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USY负载Dawson型磷钨酸催化合成乙酸正丁酯 被引量:1
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作者 伍金平 曹小华 李美丹 《化学工程》 CAS CSCD 北大核心 2019年第12期27-32,共6页
以n(Si)/n(Al)比为1∶2的USY为载体,通过浸渍法制备出30%H6P2W18O62/USY催化剂。采用FT-IR,XRD,BET,SEM和EDS表征系列测试方法对催化剂进行表征。结果表明:磷钨酸均匀地分散在USY载体上,且保持Dawson结构不变,负载后催化剂的比表面积明... 以n(Si)/n(Al)比为1∶2的USY为载体,通过浸渍法制备出30%H6P2W18O62/USY催化剂。采用FT-IR,XRD,BET,SEM和EDS表征系列测试方法对催化剂进行表征。结果表明:磷钨酸均匀地分散在USY载体上,且保持Dawson结构不变,负载后催化剂的比表面积明显增大。用单因素实验探索反应温度、反应时间、催化剂用量、醇酸摩尔比对酯收率的影响。结果表明:当正丁醇用量为18.4 mL,30%H6P2W18O62/USY用量为0.6 g(占原料质量分数为2.89%),n(正丁醇)/n(乙酸)为2∶1,120℃回馏反应2.0 h,酯化率达到88.38%。在优化条件下,催化剂重复套用6次,酯化率仍有78.44%。 展开更多
关键词 USY 30%H6P2W18O62/USY 负载型磷钨酸催化剂 乙酸正丁酯 绿色催化
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CUSUM control charts based on likelihood ratio for preliminary analysis 被引量:3
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作者 Yi DAI Zhao-jun WANG Chang-liang ZOU 《Science China Mathematics》 SCIE 2007年第1期47-62,共16页
To detect and estimate a shift in either the mean and the deviation or both for the preliminary analysis, the statistical process control (SPC) tool, the control chart based on the likelihood ratio test (LRT), is the ... To detect and estimate a shift in either the mean and the deviation or both for the preliminary analysis, the statistical process control (SPC) tool, the control chart based on the likelihood ratio test (LRT), is the most popular method. Sullivan and woodall pointed out the test statistic lrt(n1, n2) is approximately distributed as x2(2) as the sample size n,n1 and n2 are very large, and the value of n1 = 2,3,..., n - 2 and that of n2 = n - n1. So it is inevitable that n1 or n2 is not large. In this paper the limit distribution of lrt(n1, n2) for fixed n1 or n2 is figured out, and the exactly analytic formulae for evaluating the expectation and the variance of the limit distribution are also obtained. In addition, the properties of the standardized likelihood ratio statistic slr(n1, n) are discussed in this paper. Although slr(n1, n) contains the most important information, slr(i, n)(i≠n1) also contains lots of information. The cumulative sum (CUSUM) control chart can obtain more information in this condition. So we propose two CUSUM control charts based on the likelihood ratio statistics for the preliminary analysis on the individual observations. One focuses on detecting the shifts in location in the historical data and the other is more general in detecting a shift in either the location and the scale or both. Moreover, the simulated results show that the proposed two control charts are, respectively, superior to their competitors not only in the detection of the sustained shifts but also in the detection of some other out-of-control situations considered in this paper. 展开更多
关键词 preliminary analysis false alarm probability CUSUM chart likelihood ratio test 62p30
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A random effects generalized linear model for reliability compositive evaluation 被引量:2
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作者 ZHAO Hui YU Dan 《Science China Mathematics》 SCIE 2009年第10期2218-2226,共9页
This paper first proposes a random effects generalized linear model to evaluate the storage life of one kind of high reliable and small sample-sized products by combining multi-sources information of products coming f... This paper first proposes a random effects generalized linear model to evaluate the storage life of one kind of high reliable and small sample-sized products by combining multi-sources information of products coming from the same population but stored at different environments. The relevant algorithms are also provided. Simulation results manifest the soundness and effectiveness of the proposed model. 展开更多
关键词 success-failure life test “case I” interval censored data Weibull distribution random effects complementary log-log link function 62N01 62p30
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多机场动态地面等待问题中起降能力的概率更新策略 被引量:5
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作者 李松娜 周杰 《四川大学学报(自然科学版)》 CAS CSCD 北大核心 2013年第5期923-926,共4页
Vranas等人提出了一种多机场地面等待随机动态模型,其关键输入参数是机场当天的各种起降能力以及相应场景发生的概率.但因其仅简单假设预设的几种场景之一必定发生而不适合实际起降能力与预设值均不相同的情形.本文给出了两种动态概率... Vranas等人提出了一种多机场地面等待随机动态模型,其关键输入参数是机场当天的各种起降能力以及相应场景发生的概率.但因其仅简单假设预设的几种场景之一必定发生而不适合实际起降能力与预设值均不相同的情形.本文给出了两种动态概率更新策略,解决了实际起降能力与预设值均不符时的概率更新问题,使模型的适用范围更广. 展开更多
关键词 空中交通流量管理 地面等待策略 随机动态模型
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