Self-assembly of octadecyl mercaptan on gold was investigated by cyclic voltammetry(CV) and electrochemical impedance spectroscopy (EIS). Results of CV experiments show thatthere are no structUral defects exposed dire...Self-assembly of octadecyl mercaptan on gold was investigated by cyclic voltammetry(CV) and electrochemical impedance spectroscopy (EIS). Results of CV experiments show thatthere are no structUral defects exposed directly to the redox couple in solution, but EISexperiments indicate that collapsed sites exist in the monolayer. A method to estimate the degree ofdisorder in the Au/thiol monolayer surface is proposed by using admittance plane plot.展开更多
文摘Self-assembly of octadecyl mercaptan on gold was investigated by cyclic voltammetry(CV) and electrochemical impedance spectroscopy (EIS). Results of CV experiments show thatthere are no structUral defects exposed directly to the redox couple in solution, but EISexperiments indicate that collapsed sites exist in the monolayer. A method to estimate the degree ofdisorder in the Au/thiol monolayer surface is proposed by using admittance plane plot.
文摘虚拟同步机(virtual synchronous generator,VSG)控制缓解了新型电力系统低惯量弱阻尼特性,但也引入了功角振荡,导致功角稳定性问题。已有研究从控制参数自适应以及控制环重构角度改进VSG控制,但存在设计困难、物理意义不明确等问题。因此,该文首先基于等面积定则(equal area criterion,EAC),利用虚拟阻抗,提出“功角能量”快速衰减的改进控制思路,从图形解法解释了底层物理意义,并设计算法求解控制各阶段虚拟阻抗大小。在此基础上,分析改进控制思路可能存在的问题。其次,从补偿“阻尼功”缺失和提高控制适用性角度,构建基于虚拟阻抗频率自适应的控制策略,以实现不同工况下功角振荡的优化抑制。最后,通过电磁暂态仿真验证前述分析的正确性,并展示所提控制策略对功角振荡抑制以及功角稳定性提高的有效性。
