To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content ...To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.展开更多
单级式双有源桥(dual active bridge,DAB)DC/AC变换器控制自由度多,变压器匝比、漏感、开关频率等参数相互耦合,导致变换器效率优化面临多重制约。该文分析变压器匝比、漏感与软开关范围、漏感电流有效值、漏感电流峰值之间的约束关系,...单级式双有源桥(dual active bridge,DAB)DC/AC变换器控制自由度多,变压器匝比、漏感、开关频率等参数相互耦合,导致变换器效率优化面临多重制约。该文分析变压器匝比、漏感与软开关范围、漏感电流有效值、漏感电流峰值之间的约束关系,提出直接表征DAB-DC/AC变换器效率的物理量:效率敏感因子。通过研究效率敏感因子对系统损耗的影响机理,实现变换器效率最优的硬件参数设计,为多参数耦合的单级式DAB-DC/AC变换器效率优化提供理论指导。最后通过一台450 W样机验证所提理论的正确性。展开更多
在两级式AC-DC变换器中,前级功率因数校正(power factor correction,PFC)固有的瞬时功率波动特性会造成母线电压存在二倍频纹波,影响后级CLLLC谐振变换器的输出电压质量。针对以上问题,该文提出了基于二阶广义积分(second order general...在两级式AC-DC变换器中,前级功率因数校正(power factor correction,PFC)固有的瞬时功率波动特性会造成母线电压存在二倍频纹波,影响后级CLLLC谐振变换器的输出电压质量。针对以上问题,该文提出了基于二阶广义积分(second order generalized integral,SOGI)的可变增益母线电压纹波前馈控制方法。采用SOGI提取母线电压纹波信息,基于品质因数Q与电压增益的关系和母线电压纹波对归一化频率的影响,解析了母线电压纹波对CLLLC谐振变换器输出电压的影响机理,得到Q值与前馈增益系数Ka的关系,采用仿真寻优加数据拟合的方法得到前馈可变增益系数曲线。仿真和实验结果表明,相比于无前馈控制,所提控制方法对CLLLC谐振变换器的输出电压纹波具有较好的抑制效果,输出电压纹波降低了72%,验证了所提算法的有效性。展开更多
Nd3＋,Eu3＋ and Tb3＋ ions doped transparent chlorophosphate glass ceramics were prepared and their frequency-conversion properties were studied. X-ray diffraction （XRD） patterns evidenced the formation of expected ...Nd3＋,Eu3＋ and Tb3＋ ions doped transparent chlorophosphate glass ceramics were prepared and their frequency-conversion properties were studied. X-ray diffraction （XRD） patterns evidenced the formation of expected halide nanocrystals. The absorption,excitation and emission spectra investigation indicated that some of rare earth （RE） ions were trapped in low phonon energy halide nanocrystals,and therefore an efficient down frequency-conversion was observed. The comparative spectroscopic studies of RE doped samples suggested that the glass ceramics systems are potentially applicable as efficient ultraviolet to visible frequency-conversion photonics materials.展开更多
基金Supported by the Science and Technology Cooperation and Exchange special project of Cooperation of Shanxi Province(202404041101014)the Fundamental Research Program of Shanxi Province(202403021212333)+3 种基金the Joint Funds of the National Natural Science Foundation of China(U24A20555)the Lvliang Key R&D of University-Local Cooperation(2023XDHZ10)the Initiation Fund for Doctoral Research of Taiyuan University of Science and Technology(20242026)the Outstanding Doctor Funding Award of Shanxi Province(20242080).
文摘To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.
文摘单级式双有源桥(dual active bridge,DAB)DC/AC变换器控制自由度多,变压器匝比、漏感、开关频率等参数相互耦合,导致变换器效率优化面临多重制约。该文分析变压器匝比、漏感与软开关范围、漏感电流有效值、漏感电流峰值之间的约束关系,提出直接表征DAB-DC/AC变换器效率的物理量:效率敏感因子。通过研究效率敏感因子对系统损耗的影响机理,实现变换器效率最优的硬件参数设计,为多参数耦合的单级式DAB-DC/AC变换器效率优化提供理论指导。最后通过一台450 W样机验证所提理论的正确性。
基金Project supported by the Applied Physics Research Centre of Imam Hossein University, Tehran, Iran (180/207/531-1388/5/5)
文摘Nd3＋,Eu3＋ and Tb3＋ ions doped transparent chlorophosphate glass ceramics were prepared and their frequency-conversion properties were studied. X-ray diffraction （XRD） patterns evidenced the formation of expected halide nanocrystals. The absorption,excitation and emission spectra investigation indicated that some of rare earth （RE） ions were trapped in low phonon energy halide nanocrystals,and therefore an efficient down frequency-conversion was observed. The comparative spectroscopic studies of RE doped samples suggested that the glass ceramics systems are potentially applicable as efficient ultraviolet to visible frequency-conversion photonics materials.
