Li_(6)ZnO_(4)was chemically modified by nickel addition,in order to develop different compositions of the solid solution Li_(6)Zn_(1-x)Ni_(x)O_(4).These materials were evaluated bifunctionally;analyzing their CO_(2)ca...Li_(6)ZnO_(4)was chemically modified by nickel addition,in order to develop different compositions of the solid solution Li_(6)Zn_(1-x)Ni_(x)O_(4).These materials were evaluated bifunctionally;analyzing their CO_(2)capture performances,aswell as on their catalytic properties for H_(2)production via dry reforming of methane(DRM).The crystal structures of Li_(6)Zn_(1-x)Ni_(x)O_(4)solid solution samples were determined through X-ray diffraction,which confirmed the integration of nickel ions up to a concentration around 20 mol%,meanwhile beyond this value,a secondary phase was detected.These results were supported by XPS and TEM analyses.Then,dynamic and isothermal thermogravimetric analyses of CO_(2)capture revealed that Li_(6)Zn_(1-x)Ni_(x)O_(4)solid solution samples exhibited good CO_(2)chemisorption efficiencies,similarly to the pristine Li_(6)ZnO_(4)chemisorption trends observed.Moreover,a kinetic analysis of CO_(2)isothermal chemisorptions,using the Avrami-Erofeev model,evidenced an increment of the constant rates as a function of the Ni content.Since Ni^(2+)ions incorporation did not reduce the CO_(2)capture efficiency and kinetics,the catalytic properties of thesematerialswere evaluated in the DRM process.Results demonstrated that nickel ions favored hydrogen(H_(2))production over the pristine Li_(6)ZnO_(4)phase,despite a second H2 production reaction was determined,methane decomposition.Thereby,Li_(6)Zn_(1-x)Ni_(x)O_(4)ceramics can be employed as bifunctional materials.展开更多
In the present experiment,fructose-1,6-diphosphate（FDP）and captopril（Cap）wereadded to the cold potassium cardioplegia solution and the levels of malondialdehyde（MDA）,cre-atine phosphokinase MB（CPK-MB）,thrombox...In the present experiment,fructose-1,6-diphosphate（FDP）and captopril（Cap）wereadded to the cold potassium cardioplegia solution and the levels of malondialdehyde（MDA）,cre-atine phosphokinase MB（CPK-MB）,thromboxane B（TXB<sub>2</sub>）and 6-keto-PGF<sub>1α</sub> in plasma weremeasured during open-heart surgery.Quantitative study of myocardial ultrastructure and obser-vation of cardiac resuscitation were also undertaken.The findings suggested that FDP,especiallywhen combined with Cap could significantly strengthen the protective effects of cold potassiumcardioplegia solution on ischemic myocardium.展开更多
Model of Casson nanofluid flow over a nonlinear shrinking surface is considered.Model of Tiwari and Das is applied to nanofluid comprising of sodium alginate with copper and silver.The governing nonlinear equations in...Model of Casson nanofluid flow over a nonlinear shrinking surface is considered.Model of Tiwari and Das is applied to nanofluid comprising of sodium alginate with copper and silver.The governing nonlinear equations incorporating the effects of the viscous dissipation are transformed into boundary value problems (BVPs) of ordinary differential equations (ODEs) by using appropriate similarity transformations.The resulting equations are converted into initial value problems (IVPs) using the shooting method which are then solved by Runge-Kutta method of fourth order.In order to determine the stability of the dual solutions obtained,stability analysis is performed and discovered that the first (second) solution is stable (unstable) and physically realizable (unrealizable).Both the thickness of the thermal boundary layer as well as temperature increase when the Casson parameter (β) is increased in the second solution.展开更多
The solution of the intermetallic phase and the homogenization of composition are important for Mg alloy biomaterials.A single-phase Mg-6Zn alloy with the average grain size of about 20μm was prepared by ECAP process...The solution of the intermetallic phase and the homogenization of composition are important for Mg alloy biomaterials.A single-phase Mg-6Zn alloy with the average grain size of about 20μm was prepared by ECAP processed for six passes at 320°C.It indicated that the ECAP could significantly promote the process of solid solution in Mg-Zn alloy.The results showed that complete dissolution of the intermetallic phase improved the corrosion resistance of Mg-6Zn alloy in 0.9%NaCl solution by turning the corrosion behavior into uniform corrosion and increased the hardness in combination with its smaller grain size.展开更多
溶质载体家族6成员6(solute carrier family 6 member 6,SLC6A6)是一种多通道膜蛋白,牛磺酸、γ-氨基丁酸(gamma-aminobutyric acid,GABA)和β-丙氨酸是SLC6A6的主要运输底物。SLC6A6的转录翻译可被多种转录因子直接或间接调控,其蛋白...溶质载体家族6成员6(solute carrier family 6 member 6,SLC6A6)是一种多通道膜蛋白,牛磺酸、γ-氨基丁酸(gamma-aminobutyric acid,GABA)和β-丙氨酸是SLC6A6的主要运输底物。SLC6A6的转录翻译可被多种转录因子直接或间接调控,其蛋白质活性还可通过磷酸化信号级联以及相关离子进行调节。SLC6A6还具有调控细胞增殖、分化、钙化和凋亡的功能。多项研究提示,在结直肠癌、肝细胞癌、乳腺癌等多种肿瘤中,SLC6A6表达异常与不良预后、细胞的增殖、侵袭转移及放化疗耐受相关。本文综述了SLC6A6的结构与调控特点,并重点聚焦其在肿瘤中的作用机制及其作为潜在治疗靶点的可行性,旨在为其作为早期癌症诊断标志物与治疗靶点的转化研究提供依据,同时指出了当前证据的局限性与未来研究方向。展开更多
In this letter, the φ^6 ＋ φ^5 model in （D ＋ 1） dimensions can be solved by a truncated series method. A series of solitary solutions of the φ^6 ＋ φ^5 model in （D ＋ 1） dimensions have be obtained.
Time-resolved IR absorption spectroscopy has been used to atudy the photochemistry of W(CO)_6 in cyclohexane, carbon tetrachloride, and the mixture of carbon tetrachloride and cyelohexane. The reastion of photolytical...Time-resolved IR absorption spectroscopy has been used to atudy the photochemistry of W(CO)_6 in cyclohexane, carbon tetrachloride, and the mixture of carbon tetrachloride and cyelohexane. The reastion of photolytically generated W(CO)_5. C_6H_(12) with CCl_4 was investigated. An intermediate with a lifetime of about 0.5ms, presumably attributed as W(GO)_5.CCl_4, was first observed.展开更多
AIthough IP vóhas been de veloped for along time,is real large-scale deploymentand application started just a few yearsago.Presently,a bt of countries ha veestablis hed ther experimental IPvónetworks,such as...AIthough IP vóhas been de veloped for along time,is real large-scale deploymentand application started just a few yearsago.Presently,a bt of countries ha veestablis hed ther experimental IPvónetworks,such as the 6Bone and the 6lnit.Some networkcarriers,such asⅢand KDDI in Japan,begin toprovide commercial IPvóacces s services.Chinahas also es tablished its experimental network,the 6TNET,and is planning the construction ofabrand-new IPv6 network,the China NextGeneration Internet(CNGI).展开更多
No. 6 East tin deposit in the Songshujiao orefield, Gejiu, is characterized by one-stage hydrothermal activity and monotonous country rocks. The authors selected this deposit and used the multivariate statistical anal...No. 6 East tin deposit in the Songshujiao orefield, Gejiu, is characterized by one-stage hydrothermal activity and monotonous country rocks. The authors selected this deposit and used the multivariate statistical analysis to study the types of association of main ore-forming elements at different temperatures and pressures and their distribution in the deposit. On that basis combined with the structural analysis of the deposit, the recto-geochemical features of No.6 East tin deposit have been revealed and the direction and channel of migration of the ore solutions in faults and the deposit have been deduced. This research can appropriately elucidate the control of faults on the migration of ore solutions and the sites where ore solutions are dispersed and accumulated, thus providing the theoretical basis for the prediction of hydrothermal deposits in question.展开更多
Znx</sub>Cd1-x</sub>S solid solutions with controlled morphology have been successfully synthe-sized by a facile solution-phase method. The prepared samples were characterized by X-ray powder diffraction (...Znx</sub>Cd1-x</sub>S solid solutions with controlled morphology have been successfully synthe-sized by a facile solution-phase method. The prepared samples were characterized by X-ray powder diffraction (XRD), UV-vis diffuse reflectance spectra, X-ray photoelec-tron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission elec-tron microscopy (TEM). The photocatalytic activity of Zn<sub>x</sub>Cd<sub>1-x</sub>S was evaluated in the 2,4,6-trichlorophenol (TCP) degradation and mineralization in aqueous solution under direct solar light illumination. The experiment demonstrated that TCP was effectively degraded by more than 95% with 120 min. The results show that ZnS with Cd doping (Znx</sub>Cd1-x</sub>S) exhibits the much stronger visible light adsorption than that of pure ZnS, the light adsorption increasing as the Cd<sup>2+</sup> doping amount. These results indicate that Cd doping into a ZnS crystal lattice can result in the shift of the valence band of ZnS to a positive direction. It may lead to its higher oxidative ability than pure ZnS, which is important for organic pollutant degradation under solar light irradiation. Further-more, the photocatalytic activity studies reveal that the prepared Znx</sub>Cd1-x</sub>S nanostructures exhibit an excellent photocatalytic performance, degrading rapidly the aqueous 2,4,6-trichlorophenol solution under solar light irradiation. These results sug-gest that Znx</sub>Cd1-x</sub>S nanostructure will be a promising candidate of photocatalyst working in solar light range.展开更多
Star-shaped six-arm polymers with hexaaza[2_(6)]orthoparacyclophane core and arms of block copolymers of poly-2-ethyl-5,6-dihydrooxazine with poly-2-isopropyl-5,6-dihydrooxazine were synthesized successfully using cat...Star-shaped six-arm polymers with hexaaza[2_(6)]orthoparacyclophane core and arms of block copolymers of poly-2-ethyl-5,6-dihydrooxazine with poly-2-isopropyl-5,6-dihydrooxazine were synthesized successfully using cationic ring-opening polymerization.The ratio of blocks,the order of their attachment to the core,and arm length were varied.Conformation of synthesized stars was determined by methods of molecular hydrodynamics and optics.It has been shown that star-shaped molecules were characterized by high intramolecular density,and the arm folding increased with their lengthening.The influence of the structure of block copolymers and their molar mass on the critical micelle concentration has been established.Complexes of synthesized star-shaped block copolymers with curcumin were obtained and the efficient binding of curcumin to polymer molecules was demonstrated.The behavior of the aqueous solutions of the prepared polymer stars and their complexes with curcumin was investigated by light scattering and turbidimetry methods.The influence of the structure and molar mass of star polymers on their thermoresponsiveness and the phase separation temperatures in aqueous solutions was analyzed.A slight increase in the phase separation temperature was found on passage from polymer solutions to solutions of polymer complexes with hydrophobic curcumin.展开更多
China still use sketch maps as control devices that guarantees consistency and accuracy of population counting in previous census.Although the rapid advancement of geospatial technologies provides many possible soluti...China still use sketch maps as control devices that guarantees consistency and accuracy of population counting in previous census.Although the rapid advancement of geospatial technologies provides many possible solutions of digital census mapping,existing researches do not answer which solution is suitable to China.Subject to many constraints originated from characteristics of China,a practical solution of census mapping based on remote sensing imagery and auxiliary geographic information was proposed and proved to be feasible through evaluation analysis and a three-stage pilot study.Imagery with 2.5 meters and higher resolution,innovative workflow of census areas delineation,easy-to-use census mapping software packages and training organization all together provide the all-around supports for the 2010 rounded census (the 6th census) mapping activities.A digital census geographic framework detailed at the level of enumeration area was established in the 2010 rounded census which fills in the gaps in the field of modern geospatial census in China.The spatially referenced digital census database,especially the detailed census units,is of great value in successive census,sampling survey and many other census-related fields.Future work including quality evaluation of census areas,census mapping solution in the Tibet Autonomous Region are also discussed.展开更多
This study is focused on a steady dissipative layer, which is generated by Marangoni convection flow over the surface resulted from an imposed temperature gradient, coupled with buoyancy effects due to gravity and ext...This study is focused on a steady dissipative layer, which is generated by Marangoni convection flow over the surface resulted from an imposed temperature gradient, coupled with buoyancy effects due to gravity and external pressure. A model is proposed with Marangoni condition in the boundary conditions at the interface. The similarity equations are determined and approximate analytical solutions are obtained by an efficient transformation, asymptotic expansion and Pade approximant technique. For the cases that buoyancy force is favorable or unfavor-able to Marangoni flow, the features of flow and temperature fields are investigated in terms of Marangoni mixed convection parameter and Prantl number.展开更多
基金This work was carried out in the framework of PAPIIT-UNAM(IN-205823)project.
文摘Li_(6)ZnO_(4)was chemically modified by nickel addition,in order to develop different compositions of the solid solution Li_(6)Zn_(1-x)Ni_(x)O_(4).These materials were evaluated bifunctionally;analyzing their CO_(2)capture performances,aswell as on their catalytic properties for H_(2)production via dry reforming of methane(DRM).The crystal structures of Li_(6)Zn_(1-x)Ni_(x)O_(4)solid solution samples were determined through X-ray diffraction,which confirmed the integration of nickel ions up to a concentration around 20 mol%,meanwhile beyond this value,a secondary phase was detected.These results were supported by XPS and TEM analyses.Then,dynamic and isothermal thermogravimetric analyses of CO_(2)capture revealed that Li_(6)Zn_(1-x)Ni_(x)O_(4)solid solution samples exhibited good CO_(2)chemisorption efficiencies,similarly to the pristine Li_(6)ZnO_(4)chemisorption trends observed.Moreover,a kinetic analysis of CO_(2)isothermal chemisorptions,using the Avrami-Erofeev model,evidenced an increment of the constant rates as a function of the Ni content.Since Ni^(2+)ions incorporation did not reduce the CO_(2)capture efficiency and kinetics,the catalytic properties of thesematerialswere evaluated in the DRM process.Results demonstrated that nickel ions favored hydrogen(H_(2))production over the pristine Li_(6)ZnO_(4)phase,despite a second H2 production reaction was determined,methane decomposition.Thereby,Li_(6)Zn_(1-x)Ni_(x)O_(4)ceramics can be employed as bifunctional materials.
基金The project was supported by the National Natural Science Foundation of China No.3880772
文摘In the present experiment,fructose-1,6-diphosphate（FDP）and captopril（Cap）wereadded to the cold potassium cardioplegia solution and the levels of malondialdehyde（MDA）,cre-atine phosphokinase MB（CPK-MB）,thromboxane B（TXB<sub>2</sub>）and 6-keto-PGF<sub>1α</sub> in plasma weremeasured during open-heart surgery.Quantitative study of myocardial ultrastructure and obser-vation of cardiac resuscitation were also undertaken.The findings suggested that FDP,especiallywhen combined with Cap could significantly strengthen the protective effects of cold potassiumcardioplegia solution on ischemic myocardium.
基金Universiti Utara Malaysia (UUM) for the moral and financial support in conducting this research
文摘Model of Casson nanofluid flow over a nonlinear shrinking surface is considered.Model of Tiwari and Das is applied to nanofluid comprising of sodium alginate with copper and silver.The governing nonlinear equations incorporating the effects of the viscous dissipation are transformed into boundary value problems (BVPs) of ordinary differential equations (ODEs) by using appropriate similarity transformations.The resulting equations are converted into initial value problems (IVPs) using the shooting method which are then solved by Runge-Kutta method of fourth order.In order to determine the stability of the dual solutions obtained,stability analysis is performed and discovered that the first (second) solution is stable (unstable) and physically realizable (unrealizable).Both the thickness of the thermal boundary layer as well as temperature increase when the Casson parameter (β) is increased in the second solution.
基金The authors gratefully acknowledge financial support from the National Natural Science Foundation of China(Grant no.51301151)Jiangsu Province Natural Science Foundation of China(Grant nos.BK20130447 and BK20160869).
文摘The solution of the intermetallic phase and the homogenization of composition are important for Mg alloy biomaterials.A single-phase Mg-6Zn alloy with the average grain size of about 20μm was prepared by ECAP processed for six passes at 320°C.It indicated that the ECAP could significantly promote the process of solid solution in Mg-Zn alloy.The results showed that complete dissolution of the intermetallic phase improved the corrosion resistance of Mg-6Zn alloy in 0.9%NaCl solution by turning the corrosion behavior into uniform corrosion and increased the hardness in combination with its smaller grain size.
文摘溶质载体家族6成员6(solute carrier family 6 member 6,SLC6A6)是一种多通道膜蛋白,牛磺酸、γ-氨基丁酸(gamma-aminobutyric acid,GABA)和β-丙氨酸是SLC6A6的主要运输底物。SLC6A6的转录翻译可被多种转录因子直接或间接调控,其蛋白质活性还可通过磷酸化信号级联以及相关离子进行调节。SLC6A6还具有调控细胞增殖、分化、钙化和凋亡的功能。多项研究提示,在结直肠癌、肝细胞癌、乳腺癌等多种肿瘤中,SLC6A6表达异常与不良预后、细胞的增殖、侵袭转移及放化疗耐受相关。本文综述了SLC6A6的结构与调控特点,并重点聚焦其在肿瘤中的作用机制及其作为潜在治疗靶点的可行性,旨在为其作为早期癌症诊断标志物与治疗靶点的转化研究提供依据,同时指出了当前证据的局限性与未来研究方向。
基金The project supported by National Natural Science Foundation of China under Grant No. 10575026.Acknowledgments The author thanks Prof. S.Y. Lou for helpful discussions.
文摘In this letter, the φ^6 ＋ φ^5 model in （D ＋ 1） dimensions can be solved by a truncated series method. A series of solitary solutions of the φ^6 ＋ φ^5 model in （D ＋ 1） dimensions have be obtained.
文摘Time-resolved IR absorption spectroscopy has been used to atudy the photochemistry of W(CO)_6 in cyclohexane, carbon tetrachloride, and the mixture of carbon tetrachloride and cyelohexane. The reastion of photolytically generated W(CO)_5. C_6H_(12) with CCl_4 was investigated. An intermediate with a lifetime of about 0.5ms, presumably attributed as W(GO)_5.CCl_4, was first observed.
文摘AIthough IP vóhas been de veloped for along time,is real large-scale deploymentand application started just a few yearsago.Presently,a bt of countries ha veestablis hed ther experimental IPvónetworks,such as the 6Bone and the 6lnit.Some networkcarriers,such asⅢand KDDI in Japan,begin toprovide commercial IPvóacces s services.Chinahas also es tablished its experimental network,the 6TNET,and is planning the construction ofabrand-new IPv6 network,the China NextGeneration Internet(CNGI).
文摘No. 6 East tin deposit in the Songshujiao orefield, Gejiu, is characterized by one-stage hydrothermal activity and monotonous country rocks. The authors selected this deposit and used the multivariate statistical analysis to study the types of association of main ore-forming elements at different temperatures and pressures and their distribution in the deposit. On that basis combined with the structural analysis of the deposit, the recto-geochemical features of No.6 East tin deposit have been revealed and the direction and channel of migration of the ore solutions in faults and the deposit have been deduced. This research can appropriately elucidate the control of faults on the migration of ore solutions and the sites where ore solutions are dispersed and accumulated, thus providing the theoretical basis for the prediction of hydrothermal deposits in question.
文摘Znx</sub>Cd1-x</sub>S solid solutions with controlled morphology have been successfully synthe-sized by a facile solution-phase method. The prepared samples were characterized by X-ray powder diffraction (XRD), UV-vis diffuse reflectance spectra, X-ray photoelec-tron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission elec-tron microscopy (TEM). The photocatalytic activity of Zn<sub>x</sub>Cd<sub>1-x</sub>S was evaluated in the 2,4,6-trichlorophenol (TCP) degradation and mineralization in aqueous solution under direct solar light illumination. The experiment demonstrated that TCP was effectively degraded by more than 95% with 120 min. The results show that ZnS with Cd doping (Znx</sub>Cd1-x</sub>S) exhibits the much stronger visible light adsorption than that of pure ZnS, the light adsorption increasing as the Cd<sup>2+</sup> doping amount. These results indicate that Cd doping into a ZnS crystal lattice can result in the shift of the valence band of ZnS to a positive direction. It may lead to its higher oxidative ability than pure ZnS, which is important for organic pollutant degradation under solar light irradiation. Further-more, the photocatalytic activity studies reveal that the prepared Znx</sub>Cd1-x</sub>S nanostructures exhibit an excellent photocatalytic performance, degrading rapidly the aqueous 2,4,6-trichlorophenol solution under solar light irradiation. These results sug-gest that Znx</sub>Cd1-x</sub>S nanostructure will be a promising candidate of photocatalyst working in solar light range.
基金financially supported by the Russian Science Foundation(No.23-13-00205)。
文摘Star-shaped six-arm polymers with hexaaza[2_(6)]orthoparacyclophane core and arms of block copolymers of poly-2-ethyl-5,6-dihydrooxazine with poly-2-isopropyl-5,6-dihydrooxazine were synthesized successfully using cationic ring-opening polymerization.The ratio of blocks,the order of their attachment to the core,and arm length were varied.Conformation of synthesized stars was determined by methods of molecular hydrodynamics and optics.It has been shown that star-shaped molecules were characterized by high intramolecular density,and the arm folding increased with their lengthening.The influence of the structure of block copolymers and their molar mass on the critical micelle concentration has been established.Complexes of synthesized star-shaped block copolymers with curcumin were obtained and the efficient binding of curcumin to polymer molecules was demonstrated.The behavior of the aqueous solutions of the prepared polymer stars and their complexes with curcumin was investigated by light scattering and turbidimetry methods.The influence of the structure and molar mass of star polymers on their thermoresponsiveness and the phase separation temperatures in aqueous solutions was analyzed.A slight increase in the phase separation temperature was found on passage from polymer solutions to solutions of polymer complexes with hydrophobic curcumin.
基金Under the auspices of National High Technology Research and Development Program of China(No.2006AA120105)National Natural Science Foundation of China(No.41001314)+1 种基金Youth Science Funds of State Key Laboratory of Resources and En-vironmental Information System(No.KA11040101)Chinese Academy of Sciences and National Science&Technology Pillar Pro-gram(No.2012BAI32B07)
文摘China still use sketch maps as control devices that guarantees consistency and accuracy of population counting in previous census.Although the rapid advancement of geospatial technologies provides many possible solutions of digital census mapping,existing researches do not answer which solution is suitable to China.Subject to many constraints originated from characteristics of China,a practical solution of census mapping based on remote sensing imagery and auxiliary geographic information was proposed and proved to be feasible through evaluation analysis and a three-stage pilot study.Imagery with 2.5 meters and higher resolution,innovative workflow of census areas delineation,easy-to-use census mapping software packages and training organization all together provide the all-around supports for the 2010 rounded census (the 6th census) mapping activities.A digital census geographic framework detailed at the level of enumeration area was established in the 2010 rounded census which fills in the gaps in the field of modern geospatial census in China.The spatially referenced digital census database,especially the detailed census units,is of great value in successive census,sampling survey and many other census-related fields.Future work including quality evaluation of census areas,census mapping solution in the Tibet Autonomous Region are also discussed.
基金Supported by the National Natural Science Foundation of China(21206009)Funding Project for Academic Human Resources Development in Institutions of Higher Learning under the Jurisdiction of Beijing Municipality(PHR201107123)Program for Doctoral Fund in Beijing University of Civil Engineering and Architecture(101102307)
文摘This study is focused on a steady dissipative layer, which is generated by Marangoni convection flow over the surface resulted from an imposed temperature gradient, coupled with buoyancy effects due to gravity and external pressure. A model is proposed with Marangoni condition in the boundary conditions at the interface. The similarity equations are determined and approximate analytical solutions are obtained by an efficient transformation, asymptotic expansion and Pade approximant technique. For the cases that buoyancy force is favorable or unfavor-able to Marangoni flow, the features of flow and temperature fields are investigated in terms of Marangoni mixed convection parameter and Prantl number.
