An AI2O3-TiB2 nanocomposite was success- fully synthesized by the high energy ball milling of A1, B2O3 and TiO2. The structures of the powdered particles formed at different milling times were evaluated by X-ray diffr...An AI2O3-TiB2 nanocomposite was success- fully synthesized by the high energy ball milling of A1, B2O3 and TiO2. The structures of the powdered particles formed at different milling times were evaluated by X-ray diffraction （XRD）, scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. Thermo- dynamic calculations showed that the composite formed in two steps via highly exothermic mechanically induced self-sustaining reactions （MSRs）. The composite started to form at milling times of 9-10 h but the reaction was not complete. The remaining starting materials were consumed by increasing the milling time to 15 h. The XRD patterns of the annealed powders showed that aluminum borate is one of the intermediate products and that it is consumed at higher temperatures. Heat treatment of the 6-h milled sample at l l00℃ led to a complete formation of the composite. Increasing the milling time to 15 h led to a refining of the crystallite sizes. A nanocomposite powder with a mean crystallite size of 35-40 nm was obtained after milling for 15 h.展开更多
Ultra high molecular weight polyethylene （UHMWPE） is widely used for articulating surfaces in total hip and knee replacements. In the present work, UHMWPE based polymer composites were synthesized by synergistic rei...Ultra high molecular weight polyethylene （UHMWPE） is widely used for articulating surfaces in total hip and knee replacements. In the present work, UHMWPE based polymer composites were synthesized by synergistic reinforcing of bioactive hydroxyapatite （HA）, bioinert aluminum oxide （Al2O3）, and carbon nanotubes （CNTs） using compression molding. Phase and microstructural analysis suggests retention of UHMWPE and reinforcing phases in the compression molded composites. Microstructural analysis elicited variation in densification due to the size effect of the reinforcing particles. The hybrid composites exhibited hardness, elastic modulus and toughness comparable to that of UHMWPE. The interfacial effect of reinforcement phases has evinced the effectiveness of Al2O3 over HA and CNT reinforcements, depicting synergistic enhancement in hardness and elastic modulus. Weak interfacial bonding of polymer matrix with HA and CNT requires utilization of coupling agents to achieve enhanced mechanical properties without deteriorating cytocompatible properties.展开更多
以镍基负载γ-Al2O3为催化剂,对环戊二烯(CPD)选择加氢制备环戊烯(CPE)的工艺过程进行了研究.以双环戊二烯(DCPD)为初始原料,经过精馏塔高温解聚后得到加氢原料环戊二烯,在装填了Ni/γ-Al2O3催化剂的常压固定床反应器中与氢气发生选择...以镍基负载γ-Al2O3为催化剂,对环戊二烯(CPD)选择加氢制备环戊烯(CPE)的工艺过程进行了研究.以双环戊二烯(DCPD)为初始原料,经过精馏塔高温解聚后得到加氢原料环戊二烯,在装填了Ni/γ-Al2O3催化剂的常压固定床反应器中与氢气发生选择加氢反应.实验结果表明:适宜的催化剂制备条件为:Ni含量20%,浸渍时间12 h;适宜的工艺操作条件为:预还原温度500℃,氢烃比1.0,液空速6.0 h 1.在此条件下,CPD的转化率达到87.7%,CPE的选择性为92.8%.展开更多
文摘An AI2O3-TiB2 nanocomposite was success- fully synthesized by the high energy ball milling of A1, B2O3 and TiO2. The structures of the powdered particles formed at different milling times were evaluated by X-ray diffraction （XRD）, scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. Thermo- dynamic calculations showed that the composite formed in two steps via highly exothermic mechanically induced self-sustaining reactions （MSRs）. The composite started to form at milling times of 9-10 h but the reaction was not complete. The remaining starting materials were consumed by increasing the milling time to 15 h. The XRD patterns of the annealed powders showed that aluminum borate is one of the intermediate products and that it is consumed at higher temperatures. Heat treatment of the 6-h milled sample at l l00℃ led to a complete formation of the composite. Increasing the milling time to 15 h led to a refining of the crystallite sizes. A nanocomposite powder with a mean crystallite size of 35-40 nm was obtained after milling for 15 h.
基金funded by the Department of Biotechnology (DBT),Govt.of India
文摘Ultra high molecular weight polyethylene （UHMWPE） is widely used for articulating surfaces in total hip and knee replacements. In the present work, UHMWPE based polymer composites were synthesized by synergistic reinforcing of bioactive hydroxyapatite （HA）, bioinert aluminum oxide （Al2O3）, and carbon nanotubes （CNTs） using compression molding. Phase and microstructural analysis suggests retention of UHMWPE and reinforcing phases in the compression molded composites. Microstructural analysis elicited variation in densification due to the size effect of the reinforcing particles. The hybrid composites exhibited hardness, elastic modulus and toughness comparable to that of UHMWPE. The interfacial effect of reinforcement phases has evinced the effectiveness of Al2O3 over HA and CNT reinforcements, depicting synergistic enhancement in hardness and elastic modulus. Weak interfacial bonding of polymer matrix with HA and CNT requires utilization of coupling agents to achieve enhanced mechanical properties without deteriorating cytocompatible properties.
文摘以镍基负载γ-Al2O3为催化剂,对环戊二烯(CPD)选择加氢制备环戊烯(CPE)的工艺过程进行了研究.以双环戊二烯(DCPD)为初始原料,经过精馏塔高温解聚后得到加氢原料环戊二烯,在装填了Ni/γ-Al2O3催化剂的常压固定床反应器中与氢气发生选择加氢反应.实验结果表明:适宜的催化剂制备条件为:Ni含量20%,浸渍时间12 h;适宜的工艺操作条件为:预还原温度500℃,氢烃比1.0,液空速6.0 h 1.在此条件下,CPD的转化率达到87.7%,CPE的选择性为92.8%.
基金supported by the National Natural Science Foundation of China(50772107)National Key Basic Research Program of China(973)(2007CB210206)National High-Tech Research and Development Program of China(863)(2009AA05Z435)~~
