The H6P2W18O62/TiO2composite catalyst was prepared by the combination of nonionic surfactant C18H37(OCH2CH2)10OH(Brij-76)as the template and the sol-gel method.As-synthesized composite was characterized by FT-TR,SEM,N...The H6P2W18O62/TiO2composite catalyst was prepared by the combination of nonionic surfactant C18H37(OCH2CH2)10OH(Brij-76)as the template and the sol-gel method.As-synthesized composite was characterized by FT-TR,SEM,N2 absorption-desorption and NH3-TPD.The results showed that the composite H6P2W18O62/TiO2 was mesoporous material(ca.3.3 nm),and large surface area(99.78 m2/g).Additionally,the aggregation of TiO2 particles was effectively inhibited,and the surface acidity was increased substantially.The photocatalytic elimination of monochlorobenzene was used as model reaction to evaluate the photocatalytic activity of the composite catalyst under visible light separately.Photocatalytic experimental results showed that the composite H6P2W18O62/TiO2 can effectively degradate monochlorobenzene.展开更多
目的合成环己酮3-氯-1,2-丙二醇缩酮。方法采用浸渍法制备了H6P2W18O62/TiO2-SiO2催化剂,并采用FT-IR、XRD、SEM对其进行了表征。以环己酮和3-氯-1,2-丙二醇为原料,催化合成环己酮3-氯-1,2-丙二醇缩酮,采用FT-IR、1 H NMR、13 C NMR等...目的合成环己酮3-氯-1,2-丙二醇缩酮。方法采用浸渍法制备了H6P2W18O62/TiO2-SiO2催化剂,并采用FT-IR、XRD、SEM对其进行了表征。以环己酮和3-氯-1,2-丙二醇为原料,催化合成环己酮3-氯-1,2-丙二醇缩酮,采用FT-IR、1 H NMR、13 C NMR等表征手段来分析合成产物为环己酮3-氯-1,2-丙二醇缩酮。结果在酮醇摩尔比为1∶1.4,带水剂环己烷用量8mL,催化剂用量为反应物总质量的2.0%,反应时间1.0h的条件下,缩酮收率可达85.0%。催化剂重复使用5次后收率有72.6%。结论 H6P2W18O62/TiO2-SiO2催化剂对合成环己酮3-氯-1,2-丙二醇缩酮不仅反应时间短,催化剂用量少,而且产品收率高。展开更多
文摘The H6P2W18O62/TiO2composite catalyst was prepared by the combination of nonionic surfactant C18H37(OCH2CH2)10OH(Brij-76)as the template and the sol-gel method.As-synthesized composite was characterized by FT-TR,SEM,N2 absorption-desorption and NH3-TPD.The results showed that the composite H6P2W18O62/TiO2 was mesoporous material(ca.3.3 nm),and large surface area(99.78 m2/g).Additionally,the aggregation of TiO2 particles was effectively inhibited,and the surface acidity was increased substantially.The photocatalytic elimination of monochlorobenzene was used as model reaction to evaluate the photocatalytic activity of the composite catalyst under visible light separately.Photocatalytic experimental results showed that the composite H6P2W18O62/TiO2 can effectively degradate monochlorobenzene.
基金2013年国家级大学生创新创业训练计划项目(201313256001)湖北师范学院硕士研究生创新科研基金项目(1051320130216)+1 种基金National Undergraduate Training Programs for Innovation and Entrepreneurship(201313256001)Postgraduate Innovation Scientific Research Foundation of Hubei Normal University(1051320130216)
文摘目的合成环己酮3-氯-1,2-丙二醇缩酮。方法采用浸渍法制备了H6P2W18O62/TiO2-SiO2催化剂,并采用FT-IR、XRD、SEM对其进行了表征。以环己酮和3-氯-1,2-丙二醇为原料,催化合成环己酮3-氯-1,2-丙二醇缩酮,采用FT-IR、1 H NMR、13 C NMR等表征手段来分析合成产物为环己酮3-氯-1,2-丙二醇缩酮。结果在酮醇摩尔比为1∶1.4,带水剂环己烷用量8mL,催化剂用量为反应物总质量的2.0%,反应时间1.0h的条件下,缩酮收率可达85.0%。催化剂重复使用5次后收率有72.6%。结论 H6P2W18O62/TiO2-SiO2催化剂对合成环己酮3-氯-1,2-丙二醇缩酮不仅反应时间短,催化剂用量少,而且产品收率高。
