Dispersion of KF on AlPO4-5 molecular sieve created basic sites and caused 1654 cm- band of bidentate carbonate in CO2 adsorption.After pre-treated above 823K. 5%KF/AlPO4-5exhibited basic catalytic activity in the iso...Dispersion of KF on AlPO4-5 molecular sieve created basic sites and caused 1654 cm- band of bidentate carbonate in CO2 adsorption.After pre-treated above 823K. 5%KF/AlPO4-5exhibited basic catalytic activity in the isomerization of butenes at 273K. and the activity increasedwith the pre-treatment temperature up to 923K.展开更多
Berlinite （α-AlPO4） is a new piezoelectric crystal material with good property. Its piezoelectric constant and mechanic-electric coupling efficiency are all higher than those ofquartz. Now berlinite of high quality...Berlinite （α-AlPO4） is a new piezoelectric crystal material with good property. Its piezoelectric constant and mechanic-electric coupling efficiency are all higher than those ofquartz. Now berlinite of high quality has been grown successfully in labs.展开更多
The quality of regional ocean reanalysis data for ＂the joining area of Asia and the Indian-Pacific Ocean （AIPO）＂ has been assessed from the perspective of ENSO-related ocean signals. The results derived from the A...The quality of regional ocean reanalysis data for ＂the joining area of Asia and the Indian-Pacific Ocean （AIPO）＂ has been assessed from the perspective of ENSO-related ocean signals. The results derived from the AIPO reanalysis, including SST, sea surface height （SSH）, and subsurface ocean temperature and currents, are compared with those of Hadley Center Sea Ice and Sea Surface Temperature （HadlSST） data set and Simple Ocean Data Assimilation （SODA） reanalysis data. Both the spatial pattern and the characteristics of evolution of the ENSO-related ocean temperature anomalies are well reproduced by the AIPO reanalysis data. The physical processes proposed to explain the life cycle of ENSO, including the delayed oscillator mechanism, recharge-discharge mechanism, and the zonal advection feedback, are reasonably represented in this dataset. However, the westward Rossby wave signal in 1992 is not obvious in the AIPO data, and the magnitude of the heat content anomalies is different from that of the SODA data. The reason for the discrepancies may lie in the different mod- els and methods for data assimilation and differences in wind stress forcing. The results demonstrate the high reliability of the AIPO reanalysis data in describing ENSO signals, implying its potential application value in ENSO- related studies.展开更多
Phase pure AlP O4 with the AlP O4-18(AEI) structure was synthesised using N,N- diisopropylethylamine as a template. Using a combination of X-ray powder diffraction and computational methods, the location and orientati...Phase pure AlP O4 with the AlP O4-18(AEI) structure was synthesised using N,N- diisopropylethylamine as a template. Using a combination of X-ray powder diffraction and computational methods, the location and orientation of the N,N-diisopropylethylamine molecules inside the cages of the AEI structure were determined. Thermogravimetric analysis confirmed that the number of template molecules per unit cell was consistent with the diffraction study. We unequivocally show that only one template molecule is present in each cage of the crystalline AEI material. Our work demonstrates that a combined approach enables accurate structure resolution of such complex materials.展开更多
文摘Dispersion of KF on AlPO4-5 molecular sieve created basic sites and caused 1654 cm- band of bidentate carbonate in CO2 adsorption.After pre-treated above 823K. 5%KF/AlPO4-5exhibited basic catalytic activity in the isomerization of butenes at 273K. and the activity increasedwith the pre-treatment temperature up to 923K.
文摘Berlinite （α-AlPO4） is a new piezoelectric crystal material with good property. Its piezoelectric constant and mechanic-electric coupling efficiency are all higher than those ofquartz. Now berlinite of high quality has been grown successfully in labs.
基金supported by the Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No. KZCX2-YW-Q11-04)the Public Science and Technology Research Funds Projects of Ocean (Grant No. 201105019-3)the National Basic Research Program of China (Grant No. 2010CB951904)
文摘The quality of regional ocean reanalysis data for ＂the joining area of Asia and the Indian-Pacific Ocean （AIPO）＂ has been assessed from the perspective of ENSO-related ocean signals. The results derived from the AIPO reanalysis, including SST, sea surface height （SSH）, and subsurface ocean temperature and currents, are compared with those of Hadley Center Sea Ice and Sea Surface Temperature （HadlSST） data set and Simple Ocean Data Assimilation （SODA） reanalysis data. Both the spatial pattern and the characteristics of evolution of the ENSO-related ocean temperature anomalies are well reproduced by the AIPO reanalysis data. The physical processes proposed to explain the life cycle of ENSO, including the delayed oscillator mechanism, recharge-discharge mechanism, and the zonal advection feedback, are reasonably represented in this dataset. However, the westward Rossby wave signal in 1992 is not obvious in the AIPO data, and the magnitude of the heat content anomalies is different from that of the SODA data. The reason for the discrepancies may lie in the different mod- els and methods for data assimilation and differences in wind stress forcing. The results demonstrate the high reliability of the AIPO reanalysis data in describing ENSO signals, implying its potential application value in ENSO- related studies.
文摘Phase pure AlP O4 with the AlP O4-18(AEI) structure was synthesised using N,N- diisopropylethylamine as a template. Using a combination of X-ray powder diffraction and computational methods, the location and orientation of the N,N-diisopropylethylamine molecules inside the cages of the AEI structure were determined. Thermogravimetric analysis confirmed that the number of template molecules per unit cell was consistent with the diffraction study. We unequivocally show that only one template molecule is present in each cage of the crystalline AEI material. Our work demonstrates that a combined approach enables accurate structure resolution of such complex materials.
