随着高比例新能源的接入,互联电力系统不同控制区间的电源结构差异日益增大,有些控制区新能源装机增加、常规机组减少导致调频需求增加但控制能力下降。传统联络线功率频率偏差控制(tie-line power and frequency bias control,TBC)模...随着高比例新能源的接入,互联电力系统不同控制区间的电源结构差异日益增大,有些控制区新能源装机增加、常规机组减少导致调频需求增加但控制能力下降。传统联络线功率频率偏差控制(tie-line power and frequency bias control,TBC)模式下的控制性能评价标准(control performance standard,CPS)标准,通过频率偏差系数来确定各控制区的考核阈值,却未考虑各控制区客观电源结构的影响,在高比例新能源电力系统中的不适应性日益凸显。首先分析了现有CPS标准的前提条件与内涵,揭示了CPS标准在高比例新能源电力系统中的不适应性,进而提出了控制区固有区域控制偏差(area control area,ACE)标准差的概念,利用固有ACE标准差确定考核阈值,提出了CPS标准的改进方法,并与原有CPS标准进行了对比。最后通过算例分析,验证了所提出改进标准比原有CPS标准更加公平合理。展开更多
To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content ...To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.展开更多
文摘随着高比例新能源的接入,互联电力系统不同控制区间的电源结构差异日益增大,有些控制区新能源装机增加、常规机组减少导致调频需求增加但控制能力下降。传统联络线功率频率偏差控制(tie-line power and frequency bias control,TBC)模式下的控制性能评价标准(control performance standard,CPS)标准,通过频率偏差系数来确定各控制区的考核阈值,却未考虑各控制区客观电源结构的影响,在高比例新能源电力系统中的不适应性日益凸显。首先分析了现有CPS标准的前提条件与内涵,揭示了CPS标准在高比例新能源电力系统中的不适应性,进而提出了控制区固有区域控制偏差(area control area,ACE)标准差的概念,利用固有ACE标准差确定考核阈值,提出了CPS标准的改进方法,并与原有CPS标准进行了对比。最后通过算例分析,验证了所提出改进标准比原有CPS标准更加公平合理。
基金Supported by the Science and Technology Cooperation and Exchange special project of Cooperation of Shanxi Province(202404041101014)the Fundamental Research Program of Shanxi Province(202403021212333)+3 种基金the Joint Funds of the National Natural Science Foundation of China(U24A20555)the Lvliang Key R&D of University-Local Cooperation(2023XDHZ10)the Initiation Fund for Doctoral Research of Taiyuan University of Science and Technology(20242026)the Outstanding Doctor Funding Award of Shanxi Province(20242080).
文摘To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.
