The Boziguoer A-type granitoids in Baicheng County,Xinjiang,belong to the northern margin of the Tarim platform as well as the neighboring EW-oriented alkaline intrusive rocks.The rocks comprise an aegirine or arfveds...The Boziguoer A-type granitoids in Baicheng County,Xinjiang,belong to the northern margin of the Tarim platform as well as the neighboring EW-oriented alkaline intrusive rocks.The rocks comprise an aegirine or arfvedsonite quartz alkali feldspar syenite,an aegirine or arfvedsonite alkali feldspar granite,and a biotite alkali feldspar syenite.The major rock-forming minerals are albite,K-feldspar,quartz,arfvedsonite,aegirine,and siderophyllite.The accessory minerals are mainly zircon,pyrochlore,thorite,fluorite,monazite,bastnaesite,xenotime,and astrophyllite.The chemical composition of the alkaline granitoids show that SiO2 varies from 64.55％ to 72.29％ with a mean value of 67.32％,Na2O＋K2O is high （9.85％-11.87％） with a mean of 11.14％,K2O is 2.39％-5.47％ （mean =4.73％）,the K2O/Na2O ratios are 0.31-0.96,Al2O3 ranges from 12.58％ to 15.44％,and total FeOT is between 2.35％ and 5.65％.CaO,MgO,MnO,and TiO2 are low.The REE content is high and the total SREE is （263-1219） ppm （mean =776 ppm）,showing LREE enrichment and HREE depletion with strong negative Eu anomalies.In addition,the chondrite-normalized REE patterns of the alkaline granitoids belong to the ＂seagull＂ pattern of the right-type.The Zr content is （113-1246） ppm （mean =594 ppm）,Zr＋Nb＋Ce＋Y is between （478-2203） ppm with a mean of 1362 ppm.Furthermore,the alkaline granitoids have high HFSE （Ga,Nb,Ta,Zr,and Hf） content and low LILE （Ba,K,and Sr） content.The Nb/Ta ratio varies from 7.23 to 32.59 （mean =16.59） and the Zr/Hf ratio is 16.69-58.04 （mean =36.80）.The zircons are depleted in LREE and enriched in HREE.The chondrite-normalized REE patterns of the zircons are of the ＂seagull＂ pattern of the left-inclined type with strong negative Eu anomaly and without a Ce anomaly.The Boziguoer A-type granitoids share similar features with A1-type granites.The average temperature of the granitic magma was estimated at 832-839℃.The Boziguoer A-type granitoids show crust-mantle mixing and may have formed in an anorogenic intraplate tectonic setting under high-temperature,anhydrous,and low oxygen fugacity conditions.展开更多
Objective Large igneous provinces （LIPs） are sites of spatially contiguous, rapidly emplaced magmatic rocks, which represent the physical and chemical transfer of material from the mantle to the crust. Exposed with...Objective Large igneous provinces （LIPs） are sites of spatially contiguous, rapidly emplaced magmatic rocks, which represent the physical and chemical transfer of material from the mantle to the crust. Exposed within some continental LIPs are felsic and rnafic plutonic and volcanic rocks. Although their volumes are minor compared to the flood basalts, the plutonic rocks of continental LIPs are often associated with economic deposits of precious metals. Within the Permian Tarim LIP of NW China, there are at least two layered ultramafic-mafic intrusions （e.g. Wajilitag and Piqiang） contain economically important Fe- Ti-V oxide deposits. Spatially associated with these layered ultramafic-mafic intrusions are syenitic and granitic plutons, which have chemical characteristics of A- type granitoids.展开更多
In paleogeographic reconstructions of the Columbia and Rodinia Supercontinents,the position of the Greater India landmass is ambiguous.This,coupled with a limited understanding of the tectonic evolution of the mobile ...In paleogeographic reconstructions of the Columbia and Rodinia Supercontinents,the position of the Greater India landmass is ambiguous.This,coupled with a limited understanding of the tectonic evolution of the mobile belts along which the mosaic of crustal domains in India accreted,impedes precise correlation among the dispersed crustal fragments in supercontinent reconstructions.Using structural,metamorphic phase equilibria,chronological and geochemical investigations,this study aims to reconstruct the tectonic evolution of the Chottanagpur Gneiss Complex(CGC)as a distinct crustal block at the eastern end of the Greater Indian Proterozoic Fold Belt(GIPFOB)along which the North India Block(NIB)and the South India Block(SIB)accreted.The study focuses on two issues,e.g.dating the Early Neoproterozoic(0.92 Ga)accretion of the CGC with the NIB contemporaneous with the assembly of Rodinia,and documenting the widespread(>24,000 km^(2))plutonism of1.5-1.4 Ga weakly peraluminous,calc-alkalic to alkali-calcic and ferroan A-type granitoids(±garnet)devoid of mafic microgrannular enclaves and coeval mafic emplacements in the crustal block.These dominantly within-plate granitoids arguably formed by asthenospheric upwelling induced partial melting of garnetbearing anatectic quartzofeldspathic gneisses that dominate the Early Mesoproterozoic basement of the block.The major and trace element chemistry of the granitoids is similar to the 1.35-1.45 Ga A-type granitoids in Laurentia/Amazonia emplaced contemporaneous with the 1.5-1.3 Ga breakup of the Columbia Supercontinent.This study suggests the Chottanagpur Gneiss Complex occured as a fragmented crustal block following the breakup of the Columbia Supercontinent;the crustal block was subsequently integrated within India during the Early Neoproterozoic oblique accretion between the NIB and SIB contemporaneous with the Rodinia Supercontinent assembly.展开更多
The magma sources,origins and precise forming ages of the miarolite from Qishan and Kuiqi intrusions are still uncertain.New results reveal that,miarolites from the Qishan and Kuiqi intrusions yield crystallization ag...The magma sources,origins and precise forming ages of the miarolite from Qishan and Kuiqi intrusions are still uncertain.New results reveal that,miarolites from the Qishan and Kuiqi intrusions yield crystallization ages of~101 and~98 Ma,and they have a high formation temperature(~910℃)and low oxygen fugacity value,indicating crystallization condition at low pressure in the upper crust with temperature of 678℃.The Qishan and Kuiqi miarolites are characterized by enrichment in SiO_(2) and high-K alkali,depletion in Ca and Mg,and belong to the high-K weak peraluminous rock series.The samples are enriched in HFSEs(i.e.,Ta,Zr and Hf)and LILEs(i.e.,Ba,P and Sr),depleted in Ba and Sr with the negative anomaly of Eu.In the primitive mantle normalized trace element spider diagram,the samples show a right-inclined‘seagull-type’pattern,combined the ratios of(La/Yb)_(N),10000×Al/Ga,Rb/Nb and Nb/Ta etc.,they were proved to be alkaline A-type granite.Combined the characterize of the trace elements,they were derived from clay-rich source accompanied pelite melting,and subjected to K-feldspar crystallization fractional.The values of ε_(Hf)(t)and tDM2 are distributed in the range of-2.8 to 3.3 with~1.2 Ga,and-6.0 to 4.0 with~1.2 Ga,revealing that they were generated from the Mesoproterozoic Cathaysia basement rocks.The comprehensive research reveals the Kuiqi and Qishan intrusions derived from crust-mantle mixing and partial melting of the crust,respectively,resulting from lithospheric extension generated by the Paleo-Pacific Plate subducted into the European-Asian Plate.展开更多
We carried out SHRIMP zircon U-Pb dating on A-type granitic intrusions from the Namaqua-Natal Province,South Africa,Sverdrupfjella,western Dronning Maud Land,Antarctica and the Nampula Province of northern Mozambique....We carried out SHRIMP zircon U-Pb dating on A-type granitic intrusions from the Namaqua-Natal Province,South Africa,Sverdrupfjella,western Dronning Maud Land,Antarctica and the Nampula Province of northern Mozambique.Zircon grains in these granitic rocks are typically elongated and oscillatory zoned,suggesting magmatic origins.Zircons from the granitoid intrusions analyzed in this study suggest^1025-1100 Ma ages,which confirm widespread Mesoproterozoic A-type granitic magmatism in the Namaqua-Natal(South Africa),Maud(Antarctica)and Mozambique metamorphic terrains.No older inherited(e.g.,~2500 Ma Achean basement or^1200 Ma island are magmatism in northern Natal)zircon grains were seen.Four plutons from the Natal Belt(Mvoti Pluton,Glendale Pluton,Kwalembe Pluton,Ntimbankulu Pluton)display 1050-1040 Ma ages,whereas the Nthlimbitwa Pluton in northern Natal indicates older 1090-1080 Ma ages.A sample from Sverdrupfjella,Antarctica has^1091 Ma old zircons along with^530 Ma metamorphic rims.Similarly,four samples analysed from the Nampula Province of Mozambique suggest crystallization ages of^1060-1090 Ma but also show significant discordance with two samples showing younger^550 Ma overgrowths.None of the Natal samples show any younger overgrowths.A single sample from southwestern Namaqualand yielded an age of^1033 Ma.Currently available chronological data suggest magmatism took place in the Namaqua-Natal-MaudMozambique(NNMM)belt between^1025 Ma and^1100 Ma with two broad phases between^1060-1020 Ma and 1100-1070 Ma respectively,with peaks at between^1030-1040 Ma and^1070-1090 Ma.The age data from the granitic intrusions from Namaqualand.combined with those from Natal,Antarctica and Mozambique suggest a crude spatial-age relationship with the older>1070 Ma ages being largely restricted close to the eastern and western margins of the Kalahari Craton in northern Natal,Mozambique.Namaqualand and WDML Antarctica whereas the younger<1060 Ma ages dominate in southern Natal and western Namaqualand and are largely restricted to the southern and possibly the western margins of the Kalahari Craton.The older ages of magmatism partially overlap with or are marginally younger than the intracratonic Mkondo Large lgneous Provinee intruded into or extruded onto the Kalahari Craton,suggesting a tectonic relationship with the Maud Belt.Similar ages from granitic augen gneisses in Sri Lanka suggest a continuous belt stretching from Namaqualand to Sri Lanka in a reconstituted Gondwana,formed during the terminal stages of amalgamation of Rodinia and predating the East African Orogen.This contiguity contributes to defining the extent of Rodinia-age crustal blocks,subsequently fragmented by the dispersal of Rodinia and Gondwana.展开更多
SHRIMP U-Pb dating on magmatic zircons extracted from a riebeckite quartz syenite in the Huangyangshan pluton in Suizhou,the southern margin of Tongbai-Dabieshan yielded an age of 439±6Ma.According to the morphol...SHRIMP U-Pb dating on magmatic zircons extracted from a riebeckite quartz syenite in the Huangyangshan pluton in Suizhou,the southern margin of Tongbai-Dabieshan yielded an age of 439±6Ma.According to the morphology and high Th/U ratios of the zircons,the age is interpreted as crystallization timing of the pluton.The Huangyangshan pluton is composed of peralkaline quartz syenite,alkaline granite and syenite.All of the rocks are characterized by high agpaitic index(A.I.=(Na+K)/Al,molar ratio)and Fe-number[FeO_(T)/(FeO_(T)+MgO)],low CaO and MgO contents,enrichment of high field strength elements(i.e.Nb,Zr,Ga,Y,Hf)and light REEs,evidently negative Eu anomalies and high Ga/Al ratios,which are consistent with anorogenic A-type granitoids.Being part of the South Qinling-South Dabieshan Paleozoic alkaline rock belt,the Huangyangshan A-type granitoid pluton results from the Paleozoic extension-initial rifting in the northern margin of the Yangtze Craton related to the opening of the eastern Paleo-Tethyan Ocean.展开更多
The basement granite gneisses from the north-central Aravalli Craton in NW India were investigated for geochemistry and geochronology.In a peneplain terrain,the granite gneiss outcrops are scanty and samples were coll...The basement granite gneisses from the north-central Aravalli Craton in NW India were investigated for geochemistry and geochronology.In a peneplain terrain,the granite gneiss outcrops are scanty and samples were collected mainly from two small hills and several ground-level exposures in the Sakhun–Ladera region.Wellfoliated granite gneiss is the dominant lithology that also hosts dark,lenticular enclaves,and is in turn,intruded by mafic dykes.The granite gneiss has silica content ranging from 61.37 wt.%to 68.27 wt.%that marks a slight overlap with the enclaves(54.32wt.%to 62.17wt.%).Both groups have a highK2O/Na2O(~2 or higher)ratio.Geochemically,the granite gneiss classify as granite–granodiorite,and enclaves as granodiorite-diorite.The In-situ LA-ICP-MS zircon U–Pb geochronology of granite gneiss has yielded a statistically valid 1721±9 Ma age that we interpret as the emplacement age for the granitic protolith.Geochemical characteristics of granite gneiss underline fractional crystallization of an I-type melt as themain process,and continuity of trends in enclaves underlines their mutual genetic link.The genetic association is further verified by a consistency in the trace element characteristics and REE patterns.The Nd-isotope signatures define a single grouping for both granite gneiss and enclaves,withεNd(t)values ranging from−6.38 to−6.61,further substantiating a common source.The geochemical tectonic discrimination schemes consistently point toward an extensional setting and A-type characteristics for granite gneiss and enclaves.These are analogous to the coeval(1.72–1.75 Ga),A-type granitoids from the Khetri and Alwar basin in the North Delhi Fold Belt,implying a much larger areal extent for the Paleoproterozoic anorogenic magmatism in the northern segment of the Aravalli Craton.The Paleoproterozoic age for the presumed‘Archean’basement in this region offers tacit evidence that the BGC–II is a stratigraphically younger terrane as compared to the Archean age,BGC–I.展开更多
The Late Cretaceous Jiepailing granitoids,located at the central Nanling Range in South China,are closely associated with significant Sn-Li-Be-F polymetallic metallogeny.The Jiepailing granitoids mainly consist of gra...The Late Cretaceous Jiepailing granitoids,located at the central Nanling Range in South China,are closely associated with significant Sn-Li-Be-F polymetallic metallogeny.The Jiepailing granitoids mainly consist of granitic porphyry and zinnwaldite granite.The two granitoids have an A-type affinity,showing elevated Rb/Sr ratios and significant depletions in Ba,Sr and P.Integrated zircon and monazite U-Pb dating results suggest that granitic porphyry and zinnwaldite granite were emplaced at~89 Ma and~94 Ma,respectively.The low Ce^(4+)/Ce^(3+)ratios of the Jiepailing granitoids,together with significant negative Eu anomalies of the zircons,indicate that their formation occurred under conditions of reduced oxygen fugacity.Through the analysis of zircon Hf-O and whole-rock Nd isotopes,it has been determined that both stages of the Jiepailing granitoids originated in the lower-middle Mesoproterozoic crustal basement[ε_(Nd)(t)=−5.33 to−4.96,t^(C)_(DM)(Nd)=1289-1234 Ma,ε_(Hf)(t)=−4.13 to+2.22,t^(C)_(DM)(Hf)=1418-1015 Ma andδ^(18)O_(Zrc)=6.33‰-7.72‰],with the involvement of mantle-derived materials.Both granitic porphyry and zinnwaldite granite exhibit elevated concentrations of fluorine(F),with the positive correlation between F and Sn emphasizing the crucial role of high F sources in tin mineralization.Drawing upon the study of the Late Cretaceous magma systems in southern Hunan and through comparison with the mineralized granites observed in coastal regions during the Late Cretaceous,a genetic model for the mineralized granites in the Nanling region is developed.When the Paleo-Pacific Plate retreated to the coastal region,the continental crust in southern China underwent extensional thinning and asthenospheric upwelling due to gravitational collapse.Such processes resulted in the partial melting of the middle-lower crustal metamorphic sedimentary basement and the subsequent formation of F-rich granitic magmas,related to tin mineralization.展开更多
The petrogenesis and genetic link to polymetallic mineralization of the granites in the Dayishan complex,southern Hunan province remain debated.Here,we present an integrated study on the petrology,zircon U-Pb ages and...The petrogenesis and genetic link to polymetallic mineralization of the granites in the Dayishan complex,southern Hunan province remain debated.Here,we present an integrated study on the petrology,zircon U-Pb ages and whole-rock geochemistry for this complex.Our findings indicate that the southern complex consists of(amphibole-bearing)biotite granites and muscovite granites emplaced at 153-151 Ma,and the central and northern complex consists of two-mica granites and tourmaline-bearing muscovite granites,respectively with the former emplaced at 164 Ma and the latter at 150 Ma.The(amphibole-bearing)biotite granites have SiO_(2) contents of 68.0-73.8 wt% and are enriched in alkalis and rare earth elements and depleted in Sr and Ba.They display Zr+Y+Ce+Nb>350 ppm and 10000×Ga/Al>2.6 along with high zircon saturation temperatures(821-883oC).The two-mica granites and(tourmaline-bearing)muscovite granites have high SiO_(2)(74.4-77.3 wt%)and low Ga/Al,Zr+Nb+Ce+Y,K/Rb,Zr/Hf,and Nb/Ta along with low zircon saturation temperatures(709-817℃).Geochemical characteristics suggest that the(amphibole-bearing)biotite granites are A-type granites generated through shallow dehydration melting of early Paleozoic granitoids,and that the two-mica granites and(tourmaline-bearing)muscovite granites are fractionated A-type granites produced through fractionation crystallization from the(amphibole-bearing)biotite granites accompanied by fluid fractionation.展开更多
Located in Southeastern Chad. The Iro lake offers a great opportunity for the study of Precambrian formations and their Phanerozoic cover. Pluton is a Cal-alkaline granite. Due to its geographical location and geologi...Located in Southeastern Chad. The Iro lake offers a great opportunity for the study of Precambrian formations and their Phanerozoic cover. Pluton is a Cal-alkaline granite. Due to its geographical location and geological features, it holds crucial information for understanding the evolution of the Saharan Meta craton (central Africa), which remains poorly studied. One of the objectives is to map the formations Precambrian age in Southeastern Chad. Based on the petrographic and geochemical results, we identified granitoids of pan-African age (biotite granite, aplite granite and pegmatite granite). This Precambrian basement is covered with sedimentary formations (clays, argillites, lateritic cuirasses, etc.). The mineral assemblage is characteristic of acid rocks. Geochemistry reveals rocks with a high SiO2 range (62% - 77%) giving sub-alkaline to calc-alkaline acid rocks with high k (4.62% to 6.39%). The granitoids are classified as S-type hyperaluminous granites. This classification is supported by the presence of peraluminous minerals (e.g., muscovite) within the Iro granitoids, which also have high (>1%). Geochemical variation within the granites is largely due to extensive crystal fractionation. The Pattern of REEs normalized to the primitive mantle shows a pronounced negative Eu anomaly, reflecting the crystallization process and fractional crystallization of plagioclase in the rock, and a positive Yb anomaly. The role of plagioclase fractionation was relatively major during the earlier intrusive stages (consistent with the presence of Eu anomalies) and slightly increased, together with biotite and K-feldspar fractionation, during the later (granitic) rock crystallization. The Pattern of the spider normalized to MORBs shows two pronounced negative anomalies in TiO2 and Cs and a slight negative anomaly in Ba. The loss of Ba, Ti and Cs may be caused by the plagioclase fractionation, apatite and ilmenite crystal. The Ba anomaly is also controlled by the presence of K-feldspar and mica. The observed Ti anomalies are due to the fractionation of magnetite indicating a subduction environment (or remelting of a source from a subduction environment).展开更多
Background The Bundelkhand Craton is significant for preserving the multiphase granitoids magmatism from Paleoarchean to Neoarchean periods.It consists of a variety of granite rocks,including TTGs,sanukitoids,and high...Background The Bundelkhand Craton is significant for preserving the multiphase granitoids magmatism from Paleoarchean to Neoarchean periods.It consists of a variety of granite rocks,including TTGs,sanukitoids,and high-K granitoids.This study presents geochemical characteristics of high-silica(68.97 wt.%–73.99 wt.%),low-silica(58.73wt.%–69.94 wt.%),and high K_(2)O(2.77 wt.%–6.16 wt.%)contents of granitoids.Objective The data on Bundelkhand Craton’s granitic magmatism and geodynamics is not sufficiently robust.Geochemical data from this study will be used to further understand the origin,source,and petrogenesis of granitoid rocks and their implications for the evolution of geodynamics.Methodology Twenty-one samples were collected and analyzed for major,trace,and REE elements.Major elements were measured using X-ray fluorescence spectrometry(XRF),and trace and REE elements were analyzed by ICP-MS.Standard procedures from the Geological Survey of India were followed.Results The geochemical analysis presents high-silica(68.97-73.99 wt.%),low-silica(58.73-69.94 wt.%),and high K_(2)O(2.77-6.16 wt.%)contents in granitoids,classified as granite-granodiorite.The rocks are calcic to calcalkalic,magnesian,and range from peraluminous to metaluminous composition.REE patterns showed strong LREE enrichment relative to HREEs,with prominent negative Eu anomalies corresponding to earlier plagioclase fractionation.Multi-element patterns revealed negative anomalies in Nb,Sr,P,and Ti and positive anomalies in Pb.Conclusion The geochemical signatures attributed to the post-collisional magma generation and continental crustal contamination.The studied rocks show A-type and A2-type lineage,suggesting they originated from the melting of continental crust during transitional/post-collisional tectonic activity.The formation of hybrid granitoids in the Bundelkhand Craton is connected to the fractionation of hybrid magmas in shallow-seated magma chambers during these tectonic processes.展开更多
The Suzhou granitic pluton is the first identified Nb-Ta-rich granite in China.To reveal the genetic link between the sequence of magmatic and hydrothermal evolution and Nb-Ta mineralization in different intrusive pha...The Suzhou granitic pluton is the first identified Nb-Ta-rich granite in China.To reveal the genetic link between the sequence of magmatic and hydrothermal evolution and Nb-Ta mineralization in different intrusive phases of the Suzhou granite,whole-rock geochemistry,geochemistry and U-Th-Pb dating of monazite was analyzed.The unique geochemical characteristics show that the Suzhou pluton can be discriminated as an A-type granite.LA-ICP-MS U-Th-Pb dating of monazite in both the medium-and coarse-grained biotite granite(MBG)and the fine-grained biotite granite(FBG)indicates that the granite formed between 124 and 127 Ma.Based on geochemical characteristics and mineral textures,the MBG(Mnz-Ia)and FBG(Mnz-Ib)monazites are classified as magmatic monazites;another monazite(Mnz-II)from the MBG formed during a magmatic-hydrothermal transitional stage.Nb-Ta in the Suzhou pluton gradually concentrated during fractional crystallization and alteration of Ti-rich minerals and biotite.Ultimately,with the involvement of F-Li-rich fluid,Nb-Ta mineralization occurred during the magmatic-hydrothermal transition.The Suzhou pluton is considered part of a 600-km-and NE-SW-trending Nb-rich A-type granite belt together with other Early Cretaceous A-type granites in the Jiangnan Orogen that offers prospects of a new target for Nb-Ta prospecting.展开更多
Granite origin is crucial to understanding the evolution of continental crust,yet many concerns about granite genesis remain yielding ongoing debates.A new integrated study of petrology,geochronology,mineral chemistry...Granite origin is crucial to understanding the evolution of continental crust,yet many concerns about granite genesis remain yielding ongoing debates.A new integrated study of petrology,geochronology,mineral chemistry and whole-rock geochemistry of the Dupangling granitic complex in South China,indicate that the granites in the western complex were emplaced during the Caledonian(418 Ma);they have SiO_(2)contents of 68.1-70.4 wt%,and are calc-alkaline and strongly peraluminous with high maficity[(TFe_(2)O_(3)+MgO)>4.0 wt%]and exhibit^(87)Sr/^(86)Sr(t)of 0.7234-0.7311 andε_(Nd)(t)of-9.0 to-6.7.The granites in the eastern complex,emplaced during the Indosinian(212 Ma),have high SiO_(2)contents(73.3-79.8 wt%)and exhibit affinities with A-type granites,such as enrichment in alkalis and rare earth elements(REEs),and depletion in Sr and Ba along with high TFeO/(TFeO+MgO),Ga/Al and Zr+Y+Ce+Nb;these granites exhibit^(87)Sr/^(86)Sr(t)of 0.7221 andε_(Nd)(t)of-9.2 to-7.5.Geochemical characteristics suggest that the older Caledonian granites were derived through dehydration melting of Paleoproterozoic metasedimentary rocks plus additional(~20%-32%)input from mafic magma,whereas the Indosinian granites were generated through shallow dehydration melting of the Caledonian granitoids.展开更多
The Edikan Mine,which consists of Fobinso and Esuajah gold deposits,lies within the Asankrangwa Gold Belt of the Birimian Supergroup in the Kumasi Basin.The metasedimentary rocks in the Basins and the faulted metavolc...The Edikan Mine,which consists of Fobinso and Esuajah gold deposits,lies within the Asankrangwa Gold Belt of the Birimian Supergroup in the Kumasi Basin.The metasedimentary rocks in the Basins and the faulted metavolcanic rocks in the Belts that make up the Birimian Supergroup were intruded by granitoids during the Eburnean Orogeny.This research aims to classify granitoids in the Edikan Mine and ascertain the petrogenetic and geochemical characteristics of some auriferous granitoids in the wider Kumasi Basin,Ghana,to understand the implications for geodynamic settings.A multi-methods approach involving field studies,petrographic studies,and whole-rock geochemical analysis was used to achieve the goal of the study.Petrographic studies revealed a relatively high abundance of plagioclase and a low percentage of K-feldspars(anorthoclase and orthoclase)in the Fobinso samples,suggesting that the samples are granodioritic in nature,while the Esuajah samples showed relatively low plagioclase abundance and a high percentage in K-feldspars,indicating that they are granitic.The granitoids from the study areas are co-magmatic.The granitoids in Esuajah and Fobinso are generally enriched in large ion lithophile elements and light rare earth elements than high field strength elements,middle rare earth elements,and heavy rare earth elements,indicating mixing with crustal sources during the evolution of the granitoids.The granitoids were tectonically formed in a syn-collisional+VAG setting,which implies that they were formed in the subduction zone setting.Fobinso granodiorites showed S-type signatures with evidence of extensive crustal contamination,while the Esuajah granites showed I-type signatures with little or no crustal contamination and are peraluminous.Gold mineralization in the study area is structurally and lithologically controlled with shear zones,faulting,and veining as the principal structures controlling the mineralization.The late-stage vein,V3,in the Edikan Mine is characterized by a low vein angle and is mineralized.展开更多
Better understanding of shoshonitic rocks is vital to unravel the formation process and spatial distribution of their associated ore deposits.Here,we conducted analyses on the shoshonitic granodiorite and its mafic mi...Better understanding of shoshonitic rocks is vital to unravel the formation process and spatial distribution of their associated ore deposits.Here,we conducted analyses on the shoshonitic granodiorite and its mafic microgranular enclaves(MMEs)from the Chadi Cu-Pb-Zn polymetallic deposit(South China),with the aim to investigate their petrogenesis and tectonic setting.Zircon U-Pb age of the MMEs(165.0±1.2 Ma)is coeval with that of the host granodiorite(164.8±0.63 Ma).The Chadi granitoids are enriched in large ion lithophile elements and light rare earth elements,but depleted in high-field-strength elements.The granodiorite displays low(^(87)Sr/^(86)Sr)_(i)(0.7069-0.7072),and negative ε_(Nd)(t)(−5.8 to−5.5)and zircon ε_(Hf)(t)(−3.6 to−0.4)values.These isotopic characteristics of the granodiorite and MMEs indicate the mixing of a mafic magma(formed from the subduction-related,metasomatically-enriched lithospheric mantle)and a felsic magma(formed from the partial melting of crustal materials),which is closely related to the Paleo-Pacific subduction.The Chadi granodioritic magma has likely low oxygen fugacity(<ΔFMQ+1),low whole-rock Sr/Y ratio(mostly<30),and low S(0.04±0.02 wt%)and Cl(0.23±0.04 wt%)contents,suggesting that the potential of forming large-scale Cu mineralization is low.展开更多
[Objective] The research aimed to induce the expression of FMDV structural protein VP1 in E.coli and purify the protein,then detect the activity.[Method] The fragment coding VP1 was amplified by PCR and doubly digeste...[Objective] The research aimed to induce the expression of FMDV structural protein VP1 in E.coli and purify the protein,then detect the activity.[Method] The fragment coding VP1 was amplified by PCR and doubly digested with BamH Ⅰ and XhoⅠ,then cloned into expression vector pGEX-4T-1 and pPROExHTb respectively to get recombinant plasmid pGEX-4T-1-VP1 and pPROExHTb-VP1.The recombinant plasmid pGEX-4T-1-VP1 and pPROExHTb-VP1 was transformed into E.coli BL21(DE3)and induced by IPTG,fusion protein was identifie...展开更多
Affected by the compressive stress from the South-Central （Indo-China） Peninsula, the Indosinian orogenesis, characterized by collision, thrust and uplifting, took place inside the South China Plate during 250-230 M...Affected by the compressive stress from the South-Central （Indo-China） Peninsula, the Indosinian orogenesis, characterized by collision, thrust and uplifting, took place inside the South China Plate during 250-230 Ma. The ages of the Indosinian granitoids in the Nanling Range and vicinity areas are mostly 240-205 Ma, indicating that they were emplaced in both late collision and post-collision geodynamic environments. No important granite-related metallogenesis occurred in this duration. A post-orogenic setting started at the beginning of the Yanshanian Period, which controlled large-scale granitic magmatism and related metallogenesis. This paper makes the first attempt to divide the Yanshanian Period into three sub-periods, i.e. the early, middle and late Yanshanian Periods, based mainly on the features of magmatism, especially granitoids and related metallogenesis and their geodynamic environments. The magmatic association of the Early Yanshanian （about 185-170 Ma） comprises four categories of magmatism, i.e. basalt, bimodal volcanics, A-type granite and intraplate high-K calc-alkaline （HKCA） magmatism, which indicates an extension-thinning of lithosphere and upwelling of mantle material to a relative small and local extent. Pb-Zn, Cu and Au mineralizations associated with HKCA magmatism represents the first high tide of Mesozoic metallogenesis in the Nanling Range area. During the middle Yanshanian, the lithosphere was subjected to more extensive and intensive extending and thinning, and hence mantle upwelling and basaltic magma underplating caused a great amount of crust remelting granitoids. This period can be further divided into two stages. The first stage （170-150 Ma） is represented by large-scale emplacement of crust remelting granites with local tungsten mineralization at its end. The second stage （150-140 Ma） is the most important time of large-scale mineralizations of non-ferrous and rare metals, e.g. W, Sn, Nb-Ta, Bi, Mo, Be, in the Nanling Range area. The late Yanshanian （140-65 Ma） was generally characterized by full extension and breakup of the lithosphere of South China. However, owing to the influence of the Pacific Plate movement, the eastern part of South China was predominated by subduction-related compression, which resulted in magmatism of calc-alkaline and shoshonite series and related metallogeneses of Au, Ag, Pb-Zn, Cu and （Mo, Sn）, followed by extension in its late stage. In the Nanling Range area, the late Yanshanian magmatism was represented by granitic volcanic-intrusive complexes and mafic dikes, which are genetically related to volcanic-type uranium and porphyry tin deposits, and the mobilization-mineralization of uranium from pre-existing Indosinian granites.展开更多
LA-ICPMS U-Pb zircon dating of the Sanpinggou, Gangou and Fengzishan granitoids in the Douling Group of the Eastern Qinling yields ages of 760-685 Ma, which represents a strong tectono-magmatic event in the southern Q...LA-ICPMS U-Pb zircon dating of the Sanpinggou, Gangou and Fengzishan granitoids in the Douling Group of the Eastern Qinling yields ages of 760-685 Ma, which represents a strong tectono-magmatic event in the southern Qinling during the late Neoproterozoic. Geochemical data show that these intrusions have wide compositions ranging from minor gabbros through diorites to granodiorites. They are relatively enriched in LILE, poor in HFSE and strongly depleted in Nb and Ta, displaying affinities of Ⅰ-type granites formed in an active continental margin with oceanic subduction. In contrast to granitoids, gabbros and enclaves in the granitoids have higher REE abundances, relatively flat REE patterns, lower LILE, slightly higher HFSE and more depletion in Nb and Ta. All these suggest that the gabbros were formed by partial melting of the upper mantle above the subduction zone and the granitoids by the partial melting of the lower crust. Combined with regional geological data, the subduction-related granitoids in the Douling Group, together with the Tuwushan A-type granite with an age of 725 Ma and contemporaneous basic dikes in the Wudang Block, provide evidence for local subduction of oceanic basins between different blocks during the rifting in the Southern Qinling in the Neoproterozoic. Thus, the coexistences of various magmatic rocks formed in different tectonic environments indicate a complicated tectonic evolution and variety of tectonic frameworks in the Qinling area in the Neoproterozoic.展开更多
Zircon U-Pb ages of 163.8-100.4 Ma and 146.6-134.5 Ma are obtained for the granitoids from the Pearl River mouth basin, and from southern Guangdong Province, respectively. These new dating data accord well with the cr...Zircon U-Pb ages of 163.8-100.4 Ma and 146.6-134.5 Ma are obtained for the granitoids from the Pearl River mouth basin, and from southern Guangdong Province, respectively. These new dating data accord well with the crystallization ages of Yanshanian granitoids broadly in the Nanling. The active continental margin of South China, as revealed by a combination of zircon U-Pb data, underwent a key granitoid-dominated magmatism in 165-100 Ma. Its evolution varied temporally, and spatially, registering under control of the paleo-Pacific slab subduction. The granitoids that occurred in 165-150 Ma broadly from the South China Sea to the Nanling are preferably related to two settings from volcanic-arc to back-arc extension, respectively. The activities of Cretaceous granitoids migrated from the southeastern Guangdong （148-130 Ma） to the Pearl River Mouth basin （127-112 Ma）, corresponding to the model of a retreating subduction. The subduction-related granitoid magmatism in South China continued until 108-97 Ma. A tectonic transformation from slab-subduction to extension should occur at -100 Ma.展开更多
Granitoids are widespread in the Songpan-Garze （松潘-甘孜） fold belt, western China. These granitoids provide insight into regional tectono-magmatic events, basement nature and tectonic evolution. However, previous ...Granitoids are widespread in the Songpan-Garze （松潘-甘孜） fold belt, western China. These granitoids provide insight into regional tectono-magmatic events, basement nature and tectonic evolution. However, previous studies mainly focused on the eastern Songpan-Garze fold belt. In this article, five granitoid intrusions from the western Songpan-Garze fold belt have been studied. These intrusions are composed of quartz-diorite and granodiorite. Using LA-ICP-MS zircon dating method, the obtained magma crystallization ages are 219±2 Ma for the quartz-diorite and 216±5 Ma for the granodiorite. The ages, combined with regional geological analyses, show that they formed in a post-coilisional tectonic setting. The quartz-diorite and granodiorite display co-linear variation in their chemical compositions. REE compositions for both the quartz-diorite and granodiorite show strongly fractionated patterns with （La/Yb）N=5.02-18.34 and Eu/Eu^＊=0.44-0.89. The quartz-diorites have initial ^87Sr/^86Sr ratios （Isr） of 0.70929-0.71197 and εNd（t） values of -8.6 to -6.1 and the granodiorites have Isr values of 0.70549-0.70997 and εNd（t） values of -8.3 to -4.3. Zircon Hf isotopic data show εHr（t） values of -3.8 to ＋1.6 for the quartz-diorites and -1.2 to ＋3.0 for the granodiorites. Geochemical and Sr-Nd-Hf isotopic compositions indicate that the quartz-diorites and granodiorites have similar petrogenesis. We suggest that the magmas for the quartz-diorites and granodiorites were derived from partial melting of lower crustal mafic source, resulting from amphibole dehydration melting reaction. The probing of the magma source reveals that the western Songpan-Garze fold belt contains an unexposed continental basement, which is similar to the eastern Songpan-Garze fold belt. Geodynamically, it is proposed that a lithospheric delamination model can account for the magma generation for the quartz-diorites and granodiorites in the western Songpan-Garze fold belt.展开更多
基金supported by the projects of "The detailed geological survey of Nb-Ta ore deposits in Boziguoer, Baicheng County, Xinjiang" and "China Geological Survey (project No. 1212011120160)"
文摘The Boziguoer A-type granitoids in Baicheng County,Xinjiang,belong to the northern margin of the Tarim platform as well as the neighboring EW-oriented alkaline intrusive rocks.The rocks comprise an aegirine or arfvedsonite quartz alkali feldspar syenite,an aegirine or arfvedsonite alkali feldspar granite,and a biotite alkali feldspar syenite.The major rock-forming minerals are albite,K-feldspar,quartz,arfvedsonite,aegirine,and siderophyllite.The accessory minerals are mainly zircon,pyrochlore,thorite,fluorite,monazite,bastnaesite,xenotime,and astrophyllite.The chemical composition of the alkaline granitoids show that SiO2 varies from 64.55％ to 72.29％ with a mean value of 67.32％,Na2O＋K2O is high （9.85％-11.87％） with a mean of 11.14％,K2O is 2.39％-5.47％ （mean =4.73％）,the K2O/Na2O ratios are 0.31-0.96,Al2O3 ranges from 12.58％ to 15.44％,and total FeOT is between 2.35％ and 5.65％.CaO,MgO,MnO,and TiO2 are low.The REE content is high and the total SREE is （263-1219） ppm （mean =776 ppm）,showing LREE enrichment and HREE depletion with strong negative Eu anomalies.In addition,the chondrite-normalized REE patterns of the alkaline granitoids belong to the ＂seagull＂ pattern of the right-type.The Zr content is （113-1246） ppm （mean =594 ppm）,Zr＋Nb＋Ce＋Y is between （478-2203） ppm with a mean of 1362 ppm.Furthermore,the alkaline granitoids have high HFSE （Ga,Nb,Ta,Zr,and Hf） content and low LILE （Ba,K,and Sr） content.The Nb/Ta ratio varies from 7.23 to 32.59 （mean =16.59） and the Zr/Hf ratio is 16.69-58.04 （mean =36.80）.The zircons are depleted in LREE and enriched in HREE.The chondrite-normalized REE patterns of the zircons are of the ＂seagull＂ pattern of the left-inclined type with strong negative Eu anomaly and without a Ce anomaly.The Boziguoer A-type granitoids share similar features with A1-type granites.The average temperature of the granitic magma was estimated at 832-839℃.The Boziguoer A-type granitoids show crust-mantle mixing and may have formed in an anorogenic intraplate tectonic setting under high-temperature,anhydrous,and low oxygen fugacity conditions.
基金financially supported by the National Natural Science Foundation of China (Grant No.41703030)research grants from the East China University of Technology (Grants No.DHBK2015323 and RGET1504)the Jiangxi Provincial Department of Education (Grant No.GJJ150556)
文摘Objective Large igneous provinces （LIPs） are sites of spatially contiguous, rapidly emplaced magmatic rocks, which represent the physical and chemical transfer of material from the mantle to the crust. Exposed within some continental LIPs are felsic and rnafic plutonic and volcanic rocks. Although their volumes are minor compared to the flood basalts, the plutonic rocks of continental LIPs are often associated with economic deposits of precious metals. Within the Permian Tarim LIP of NW China, there are at least two layered ultramafic-mafic intrusions （e.g. Wajilitag and Piqiang） contain economically important Fe- Ti-V oxide deposits. Spatially associated with these layered ultramafic-mafic intrusions are syenitic and granitic plutons, which have chemical characteristics of A- type granitoids.
基金the financial support provided by UGC(India)fellowshipthe financial support for fieldwork provided through the CPDA funding scheme by Indian Institute of Technology,Kharagpur+2 种基金Invaluable support by Atreyee Bhattacharya(INSTAAR,Boulder)via internal educational initiative grants at University of ColoradoBoulder for the SIMS geochronology work at UCLA is greatly appreciatedThe UCLA Ion Microprobe Laboratory is partially supported by a grant from NSF-EAR’s Instrumentation and Facilities Program(1734856)。
文摘In paleogeographic reconstructions of the Columbia and Rodinia Supercontinents,the position of the Greater India landmass is ambiguous.This,coupled with a limited understanding of the tectonic evolution of the mobile belts along which the mosaic of crustal domains in India accreted,impedes precise correlation among the dispersed crustal fragments in supercontinent reconstructions.Using structural,metamorphic phase equilibria,chronological and geochemical investigations,this study aims to reconstruct the tectonic evolution of the Chottanagpur Gneiss Complex(CGC)as a distinct crustal block at the eastern end of the Greater Indian Proterozoic Fold Belt(GIPFOB)along which the North India Block(NIB)and the South India Block(SIB)accreted.The study focuses on two issues,e.g.dating the Early Neoproterozoic(0.92 Ga)accretion of the CGC with the NIB contemporaneous with the assembly of Rodinia,and documenting the widespread(>24,000 km^(2))plutonism of1.5-1.4 Ga weakly peraluminous,calc-alkalic to alkali-calcic and ferroan A-type granitoids(±garnet)devoid of mafic microgrannular enclaves and coeval mafic emplacements in the crustal block.These dominantly within-plate granitoids arguably formed by asthenospheric upwelling induced partial melting of garnetbearing anatectic quartzofeldspathic gneisses that dominate the Early Mesoproterozoic basement of the block.The major and trace element chemistry of the granitoids is similar to the 1.35-1.45 Ga A-type granitoids in Laurentia/Amazonia emplaced contemporaneous with the 1.5-1.3 Ga breakup of the Columbia Supercontinent.This study suggests the Chottanagpur Gneiss Complex occured as a fragmented crustal block following the breakup of the Columbia Supercontinent;the crustal block was subsequently integrated within India during the Early Neoproterozoic oblique accretion between the NIB and SIB contemporaneous with the Rodinia Supercontinent assembly.
基金granted by Opening Foundation of State Key Laboratory of Continental Dynamics(Grant No.21LCD08),Northwest University。
文摘The magma sources,origins and precise forming ages of the miarolite from Qishan and Kuiqi intrusions are still uncertain.New results reveal that,miarolites from the Qishan and Kuiqi intrusions yield crystallization ages of~101 and~98 Ma,and they have a high formation temperature(~910℃)and low oxygen fugacity value,indicating crystallization condition at low pressure in the upper crust with temperature of 678℃.The Qishan and Kuiqi miarolites are characterized by enrichment in SiO_(2) and high-K alkali,depletion in Ca and Mg,and belong to the high-K weak peraluminous rock series.The samples are enriched in HFSEs(i.e.,Ta,Zr and Hf)and LILEs(i.e.,Ba,P and Sr),depleted in Ba and Sr with the negative anomaly of Eu.In the primitive mantle normalized trace element spider diagram,the samples show a right-inclined‘seagull-type’pattern,combined the ratios of(La/Yb)_(N),10000×Al/Ga,Rb/Nb and Nb/Ta etc.,they were proved to be alkaline A-type granite.Combined the characterize of the trace elements,they were derived from clay-rich source accompanied pelite melting,and subjected to K-feldspar crystallization fractional.The values of ε_(Hf)(t)and tDM2 are distributed in the range of-2.8 to 3.3 with~1.2 Ga,and-6.0 to 4.0 with~1.2 Ga,revealing that they were generated from the Mesoproterozoic Cathaysia basement rocks.The comprehensive research reveals the Kuiqi and Qishan intrusions derived from crust-mantle mixing and partial melting of the crust,respectively,resulting from lithospheric extension generated by the Paleo-Pacific Plate subducted into the European-Asian Plate.
基金supported by a Grant-in-Aid for Scientific Research from the Japan Society for the Promotion of Science to K.S.(Nos.09041116and 13440151)a Grant-in-Aid for the Young Scientists from JSPS to T.H.Antarctic Research funding to GHG from the NRF,SouthAfrica,Grant ID.110739
文摘We carried out SHRIMP zircon U-Pb dating on A-type granitic intrusions from the Namaqua-Natal Province,South Africa,Sverdrupfjella,western Dronning Maud Land,Antarctica and the Nampula Province of northern Mozambique.Zircon grains in these granitic rocks are typically elongated and oscillatory zoned,suggesting magmatic origins.Zircons from the granitoid intrusions analyzed in this study suggest^1025-1100 Ma ages,which confirm widespread Mesoproterozoic A-type granitic magmatism in the Namaqua-Natal(South Africa),Maud(Antarctica)and Mozambique metamorphic terrains.No older inherited(e.g.,~2500 Ma Achean basement or^1200 Ma island are magmatism in northern Natal)zircon grains were seen.Four plutons from the Natal Belt(Mvoti Pluton,Glendale Pluton,Kwalembe Pluton,Ntimbankulu Pluton)display 1050-1040 Ma ages,whereas the Nthlimbitwa Pluton in northern Natal indicates older 1090-1080 Ma ages.A sample from Sverdrupfjella,Antarctica has^1091 Ma old zircons along with^530 Ma metamorphic rims.Similarly,four samples analysed from the Nampula Province of Mozambique suggest crystallization ages of^1060-1090 Ma but also show significant discordance with two samples showing younger^550 Ma overgrowths.None of the Natal samples show any younger overgrowths.A single sample from southwestern Namaqualand yielded an age of^1033 Ma.Currently available chronological data suggest magmatism took place in the Namaqua-Natal-MaudMozambique(NNMM)belt between^1025 Ma and^1100 Ma with two broad phases between^1060-1020 Ma and 1100-1070 Ma respectively,with peaks at between^1030-1040 Ma and^1070-1090 Ma.The age data from the granitic intrusions from Namaqualand.combined with those from Natal,Antarctica and Mozambique suggest a crude spatial-age relationship with the older>1070 Ma ages being largely restricted close to the eastern and western margins of the Kalahari Craton in northern Natal,Mozambique.Namaqualand and WDML Antarctica whereas the younger<1060 Ma ages dominate in southern Natal and western Namaqualand and are largely restricted to the southern and possibly the western margins of the Kalahari Craton.The older ages of magmatism partially overlap with or are marginally younger than the intracratonic Mkondo Large lgneous Provinee intruded into or extruded onto the Kalahari Craton,suggesting a tectonic relationship with the Maud Belt.Similar ages from granitic augen gneisses in Sri Lanka suggest a continuous belt stretching from Namaqualand to Sri Lanka in a reconstituted Gondwana,formed during the terminal stages of amalgamation of Rodinia and predating the East African Orogen.This contiguity contributes to defining the extent of Rodinia-age crustal blocks,subsequently fragmented by the dispersal of Rodinia and Gondwana.
基金the National Natural Science Foundation of China(Grant No.40334037)the Besearch Fumd for the Doctoral Program of Higher Education(Grant No.20010491018).
文摘SHRIMP U-Pb dating on magmatic zircons extracted from a riebeckite quartz syenite in the Huangyangshan pluton in Suizhou,the southern margin of Tongbai-Dabieshan yielded an age of 439±6Ma.According to the morphology and high Th/U ratios of the zircons,the age is interpreted as crystallization timing of the pluton.The Huangyangshan pluton is composed of peralkaline quartz syenite,alkaline granite and syenite.All of the rocks are characterized by high agpaitic index(A.I.=(Na+K)/Al,molar ratio)and Fe-number[FeO_(T)/(FeO_(T)+MgO)],low CaO and MgO contents,enrichment of high field strength elements(i.e.Nb,Zr,Ga,Y,Hf)and light REEs,evidently negative Eu anomalies and high Ga/Al ratios,which are consistent with anorogenic A-type granitoids.Being part of the South Qinling-South Dabieshan Paleozoic alkaline rock belt,the Huangyangshan A-type granitoid pluton results from the Paleozoic extension-initial rifting in the northern margin of the Yangtze Craton related to the opening of the eastern Paleo-Tethyan Ocean.
文摘The basement granite gneisses from the north-central Aravalli Craton in NW India were investigated for geochemistry and geochronology.In a peneplain terrain,the granite gneiss outcrops are scanty and samples were collected mainly from two small hills and several ground-level exposures in the Sakhun–Ladera region.Wellfoliated granite gneiss is the dominant lithology that also hosts dark,lenticular enclaves,and is in turn,intruded by mafic dykes.The granite gneiss has silica content ranging from 61.37 wt.%to 68.27 wt.%that marks a slight overlap with the enclaves(54.32wt.%to 62.17wt.%).Both groups have a highK2O/Na2O(~2 or higher)ratio.Geochemically,the granite gneiss classify as granite–granodiorite,and enclaves as granodiorite-diorite.The In-situ LA-ICP-MS zircon U–Pb geochronology of granite gneiss has yielded a statistically valid 1721±9 Ma age that we interpret as the emplacement age for the granitic protolith.Geochemical characteristics of granite gneiss underline fractional crystallization of an I-type melt as themain process,and continuity of trends in enclaves underlines their mutual genetic link.The genetic association is further verified by a consistency in the trace element characteristics and REE patterns.The Nd-isotope signatures define a single grouping for both granite gneiss and enclaves,withεNd(t)values ranging from−6.38 to−6.61,further substantiating a common source.The geochemical tectonic discrimination schemes consistently point toward an extensional setting and A-type characteristics for granite gneiss and enclaves.These are analogous to the coeval(1.72–1.75 Ga),A-type granitoids from the Khetri and Alwar basin in the North Delhi Fold Belt,implying a much larger areal extent for the Paleoproterozoic anorogenic magmatism in the northern segment of the Aravalli Craton.The Paleoproterozoic age for the presumed‘Archean’basement in this region offers tacit evidence that the BGC–II is a stratigraphically younger terrane as compared to the Archean age,BGC–I.
基金financially supported by the National Natural Science Foundation of China(Grant No.42303073).
文摘The Late Cretaceous Jiepailing granitoids,located at the central Nanling Range in South China,are closely associated with significant Sn-Li-Be-F polymetallic metallogeny.The Jiepailing granitoids mainly consist of granitic porphyry and zinnwaldite granite.The two granitoids have an A-type affinity,showing elevated Rb/Sr ratios and significant depletions in Ba,Sr and P.Integrated zircon and monazite U-Pb dating results suggest that granitic porphyry and zinnwaldite granite were emplaced at~89 Ma and~94 Ma,respectively.The low Ce^(4+)/Ce^(3+)ratios of the Jiepailing granitoids,together with significant negative Eu anomalies of the zircons,indicate that their formation occurred under conditions of reduced oxygen fugacity.Through the analysis of zircon Hf-O and whole-rock Nd isotopes,it has been determined that both stages of the Jiepailing granitoids originated in the lower-middle Mesoproterozoic crustal basement[ε_(Nd)(t)=−5.33 to−4.96,t^(C)_(DM)(Nd)=1289-1234 Ma,ε_(Hf)(t)=−4.13 to+2.22,t^(C)_(DM)(Hf)=1418-1015 Ma andδ^(18)O_(Zrc)=6.33‰-7.72‰],with the involvement of mantle-derived materials.Both granitic porphyry and zinnwaldite granite exhibit elevated concentrations of fluorine(F),with the positive correlation between F and Sn emphasizing the crucial role of high F sources in tin mineralization.Drawing upon the study of the Late Cretaceous magma systems in southern Hunan and through comparison with the mineralized granites observed in coastal regions during the Late Cretaceous,a genetic model for the mineralized granites in the Nanling region is developed.When the Paleo-Pacific Plate retreated to the coastal region,the continental crust in southern China underwent extensional thinning and asthenospheric upwelling due to gravitational collapse.Such processes resulted in the partial melting of the middle-lower crustal metamorphic sedimentary basement and the subsequent formation of F-rich granitic magmas,related to tin mineralization.
基金supported financially by the National Natural Science Foundation of China(Grant Nos.41872054 and 41272083)。
文摘The petrogenesis and genetic link to polymetallic mineralization of the granites in the Dayishan complex,southern Hunan province remain debated.Here,we present an integrated study on the petrology,zircon U-Pb ages and whole-rock geochemistry for this complex.Our findings indicate that the southern complex consists of(amphibole-bearing)biotite granites and muscovite granites emplaced at 153-151 Ma,and the central and northern complex consists of two-mica granites and tourmaline-bearing muscovite granites,respectively with the former emplaced at 164 Ma and the latter at 150 Ma.The(amphibole-bearing)biotite granites have SiO_(2) contents of 68.0-73.8 wt% and are enriched in alkalis and rare earth elements and depleted in Sr and Ba.They display Zr+Y+Ce+Nb>350 ppm and 10000×Ga/Al>2.6 along with high zircon saturation temperatures(821-883oC).The two-mica granites and(tourmaline-bearing)muscovite granites have high SiO_(2)(74.4-77.3 wt%)and low Ga/Al,Zr+Nb+Ce+Y,K/Rb,Zr/Hf,and Nb/Ta along with low zircon saturation temperatures(709-817℃).Geochemical characteristics suggest that the(amphibole-bearing)biotite granites are A-type granites generated through shallow dehydration melting of early Paleozoic granitoids,and that the two-mica granites and(tourmaline-bearing)muscovite granites are fractionated A-type granites produced through fractionation crystallization from the(amphibole-bearing)biotite granites accompanied by fluid fractionation.
文摘Located in Southeastern Chad. The Iro lake offers a great opportunity for the study of Precambrian formations and their Phanerozoic cover. Pluton is a Cal-alkaline granite. Due to its geographical location and geological features, it holds crucial information for understanding the evolution of the Saharan Meta craton (central Africa), which remains poorly studied. One of the objectives is to map the formations Precambrian age in Southeastern Chad. Based on the petrographic and geochemical results, we identified granitoids of pan-African age (biotite granite, aplite granite and pegmatite granite). This Precambrian basement is covered with sedimentary formations (clays, argillites, lateritic cuirasses, etc.). The mineral assemblage is characteristic of acid rocks. Geochemistry reveals rocks with a high SiO2 range (62% - 77%) giving sub-alkaline to calc-alkaline acid rocks with high k (4.62% to 6.39%). The granitoids are classified as S-type hyperaluminous granites. This classification is supported by the presence of peraluminous minerals (e.g., muscovite) within the Iro granitoids, which also have high (>1%). Geochemical variation within the granites is largely due to extensive crystal fractionation. The Pattern of REEs normalized to the primitive mantle shows a pronounced negative Eu anomaly, reflecting the crystallization process and fractional crystallization of plagioclase in the rock, and a positive Yb anomaly. The role of plagioclase fractionation was relatively major during the earlier intrusive stages (consistent with the presence of Eu anomalies) and slightly increased, together with biotite and K-feldspar fractionation, during the later (granitic) rock crystallization. The Pattern of the spider normalized to MORBs shows two pronounced negative anomalies in TiO2 and Cs and a slight negative anomaly in Ba. The loss of Ba, Ti and Cs may be caused by the plagioclase fractionation, apatite and ilmenite crystal. The Ba anomaly is also controlled by the presence of K-feldspar and mica. The observed Ti anomalies are due to the fractionation of magnetite indicating a subduction environment (or remelting of a source from a subduction environment).
基金Geological Survey of India,Northern Region have provided the financial funding for the study.
文摘Background The Bundelkhand Craton is significant for preserving the multiphase granitoids magmatism from Paleoarchean to Neoarchean periods.It consists of a variety of granite rocks,including TTGs,sanukitoids,and high-K granitoids.This study presents geochemical characteristics of high-silica(68.97 wt.%–73.99 wt.%),low-silica(58.73wt.%–69.94 wt.%),and high K_(2)O(2.77 wt.%–6.16 wt.%)contents of granitoids.Objective The data on Bundelkhand Craton’s granitic magmatism and geodynamics is not sufficiently robust.Geochemical data from this study will be used to further understand the origin,source,and petrogenesis of granitoid rocks and their implications for the evolution of geodynamics.Methodology Twenty-one samples were collected and analyzed for major,trace,and REE elements.Major elements were measured using X-ray fluorescence spectrometry(XRF),and trace and REE elements were analyzed by ICP-MS.Standard procedures from the Geological Survey of India were followed.Results The geochemical analysis presents high-silica(68.97-73.99 wt.%),low-silica(58.73-69.94 wt.%),and high K_(2)O(2.77-6.16 wt.%)contents in granitoids,classified as granite-granodiorite.The rocks are calcic to calcalkalic,magnesian,and range from peraluminous to metaluminous composition.REE patterns showed strong LREE enrichment relative to HREEs,with prominent negative Eu anomalies corresponding to earlier plagioclase fractionation.Multi-element patterns revealed negative anomalies in Nb,Sr,P,and Ti and positive anomalies in Pb.Conclusion The geochemical signatures attributed to the post-collisional magma generation and continental crustal contamination.The studied rocks show A-type and A2-type lineage,suggesting they originated from the melting of continental crust during transitional/post-collisional tectonic activity.The formation of hybrid granitoids in the Bundelkhand Craton is connected to the fractionation of hybrid magmas in shallow-seated magma chambers during these tectonic processes.
基金supported by the National Natural Science Foundation of China(Grant Nos.41903025 and 41803048)the National Nonprofit Institute Research Grant of IGGE(Grant Nos.AS2024J03,JY202106 and AS2022P03)+2 种基金the Hebei Key Science and Technology Program(Grant No.19057411Z)the National Science and Technology Major Project(Grant No.2024ZD1002402)the China Geological Survey Project(Grant No.DD20221807).
文摘The Suzhou granitic pluton is the first identified Nb-Ta-rich granite in China.To reveal the genetic link between the sequence of magmatic and hydrothermal evolution and Nb-Ta mineralization in different intrusive phases of the Suzhou granite,whole-rock geochemistry,geochemistry and U-Th-Pb dating of monazite was analyzed.The unique geochemical characteristics show that the Suzhou pluton can be discriminated as an A-type granite.LA-ICP-MS U-Th-Pb dating of monazite in both the medium-and coarse-grained biotite granite(MBG)and the fine-grained biotite granite(FBG)indicates that the granite formed between 124 and 127 Ma.Based on geochemical characteristics and mineral textures,the MBG(Mnz-Ia)and FBG(Mnz-Ib)monazites are classified as magmatic monazites;another monazite(Mnz-II)from the MBG formed during a magmatic-hydrothermal transitional stage.Nb-Ta in the Suzhou pluton gradually concentrated during fractional crystallization and alteration of Ti-rich minerals and biotite.Ultimately,with the involvement of F-Li-rich fluid,Nb-Ta mineralization occurred during the magmatic-hydrothermal transition.The Suzhou pluton is considered part of a 600-km-and NE-SW-trending Nb-rich A-type granite belt together with other Early Cretaceous A-type granites in the Jiangnan Orogen that offers prospects of a new target for Nb-Ta prospecting.
基金supported financially by the National Natural Science Foundation of China(Grant Nos.41872054 and 41272083)。
文摘Granite origin is crucial to understanding the evolution of continental crust,yet many concerns about granite genesis remain yielding ongoing debates.A new integrated study of petrology,geochronology,mineral chemistry and whole-rock geochemistry of the Dupangling granitic complex in South China,indicate that the granites in the western complex were emplaced during the Caledonian(418 Ma);they have SiO_(2)contents of 68.1-70.4 wt%,and are calc-alkaline and strongly peraluminous with high maficity[(TFe_(2)O_(3)+MgO)>4.0 wt%]and exhibit^(87)Sr/^(86)Sr(t)of 0.7234-0.7311 andε_(Nd)(t)of-9.0 to-6.7.The granites in the eastern complex,emplaced during the Indosinian(212 Ma),have high SiO_(2)contents(73.3-79.8 wt%)and exhibit affinities with A-type granites,such as enrichment in alkalis and rare earth elements(REEs),and depletion in Sr and Ba along with high TFeO/(TFeO+MgO),Ga/Al and Zr+Y+Ce+Nb;these granites exhibit^(87)Sr/^(86)Sr(t)of 0.7221 andε_(Nd)(t)of-9.2 to-7.5.Geochemical characteristics suggest that the older Caledonian granites were derived through dehydration melting of Paleoproterozoic metasedimentary rocks plus additional(~20%-32%)input from mafic magma,whereas the Indosinian granites were generated through shallow dehydration melting of the Caledonian granitoids.
文摘The Edikan Mine,which consists of Fobinso and Esuajah gold deposits,lies within the Asankrangwa Gold Belt of the Birimian Supergroup in the Kumasi Basin.The metasedimentary rocks in the Basins and the faulted metavolcanic rocks in the Belts that make up the Birimian Supergroup were intruded by granitoids during the Eburnean Orogeny.This research aims to classify granitoids in the Edikan Mine and ascertain the petrogenetic and geochemical characteristics of some auriferous granitoids in the wider Kumasi Basin,Ghana,to understand the implications for geodynamic settings.A multi-methods approach involving field studies,petrographic studies,and whole-rock geochemical analysis was used to achieve the goal of the study.Petrographic studies revealed a relatively high abundance of plagioclase and a low percentage of K-feldspars(anorthoclase and orthoclase)in the Fobinso samples,suggesting that the samples are granodioritic in nature,while the Esuajah samples showed relatively low plagioclase abundance and a high percentage in K-feldspars,indicating that they are granitic.The granitoids from the study areas are co-magmatic.The granitoids in Esuajah and Fobinso are generally enriched in large ion lithophile elements and light rare earth elements than high field strength elements,middle rare earth elements,and heavy rare earth elements,indicating mixing with crustal sources during the evolution of the granitoids.The granitoids were tectonically formed in a syn-collisional+VAG setting,which implies that they were formed in the subduction zone setting.Fobinso granodiorites showed S-type signatures with evidence of extensive crustal contamination,while the Esuajah granites showed I-type signatures with little or no crustal contamination and are peraluminous.Gold mineralization in the study area is structurally and lithologically controlled with shear zones,faulting,and veining as the principal structures controlling the mineralization.The late-stage vein,V3,in the Edikan Mine is characterized by a low vein angle and is mineralized.
基金granted by the Basic Scientific Research Fund of Chinese Academy of Geological Sciences[Grant No.JKY202505,JYYWF20180601,KK2207]the National Natural Science Foundation of China(Grant No.41702083,41820104010)China Scholarship Council(Grant No.CSC 201908110163)。
文摘Better understanding of shoshonitic rocks is vital to unravel the formation process and spatial distribution of their associated ore deposits.Here,we conducted analyses on the shoshonitic granodiorite and its mafic microgranular enclaves(MMEs)from the Chadi Cu-Pb-Zn polymetallic deposit(South China),with the aim to investigate their petrogenesis and tectonic setting.Zircon U-Pb age of the MMEs(165.0±1.2 Ma)is coeval with that of the host granodiorite(164.8±0.63 Ma).The Chadi granitoids are enriched in large ion lithophile elements and light rare earth elements,but depleted in high-field-strength elements.The granodiorite displays low(^(87)Sr/^(86)Sr)_(i)(0.7069-0.7072),and negative ε_(Nd)(t)(−5.8 to−5.5)and zircon ε_(Hf)(t)(−3.6 to−0.4)values.These isotopic characteristics of the granodiorite and MMEs indicate the mixing of a mafic magma(formed from the subduction-related,metasomatically-enriched lithospheric mantle)and a felsic magma(formed from the partial melting of crustal materials),which is closely related to the Paleo-Pacific subduction.The Chadi granodioritic magma has likely low oxygen fugacity(<ΔFMQ+1),low whole-rock Sr/Y ratio(mostly<30),and low S(0.04±0.02 wt%)and Cl(0.23±0.04 wt%)contents,suggesting that the potential of forming large-scale Cu mineralization is low.
基金Supported by National Supporting Plan(2006BAD06A14)Transgenic Major Projects(2008ZX08011-004)~~
文摘[Objective] The research aimed to induce the expression of FMDV structural protein VP1 in E.coli and purify the protein,then detect the activity.[Method] The fragment coding VP1 was amplified by PCR and doubly digested with BamH Ⅰ and XhoⅠ,then cloned into expression vector pGEX-4T-1 and pPROExHTb respectively to get recombinant plasmid pGEX-4T-1-VP1 and pPROExHTb-VP1.The recombinant plasmid pGEX-4T-1-VP1 and pPROExHTb-VP1 was transformed into E.coli BL21(DE3)and induced by IPTG,fusion protein was identifie...
基金The present study is supported by the State Key Fundamental Research Project(Grant No.G1999043209)National Natural Science Foundation of China(Grant No.40132010).
文摘Affected by the compressive stress from the South-Central （Indo-China） Peninsula, the Indosinian orogenesis, characterized by collision, thrust and uplifting, took place inside the South China Plate during 250-230 Ma. The ages of the Indosinian granitoids in the Nanling Range and vicinity areas are mostly 240-205 Ma, indicating that they were emplaced in both late collision and post-collision geodynamic environments. No important granite-related metallogenesis occurred in this duration. A post-orogenic setting started at the beginning of the Yanshanian Period, which controlled large-scale granitic magmatism and related metallogenesis. This paper makes the first attempt to divide the Yanshanian Period into three sub-periods, i.e. the early, middle and late Yanshanian Periods, based mainly on the features of magmatism, especially granitoids and related metallogenesis and their geodynamic environments. The magmatic association of the Early Yanshanian （about 185-170 Ma） comprises four categories of magmatism, i.e. basalt, bimodal volcanics, A-type granite and intraplate high-K calc-alkaline （HKCA） magmatism, which indicates an extension-thinning of lithosphere and upwelling of mantle material to a relative small and local extent. Pb-Zn, Cu and Au mineralizations associated with HKCA magmatism represents the first high tide of Mesozoic metallogenesis in the Nanling Range area. During the middle Yanshanian, the lithosphere was subjected to more extensive and intensive extending and thinning, and hence mantle upwelling and basaltic magma underplating caused a great amount of crust remelting granitoids. This period can be further divided into two stages. The first stage （170-150 Ma） is represented by large-scale emplacement of crust remelting granites with local tungsten mineralization at its end. The second stage （150-140 Ma） is the most important time of large-scale mineralizations of non-ferrous and rare metals, e.g. W, Sn, Nb-Ta, Bi, Mo, Be, in the Nanling Range area. The late Yanshanian （140-65 Ma） was generally characterized by full extension and breakup of the lithosphere of South China. However, owing to the influence of the Pacific Plate movement, the eastern part of South China was predominated by subduction-related compression, which resulted in magmatism of calc-alkaline and shoshonite series and related metallogeneses of Au, Ag, Pb-Zn, Cu and （Mo, Sn）, followed by extension in its late stage. In the Nanling Range area, the late Yanshanian magmatism was represented by granitic volcanic-intrusive complexes and mafic dikes, which are genetically related to volcanic-type uranium and porphyry tin deposits, and the mobilization-mineralization of uranium from pre-existing Indosinian granites.
基金the National Natural Science Foundation of China(grant Nos.40032010-C,40072065 , 40372039) the Foundation of Senior Visiting Scholarship of Western Colleges,Ministry of Education,China.
文摘LA-ICPMS U-Pb zircon dating of the Sanpinggou, Gangou and Fengzishan granitoids in the Douling Group of the Eastern Qinling yields ages of 760-685 Ma, which represents a strong tectono-magmatic event in the southern Qinling during the late Neoproterozoic. Geochemical data show that these intrusions have wide compositions ranging from minor gabbros through diorites to granodiorites. They are relatively enriched in LILE, poor in HFSE and strongly depleted in Nb and Ta, displaying affinities of Ⅰ-type granites formed in an active continental margin with oceanic subduction. In contrast to granitoids, gabbros and enclaves in the granitoids have higher REE abundances, relatively flat REE patterns, lower LILE, slightly higher HFSE and more depletion in Nb and Ta. All these suggest that the gabbros were formed by partial melting of the upper mantle above the subduction zone and the granitoids by the partial melting of the lower crust. Combined with regional geological data, the subduction-related granitoids in the Douling Group, together with the Tuwushan A-type granite with an age of 725 Ma and contemporaneous basic dikes in the Wudang Block, provide evidence for local subduction of oceanic basins between different blocks during the rifting in the Southern Qinling in the Neoproterozoic. Thus, the coexistences of various magmatic rocks formed in different tectonic environments indicate a complicated tectonic evolution and variety of tectonic frameworks in the Qinling area in the Neoproterozoic.
基金supported by the State Key Program of the National Natural Science of China(grant no2008ZX05023-003)the project of the State Key Laboratory of Marine Geology(grant noMG200904)the National Natural Science Foundation of China (grant no40872138)
文摘Zircon U-Pb ages of 163.8-100.4 Ma and 146.6-134.5 Ma are obtained for the granitoids from the Pearl River mouth basin, and from southern Guangdong Province, respectively. These new dating data accord well with the crystallization ages of Yanshanian granitoids broadly in the Nanling. The active continental margin of South China, as revealed by a combination of zircon U-Pb data, underwent a key granitoid-dominated magmatism in 165-100 Ma. Its evolution varied temporally, and spatially, registering under control of the paleo-Pacific slab subduction. The granitoids that occurred in 165-150 Ma broadly from the South China Sea to the Nanling are preferably related to two settings from volcanic-arc to back-arc extension, respectively. The activities of Cretaceous granitoids migrated from the southeastern Guangdong （148-130 Ma） to the Pearl River Mouth basin （127-112 Ma）, corresponding to the model of a retreating subduction. The subduction-related granitoid magmatism in South China continued until 108-97 Ma. A tectonic transformation from slab-subduction to extension should occur at -100 Ma.
基金supported by the National Natural Science Foundation of China (Nos. 40773019 and 40821061)the Ministry of Education of China and the State Administration of Foreign Expert Affairs of China (No. B07039)
文摘Granitoids are widespread in the Songpan-Garze （松潘-甘孜） fold belt, western China. These granitoids provide insight into regional tectono-magmatic events, basement nature and tectonic evolution. However, previous studies mainly focused on the eastern Songpan-Garze fold belt. In this article, five granitoid intrusions from the western Songpan-Garze fold belt have been studied. These intrusions are composed of quartz-diorite and granodiorite. Using LA-ICP-MS zircon dating method, the obtained magma crystallization ages are 219±2 Ma for the quartz-diorite and 216±5 Ma for the granodiorite. The ages, combined with regional geological analyses, show that they formed in a post-coilisional tectonic setting. The quartz-diorite and granodiorite display co-linear variation in their chemical compositions. REE compositions for both the quartz-diorite and granodiorite show strongly fractionated patterns with （La/Yb）N=5.02-18.34 and Eu/Eu^＊=0.44-0.89. The quartz-diorites have initial ^87Sr/^86Sr ratios （Isr） of 0.70929-0.71197 and εNd（t） values of -8.6 to -6.1 and the granodiorites have Isr values of 0.70549-0.70997 and εNd（t） values of -8.3 to -4.3. Zircon Hf isotopic data show εHr（t） values of -3.8 to ＋1.6 for the quartz-diorites and -1.2 to ＋3.0 for the granodiorites. Geochemical and Sr-Nd-Hf isotopic compositions indicate that the quartz-diorites and granodiorites have similar petrogenesis. We suggest that the magmas for the quartz-diorites and granodiorites were derived from partial melting of lower crustal mafic source, resulting from amphibole dehydration melting reaction. The probing of the magma source reveals that the western Songpan-Garze fold belt contains an unexposed continental basement, which is similar to the eastern Songpan-Garze fold belt. Geodynamically, it is proposed that a lithospheric delamination model can account for the magma generation for the quartz-diorites and granodiorites in the western Songpan-Garze fold belt.
