The reverse ATRP of MMA using AIBN/FeCl3/ isophthalic acid as the initiating system was successfully performed. The new initiating system can be used to synthesize PMMA with high molecular weight and narrow polydis-pe...The reverse ATRP of MMA using AIBN/FeCl3/ isophthalic acid as the initiating system was successfully performed. The new initiating system can be used to synthesize PMMA with high molecular weight and narrow polydis-persity index. The polymerization shows ’living’/controlled characteristics. Compared with other initiating system used in reverse ATRP, the easy availability and non-toxicity of isophthalic acid make it very attractive.展开更多
Recently, in researches on the effect of the magnetic field on radical polymerization of vinyl monomers, it was found that the molecular weight and stereoregularity of polystyrene were increased and the molecular weig...Recently, in researches on the effect of the magnetic field on radical polymerization of vinyl monomers, it was found that the molecular weight and stereoregularity of polystyrene were increased and the molecular weight distribution of it was narrowed with the increment of magnetic field strength when the styrene bulk so-展开更多
文摘The reverse ATRP of MMA using AIBN/FeCl3/ isophthalic acid as the initiating system was successfully performed. The new initiating system can be used to synthesize PMMA with high molecular weight and narrow polydis-persity index. The polymerization shows ’living’/controlled characteristics. Compared with other initiating system used in reverse ATRP, the easy availability and non-toxicity of isophthalic acid make it very attractive.
文摘Recently, in researches on the effect of the magnetic field on radical polymerization of vinyl monomers, it was found that the molecular weight and stereoregularity of polystyrene were increased and the molecular weight distribution of it was narrowed with the increment of magnetic field strength when the styrene bulk so-
