The electrochemical synthesis of urea by simultaneous reduction of nitrite and CO2 was performed in 0.02 mol·L-1 NaNO2 and 0.2 mol·L-1 NaHCO3 aqueous solutions at 925 Ag electrode in laboratory-scale experim...The electrochemical synthesis of urea by simultaneous reduction of nitrite and CO2 was performed in 0.02 mol·L-1 NaNO2 and 0.2 mol·L-1 NaHCO3 aqueous solutions at 925 Ag electrode in laboratory-scale experiments.The effect of several parameters, including electrolysis potential, temperature, and CO2 pressure, on urea formation was investigated.At the temperature of 293 K,CO2 pressure of 0.7 MPa, the electrolytic potential of -0.6 V, the current efficiency of urea formation reached 37%.Under the conditions of temperature of 273 K and electrolytic potential of -1.7 V, the current efficiency reached 26% under normal ambient pressure.Based on the relationship of current efficiency and formation of CO, NH3 and urea, a tentative reaction pathway was proposed.展开更多
文摘The electrochemical synthesis of urea by simultaneous reduction of nitrite and CO2 was performed in 0.02 mol·L-1 NaNO2 and 0.2 mol·L-1 NaHCO3 aqueous solutions at 925 Ag electrode in laboratory-scale experiments.The effect of several parameters, including electrolysis potential, temperature, and CO2 pressure, on urea formation was investigated.At the temperature of 293 K,CO2 pressure of 0.7 MPa, the electrolytic potential of -0.6 V, the current efficiency of urea formation reached 37%.Under the conditions of temperature of 273 K and electrolytic potential of -1.7 V, the current efficiency reached 26% under normal ambient pressure.Based on the relationship of current efficiency and formation of CO, NH3 and urea, a tentative reaction pathway was proposed.
