The transient phenomena of re-oxidation and slag entrapment occurring in the tundish during the ladle change-over process have been proven detrimental to clean steel production.Therefore,an unsteady three-phase turbul...The transient phenomena of re-oxidation and slag entrapment occurring in the tundish during the ladle change-over process have been proven detrimental to clean steel production.Therefore,an unsteady three-phase turbulence model,coupling velocity,temperature,and phase field was established to study the effect of the ladle shroud immersion depth on the slag eye formation,slag entrainment,slag dragging,air dragging,and flow characteristics during the ladle change-over process of a two-strand tundish.The results showed that reducing the immersion depth decreases the high-velocity region area under the slag layer in the quasi-steady process.During the emptying stage,as the molten bath level gradually decreases,the outlet temperature exhibits a trend of initially decreasing and subsequently increasing across all three shroud immersion depths.However,under a 210 mm shroud immersion depth,molten slag and air are dragged into the shroud,forming slag droplets and causing significant fluctuations,with a maximum scalar velocity of 0.0764 m/s at the monitoring point.In the filling stage,air and molten slag are dragged into the molten bath,forming bubbles and slag droplets at an immersion depth of 210 mm.Bubbles are observed within the molten slag layer,which can readily cause an emulsification phenomenon,making it easier to be dragged as slag droplets.Additionally,the slag eye area measured under 210 mm immersion depth at 45 s is 0.303 m^(2),while the maximum scalar velocity of 2.4259 m/s is detected at 12 s.At an immersion depth of 360 mm,the average area of the slag eye is minimized to 0.06268 m2,with corresponding variances of 0.006753,representing the optimal immersion depth.展开更多
The flow behavior of molten steel in the thin slab mold under high casting speed conditions was investigated,with a focus on the multi-mode continuous casting and rolling mold.A steel-slag two-phase flow model was est...The flow behavior of molten steel in the thin slab mold under high casting speed conditions was investigated,with a focus on the multi-mode continuous casting and rolling mold.A steel-slag two-phase flow model was established using large eddy simulation,the volume of fluid,and magnetohydrodynamics methods through numerical simulation.The maximum flow velocity and wave height at the steel-slag interface within the mold are critical evaluation criteria for analyzing asymmetric flow under varying casting speeds and electromagnetic braking.The results indicate that the asymmetric flows within the mold do not occur synchronously.The severity of the asymmetric flow correlates with the velocity difference across the steel-slag interface.A greater biased flow prolongs the time required to revert to a steady state.When the magnetic field intensity is set to 0.24 T and the magnetic pole position is at 390 mm from the steel-slag interface,this configuration can reduce the velocity of the steel-slag interface,thereby mitigating the asymmetric flow.Additionally,it can diminish the velocity,impact depth,and impact intensity on the narrow face of the jet,thus improving the distribution of velocity and turbulent kinetic energy within the mold.This configuration prolongs the time required for the steel-slag interface to transition from a stable state to its maximum velocity and shortens the time for the interface to return to stability from an unstable state.Moreover,it ensures the positional stability of the steel-slag interface,confining its position within−3 mm.展开更多
The electromagnetic swirling flow in nozzle(EMSFN)technique is designed to mitigate the adverse effects of unstable and uneven flow within the submerged entry nozzle in continuous casting.Utilizing electromagnetic for...The electromagnetic swirling flow in nozzle(EMSFN)technique is designed to mitigate the adverse effects of unstable and uneven flow within the submerged entry nozzle in continuous casting.Utilizing electromagnetic forces,EMSFN stabilizes the flow within the nozzle,leading to a more controlled flow in the mold.Numerical simulations were used to quantitatively analyze the magnetic and flow fields in a slab continuous casting system under EMSFN.Results indicate that EMSFN significantly stabilizes the outflow from the nozzle,with stability increasing with higher current intensity.At 10,000 Ampere-turns(At)of the coil,meniscus fluctuations were unstable.They stabilized at 13,000 At,with minimal changes observed beyond this point.The optimal current intensity for stable mold flow,at a casting speed of 1.56 m/min,is 13,000 At.These findings confirm the effectiveness of EMSFN in stabilizing the internal flow field of the slab mold and determining optimal operational current intensity.展开更多
Cutting-edge research has primarily focused on flow synthesis of linear block copolymers,lacking the ability for manipulating chain architectures for more extensive applications.Herein,we develop a flow chemistry plat...Cutting-edge research has primarily focused on flow synthesis of linear block copolymers,lacking the ability for manipulating chain architectures for more extensive applications.Herein,we develop a flow chemistry platform for the continuous microflow synthesis of bottlebrush block copolymers(BBCPs)using a grafting-through method.This involves performing ring-opening metathesis polymerization(ROMP)of two different macromonomers within two microfluidic reactors connected in series.The microflow environment allows for complete monomer conversion within a few tens of seconds,benefiting from the superior mixing efficiency achieved in Z-shaped channels as indicated by both theoretical simulations and experimental results.Consequently,a library of well-defined BBCPs of up to 528 distinct samples can be produced within one day through automation of the continuous procedure,while keeping precise control on degree of polymerization(DP<4)and polydispersity indices(PDI<1.2).The synthetic method is generally applicable to different macromonomers with different compositions and contour lengths,yielding libraries of branched block copolymers with great diversity in physiochemical properties and chain architectures.This work presents a powerful platform for high-throughput production of branched copolymers,significantly lowering the costs of the materials for real applications.展开更多
A universal expression for the transmitted power to the flexible foundation via the finite continuous isolation system of asymmetry is derived where the concept of effective mobility for the coupled system with con...A universal expression for the transmitted power to the flexible foundation via the finite continuous isolation system of asymmetry is derived where the concept of effective mobility for the coupled system with continuous contact points is put forward. On the basis of the theoretic calculation and analysis, effects of structure parameters of the system on the power flow transmission as well as on the isolation efficiency are fully investigated.展开更多
An opposite combined vertical linear electromagnetic stirring(CV-LEMS)was proposed,which is applied in the final solidification zone of bloom continuous casting.The melt flow,heat transfer,and solidification under CV-...An opposite combined vertical linear electromagnetic stirring(CV-LEMS)was proposed,which is applied in the final solidification zone of bloom continuous casting.The melt flow,heat transfer,and solidification under CV-LEMS were investigated by establishing a three-dimensional numerical simulation model and a pilot continuous casting simulation experiment and compared with the conventional rotary electromagnetic stirring(REMS).The results show that a longitudinally symmetric linear magnetic field is formed in the liquid core of the bloom by applying CV-LEMS,which induces a strong longitudinal circulation flow both on the inner arc side and the outer arc side in the liquid core of the bloom.The height of the melt longitudinal effective mixing range under CV-LEMS reaches 0.9 m,which is greater than that of the REMS and makes up for the deficiency of REMS sensitivity to the position of the final solidification zone.CV-LEMS strongly promotes the mixing of upper melt with high temperature and the lower part melt with low temperature in the liquid core,improves the uniformity of melt temperature distribution and significantly increases the melt temperature near the solidification front,and the width of the liquid core increases by 4.2 mm at maximum.This shows that the appliction of CV-LEMS is more helpful to strengthen the feeding effect of the upper melt to the solidification shrinkage of the lower melt than the conventional REMS and inhibits the formation of porosity,shrinkage cavity and crack defects in the center of the bloom.展开更多
In this article, polyphosphate-accumulating organisms （PAOs） from a lab-scale continuous-flow two-sludge system was isolated and identified, the different phosphorus accumulation characteristics of the isolates unde...In this article, polyphosphate-accumulating organisms （PAOs） from a lab-scale continuous-flow two-sludge system was isolated and identified, the different phosphorus accumulation characteristics of the isolates under anoxic and aerobic conditions were investigated. Two kinds of PAOs were both found in the anoxic zones of the two-sludge system, one of them utilized only oxygen as electron aeceptor, and the other one utilized either nitrate or oxygen as electron aeceptor. Of the total eight isolates, five isolates were capable of utilizing both nitrate and oxygen as electron acceptors to uptake phosphorus to some extent. And three of the five isolates showed good phosphorus accumulative capacities both under anoxic or aerobic conditions, two identified as Alcaligenes and one identified as Pseudomonas. Streptococcus was observed weak anoxic phosphorus accumulation because of its weak denitrification capacity, but it showed good phosphorus accumulation capacity under aerobic conditions. One isolates identified as Enterobacteriaceae was proved to be a special species of PAOs, which could only uptake small amounts of phosphorus under anoxic conditions, although its denitrification capacity and aerobic phosphorus accumulation capacity were excellent.展开更多
A new process for swirling flow generation in the submerged entry nozzle （SEN） in continuous casting process of steel was proposed. A rotating electromagnetic field was set up around the SEN to induce swirling flow ...A new process for swirling flow generation in the submerged entry nozzle （SEN） in continuous casting process of steel was proposed. A rotating electromagnetic field was set up around the SEN to induce swirling flow by Lorentz force. The flow and temperature fields in the SEN and round billet mold with electromagnetic swirling were numerically simulated and then verified by the electromagnetic swirling model experiment of low melting point alloy. The effects of divergent angle of the SEN on the flow and temperature fields in mold with electromagnetic swirling were investigated. The electromagnetic swirling flow generator （EMSFG） could effectively induce swirling flow of molten steel in the SEN, which consequently improved greatly the flow and temperature fields in the mold. Below the nozzle outlet in mold, with the increase of divergent angle, the stream of bulk flow diverged more widely, the high temperature zone shifted up, and the temperature field became more uniform. Above the nozzle outlet in mold, with 350 A electromagnetic swirling, when the divergent angle of the SEN increased, the upward flow velocity and the meniscus temperature first increased and then decreased. With a divergent angle of 60~, the upward flow velocity and meniscus temperature reaced the largest value.展开更多
A 1∶2.5 scale tundish model was set up in laboratory for a six-strand billet continuous casting tundish with different configurations to investigate fluid flow characteristics under different operational conditions b...A 1∶2.5 scale tundish model was set up in laboratory for a six-strand billet continuous casting tundish with different configurations to investigate fluid flow characteristics under different operational conditions by measuring residence time distribution curves.It was found that minimum residence time,maximum concentration time and average residence time of the three strands on the same side of the tundish with the former configuration under normal operation,that is,six strands were open,were small and non-uniform and the tundish had large dead volume fraction.Vortexes easily formed on the liquid surface in the pouring zone of the tundish.The fluid flow characteristics in the tundish with the optimal turbulence inhibitor and baffles were improved and became less non-uniform among the strands.Vortexes were not found on the pouring zone surface in the optimal tundish.For non-normal operation,that is,one strand was close,it was important to choose which strand to be closed for maintaining flow characteristics of the rest two strands.It was found from this investigation that fluid flow characteristics in the optimal configuration tundish with closing strand 2 were better than those with closing strand 3 on the same side.展开更多
Based on turbulent theory, a 3D coupled model of fluid flow and solidification was built using finite difference method and used to study the influence of superheating degree and casting speed on fluid flow and solidi...Based on turbulent theory, a 3D coupled model of fluid flow and solidification was built using finite difference method and used to study the influence of superheating degree and casting speed on fluid flow and solidification, analyze the interaction between shell and molten steel, and compare the temperature distribution under different technological conditions. The results indicate that high superheating degree can lengthen the liquid-core depth and make the crack and breakout possible, so suitable superheating should be controlled within 35℃ according to the simulation results. Casting speed which is one of the most important technological parameters of improving production rate, should be controlled between 0. 85 m/min and 1.05 m/min and the caster has great potential in the improvement of blank quality.展开更多
A conventional turbulence inhibitor is compared with a swirling chamber from the points of view of fluid flow and removal rate of inclusion in the tundish. Comparing the RTD curves, inclusion removals, and the streaml...A conventional turbulence inhibitor is compared with a swirling chamber from the points of view of fluid flow and removal rate of inclusion in the tundish. Comparing the RTD curves, inclusion removals, and the streamlines in water model experiments, it can be found that the tundish equipped with a swirling chamber has a great effect on improving the flow field, and the floatation rate of inclusion is higher than the tundish with a turbulence inhibitor. Because of the introduction of the swirling chamber, the flow field and inclusion removal in a two-strand swirling flow tundish are asymmetrical. Rotating the inlet direction of swirling chamber 60 degree is a good strategy to improve the asymmetrical flow field.展开更多
The degradation of formaldehyde gas was studied using UV/TiO2/O3 process under the condition of continuous flow mode. The effects of humidity, initial formaldehyde concentration, residence time and ozone adding amount...The degradation of formaldehyde gas was studied using UV/TiO2/O3 process under the condition of continuous flow mode. The effects of humidity, initial formaldehyde concentration, residence time and ozone adding amount on degradation of formaldehyde gas were investigated. The experimental results indicated that the combination of ozonation with photocatalytic oxidation on the degradation of formaldehyde showed a synergetic action, e.g,, it could considerably increase decomposing of formaldehyde. The degradation efficiency of formaldehyde was between 73.6% and 79.4% while the initial concentration in the range of 1.84--24 mg/m^3 by O3/TiO2flJV process. The optimal humidity was about 50% in UV/TiO2/O3 processs and degradation of formaldehyde increases from 39.0% to 94.1% when the ozone content increased from 0 to 141 mg/m^3. Furthermore, the kinetics of formaldehyde degradation reaction could be described by Langmuir-Hinshelwood model. The rate constant k of 46.72 mg/（m^3.min） and Langmuir adsorption coefficient K of 0.0268 m^3/mg were obtained.展开更多
An Eulerian-Eulerian two-fluid model was developed to study the vortex flow inside a slab continuous casting mold with argon gas injection. Interracial momentum transfer that accommodated various interracial forces in...An Eulerian-Eulerian two-fluid model was developed to study the vortex flow inside a slab continuous casting mold with argon gas injection. Interracial momentum transfer that accommodated various interracial forces including drag force, lift force, virtual mass force, and turbulent dispersion force was considered. Predicted results agree well vaith experimental measurements of the water model in two-phase flow pattern and vortex flow structures. Three typical flow patterns with different argon steel ratios （ASRs） have been obtained： ＂double roll＂, ＂three roll＂, and ＂single roll＂. The flow pattern inside the mold alternates among the three types or it may attain some intermedi ate condition. With increasing ASR, the positions of vortices move from the submerged entry nozzle to the narrow face of the mold, and the sizes of vortices are reduced gradually. The rotating directions of vortices are all from high velocity area to low velocity area. Two mechanisms of vortex formation on the top surface have been suggested, i. e. , congruous shear flow and incongruous shear flow.展开更多
The magnetic,heat transfer and flow phenomenon occurring in the continuous casting process under the mold electromagnetic stirring was further analyzed by solving the 3-D electromagnetic field mathematical model and f...The magnetic,heat transfer and flow phenomenon occurring in the continuous casting process under the mold electromagnetic stirring was further analyzed by solving the 3-D electromagnetic field mathematical model and flow solidification model with finite element method and finite volume method,respectively.The results indicate that the solidified shell thickness located in the effective stirring region fluctuates because of the unsteady scouring under the mold electromagnetic stirring.The maximum rotational velocity is a key parameter to the solidification of the billet when controlling the stirring intensity.When the rotational velocity reaches 0.32 m/s,the mush zone enlarges significantly and the solidification rate is further accelerated.The number of vortexes in the lower recirculation zone is not only two and depends on the stirring parameters.Besides,the secondary flow is closely associated with the solidification.Compared with the results of the model ignoring the influence of solidification on the flow of molten steel,the flow pattern within the lower recirculation region changes dramatically,and thus a coupling analysis of the flow,heat transfer,and solidification is essential when simulating the electromagnetic continuous casting process.展开更多
A three-dimensional mathematical model was established to investigate the behavior of molten steel flow and steel/slag interface with different processes and electromagnetic parameters under two different static magne...A three-dimensional mathematical model was established to investigate the behavior of molten steel flow and steel/slag interface with different processes and electromagnetic parameters under two different static magnetic field configurations [ruler-type electromagnetic brake （EMBr ruler） and vertical electromagnetic brake （V-EMBr）] in a continuous casting mold. The results showed that the brake effect of EMBr ruler is significantly influenced by its configuration parameters, the distance between the pole and bottom of the submerged entry nozzle （SEN）, and the port angle of the SEN outlet; therefore, it is not helpful to depress the diffusion of jet flow along the thickness direction of mold. For a constant SEN depth and port angle, there is a reasonable pole position （P = 0 mm） where the pole simultaneously covers three key zones, i.e., the jet flow impact zone and the upward and downward backflow zones. For V-EMBr, the magnetic field can simultaneously cover the three key zones and depress the diffusion of jet flow along the casting and thickness directions of the mold. Both the meniscus height and the impact intensity of the jet flow can be obviously depressed by V-EMBr even if the SEN depth and port angle have changed in the continuous casting process.展开更多
The fluid flow and the interfacial phenomenon of slag and metal in tundish with gas blowing were studied with mathematical and physical modeling, and the effects of gas flowrate, the placement of porous beam for the g...The fluid flow and the interfacial phenomenon of slag and metal in tundish with gas blowing were studied with mathematical and physical modeling, and the effects of gas flowrate, the placement of porous beam for the generation of bubbles, and the combination of flow control devices on the flow and slag-metal interface were investigated. The results show that the position of gas bubbling has a significant effect on the flow in tundish, and the placement of porous beam and gas flowrate are the two main factors affecting the entrapment of slag in tundish. The closer the porous beam to the weir, the more reasonable is the flow, which is in favor of the control of slag entrapment in tundish.展开更多
In order to weaken the bias flow in the submerged entry nozzle （SEN） with slide- gate, the rotating magnetic field was imposed. The numerical method was employed to investigate the effect of rotating magnetic field ...In order to weaken the bias flow in the submerged entry nozzle （SEN） with slide- gate, the rotating magnetic field was imposed. The numerical method was employed to investigate the effect of rotating magnetic field on the flow field in the SEN and the mold under different slide-gate opening ratios. Numerical results showed that when the slide-gate opening ratio is smaller than 100%, the flow field in the SEN and the mold become asymmetry and there is an obvious circulation under the slide- gate in the SEN. With increasing exciting current, the divergent angle of liquid steel at the SEN outlet increases, the impact depth of liquid steel in the mold decreases. With increasing slide-gate opening ratio, the impact depth of liquid steel in the mold increases and the required exciting current to weaken the bias flow should increase.展开更多
The flow characteristics and inclusion removal in a ten-strand continuous casting tundish were investigated with physical modelling and industrial trials. The results show that, among the strands, the strand with the ...The flow characteristics and inclusion removal in a ten-strand continuous casting tundish were investigated with physical modelling and industrial trials. The results show that, among the strands, the strand with the mini mum dimensionless time of the first appearance of tracer at the tundish exit appears to be the worst one for inclusion removal, while the strand with the maximum dimensionless mean residence time shows the best inclusion removal efficiency. The inclusion number decreases with increasing inclusion size for all strands. The inclusion number distri bution among strands is the same for all inclusion sizes and the descending order of inclusion number is basically con sistent with the ascending order of dimensionless mean residence time among individual strands. However, when the strand with the minimum dimensionless time of the first appearance of tracer at the tundish exit is not the same one with the minimum dimensionless mean residence time, the former seems to be inferior to the latter for inclusion re moval.展开更多
The configuration of the tundish for a two-strand horizontal continuous caster was designed and optimized through water modeling. Three designs of the tundish were studied： the original tundish without any flow contr...The configuration of the tundish for a two-strand horizontal continuous caster was designed and optimized through water modeling. Three designs of the tundish were studied： the original tundish without any flow control devices, the tundish with a turbulence inhibitor at the bottom, and the tundish with an inlet launder and an inclined dam. The residence time, the location and size of the dead zone, and the fluid field pattern were investigated. At the same time, the asymmetry flow field and wavy inlet jet in the horizontal tundish were observed and the reasons for them were discussed. The results indicate that the mndish with an inlet launder and an inclined dam is the best of the three designs.展开更多
Sliding gate control system is widely employed in continuous casting process of steel to control flow rate of molten steel.As molten steel passes through a sliding gate,uneven flow develops.This will cause asymmetrica...Sliding gate control system is widely employed in continuous casting process of steel to control flow rate of molten steel.As molten steel passes through a sliding gate,uneven flow develops.This will cause asymmetrical distribution of flow and temperature field in mold consequently,formation of vortex near the nozzle and entrapment of CC powder into the molten steel.etc,which have negative effect on process productivity and product quality.To suppress the uneven flow,electromagnetic swirling flow has been proposed to impose on the flow in submerged entry nozzle below the sliding gate.In this study the uneven flow developed by incompletely open sliding gate and the suppression of this uneven flow using electromagnetic swirling flow are numerically studied in round billet continuous casting of steel process.The improvement of the flow and temperature filed in the submerged entry nozzle and mold are investigated.It is found that:The uneven velocity in nozzle can be suppressed by electromagnetic swirling flow,and the flow and temperature field in mold be improved obviously;With the increase of electromagnetic swirling intensity,the effect of uneven flow can be almost completely suppressed.展开更多
基金supported by the National Natural Science Foundation of China(Nos.52422408 and 52171031)the Liaoning Xingliao Talents-Top-notch Young Talents Project(No.XLYC2203064)+1 种基金the Excellent Youth Fund of Liaoning Natural Science Foundation(No.2023JH3/10200001)the Fundamental Research Funds for the Central Universities(No.N2425004).
文摘The transient phenomena of re-oxidation and slag entrapment occurring in the tundish during the ladle change-over process have been proven detrimental to clean steel production.Therefore,an unsteady three-phase turbulence model,coupling velocity,temperature,and phase field was established to study the effect of the ladle shroud immersion depth on the slag eye formation,slag entrainment,slag dragging,air dragging,and flow characteristics during the ladle change-over process of a two-strand tundish.The results showed that reducing the immersion depth decreases the high-velocity region area under the slag layer in the quasi-steady process.During the emptying stage,as the molten bath level gradually decreases,the outlet temperature exhibits a trend of initially decreasing and subsequently increasing across all three shroud immersion depths.However,under a 210 mm shroud immersion depth,molten slag and air are dragged into the shroud,forming slag droplets and causing significant fluctuations,with a maximum scalar velocity of 0.0764 m/s at the monitoring point.In the filling stage,air and molten slag are dragged into the molten bath,forming bubbles and slag droplets at an immersion depth of 210 mm.Bubbles are observed within the molten slag layer,which can readily cause an emulsification phenomenon,making it easier to be dragged as slag droplets.Additionally,the slag eye area measured under 210 mm immersion depth at 45 s is 0.303 m^(2),while the maximum scalar velocity of 2.4259 m/s is detected at 12 s.At an immersion depth of 360 mm,the average area of the slag eye is minimized to 0.06268 m2,with corresponding variances of 0.006753,representing the optimal immersion depth.
基金support from the National Natural Science Foundation of China(Grant Nos.52174313 and 52304350)thank all members of the Hebei High Quality Steel Continuous Casting Engineering Technology Research Center at North China University of Science and Technology,Tangshan,China.
文摘The flow behavior of molten steel in the thin slab mold under high casting speed conditions was investigated,with a focus on the multi-mode continuous casting and rolling mold.A steel-slag two-phase flow model was established using large eddy simulation,the volume of fluid,and magnetohydrodynamics methods through numerical simulation.The maximum flow velocity and wave height at the steel-slag interface within the mold are critical evaluation criteria for analyzing asymmetric flow under varying casting speeds and electromagnetic braking.The results indicate that the asymmetric flows within the mold do not occur synchronously.The severity of the asymmetric flow correlates with the velocity difference across the steel-slag interface.A greater biased flow prolongs the time required to revert to a steady state.When the magnetic field intensity is set to 0.24 T and the magnetic pole position is at 390 mm from the steel-slag interface,this configuration can reduce the velocity of the steel-slag interface,thereby mitigating the asymmetric flow.Additionally,it can diminish the velocity,impact depth,and impact intensity on the narrow face of the jet,thus improving the distribution of velocity and turbulent kinetic energy within the mold.This configuration prolongs the time required for the steel-slag interface to transition from a stable state to its maximum velocity and shortens the time for the interface to return to stability from an unstable state.Moreover,it ensures the positional stability of the steel-slag interface,confining its position within−3 mm.
基金supported by the Application Technology of Automotive Steels(No.2021040300048)the National Natural Science Foundation of China(No.52304347)+2 种基金Hebei Provincial Natural Science Foundation(No.E2019501008),China Baowu Low Carbon Metallurgy Innovation Foundation(BWLCF202320)Natural Science Foundation of Liaoning Province(Nos.2023-MSBA-135 and 2023-BSBA-107)Fundamental Research Funds for the Central Universities(Nos.N2409008 and N2409006).
文摘The electromagnetic swirling flow in nozzle(EMSFN)technique is designed to mitigate the adverse effects of unstable and uneven flow within the submerged entry nozzle in continuous casting.Utilizing electromagnetic forces,EMSFN stabilizes the flow within the nozzle,leading to a more controlled flow in the mold.Numerical simulations were used to quantitatively analyze the magnetic and flow fields in a slab continuous casting system under EMSFN.Results indicate that EMSFN significantly stabilizes the outflow from the nozzle,with stability increasing with higher current intensity.At 10,000 Ampere-turns(At)of the coil,meniscus fluctuations were unstable.They stabilized at 13,000 At,with minimal changes observed beyond this point.The optimal current intensity for stable mold flow,at a casting speed of 1.56 m/min,is 13,000 At.These findings confirm the effectiveness of EMSFN in stabilizing the internal flow field of the slab mold and determining optimal operational current intensity.
基金financially supported by the National Natural Science Foundation of China(No.22071176)。
文摘Cutting-edge research has primarily focused on flow synthesis of linear block copolymers,lacking the ability for manipulating chain architectures for more extensive applications.Herein,we develop a flow chemistry platform for the continuous microflow synthesis of bottlebrush block copolymers(BBCPs)using a grafting-through method.This involves performing ring-opening metathesis polymerization(ROMP)of two different macromonomers within two microfluidic reactors connected in series.The microflow environment allows for complete monomer conversion within a few tens of seconds,benefiting from the superior mixing efficiency achieved in Z-shaped channels as indicated by both theoretical simulations and experimental results.Consequently,a library of well-defined BBCPs of up to 528 distinct samples can be produced within one day through automation of the continuous procedure,while keeping precise control on degree of polymerization(DP<4)and polydispersity indices(PDI<1.2).The synthetic method is generally applicable to different macromonomers with different compositions and contour lengths,yielding libraries of branched block copolymers with great diversity in physiochemical properties and chain architectures.This work presents a powerful platform for high-throughput production of branched copolymers,significantly lowering the costs of the materials for real applications.
基金This project is supported by National Natural Science Foundation of China (No.59975053)
文摘A universal expression for the transmitted power to the flexible foundation via the finite continuous isolation system of asymmetry is derived where the concept of effective mobility for the coupled system with continuous contact points is put forward. On the basis of the theoretic calculation and analysis, effects of structure parameters of the system on the power flow transmission as well as on the isolation efficiency are fully investigated.
基金the National Natural Science Foundation of China(Grant No.U1760206 and Grant No.51574083)the 111 Project(2.0)of China(No.BP0719037)for the financial support。
文摘An opposite combined vertical linear electromagnetic stirring(CV-LEMS)was proposed,which is applied in the final solidification zone of bloom continuous casting.The melt flow,heat transfer,and solidification under CV-LEMS were investigated by establishing a three-dimensional numerical simulation model and a pilot continuous casting simulation experiment and compared with the conventional rotary electromagnetic stirring(REMS).The results show that a longitudinally symmetric linear magnetic field is formed in the liquid core of the bloom by applying CV-LEMS,which induces a strong longitudinal circulation flow both on the inner arc side and the outer arc side in the liquid core of the bloom.The height of the melt longitudinal effective mixing range under CV-LEMS reaches 0.9 m,which is greater than that of the REMS and makes up for the deficiency of REMS sensitivity to the position of the final solidification zone.CV-LEMS strongly promotes the mixing of upper melt with high temperature and the lower part melt with low temperature in the liquid core,improves the uniformity of melt temperature distribution and significantly increases the melt temperature near the solidification front,and the width of the liquid core increases by 4.2 mm at maximum.This shows that the appliction of CV-LEMS is more helpful to strengthen the feeding effect of the upper melt to the solidification shrinkage of the lower melt than the conventional REMS and inhibits the formation of porosity,shrinkage cavity and crack defects in the center of the bloom.
基金Project supported by the Science and Technology Project of Heilongjiang Province (No. GA01C201-03).
文摘In this article, polyphosphate-accumulating organisms （PAOs） from a lab-scale continuous-flow two-sludge system was isolated and identified, the different phosphorus accumulation characteristics of the isolates under anoxic and aerobic conditions were investigated. Two kinds of PAOs were both found in the anoxic zones of the two-sludge system, one of them utilized only oxygen as electron aeceptor, and the other one utilized either nitrate or oxygen as electron aeceptor. Of the total eight isolates, five isolates were capable of utilizing both nitrate and oxygen as electron acceptors to uptake phosphorus to some extent. And three of the five isolates showed good phosphorus accumulative capacities both under anoxic or aerobic conditions, two identified as Alcaligenes and one identified as Pseudomonas. Streptococcus was observed weak anoxic phosphorus accumulation because of its weak denitrification capacity, but it showed good phosphorus accumulation capacity under aerobic conditions. One isolates identified as Enterobacteriaceae was proved to be a special species of PAOs, which could only uptake small amounts of phosphorus under anoxic conditions, although its denitrification capacity and aerobic phosphorus accumulation capacity were excellent.
基金Item Sponsored by Fundamental Research Funds for Central Universities of China(N100409010)Project for Key Laboratory of Liaoning Province of China(LS2010065)"111 Project"of Northeastern University of China(B07015)
文摘A new process for swirling flow generation in the submerged entry nozzle （SEN） in continuous casting process of steel was proposed. A rotating electromagnetic field was set up around the SEN to induce swirling flow by Lorentz force. The flow and temperature fields in the SEN and round billet mold with electromagnetic swirling were numerically simulated and then verified by the electromagnetic swirling model experiment of low melting point alloy. The effects of divergent angle of the SEN on the flow and temperature fields in mold with electromagnetic swirling were investigated. The electromagnetic swirling flow generator （EMSFG） could effectively induce swirling flow of molten steel in the SEN, which consequently improved greatly the flow and temperature fields in the mold. Below the nozzle outlet in mold, with the increase of divergent angle, the stream of bulk flow diverged more widely, the high temperature zone shifted up, and the temperature field became more uniform. Above the nozzle outlet in mold, with 350 A electromagnetic swirling, when the divergent angle of the SEN increased, the upward flow velocity and the meniscus temperature first increased and then decreased. With a divergent angle of 60~, the upward flow velocity and meniscus temperature reaced the largest value.
基金Item Sponsored by National High Technology Research and Development Plan of China(2007AA04Z194)
文摘A 1∶2.5 scale tundish model was set up in laboratory for a six-strand billet continuous casting tundish with different configurations to investigate fluid flow characteristics under different operational conditions by measuring residence time distribution curves.It was found that minimum residence time,maximum concentration time and average residence time of the three strands on the same side of the tundish with the former configuration under normal operation,that is,six strands were open,were small and non-uniform and the tundish had large dead volume fraction.Vortexes easily formed on the liquid surface in the pouring zone of the tundish.The fluid flow characteristics in the tundish with the optimal turbulence inhibitor and baffles were improved and became less non-uniform among the strands.Vortexes were not found on the pouring zone surface in the optimal tundish.For non-normal operation,that is,one strand was close,it was important to choose which strand to be closed for maintaining flow characteristics of the rest two strands.It was found from this investigation that fluid flow characteristics in the optimal configuration tundish with closing strand 2 were better than those with closing strand 3 on the same side.
文摘Based on turbulent theory, a 3D coupled model of fluid flow and solidification was built using finite difference method and used to study the influence of superheating degree and casting speed on fluid flow and solidification, analyze the interaction between shell and molten steel, and compare the temperature distribution under different technological conditions. The results indicate that high superheating degree can lengthen the liquid-core depth and make the crack and breakout possible, so suitable superheating should be controlled within 35℃ according to the simulation results. Casting speed which is one of the most important technological parameters of improving production rate, should be controlled between 0. 85 m/min and 1.05 m/min and the caster has great potential in the improvement of blank quality.
文摘A conventional turbulence inhibitor is compared with a swirling chamber from the points of view of fluid flow and removal rate of inclusion in the tundish. Comparing the RTD curves, inclusion removals, and the streamlines in water model experiments, it can be found that the tundish equipped with a swirling chamber has a great effect on improving the flow field, and the floatation rate of inclusion is higher than the tundish with a turbulence inhibitor. Because of the introduction of the swirling chamber, the flow field and inclusion removal in a two-strand swirling flow tundish are asymmetrical. Rotating the inlet direction of swirling chamber 60 degree is a good strategy to improve the asymmetrical flow field.
基金Project supported by the Science Project of Harbin City(No. H2001-12)the Youth Foundation of School of Municipal and Environmental Engineering in Harbin Institute of Technology(No. 01306914).
文摘The degradation of formaldehyde gas was studied using UV/TiO2/O3 process under the condition of continuous flow mode. The effects of humidity, initial formaldehyde concentration, residence time and ozone adding amount on degradation of formaldehyde gas were investigated. The experimental results indicated that the combination of ozonation with photocatalytic oxidation on the degradation of formaldehyde showed a synergetic action, e.g,, it could considerably increase decomposing of formaldehyde. The degradation efficiency of formaldehyde was between 73.6% and 79.4% while the initial concentration in the range of 1.84--24 mg/m^3 by O3/TiO2flJV process. The optimal humidity was about 50% in UV/TiO2/O3 processs and degradation of formaldehyde increases from 39.0% to 94.1% when the ozone content increased from 0 to 141 mg/m^3. Furthermore, the kinetics of formaldehyde degradation reaction could be described by Langmuir-Hinshelwood model. The rate constant k of 46.72 mg/（m^3.min） and Langmuir adsorption coefficient K of 0.0268 m^3/mg were obtained.
基金Sponsored by National Natural Science Foundation of China(51210007,51004029)
文摘An Eulerian-Eulerian two-fluid model was developed to study the vortex flow inside a slab continuous casting mold with argon gas injection. Interracial momentum transfer that accommodated various interracial forces including drag force, lift force, virtual mass force, and turbulent dispersion force was considered. Predicted results agree well vaith experimental measurements of the water model in two-phase flow pattern and vortex flow structures. Three typical flow patterns with different argon steel ratios （ASRs） have been obtained： ＂double roll＂, ＂three roll＂, and ＂single roll＂. The flow pattern inside the mold alternates among the three types or it may attain some intermedi ate condition. With increasing ASR, the positions of vortices move from the submerged entry nozzle to the narrow face of the mold, and the sizes of vortices are reduced gradually. The rotating directions of vortices are all from high velocity area to low velocity area. Two mechanisms of vortex formation on the top surface have been suggested, i. e. , congruous shear flow and incongruous shear flow.
文摘The magnetic,heat transfer and flow phenomenon occurring in the continuous casting process under the mold electromagnetic stirring was further analyzed by solving the 3-D electromagnetic field mathematical model and flow solidification model with finite element method and finite volume method,respectively.The results indicate that the solidified shell thickness located in the effective stirring region fluctuates because of the unsteady scouring under the mold electromagnetic stirring.The maximum rotational velocity is a key parameter to the solidification of the billet when controlling the stirring intensity.When the rotational velocity reaches 0.32 m/s,the mush zone enlarges significantly and the solidification rate is further accelerated.The number of vortexes in the lower recirculation zone is not only two and depends on the stirring parameters.Besides,the secondary flow is closely associated with the solidification.Compared with the results of the model ignoring the influence of solidification on the flow of molten steel,the flow pattern within the lower recirculation region changes dramatically,and thus a coupling analysis of the flow,heat transfer,and solidification is essential when simulating the electromagnetic continuous casting process.
基金This work was financially supported by the National Natural Science Foundation of China （No. 51574083） and the Program of Introducing Talents of Discipline to Universities （The 111 Project of China, No. B07015）. The authors would also like to thank the referees for their work which has contributed to this paper.
文摘A three-dimensional mathematical model was established to investigate the behavior of molten steel flow and steel/slag interface with different processes and electromagnetic parameters under two different static magnetic field configurations [ruler-type electromagnetic brake （EMBr ruler） and vertical electromagnetic brake （V-EMBr）] in a continuous casting mold. The results showed that the brake effect of EMBr ruler is significantly influenced by its configuration parameters, the distance between the pole and bottom of the submerged entry nozzle （SEN）, and the port angle of the SEN outlet; therefore, it is not helpful to depress the diffusion of jet flow along the thickness direction of mold. For a constant SEN depth and port angle, there is a reasonable pole position （P = 0 mm） where the pole simultaneously covers three key zones, i.e., the jet flow impact zone and the upward and downward backflow zones. For V-EMBr, the magnetic field can simultaneously cover the three key zones and depress the diffusion of jet flow along the casting and thickness directions of the mold. Both the meniscus height and the impact intensity of the jet flow can be obviously depressed by V-EMBr even if the SEN depth and port angle have changed in the continuous casting process.
基金Item Sponsored by National Natural Science Foundation of China (50674020)Program for New Century Excellent Talents in University (NCET-04-0285)
文摘The fluid flow and the interfacial phenomenon of slag and metal in tundish with gas blowing were studied with mathematical and physical modeling, and the effects of gas flowrate, the placement of porous beam for the generation of bubbles, and the combination of flow control devices on the flow and slag-metal interface were investigated. The results show that the position of gas bubbling has a significant effect on the flow in tundish, and the placement of porous beam and gas flowrate are the two main factors affecting the entrapment of slag in tundish. The closer the porous beam to the weir, the more reasonable is the flow, which is in favor of the control of slag entrapment in tundish.
基金financially supported by the National High Technical Research and Development Programme of China (No. 2009AA03Z530)the National Natural Science Foundation of China and Shanghai Baosteel (No. 50834010)+3 种基金the National Natural Science Foundation of China (Nos. 51174058, 51104047 and 51004035)111 Project (No. B07015)the Fundamental Research Funds for the Central Universities(No. N100409007)the Doctor Startup Foundation of Liaoning Province (No.20111009)
文摘In order to weaken the bias flow in the submerged entry nozzle （SEN） with slide- gate, the rotating magnetic field was imposed. The numerical method was employed to investigate the effect of rotating magnetic field on the flow field in the SEN and the mold under different slide-gate opening ratios. Numerical results showed that when the slide-gate opening ratio is smaller than 100%, the flow field in the SEN and the mold become asymmetry and there is an obvious circulation under the slide- gate in the SEN. With increasing exciting current, the divergent angle of liquid steel at the SEN outlet increases, the impact depth of liquid steel in the mold decreases. With increasing slide-gate opening ratio, the impact depth of liquid steel in the mold increases and the required exciting current to weaken the bias flow should increase.
基金Item Sponsored by National Natural Science Foundation of China(51474059,51204042)Fundamental Research Funds for the Central Universities of China(N140205003,L1502006)
文摘The flow characteristics and inclusion removal in a ten-strand continuous casting tundish were investigated with physical modelling and industrial trials. The results show that, among the strands, the strand with the mini mum dimensionless time of the first appearance of tracer at the tundish exit appears to be the worst one for inclusion removal, while the strand with the maximum dimensionless mean residence time shows the best inclusion removal efficiency. The inclusion number decreases with increasing inclusion size for all strands. The inclusion number distri bution among strands is the same for all inclusion sizes and the descending order of inclusion number is basically con sistent with the ascending order of dimensionless mean residence time among individual strands. However, when the strand with the minimum dimensionless time of the first appearance of tracer at the tundish exit is not the same one with the minimum dimensionless mean residence time, the former seems to be inferior to the latter for inclusion re moval.
文摘The configuration of the tundish for a two-strand horizontal continuous caster was designed and optimized through water modeling. Three designs of the tundish were studied： the original tundish without any flow control devices, the tundish with a turbulence inhibitor at the bottom, and the tundish with an inlet launder and an inclined dam. The residence time, the location and size of the dead zone, and the fluid field pattern were investigated. At the same time, the asymmetry flow field and wavy inlet jet in the horizontal tundish were observed and the reasons for them were discussed. The results indicate that the mndish with an inlet launder and an inclined dam is the best of the three designs.
基金Item Sponsored by The Central Universities(N100409010)Project for Key Laboratory of Liaoning Province(LS2010065)"111 project" of Northeastern University,China(B07015)
文摘Sliding gate control system is widely employed in continuous casting process of steel to control flow rate of molten steel.As molten steel passes through a sliding gate,uneven flow develops.This will cause asymmetrical distribution of flow and temperature field in mold consequently,formation of vortex near the nozzle and entrapment of CC powder into the molten steel.etc,which have negative effect on process productivity and product quality.To suppress the uneven flow,electromagnetic swirling flow has been proposed to impose on the flow in submerged entry nozzle below the sliding gate.In this study the uneven flow developed by incompletely open sliding gate and the suppression of this uneven flow using electromagnetic swirling flow are numerically studied in round billet continuous casting of steel process.The improvement of the flow and temperature filed in the submerged entry nozzle and mold are investigated.It is found that:The uneven velocity in nozzle can be suppressed by electromagnetic swirling flow,and the flow and temperature field in mold be improved obviously;With the increase of electromagnetic swirling intensity,the effect of uneven flow can be almost completely suppressed.
