study proposes a multi-objective optimization method for the spraying trajectory that integrates spraying process constraints into the optimization process.First,a 7-degree-of-freedom rigid-flexible coupling serial spray painting robot system is introduced,which includes a motion decoupling mechanism and a tension amplification mechanism.Subsequently,a paint deposition model for the spray gun was established,and the influence of process constraints on spraying quality was analyzed.Trajectory planning for the spray painting robot,based on the septic B-spline interpolation method,was then performed.Based on this foundation,objective functions and constraint equations for spraying trajectory optimization were established.A multi-objective trajectory optimization method for spraying by the robot is proposed based on the NSGA-Ⅱ,which integrates the spraying process constraints.Finally,a prototype system of a 7-degree-of-freedom rigid-flexible coupling serial spray painting robot was constructed.Simulations and spraying experiments were conducted to verify the effectiveness of the proposed multi-objective trajectory optimization method.This paper presents a multi-objective optimization method for the spraying trajectory of a robot.In the proposed method,the optimized spraying trajectory is generated with the spraying process as the constraint and time,energy consumption,and impact during the spraying operation of the robot as the optimization objectives. 展开更多
关键词 Rigid-flexible coupling spray-painting robot Painting process Multi-objective optimization Trajectory planning NSGA-II
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Coupled Dissolution-Precipitation Mineralized Process in Bailongshan Li Deposit,West Kunlun(NW China),Evidenced by the Mineralogy of Cassiterite,Columbite-Group Minerals and Elbaite
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作者 Tao Hong ZhangZhang +2 位作者 Zeli Jiang Mingxi Hu Pengli Jiao 《Journal of Earth Science》 2025年第3期1033-1050,共18页
Coupled dissolution-precipitation is one of the critical processes influencing the mineralogical and geochemical evolution of pegmatites.This mechanism involves the simultaneous dissolution of primary mineral phases a... Coupled dissolution-precipitation is one of the critical processes influencing the mineralogical and geochemical evolution of pegmatites.This mechanism involves the simultaneous dissolution of primary mineral phases and the precipitation of secondary phases,driven by changes in the chemical environment,often mediated by hydrothermal fluids.The Bailongshan Li deposit,located in the West Kunlun region of northwest China,is a significant geological formation known for its rich lithium content and associated rare metals such as tantalum,niobium,and tin.This study investigates the coupled dissolution-precipitation processes that have played a crucial role in the mineralization of this deposit,focusing on key minerals,including cassiterite(Cst),columbite-group minerals(CGM),and elbaite(Elb).Using a combination of petrographic analysis,back-scattered electron(BSE)imaging,cathodoluminescence(CL)imaging,and micro X-ray fluorescence(XRF)mapping,we examined the textural and chemical characteristics of these minerals.Our findings reveal intricate patchy zoning patterns and element distributions(indicated by the Nb,Ta,W,Mn,Fe,Hf,Ti for CGM;Hf,Ti Rb,W,Nb,Ta for Cst;Ti,Zn,Fe,W,Hf,Mn,K for Elb)that indicate multiple stages of mineral alteration driven by fluid-mediated processes.The coupled dissolution-precipitation mechanisms observed in the Bailongshan deposit have resulted in significant redistribution and enrichment of economically valuable elements.The study highlights the importance of hydrothermal fluids in altering primary mineral phases and precipitating secondary phases with distinct compositions.These processes not only modified the mineralogical makeup of the pegmatite but also enhanced its economic potential by concentrating rare metals.Signatures of coupled dissolutionprecipitation processes can serve as an essential tool for mineral exploration,guiding the search for high-grade zones within similar pegmatitic formations. 展开更多
关键词 coupled dissolution-precipitation mineralized process West Kunlun MINERALOGY pegmatite Li deposit ore deposits
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STAP with adaptive calibration of array mutual coupling and gain/phase errors
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作者 Quanyang BI Dan LI Jianqiu ZHANG 《Chinese Journal of Aeronautics》 2025年第7期545-556,共12页
To address the significant degradation of Space-Time Adaptive Processing(STAP)performance when the array elements have mutual coupling and gain/phase errors,a STAP algorithm with adaptive calibration for the above two... To address the significant degradation of Space-Time Adaptive Processing(STAP)performance when the array elements have mutual coupling and gain/phase errors,a STAP algorithm with adaptive calibration for the above two array errors is proposed in this article.First,based on a defined error matrix that simultaneously considers both array mutual coupling and gain/phase errors,a STAP signal model including these errors is given.Then,utilizing the defined signal model,it is demonstrated that the estimation of the defined error matrix can be formulized as a standard convex optimization problem with the low-rank structure of the clutter covariance matrix and the subspace projection theory.Once the defined error matrix is estimated by solving the convex optimization problem,it is illustrated that a STAP method with adaptive calibration of the mutual coupling and gain/phase errors is coined.Analyses also show that the proposed adaptive calibration algorithm only needs one training sample to construct the adaptive weight vector.Therefore,it can achieve a good detection performance even with severe non-homogeneous clutter environments.Finally,the simulation experiments verify the effectiveness of the proposed algorithm and the correctness of the analytical results. 展开更多
关键词 Gain/phase error Mutual coupling Subspace projection Space-time adaptive processing Adaptive calibration
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AN ADAPTIVE EFG-FE COUPLING METHOD FOR THE NUMERICAL SIMULATION OF EXTRUSION PROCESSES
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作者 L.C. Liu X.H. Doug C.X. Li 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2008年第5期380-388,共9页
An adaptive EFG-FE coupling method is proposed and developed for the numerical simulation of lateral extrusion and forward-backward extrusion. Initially, the simulation has been implemented by using a conventional FE ... An adaptive EFG-FE coupling method is proposed and developed for the numerical simulation of lateral extrusion and forward-backward extrusion. Initially, the simulation has been implemented by using a conventional FE model. During the deforming process, mesh quality is checked at every incremental step. Distorted elements are automatically converted to EFG nodes, whereas, the less distorted elements are reserved. A new algorithm to generate EFG nodes and interface elements is presented. This method is capable of dealing with large deformation and has higher computational efficiency than using an EFG method wholly. Numerical results demonstrate that the adaptive EFG-FE coupling method has reasonable accuracy and is effective for local bulk metal forming such as extrusion processes. 展开更多
关键词 Meshless method coupling method Numerical simulation Extrusion process
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Formation Mechanism in Alloy Steel Rolling Process Using Thermo-mechanical Coupling Method
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作者 杨理诚 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2012年第3期422-426,共5页
Based on the theory of elastic-plastic finite element method, the high-speed hot continuous rolling process of a billet is simulated and analyzed in vertical and horizontal passes. The billet is dragged into the passe... Based on the theory of elastic-plastic finite element method, the high-speed hot continuous rolling process of a billet is simulated and analyzed in vertical and horizontal passes. The billet is dragged into the passes by contact friction force between the billet and rollers. The rollers and billet are represented by respectively rigid and deformable bodies, and three-dimensional models are developed for the billet and rollers. The distribution of deformation field, effective strain, rolling force and temperature field are accurately calculated for the whole rolling process (including unstable and stable stages). In addition, the rolling pressure on the width symmetry center is compared with that in the in-situ experimental measurements. It is revealed that various heat exchange phenomena among the billet, rollers and surroundings can result in unbalanced temperature distribution on the cross section. Rolling force and strain can change significantly when the billet is moved towards or away from the roller gap, and keep almost invariable in the stable stage. It is expected that the simulation results would be useful for practical manufacture and provide the theoretical foundation for improvement of process planning and optimization of process parameters. 展开更多
关键词 thermo-mechanical coupling temperature field deformation mechanism hot rolling process
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Graphene-Metal Hybrid Metasurface for Broadband Terahertz Logic Encoder Induced by Near-Field Coupling
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作者 Yufan Zhang Longhui Zhang +6 位作者 Mingzhu Jiang Chenyue Xi Fangrong Hu Yatao Zhou Shangjun Lin Xinlong Xu Zengxiu Zhao 《Chinese Physics Letters》 2025年第10期101-116,共16页
High-performance terahertz(THz)logic gate devices are crucial components for signal processing and modulation,playing a significant role in the application of THz communication and imaging.Here,we propose a THz broadb... High-performance terahertz(THz)logic gate devices are crucial components for signal processing and modulation,playing a significant role in the application of THz communication and imaging.Here,we propose a THz broadband NOR logic encoder based on a graphene-metal hybrid metasurface.The unit structure consists of two symmetrical dual-gap metal split-ring resonators(DSRRs)arranged in a staggered configuration,with graphene strips embedded in their gaps.The NOR logic gate metadevice is controlled by the bias voltages independently applied to the two electrodes.Experiments show that when the bias voltages are applied to both electrodes,the metadevice achieves the NOR logic gate within a 0.52 THz bandwidth,with an average modulation depth above 80%.The experimental results match well with theoretical simulations.Additionally,the strong near-field coupling induced by the staggered DSRRs causes redshift at both LC resonance and dipole resonance.This phenomenon was demonstrated by coupled mode theory.Besides,we analyze the surface current distribution at resonances and propose four equivalent circuit models to elucidate the physical mechanisms of modulation under distinct loaded voltage conditions.The results not only advance modulation and logic gate designs for THz communication but also demonstrate significant potential applications in 6G networks,THz imaging,and radar systems. 展开更多
关键词 signal processing Broadband terahertz logic encoder Near field coupling thz broadband logic encoder Graphene metal hybrid metasurface bias vo Modulation Terahertz logic gate
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Effects of Tensor Couplings on Nucleonic Direct URCA Processes in Neutron Star Matter
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作者 许妍 黄修林 +2 位作者 刘承志 特木尔巴根 刘广洲 《Chinese Physics Letters》 SCIE CAS CSCD 2016年第9期132-135,共4页
The relativistic neutrino emissivity of the nucleonic direct URCA processes in neutron star matter is investigated within the relativistic Hartree-Fock approximation. We particularly study the influences of the tensor... The relativistic neutrino emissivity of the nucleonic direct URCA processes in neutron star matter is investigated within the relativistic Hartree-Fock approximation. We particularly study the influences of the tensor couplings of vector mesons ω and ρ on the nucleonic direct URCA processes. It is found that the inclusion of the tensor couplings of vector mesons w and p can slightly increase the maximum mass of neutron stars. In addition, the results indicate that the tensor couplings of vector mesons ω and ρ lead to obvious enhancement of the total neutrino emissivity for the nucleonic direct URCA processes, which must accelerate the cooling rate of the non- superfluid neutron star matter. However, when considering only the tensor coupling of vector meson ρ, the neutrino emissivity for the nucleonic direct URCA processes slightly declines at low densities and significantly increases at high densities. That is, the tensor coupling of vector meson ρ leads to the slow cooling rate of a low-mass neutron star and rapid cooling rate of a massive neutron star. 展开更多
关键词 of is it for Effects of Tensor couplings on Nucleonic Direct URCA processes in Neutron Star Matter in on
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Numerical simulation of thermoehydraulic coupling processes in fractured karst geothermal reservoirs 被引量:1
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作者 Jun Yaoa Xu Zhang +3 位作者 Zhaoqin Huang Liang Gong Wendong Yang Yang Li 《Natural Gas Industry B》 2022年第6期511-520,共10页
Fractured karst geothermal reservoir is a kind of typical geothermal reservoirs with the advantages of abundant storage water and easy reinjection of tail water during the period of geothermal utilization.Such geother... Fractured karst geothermal reservoir is a kind of typical geothermal reservoirs with the advantages of abundant storage water and easy reinjection of tail water during the period of geothermal utilization.Such geothermal system is also one of the geothermal reservoirs with the greatest potential for the development and utilization of geothermal energy in China.However,its geological structures are diverse(e.g.pore,fracture and vug),exhibiting complex characteristics of multiple scales,strong heterogeneity and various flow regimes.Therefore,the fluid-heat transfer processes and geothermal production performance of fractured karst geothermal reservoirs are not clarified.In this paper,a numerical model considering thermoehydraulic coupling processes based on the discrete fractureevug network approach is put forward,according to the characteristics of fracturedevuggy geothermal reservoirs.In addition,the accuracy of the numerical model is verified.The results obtained from this research are as follows.First,the numerical model considering the thermoehydraulic coupling process is put forward,in which the Darcy's law is used to describe the flow zone of porous medium,the NaviereStokes equation is used to illustrate the free flow zone of vugs,and the BeaverseJosepheSaffman boundary condition is used to couple the fluid flow between these two zones.Second,the connectivity of fracture network is the key parameter to control and evaluate the flow and heat transfer effects in fractured vuggy geothermal reservoirs.The existence of vugs plays an important role in the fluid flow and heat transfer in geothermal reservoirs.Third,the thermoehydraulic coupling model based on the discrete fractureevug network can effectively describe the fluid flow and heat transfer processes in fractured vuggy geothermal reservoirs.The connectivity of fracture networks controls the thermoehydraulic coupling processes in fractured vuggy geothermal reservoirs.Fourth,the existence of vugs seriously impacts the thermoehydraulic coupling processes in geothermal reservoirs.For instance,on the one hand,it increases the number of high-speed flow channels spanning across the system and even makes the system get connected.On the other hand,it increases the speed of local flow channels inside the system.In conclusion,this proposed method is of great significance for studying the development characteristics and optimizing their geothermal production performance of fractured vuggy geothermal reservoirs. 展开更多
关键词 Geothermal energy Fractured karst geothermal reservoir Discrete fractureevug network model Numerical simulation Thermoehydraulic coupling process CONNECTIVITY FRACTURE Vug
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Dynamic modeling and analysis on rigid-flexible coupling between vertical chatter and transverse bending vibration in process of cold rolling
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作者 Xiao-yong Wang Zhi-ying Gao +1 位作者 Yan-li Xin Qing-dong Zhang 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2024年第11期2740-2754,共15页
Considering the dynamic variation of roll gap and the transverse distribution of dynamic rolling force along the work roll width direction, the movement and deformation of rolls system, influenced by the coupling of v... Considering the dynamic variation of roll gap and the transverse distribution of dynamic rolling force along the work roll width direction, the movement and deformation of rolls system, influenced by the coupling of vertical chatter and transverse bending vibration, may cause instability and also bring product defect of thickness difference. Therefore, a rigid-flexible coupling vibration model of the rolls system was presented. The influence of dynamic characteristics on the rolling process stability and strip thickness distribution was investigated. Firstly, assuming the symmetry of upper and lower structures of six-high rolling mill, a transverse bending vibration model of three-beam system under simply supported boundary conditions was established, and a semi-analytical solution method was proposed to deal with this model. Then, considering both variation and change rate of the roll gap, a roll vertical chatter model with structure and process coupled was constructed, and the critical rolling speed for self-excited instability was determined by Routh stability criterion. Furthermore, a rigid-flexible coupling vibration model of the rolls system was built by connecting the vertical chatter model and transverse bending vibration model through the distribution of dynamic rolling force, and the dynamic characteristics of rolls system were analyzed. Finally, the strip exit thickness distributions under the stable and unstable rolling process were compared, and the product shape and thickness distribution characteristics were quantitatively evaluated by the crown and maximum longitudinal thickness difference. 展开更多
关键词 Transverse bending vibration Vertical chatter Rigid-flexible coupling vibration Strip thickness distribution Rolling process stability
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Modeling and Simulation for CODAD Propulsion Plant with Fluid Coupling during Engaging and Disengaging Process
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作者 Yutao Chen Fanming Zeng Ying Wu Guojun Chen 《通讯和计算机(中英文版)》 2005年第11期72-76,81,共6页
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Decoupling multimode vibrational relaxations in multi-component gas mixtures: Analysis of sound relaxational absorption spectra 被引量:10
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作者 张克声 王殊 +2 位作者 朱明 丁毅 胡轶 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第1期328-337,共10页
Decoupling the complicated vibrational-vibrational (V-V) coupling of a multimode vibrational relaxation remains a challenge for analyzing the sound relaxational absorption in multi-component gas mixtures. In our pre... Decoupling the complicated vibrational-vibrational (V-V) coupling of a multimode vibrational relaxation remains a challenge for analyzing the sound relaxational absorption in multi-component gas mixtures. In our previous work [Acta Phys. Sin. 61 174301 (2012)], an analytical model to predict the sound absorption from vibrational relaxation in a gas medium is proposed. In this paper, we develop the model to decouple the V-V coupled energy to each vibrationaltranslational deexcitation path, and analyze how the multimode relaxations form the peaks of sound absorption spectra in gas mixtures. We prove that a multimode relaxation is the sum of its decoupled single-relaxation processes, and only the decoupled process with a significant isochoric-molar-heat can be observed as an absorption peak. The decoupling model clarifies the essential processes behind the peaks in spectra arising from the multimode relaxations in multi-component gas mixtures. The simulation validates the proposed decoupling model. 展开更多
关键词 vibrational relaxation sound absorption vibrational-vibrational coupling decoupled singlerelaxation process
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Coupling catalytic hydrolysis and oxidation for CS_2 removal 被引量:5
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作者 WANG Li WU Diyong WANG Shudong YUAN Quan 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2008年第4期436-440,共5页
CS2 removal was obtained by coupling catalytic hyidation on bi-functional catalyst. On the hydrolysis active sites, CS2 is hydrolyzed to HES, while on the oxidation active sites, HES is oxidized to elemental S or sulf... CS2 removal was obtained by coupling catalytic hyidation on bi-functional catalyst. On the hydrolysis active sites, CS2 is hydrolyzed to HES, while on the oxidation active sites, HES is oxidized to elemental S or sulfuric acid deposited on the porous support. The above process can be expressed as follows: CS2 H2O→ COS H2O→ H2S O2→ S/SO4^2-. H2S oxidation eliminates its prohibition on C52 hydrolysis so that the rate of coupling removal CS2 is 5 times higher than that of CS2 hydrolysis. The same active energy of hydrolysis and coupling reaction also indicates that HES oxidation does not change the reaction mechanism of CS2 hydrolysis. Temperature has obvious effect on the process while the mole ratio of O2 concentration to CS2 concentration (O/S) does not, especially in excess of 2.5. The formation of sulfuric acid on the catalyst surface poisons hydrolysis active sites and causes the decrease of left OH^-1 concentration on the catalysts surface. Lower temperature is suggested for this bi-functional catalyst owing to the low yield ratio of S/SO4^2-. 展开更多
关键词 carbon disulfide coupling process low-temperature removal
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Numerical manifold method modeling of coupled processes in fractured geological media at multiple scales 被引量:5
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作者 Mengsu Hu Jonny Rutqvist 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2020年第4期667-681,共15页
The greatest challenges of rigorously modeling coupled hydro-mechanical(HM)processes in fractured geological media at different scales are associated with computational geometry.These challenges include dynamic sheari... The greatest challenges of rigorously modeling coupled hydro-mechanical(HM)processes in fractured geological media at different scales are associated with computational geometry.These challenges include dynamic shearing and opening of intersecting fractures at discrete fracture scales as a result of coupled processes,and contact alteration along rough fracture surfaces that triggers structural and physical changes of fractures at micro-asperity scale.In this paper,these challenges are tackled by developing a comprehensive modeling approach for coupled processes in fractured geological media based on numerical manifold method(NMM)at multiple scales.Based on their distinct geometric features,fractures are categorized into three different scales:dominant fracture,discrete fracture,and discontinuum asperity scales.Here the scale is relative,that of the fracture relative to that of the research interest or domain.Different geometric representations of fractures at different scales are used,and different governing equations and constitutive relationships are applied.For dominant fractures,a finite thickness zone model is developed to treat a fracture as a porous nonlinear domain.Nonlinear fracture mechanical behavior is accurately modeled with an implicit approach based on strain energy.For discrete fractures,a zero-dimensional model was developed for analyzing fluid flow and mechanics in fractures that are geometrically treated as boundaries of the rock matrix.With the zero-dimensional model,these fractures can be modeled with arbitrary orientations and intersections.They can be fluid conduits or seals,and can be open,bonded or sliding.For the discontinuum asperity scale,the geometry of rough fracture surfaces is explicitly represented and contacts involving dynamic alteration of contacts among asperities are rigorously calculated.Using this approach,fracture alteration caused by deformation,re-arrangement and sliding of rough surfaces can be captured.Our comprehensive model is able to handle the computational challenges with accurate representation of intersections and shearing of fractures at the discrete fracture scale and rigorously treats contacts along rough fracture surfaces at the discontinuum asperity scale.With future development of three-dimensional(3D)geometric representation of discrete fracture networks in porous rock and contacts among multi-body systems,this model is promising as a basis of 3D fully coupled analysis of fractures at multiple scales,for advancing understanding and optimizing energy recovery and storage in fractured geological media. 展开更多
关键词 Dominant fractures Discrete fractures Discontinuum asperity scale coupled processes Numerical manifold method(NMM)
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Coupling of sulfur and boron in carbonaceous material to strengthen persulfate activation for antibiotic degradation:Active sites,mechanism,and toxicity assessment 被引量:1
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作者 Feng Ye Wei Sun +3 位作者 Kangfeng Pang Wenchao Yang Mengjie Pu Qichun Zhang 《Chinese Chemical Letters》 SCIE CAS CSCD 2023年第5期292-301,共10页
Carbon-mediated persulfate advanced oxidation processes(PS-AOPs)are appealing in contaminant remediation.For the first time,S,B-co-doped carbon-based persulfate activators were synthesized through direct carbonization... Carbon-mediated persulfate advanced oxidation processes(PS-AOPs)are appealing in contaminant remediation.For the first time,S,B-co-doped carbon-based persulfate activators were synthesized through direct carbonization of sodium lignosulfonate and boric acid.By degrading sulfamethoxazole(SMX),CSB-750 obtained 98.7%removal and 81.4%mineralization within 30 min.In comparison with solo S or B doping,S and B co-doped carbon showed the coupling effect for enhanced catalysis.The rate constant(kobs)of 0.1679 min^(-1)was 22.38-and 279.83-fold higher than those of CS-750(0.0075 min^(-1))and CB-750(0.0006 min^(-1)),respectively.The degradation was efficient at strong acidic and weak basic conditions(pH 3-9).Substantial inhibition effect was presented at strong basic condition(pH 10.95)and in presence of CO_(3)^(2-).The CO_(3)^(2-)-caused inhibition was the combined result of the cooperation of pH and quenching O_(2)^(·-).Thiophene sulfur,BC_(3),BC_(2)O,and structural defects were identified as the active sites for PS activation.Radical and nonradical pathways were both involved in the CSB-750/PS/SMX system,where^(1)O_(2)dominated the degradation,SO_(4)^(·-),·OH and direct electron transfer played the subordinate role,and O_(2)^(·-)served as a precursor for the formation of partial^(1)O_(2).The toxicity of degradation system,the effect of real water matrix,and the reusability of carbocatalysts were comprehensively analyzed.Nine possible degradation pathways were proposed.This work focuses on the catalytic performance improvement through the coupling effect of S,B co-doping,and develops an advanced heteroatom doping system to fabricate carbonaceous persulfate activators. 展开更多
关键词 S B-co-doped carbons Advanced oxidation process Nonradical pathway coupling effect
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NUMERICAL MODELING FOR COUPLED THERMO-HYDRO-MECHANICAL AND CHEMICAL PROCESSES (THMC) OF GEOLOGICAL MEDIA——INTERNATIONAL AND CHINESE EXPERIENCES 被引量:18
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作者 Jing Lanru,Feng Xiating (Institute of Rock and Soil Mechanics,The Chinese Academy of Sciences, Wuhan 430071 China) 《岩石力学与工程学报》 EI CAS CSCD 北大核心 2003年第10期1704-1715,共12页
The coupled thermo-hydro-mechanical and chemical (THMC) processes of stress/deformation,fluid flow,temperature and geochemical reactions of the geological media,namely fractured rocks and soils,play an important role ... The coupled thermo-hydro-mechanical and chemical (THMC) processes of stress/deformation,fluid flow,temperature and geochemical reactions of the geological media,namely fractured rocks and soils,play an important role in design,construction,operation and environmental impact assessments of rock and soil engineering works such as underground nuclear waste repositories,oil/gas production and storage,geothermal energy extraction,landslides and slope stability,hydropower and water conservancy complexes,etc. This paper presents an overview of the international and Chinese experiences in numerical modeling of the coupled THMC processes for both the state-of-the-knowledge,remaining challenges and possible future prospects. 展开更多
关键词 地质力学 化学耦合反应 数值模拟 国外
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