Fluorescent probes based on intramolecular charge transfer(ICT) have obvious advantages for accurate quantitative analysis.To obtain high-performance ratiometric probes requires distinct photophysical properties durin...Fluorescent probes based on intramolecular charge transfer(ICT) have obvious advantages for accurate quantitative analysis.To obtain high-performance ratiometric probes requires distinct photophysical properties during recognition reaction process,which is closely related to their ICT characteristics.1,8-Naphthalimide is known as a typical fluorophore with desirable ICT property when functionalized with an electron-donating moiety at the para-position of the naphthalene chromophore.Although the photophysical properties of para-substituted 1,8-naphthalimide have been well studied,its meta-substituted counterpart has not been fully evaluated since the meta-position is conventionally thought to be weakly conjugated.Herein,combined experimental and theoretical studies are performed which consistently indicate that stronger charge transfer(CT) is exhibited by the meta-amino substituted 1,8-naphthalimide(m-NH_(2)) compared to the para-amino substituted one(p-NH_(2)).The ratiometric response of fluorescence with significant changes in wavelength and intensity upon acetylation(m-NAc and p-NAc) can be attributed to the larger ICT and stronger-NH_(2) vibrations.This observation is further demonstrated by deuterium oxide experiments,viscosity experiments and quantum chemical calculations.The practical application of meta-amino-1,8-naphthalimide ICT-based probes is also confirmed.This research is expected to bring an in-depth understanding of π-conjugated systems with ICT characteristics,and facilitates the design of sensitive ICT fluorescent probes with meta-amino substitution.展开更多
Under the condition of frequent replacement of wind tunnel models,multiple types of wind tunnel models are fixed by a slender support sting with low stiffness damping.When excited by wind load,various models produce r...Under the condition of frequent replacement of wind tunnel models,multiple types of wind tunnel models are fixed by a slender support sting with low stiffness damping.When excited by wind load,various models produce random multi-dimensional vibration with different characteristics,which makes it impossible to obtain accurate and efficient aerodynamic data.Therefore,in order to ensure the reliable and efficient conduction of wind tunnel test,a wind-tunnel-modeladaptive vibration control method is proposed in this paper.First,the split type adaptive vibration suppression structure is designed.Second,the multi-dimensional vibration characteristic characterization method is derived and the vibration characteristic identification method of the system is designed.Then,a vibration state estimation model is established according to the identification results of vibration characteristics,and a multi-actuator cooperative control method based on vibration state estimation is constructed.Finally,a model-adaptive vibration control system is built,and vibration characteristics identification and hammer experiments are carried out for two types of typical models.The results show that the proposed model-adaptive vibration control method increases the equivalent damping ratio of pitch and yaw dimensions of the high-aspect-ratio class model by 8.19 times and 48.81 times,respectively.The equivalent damping ratio of pitch and yaw dimensions of the highslenderness-ratio class model is increased by 16.44 and 5.43 times,respectively.It provides a strong guarantee for the reliable and efficient development of multi-type wind tunnel test tasks.展开更多
Inspired that kangaroo can buffer the impact and absorb vibration from the ground and keep the whole-body stable,an integrated kangaroo bio-inspired vibration suppression(IKBVS)structure considering vibration isolatio...Inspired that kangaroo can buffer the impact and absorb vibration from the ground and keep the whole-body stable,an integrated kangaroo bio-inspired vibration suppression(IKBVS)structure considering vibration isolation-absorption simultaneously is proposed for low/wide band frequency vibration control.Based on skeleton mass,articulation friction,and the synergistic action among skeleton,articulation,and muscle/tendon,a vibration suppression model with more biological basic characteristics is derived.The validity of model and method is confirmed,and the static and dynamic analysis of the IKBVS system is carried out to investigate the vibration suppression performance.The quasi-zero stiffness region can be achieved with a smaller initial installation angle,medium rod length,smaller foot stiffness,and slightly lighter isolated mass in a wide displacement interval.The coupling mechanism of vibration isolation-absorption is revealed by parameter analysis.The results indicate that the IKBVS structure has favorite dynamic properties due to adjustable nonlinearity,namely,lower and adjustable resonance and anti-resonance frequency/peak and different levels of vibration suppression effect in high-frequency range are achieved readily.This research provides new insight into application of bio-inspired vibration suppression structures in various engineering systems for better vibration control.展开更多
High-pressure hydrides have emerged as promising superconducting materials,attracting considerable attention in recent years.In this work,by combining the stochastic self-consistent harmonic approximation with first-p...High-pressure hydrides have emerged as promising superconducting materials,attracting considerable attention in recent years.In this work,by combining the stochastic self-consistent harmonic approximation with first-principles calculations,we elucidate crucial corrections to the vibrational and superconducting properties arising from quantum and anharmonic ionic vibrations of SnH4 in P63/mmc phase at 150–240 GPa.Compared with the classical harmonic approximation,inclusion of these effects results in a pronounced softening(over 500 cm^(−1))of hydrogen-derived optical phonon modes,and increases the superconducting critical temperature(Tc)from 65 K to 79 K(μ^(*)=0.1;isotropic Migdal–Eliashberg theory),corresponding to a 22%enhancement.For μ^(*)=0.13,the predicted Tc is approximately 70 K.Analysis of the Eliashberg spectral function confirms that hydrogen vibrational modes constitute the dominant tuning mechanism.These results provide quantitative insights into quantum ionic effects in hydride superconductors.展开更多
A novel vibration isolation system designed for superior performance in low-frequency environments is proposed in this work.The isolator is based on a unique hexagonal arrangement of linear springs,allowing for an adj...A novel vibration isolation system designed for superior performance in low-frequency environments is proposed in this work.The isolator is based on a unique hexagonal arrangement of linear springs,allowing for an adjustable geometric configuration via the initial inclination angle.Based on the principle of Lagrangian mechanics,the equation of motion governing the structural dynamics is rigorously derived.The system is modeled as a strongly nonlinear single-degree-of-freedom dynamical system,loaded with a normalized payload and subject to harmonic base excitation.To analyze the steady-state response,the harmonic balance method is employed,providing accurate predictions of the payload's vibration amplitude and displacement transmissibility as functions of both the base excitation amplitude and frequency.The analysis reveals a direct relationship between the isolator's geometric and stiffness parameters and its load-bearing capacity,leading to the identification of three distinct operational regimes.Depending on the unloaded initial inclination angle,the equivalent stiffness ratio,and the payload design configuration,the system can exhibit one of three vibration isolation modes:(i)the quasizero stiffness(QZS)isolation mode,(ii)the zero linear stiffness with controllable nonlinear stiffness,and(iii)the full-band perfect zero stiffness.The vibration isolation performance of the proposed structure is thoroughly discussed for all three oscillation modes in terms of frequency response curves,displacement transmissibility,and time-domain responses.The key novel finding is that this structure can operate as a full-band,high-performance vibration isolator when the initial inclination angle is designed to be a right angle,enabling full isolation of the maximum possible payload.Moreover,the analytical results and numerical simulations demonstrate that the isolator's displacement transmissibility T with the unit dB tends to-∞as the air-damping coefficient approaches zero,enabling ideal vibration isolation across the entire excitation frequency range.These analytical insights are validated through comprehensive numerical simulations,which show excellent agreement with the theoretical predictions.展开更多
基金financially supported by National Key Research and Development Programs (Nos.2022YFD1700403 and 2023YFD1700303)National Natural Science Foundation of China (Nos.12274128 and 12250003)+2 种基金Shanghai Rising-Star Program (No.21QA1402600)the support of NYU-ECNU Center for Computational Chemistry at NYU Shanghaithe University of Bath and the Open Research Fund of the School of Chemistry and Chemical Engineering,Henan Normal University (No.2020ZD01) for support。
文摘Fluorescent probes based on intramolecular charge transfer(ICT) have obvious advantages for accurate quantitative analysis.To obtain high-performance ratiometric probes requires distinct photophysical properties during recognition reaction process,which is closely related to their ICT characteristics.1,8-Naphthalimide is known as a typical fluorophore with desirable ICT property when functionalized with an electron-donating moiety at the para-position of the naphthalene chromophore.Although the photophysical properties of para-substituted 1,8-naphthalimide have been well studied,its meta-substituted counterpart has not been fully evaluated since the meta-position is conventionally thought to be weakly conjugated.Herein,combined experimental and theoretical studies are performed which consistently indicate that stronger charge transfer(CT) is exhibited by the meta-amino substituted 1,8-naphthalimide(m-NH_(2)) compared to the para-amino substituted one(p-NH_(2)).The ratiometric response of fluorescence with significant changes in wavelength and intensity upon acetylation(m-NAc and p-NAc) can be attributed to the larger ICT and stronger-NH_(2) vibrations.This observation is further demonstrated by deuterium oxide experiments,viscosity experiments and quantum chemical calculations.The practical application of meta-amino-1,8-naphthalimide ICT-based probes is also confirmed.This research is expected to bring an in-depth understanding of π-conjugated systems with ICT characteristics,and facilitates the design of sensitive ICT fluorescent probes with meta-amino substitution.
基金supported in part by the National Natural Science Foundation of China(Nos.52475550,52305095)in part by the Key R&D Project of Liaoning Province,China(No.2023JH2/101800026)。
文摘Under the condition of frequent replacement of wind tunnel models,multiple types of wind tunnel models are fixed by a slender support sting with low stiffness damping.When excited by wind load,various models produce random multi-dimensional vibration with different characteristics,which makes it impossible to obtain accurate and efficient aerodynamic data.Therefore,in order to ensure the reliable and efficient conduction of wind tunnel test,a wind-tunnel-modeladaptive vibration control method is proposed in this paper.First,the split type adaptive vibration suppression structure is designed.Second,the multi-dimensional vibration characteristic characterization method is derived and the vibration characteristic identification method of the system is designed.Then,a vibration state estimation model is established according to the identification results of vibration characteristics,and a multi-actuator cooperative control method based on vibration state estimation is constructed.Finally,a model-adaptive vibration control system is built,and vibration characteristics identification and hammer experiments are carried out for two types of typical models.The results show that the proposed model-adaptive vibration control method increases the equivalent damping ratio of pitch and yaw dimensions of the high-aspect-ratio class model by 8.19 times and 48.81 times,respectively.The equivalent damping ratio of pitch and yaw dimensions of the highslenderness-ratio class model is increased by 16.44 and 5.43 times,respectively.It provides a strong guarantee for the reliable and efficient development of multi-type wind tunnel test tasks.
基金supported by the Natural Science Foundation of China(Grant No.52275091)Natural Science Foundation of Liaoning Province(Grant No.2022-MS-125)+1 种基金Shenyang Natural Science Foundation(Grant No.23-503-6-02)Fundamental Research Funds for the Central Universities(Grant No.N2303011).
文摘Inspired that kangaroo can buffer the impact and absorb vibration from the ground and keep the whole-body stable,an integrated kangaroo bio-inspired vibration suppression(IKBVS)structure considering vibration isolation-absorption simultaneously is proposed for low/wide band frequency vibration control.Based on skeleton mass,articulation friction,and the synergistic action among skeleton,articulation,and muscle/tendon,a vibration suppression model with more biological basic characteristics is derived.The validity of model and method is confirmed,and the static and dynamic analysis of the IKBVS system is carried out to investigate the vibration suppression performance.The quasi-zero stiffness region can be achieved with a smaller initial installation angle,medium rod length,smaller foot stiffness,and slightly lighter isolated mass in a wide displacement interval.The coupling mechanism of vibration isolation-absorption is revealed by parameter analysis.The results indicate that the IKBVS structure has favorite dynamic properties due to adjustable nonlinearity,namely,lower and adjustable resonance and anti-resonance frequency/peak and different levels of vibration suppression effect in high-frequency range are achieved readily.This research provides new insight into application of bio-inspired vibration suppression structures in various engineering systems for better vibration control.
基金supported by the Scientific Research Program Funded by Shaanxi Provincial Education Department (Grant No.24JP126)the National Natural Science Foundation of China (Grant No.62174136)the Natural Science Basic Research Program of Shaanxi Province (Grant No.2025JC-YBMS-063)。
文摘High-pressure hydrides have emerged as promising superconducting materials,attracting considerable attention in recent years.In this work,by combining the stochastic self-consistent harmonic approximation with first-principles calculations,we elucidate crucial corrections to the vibrational and superconducting properties arising from quantum and anharmonic ionic vibrations of SnH4 in P63/mmc phase at 150–240 GPa.Compared with the classical harmonic approximation,inclusion of these effects results in a pronounced softening(over 500 cm^(−1))of hydrogen-derived optical phonon modes,and increases the superconducting critical temperature(Tc)from 65 K to 79 K(μ^(*)=0.1;isotropic Migdal–Eliashberg theory),corresponding to a 22%enhancement.For μ^(*)=0.13,the predicted Tc is approximately 70 K.Analysis of the Eliashberg spectral function confirms that hydrogen vibrational modes constitute the dominant tuning mechanism.These results provide quantitative insights into quantum ionic effects in hydride superconductors.
基金Project supported by the National Key R&D Program of China(No.2023YFE0125900)。
文摘A novel vibration isolation system designed for superior performance in low-frequency environments is proposed in this work.The isolator is based on a unique hexagonal arrangement of linear springs,allowing for an adjustable geometric configuration via the initial inclination angle.Based on the principle of Lagrangian mechanics,the equation of motion governing the structural dynamics is rigorously derived.The system is modeled as a strongly nonlinear single-degree-of-freedom dynamical system,loaded with a normalized payload and subject to harmonic base excitation.To analyze the steady-state response,the harmonic balance method is employed,providing accurate predictions of the payload's vibration amplitude and displacement transmissibility as functions of both the base excitation amplitude and frequency.The analysis reveals a direct relationship between the isolator's geometric and stiffness parameters and its load-bearing capacity,leading to the identification of three distinct operational regimes.Depending on the unloaded initial inclination angle,the equivalent stiffness ratio,and the payload design configuration,the system can exhibit one of three vibration isolation modes:(i)the quasizero stiffness(QZS)isolation mode,(ii)the zero linear stiffness with controllable nonlinear stiffness,and(iii)the full-band perfect zero stiffness.The vibration isolation performance of the proposed structure is thoroughly discussed for all three oscillation modes in terms of frequency response curves,displacement transmissibility,and time-domain responses.The key novel finding is that this structure can operate as a full-band,high-performance vibration isolator when the initial inclination angle is designed to be a right angle,enabling full isolation of the maximum possible payload.Moreover,the analytical results and numerical simulations demonstrate that the isolator's displacement transmissibility T with the unit dB tends to-∞as the air-damping coefficient approaches zero,enabling ideal vibration isolation across the entire excitation frequency range.These analytical insights are validated through comprehensive numerical simulations,which show excellent agreement with the theoretical predictions.
