期刊文献+
共找到3篇文章
< 1 >
每页显示 20 50 100
Eu^(2+)掺杂A_(2)CaPO_(4)F(A=K,Rb)格位占据和发光性质的第一性原理研究 被引量:1
1
作者 乔政 马健 +1 位作者 营逍 宁利新 《发光学报》 EI CAS CSCD 北大核心 2022年第9期1340-1349,共10页
Eu^(2+)⁃激活A_(2)CaPO_(4)F(A=K,Rb)荧光粉因具有优异的发光性能而引起研究人员的重点关注。然而,Eu^(2+)掺杂格位占据和光谱指认及其光谱调控机制依然不甚清楚。本文采用密度泛函理论系统计算了Eu^(2+)占据不同晶体学格位时的缺陷形... Eu^(2+)⁃激活A_(2)CaPO_(4)F(A=K,Rb)荧光粉因具有优异的发光性能而引起研究人员的重点关注。然而,Eu^(2+)掺杂格位占据和光谱指认及其光谱调控机制依然不甚清楚。本文采用密度泛函理论系统计算了Eu^(2+)占据不同晶体学格位时的缺陷形成能及光学跃迁能量,以此为基础对发射光谱进行指认。结果表明,K_(2)CaPO_(4)F∶Eu^(2+)位于660 nm附近和480 nm附近的发射峰虽然都来自Eu^(2+)占据在K格位,但二者的电荷补偿方式不同:前者两个配位F原子被O原子取代,同时与其中一个O原子近邻的K原子被Ca原子取代;后者只有一个配位F原子被O原子取代。Rb_(2)CaPO_(4)F∶Eu^(2+)位于480 nm附近的发射峰来自Eu^(2+)占据Rb格位,电荷补偿方式为:两个配位F原子被O原子取代,同时与两个O原子都相邻的K原子被Ca原子取代。此外,对Eu^(2+)占据格位的配位环境和电子结构进行分析,讨论了其与光谱发射峰位置之间的变化关系。本工作不仅诠释了实验现象,还可以为实验上进一步优化荧光粉发光性能提供理论参考。 展开更多
关键词 Eu^(2+)掺杂 A_(2)CaPO_(4)F(a=k Rb) 密度泛函理论计算 格位占据 发光性质
在线阅读 下载PDF
Magnetism in Quasi-One-Dimensional A2Cr3As3(A=K,Rb) Superconductors 被引量:2
2
作者 吴贤新 勒聪聪 +2 位作者 袁静 范桁 胡江平 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第5期119-123,共5页
We predict that the recently discovered quasi-one-dimensional superconductors, A2 Cr3As3 (A=K, Rb), possess strong frustrated magnetic fluctuations and are nearby a novel in-out co-planar magnetic ground state. The ... We predict that the recently discovered quasi-one-dimensional superconductors, A2 Cr3As3 (A=K, Rb), possess strong frustrated magnetic fluctuations and are nearby a novel in-out co-planar magnetic ground state. The frustrated magnetism is very sensitive to the c-axis lattice constant and can thus be suppressed by increasing pressure. Our results qualitatively explain strong non-Fermi liquid behaviors observed in the normal state of the superconductors as the intertwining between the magnetism and superconductivity can create a large quantum critical region in quasi-one-dimensional systems and also suggest that the materials share similar phase diagrams and superconducting mechanism with other unconventional superconductors, such as cuprates and iron-based superconductors. 展开更多
关键词 AS a=k Rb SUPERCONDUCTORS Magnetism in Quasi-One-Dimensional A2Cr3As3 CR
原文传递
AN INVESTIGATION ON THE MECHANISM OF SUPERCONDUCTIVITY IN ALKALI-DOPED BUCKMINSTERFULLERENE A_3C_(60)(A=K,Rb,Cs)
3
作者 Ji Min YAN Institute of Chemistry,Academia Sinica,Beijing 100080 《Chinese Chemical Letters》 SCIE CAS CSCD 1993年第2期159-162,共4页
For the superconductors(Rb_xK_(1-x))_3C_(60)(x=0.1),according to BCS theory and assuming that the virtual phonon acting on electron-pair is corresponding to the intrasolecular vibration in the bnckminnterfullerene C_(... For the superconductors(Rb_xK_(1-x))_3C_(60)(x=0.1),according to BCS theory and assuming that the virtual phonon acting on electron-pair is corresponding to the intrasolecular vibration in the bnckminnterfullerene C_(60),a linear relationship of the superconducting transition temperature T_c with x has been derived,which is in agreement with the experimentals, 展开更多
关键词 RB a=k Rb Cs A AN INVESTIGATION ON THE MECHANISM OF SUPERCONDUCTIVITY IN ALkALI-DOPED BUCkMINSTERFULLERENE A3C
在线阅读 下载PDF
上一页 1 下一页 到第
使用帮助 返回顶部