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2.5-dimensional Voronoi numerical simulation method for migration of direct roof in a longwall face
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作者 Bin Yu Yong Li +2 位作者 Yang Tai Weibing Zhu Wenyang Zhang 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第9期5560-5579,共20页
The fracture and migration patterns of direct roofs play a critical role in excavation stability and mining pressure.However,current methods fail to capture the irregular three-dimensional(3D)behavior of these roofs.I... The fracture and migration patterns of direct roofs play a critical role in excavation stability and mining pressure.However,current methods fail to capture the irregular three-dimensional(3D)behavior of these roofs.In this study,the problem was solved by introducing an innovative 2.5-dimensional(2.5D)Voronoi numerical simulation method,dividing rock layers into 2.5D Voronoi blocks and developing cohesive element-based failure models,supported by a strain-softening HoekeBrown model.The method was applied to the 8311 working face in the Taishan Mine in China,and its accuracy was confirmed through physical experiments.The following conclusions were drawn.The first roof break typically followed an"O-X"pattern.The direct roof did not break randomly over time;instead,it followed three distinct scenarios:(1)A complete break of the direct roof occurred,followed by a sequential collapse(ScenarioⅠ).(2)Regional irregular stacking in one area was followed by sequential collapse in other zones(ScenarioⅡ).(3)The staged breakdown of the direct roof led to separate and sequential collapses on the left and right flanks(ScenarioⅢ).Scenario I was quite common during the 400 m advance of the working face and occurred five times.The fracture characteristics in Scenario I led to widespread pressure on the hydraulic supports in the middle of the working face.Finally,the direct roof from the working face towards the goaf area underwent phases of overhanging,hinging,and collapsing plates.After the first and periodic breaks,the basic roof formed stable hinged plate structures reinforced by overhanging plates and irregular accumulations of the direct roof. 展开更多
关键词 2.5-dimensional(2.5D)Voronoi Direct roof Migration law Longwall face
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A 2.5-dimensional Analytical Model of Cold Leveling for Plates with Transverse Wave Defects 被引量:5
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作者 Wei-hua CHEN Juan LIU +2 位作者 Zhen-shan CUI Ying-jie WANG Ying-rui WANG 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2015年第8期664-671,共8页
Waves occurring in cold-rolled plates or sheets can be divided into longitudinal and transverse waves. Classical leveling theories merely solve the problem of longitudinal waves, while no well accepted method can be e... Waves occurring in cold-rolled plates or sheets can be divided into longitudinal and transverse waves. Classical leveling theories merely solve the problem of longitudinal waves, while no well accepted method can be employed for transverse waves. In order to investigate the essential deformation law of leveling for plates with transverse waves, a 2.5-dimensional (2.5- D) analytical approach was proposed. In this model, the plate was transversely divided into some strips with equal width; the strips are considered to be in the state of plane strain and each group of adjacent strips are assumed to be deformation compatible under stress. After calculation, the bending deformation of each strip and the leveling effect of overall plate were obtained by comprehensNe consideration of various strips along with the width. Bending of roller is a main approach to eliminate the transverse waves, which is widely accepted by the industry, but the essential effect of bending of roller on the deformation of plates and the calculation of bending of roller are unknown. According to the 2.5-D analytical model, it can be found that, for plates, it is neutral plane offsetting and middle plane elongation or contraction under inner stress that can effectively improve plate shape. Taking double side waves as an example, the appropriate values of bending of roller were obtained by the 2.5-D analytical model related to different initial unevenness, which was applicable to the current on-line adjusting of bending of roller in rolling industry. 展开更多
关键词 plate leveling 2.5-dimensional analytical model transverse wave middle plane deformation
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Hyperverse, 5-Dimensional Gravity and Multiverses as Nested Gogberashvili Shells
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作者 Igor Yu. Potemine 《Journal of High Energy Physics, Gravitation and Cosmology》 CAS 2022年第4期983-989,共7页
We consider the Hyperverse as a collection of multiverses in 5-dimensional spacetime with gravitational constant G. Each multiverse in our simplified model is a bouquet of nested spherical Gogberashvili shells. If g&l... We consider the Hyperverse as a collection of multiverses in 5-dimensional spacetime with gravitational constant G. Each multiverse in our simplified model is a bouquet of nested spherical Gogberashvili shells. If g<sub>k</sub> is the gravitational constant of a thin shell S<sub>k</sub> and ε<sub>k</sub>, its thickness then G ~ ε<sub>k</sub>g<sub>k</sub>. The physical universe is supposed to be one of those shells inside the local nested bouquet called Local Multiverse. We relate this construction to Robinson-Trautman metrics describing expanding spacetimes with spherical gravitational waves. Supermassive astronomical black holes, located at cores of elliptic/spiral galaxies, are also conjecturally described within this theory. Our constructions are equally consistent with the modern theory of cosmological coupling. 展开更多
关键词 5-dimensional Gravity Black Hole MULTIVERSE Spherical Shell
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The Mass and Size of Photons in the 5-Dimensional Extended Space Model
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作者 V. A. Andreev D. Yu. Tsipenyuk 《Journal of Modern Physics》 2016年第11期1308-1315,共8页
We propose the generalization of Einstein’s special theory of relativity (STR). In our model, we use the (1 + 4)-dimensional space G, which is the extension of the (1 + 3)-dimensional Minkowski space M. As a fifth ad... We propose the generalization of Einstein’s special theory of relativity (STR). In our model, we use the (1 + 4)-dimensional space G, which is the extension of the (1 + 3)-dimensional Minkowski space M. As a fifth additional coordinate, the interval S is used. This value is constant under the usual Lorentz transformations in M, but it changes when the transformations in the extended space G are used. We call this model the Extended space model (ESM). From a physical point of view, our expansion means that processes in which the rest mass of the particles changes are acceptable now. In the ESM, gravity and electromagnetism are combined in one field. In the ESM, a photon can have a nonzero mass and this mass can be either positive or negative. It is also possible to establish in the frame of ESM connection between mass of a particle and its size. 展开更多
关键词 Photon MASS SIZE 5-dimensional Space Extended Space Model GRAVITATION Special Theory of Relativity
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The 5-dimensional model for electromagnetism and gravity
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作者 V. A. Andreev D. Yu. Tsipenyuk 《Natural Science》 2014年第4期248-253,共6页
The generalization of Einstein’s special theory of relativity (SRT) is proposed. In this model, the possibility of unification of scalar gravity and electromagnetism into a single unified field is considered. Formall... The generalization of Einstein’s special theory of relativity (SRT) is proposed. In this model, the possibility of unification of scalar gravity and electromagnetism into a single unified field is considered. Formally, the generalization of the SRT is that instead of (1+3)-dimensional Minkowski space the (1+4)-dimensional extension G is considered. As the fifth additional coordinate the interval S is used. This value is saved under the usual Lorentz transformations in Minkowski space M, but it changes when the transformations in the extended space G are used. We call this model the extended space model (ESM). From a physical point of view, our expansion means that processes in which the rest mass of the particles changes are acceptable now. If the rest mass of a particle does not change and the physical quantities do not depend on an additional variable S, then the electromagnetic and gravitational fields exist independently of each other. But if the rest mass is variable and there is a dependence on S, then these two fields are combined into a single unified field. In the extended space model a photon can have a nonzero mass and this mass can be either positive or negative. In this model the 5- vectors which components correspond to energy, pulse and mass of a particle are isotropic both for massive and massless particles. The rotations in the (1+4) dimensional extended space G can transform massive particles into massless and vice versa. 展开更多
关键词 GRAVITY Electromagnetism (1+4)-dimensional SPACE MASS of PHOTON NEGATIVE MASS
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Dynamic Behaviors of Localized Waves of the(2+1)-Dimensional Yu-Toda-Sasa-Fukuyama Equation
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作者 SUN Xiaoqing XIA Yarong +1 位作者 YAO Ruoxia WANG Weiqing 《应用数学》 北大核心 2026年第2期624-638,共15页
In this article,by employing the Hirota bilinear approach and the long wave limit method,we not only derive soliton solutions,lump solutions,and hybrid solutions for the(2+1)-dimensional Yu-Toda-Sasa-Fukuyama(YTSF)equ... In this article,by employing the Hirota bilinear approach and the long wave limit method,we not only derive soliton solutions,lump solutions,and hybrid solutions for the(2+1)-dimensional Yu-Toda-Sasa-Fukuyama(YTSF)equation,but also analyze the dynamical behaviors of nonlinear local wave propagation in shallow water.Firstly,based on the Hirota bilinear approach,one to four-order soliton solutions of the YTSF equation are obtained,and the effects of different parameters on the amplitude,propagation trajectory,and displacement of solitons are investigated.Secondly,using the long wave limit approach,one to three-order lump solutions and various physical quantities of the YTSF equation are derived.It is found that the real and imaginary parts of the parameter pi dominate the propagation trajectory and the shape of lump waves,respectively.Furthermore,we construct the hybrid solution for the YTSF equation,leading to the conclusion that the interaction between lumps and solitons constitutes an elastic collision.To intuitively understand the dynamic behaviors of these solutions,we conduct numerical simulations to present vivid three-dimensional visualizations. 展开更多
关键词 (2+1)-dimensional Yu-Toda-Sasa-Fukuyama equation Hirota bilinear approach Lump solutions Dynamic behaviors
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A multi-dimensional trust attestation solution in 5G-IoT
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作者 Xiangrong Li Yu Zhang +2 位作者 Haotian Zhu Yubo Wang Junjia Huang 《Digital Communications and Networks》 2025年第1期225-233,共9页
The core missions of IoT are to sense data,transmit data and give feedback to the real world based on the calculation of the sensed data.The trust of sensing source data and transmission network is extremely important... The core missions of IoT are to sense data,transmit data and give feedback to the real world based on the calculation of the sensed data.The trust of sensing source data and transmission network is extremely important to IoT security.5G-IoT with its low latency,wide connectivity and high-speed transmission extends the business scenarios of IoT,yet it also brings new challenges to trust proof solutions of IoT.Currently,there is a lack of efficient and reliable trust proof solutions for massive dynamically connected nodes,while the existing solutions have high computational complexity and can't adapt to time-sensitive services in 5G-IoT scenarios.In order to solve the above problems,this paper proposes an adaptive multi-dimensional trust proof solution.Firstly,the static and dynamic attributes of sensing nodes are metricized,and the historical interaction as well as the recommendation information are combined with the comprehensive metric of sensing nodes,and a multi-dimensional fine-grained trusted metric model is established in this paper.Then,based on the comprehensive metrics,the sensing nodes are logically grouped and assigned with service levels to achieve the screening and isolation of malicious nodes.At the same time,the proposed solution reduces the energy consumption of the metric process and optimizes the impact of real-time metrics on the interaction latency.Simulation experiments show that the solution can accurately and efficiently identify malicious nodes and effectively guarantee the safe and trustworthy operation of 5G-IoT nodes,while having a small impact on the latency of the 5G network. 展开更多
关键词 5G-IoT Trusted metrics Trust model
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Amorphous-to-crystalline transition-induced two-step thin film growth of quasi-one-dimensional penta-telluride ZrTe_(5)
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作者 Yi Shuang Yuta Saito +3 位作者 Shogo Hatayama Paul Fons Ando Daisuke Yuji Sutou 《Journal of Materials Science & Technology》 2025年第7期246-253,共8页
Quasi-one-dimensional(quasi-1D)van der Waals(vdWs)materials,such as ZrTe_(5),exhibit unique elec-trical properties and quantum phenomena,making them attractive for advanced electronic applications.However,large-scale ... Quasi-one-dimensional(quasi-1D)van der Waals(vdWs)materials,such as ZrTe_(5),exhibit unique elec-trical properties and quantum phenomena,making them attractive for advanced electronic applications.However,large-scale growth of ZrTe_(5) thin films presents challenges.We address this by employing sput-tering,a common semiconductor industry technique.The as-deposited ZrTe_(5) film is amorphous,and post-annealing induces a crystallization process akin to transition-metal dichalcogenides.Our study in-vestigates the electrical and optical properties during this amorphous-to-crystalline transition,reveal-ing insights into the underlying mechanism.This work contributes to the fundamental understanding of quasi-1D materials and introduces a scalable fabrication method for ZrTe_(5) which offers the possibility of fabricating unique future electronic and optical devices. 展开更多
关键词 QUASI-ONE-dimensional ZrTe_(5) Large-scale Thin film PHASE-CHANGE
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Application of CPML to truncate the open boundaries of cylindrical waveguides in 2.5-dimensional problems 被引量:1
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作者 WANG Yue WANG Jianguo ZHANG Dianhui 《Science in China(Series F)》 2005年第5期656-669,共14页
In order to solve the problem of truncating the open boundaries of cylindrical waveguides used in the simulation of high power microwave (HPM) sources, this paper studies the convolutional PML (CPML) in the cylind... In order to solve the problem of truncating the open boundaries of cylindrical waveguides used in the simulation of high power microwave (HPM) sources, this paper studies the convolutional PML (CPML) in the cylindrical coordinate system. The electromagnetic field's FDTD equations and the expressions of axis boundary conditions are presented. Numerical experiments are conducted to validate the equations and axis boundary conditions. The performance of CPML is simulated when it is used to truncate the cylindrical waveguides excited by the sources with different frequencies and modes in the 2.5-dimensional problems. Numerical results show that the maximum relative errors are all less than -90 dB. The CPML method is introduced in the 2.5-dimensional electromagnetic PIC software, and the relativistic backward wave oscillator is simulated by using this method. The results show that the property of CPML is much better than that of the Mur-type absorbing boundary condition when they are used to truncate the open boundaries of waveguides. The CPML is especially suitable for truncating the open boundaries of the dispersive waveguide devices in the simulation of HPM sources. 展开更多
关键词 convolutional perfectly matched layer FDTD 2-5-dimensional problem WAVEGUIDE backwardwave oscillator TRUNCATION particle simulation.
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基于CDK16/MYC探讨葛根芩连汤含药血清抑制糖酵解促进结直肠癌细胞5-氟尿嘧啶敏感性的作用机制
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作者 蔡蓉 王上 +3 位作者 程福晴 周燕萍 胡作为 李云海 《中国实验方剂学杂志》 北大核心 2026年第8期1-9,共9页
目的:基于细胞周期蛋白依赖性激酶16(CDK16)/MYC多效转录因子通路探究葛根芩连汤含药血清抑制糖酵解促进结直肠癌(CRC)5-氟尿嘧啶(5-FU)耐药细胞化疗敏感性的分子机制。方法:在(5%,10%,20%和30%)葛根芩连汤含药血清的干预下,运用细胞增... 目的:基于细胞周期蛋白依赖性激酶16(CDK16)/MYC多效转录因子通路探究葛根芩连汤含药血清抑制糖酵解促进结直肠癌(CRC)5-氟尿嘧啶(5-FU)耐药细胞化疗敏感性的分子机制。方法:在(5%,10%,20%和30%)葛根芩连汤含药血清的干预下,运用细胞增殖与活性检测(CCK-8)法检测葛根芩连汤对人结肠癌细胞HCT-116/5-FU细胞中5-FU敏感性的影响,选定后续5-FU和葛根芩连汤的实验浓度;采用5-乙炔基-2′-脱氧尿苷(EDU)染色和Annexin V-FITC/碘化丙啶(PI)双染法分别检测单独5-FU、单独葛根芩连汤及二者联合应用时HCT-116/5-FU细胞的增殖和凋亡水平变化,并用比色法测定葡萄糖消耗量、三磷酸腺苷(ATP)和乳酸产生的变化;蛋白免疫印迹法(Western blot)检测糖酵解相关蛋白、CDK16、MYC及磷酸化表达。免疫共沉淀(Co-IP)技术探究CDK16和MYC的蛋白相互作用关系,环己酰亚胺(CHX)处理检测过表达CDK16对MYC蛋白稳定性的影响。结果:与空白组比较,HCT-116细胞在加入2.5 mg·L^(-1)5-FU后细胞活力被显著抑制,且抑制效果随5-FU浓度升高而升高;而HCT-116/5-FU细胞在加入5 mg·L^(-1)5-FU后细胞活力才被明显抑制(P<0.05),选择5 mg·L^(-1)浓度造模。与单独5-FU组比较,当加入葛根芩连汤含药血清体积分数为5%后,HCT-116/5-FU的细胞活力被明显抑制(P<0.05),且抑制效果随葛根芩连汤含药血清浓度升高而升高,之后选用5%的葛根芩连汤含药血清处理。与空白组比较,5-FU组、葛根芩连汤组和5-FU+葛根芩连汤组细胞增殖能力均明显下降(P<0.05),且细胞凋亡水平也显著上调(P<0.01),但相较于5-FU组和葛根芩连汤组,5-FU+葛根芩连汤组抑制细胞增殖更为显著(P<0.01),且葡萄糖消耗量、ATP产生和乳酸产生水平下降也更为显著(P<0.01);此外,分别与空白组、5-FU组、葛根芩连汤组比较,5-FU+葛根芩连汤组对MYC及其磷酸化水平的抑制效果更为显著(P<0.01),且对糖酵解相关酶己糖激酶2(HK2)、3-磷酸肌醇依赖性蛋白激酶1(PDK1)、乳酸脱氢酶A(LDHA)和M2型丙酮酸激酶(PKM2)的抑制作用也显著增加(P<0.01)。同时,与5-FU组比较,5-FU+葛根芩连汤组中CDK16的表达下调(P<0.01),且MYC及其磷酸化蛋白的表达水平显著下降(P<0.01)。此外,与5-FU组比较,5-FU+葛根芩连汤组中MYC蛋白的稳定性随时间的变化明显降低(P<0.05),但被过表达CDK16所挽救(P<0.05)。结论:葛根芩连汤能显著增强HCT-116/5-FU细胞对5-FU的敏感性,其机制可能是葛根芩连汤通过抑制CDK16从而降低MYC介导的糖酵解。 展开更多
关键词 结直肠癌 5-氟尿嘧啶(5-FU)耐药 MYC 糖酵解 细胞周期蛋白依赖性激酶16(CDK16)
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中科发5号背景下东北粳稻育种目标与策略的思考
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作者 马兆惠 全成哲 +3 位作者 程海涛 杨衎劼 李欣蕊 吕文彦 《中国农业科学》 北大核心 2026年第5期927-936,共10页
中科发5号是李家洋院士团队利用分子设计育种理念培育的新品种。运用表型与分子标记选择相结合的方法,聚合了GL7(多拷贝)、GS3和GW5基因型组合,形成了水稻的细长籽粒,且含有高产的基因/QTL qSB2、qSB8、qSB10和SCM2等,以及携带稻瘟病抗... 中科发5号是李家洋院士团队利用分子设计育种理念培育的新品种。运用表型与分子标记选择相结合的方法,聚合了GL7(多拷贝)、GS3和GW5基因型组合,形成了水稻的细长籽粒,且含有高产的基因/QTL qSB2、qSB8、qSB10和SCM2等,以及携带稻瘟病抗性等位基因Pib、qBR10、Pi-ta和Ptr。基于此,该品种综合农艺性状表现出高产、多抗、品质优良等特点,在2014年位列中国十大主栽品种之列,已成为东北标志性品种。面对这一局面,未来东北粳稻应该以此为基准,实现超越。结合大米供需市场状况,育种目标应是以高产为基础的长粒香。具体产量目标为9500 kg·hm^(-2)以上,而实现这一目标的性状组配是株高95.0—105.0 cm、有效穗数375.0万—420.0万株/hm^(2)、穗粒数120.0粒以上、千粒重大于25.0 g;品质目标为粒长大于6.5 mm、长宽比大于2.8、整精米率达到审定标准、外观优良、食味80分以上、具有香味。除此之外,还要具有良好的适应性与抗性。为实现该目标,首先要加强辩证思维,要在实践中坚决淘汰大量不能达到育种目标的材料,同时,加强优良性状组配及其与当地栽培条件适应性的实践检验。在育种过程中,协调使用高产资源和长粒资源,加强复合杂交,同时优化育种过程,积极采用分子育种等现代育种技术。育种策略关键是要拓展具有广亲和性的籼粳亚种杂交稻恢复系的运用,特别是高产籼粳三系杂交稻的利用。由于高产三系杂交稻本身产量较高,其配子存在广泛重组,更有期望出现突破性类型。利用具有广亲和性的粳稻恢复系与长粒香型籼型杂交稻配组,可能是实现长粒香育种目标的最好策略,但还需进一步检验。 展开更多
关键词 粳稻 中科发5 辩证思维 育种目标 育种策略
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格拉瑟菌血清5型cpxAR双组分基因缺失株的生物学特性研究
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作者 徐引弟 王治方 +8 位作者 蔡旭旺 徐晓娟 张立宪 焦文强 朱文豪 李海利 游一 张家庆 雷亚楠 《河南农业科学》 北大核心 2026年第2期126-135,共10页
为研究cpxAR双组分基因在格拉瑟菌中的致病机制,同时筛选格拉瑟菌血清5型缺失弱毒株,构建格拉瑟菌血清5型临床分离株(GPS5)的cpxAR双基因缺失株(ΔcpxAR),并对缺失株的生长特性、生物膜形成能力、环境胁迫抗性及豚鼠致病力等生物学特性... 为研究cpxAR双组分基因在格拉瑟菌中的致病机制,同时筛选格拉瑟菌血清5型缺失弱毒株,构建格拉瑟菌血清5型临床分离株(GPS5)的cpxAR双基因缺失株(ΔcpxAR),并对缺失株的生长特性、生物膜形成能力、环境胁迫抗性及豚鼠致病力等生物学特性进行系统研究。结果表明,cpxAR基因缺失后,ΔcpxAR与亲本株GPS5相比,菌落形态和生长速率无明显差异,但生物膜形成能力明显减弱,对渗透压、热休克、氧化应激及碱性胁迫的抗性显著降低,对豚鼠的毒力也显著减弱。综上,cpxAR基因对GPS5的生长无明显调控作用,但对其生物膜形成、环境胁迫抗性及毒力均具有重要调控作用,为深入探究cpxAR双组分系统在格拉瑟菌中的生物学功能,以及筛选格拉瑟菌血清5型弱毒株奠定了基础。 展开更多
关键词 格拉瑟菌血清5 cpxAR基因缺失株 生长 生物膜 抗性 毒力
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热化学催化5-羟甲基糠醛连续氧化制备2,5-呋喃二甲酸的研究进展
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作者 王超 吴慨凡 +6 位作者 王忠铭 庄新姝 刘小春 冯颖 李连华 苗长林 罗文 《新能源进展》 北大核心 2026年第1期88-98,共11页
2,5-呋喃二甲酸(FDCA)可广泛应用于聚酯、增塑剂、医药、香料、农药等多个领域,也可用于生产可降解塑料、半芳香尼龙、不饱和树脂等短期可作为石油基高分子的改性剂,市场潜力巨大。5-羟甲基糠醛(HMF)是一种来源于生物质的可再生资源,可... 2,5-呋喃二甲酸(FDCA)可广泛应用于聚酯、增塑剂、医药、香料、农药等多个领域,也可用于生产可降解塑料、半芳香尼龙、不饱和树脂等短期可作为石油基高分子的改性剂,市场潜力巨大。5-羟甲基糠醛(HMF)是一种来源于生物质的可再生资源,可用于生产FDCA。简要概述了热化学催化氧化HMF的反应路径,系统总结了HMF催化反应体系的研究进展,分析提升催化剂活性的方法和当前面临的挑战,最后对催化剂的改性方向进行展望。可为HMF连续氧化制备FDCA的研究提供理论指导和参考,以促进生物质衍生物的应用。 展开更多
关键词 5-羟甲基糠醛 2 5-呋喃二甲酸 热化学催化 非贵金属催化剂
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g-C_(3)N_(5)基异质结光催化降解水中有机污染物的研究进展
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作者 刘亚利 赵亚龙 +3 位作者 汪鹏 康晓荣 荆肇乾 王祝来 《精细化工》 北大核心 2026年第4期743-756,共14页
富氮石墨氮化碳(g-C_(3)N_(5))凭借其窄带隙(~2.2 eV)、可吸收波长≤660 nm可见光的特性,在光催化领域展现出巨大的潜能。但单一g-C_(3)N_(5)半导体面临光生载流子复合率高、量子效率低等瓶颈问题。构建异质结调控界面电荷的迁移路径,... 富氮石墨氮化碳(g-C_(3)N_(5))凭借其窄带隙(~2.2 eV)、可吸收波长≤660 nm可见光的特性,在光催化领域展现出巨大的潜能。但单一g-C_(3)N_(5)半导体面临光生载流子复合率高、量子效率低等瓶颈问题。构建异质结调控界面电荷的迁移路径,是提升其光催化性能的有效手段。该文重点总结了g-C_(3)N_(5)基异质结的结构、电荷迁移路径及改性,归纳了其对水中染料、药物等有机污染物的光催化性能及反应机理。结合研究现状,提出了未来的研究方向应开发环境友好型无机半导体用于异质结的构建;建立“机器学习筛选-密度泛函理论计算深入分析-实验验证”模式,加速高性能异质结的研发与优化;运用高效精准的电荷检测技术揭示异质结结构及电荷转移机制;开展长期连续应用研究以评估光催化剂的稳定性和实际应用价值。 展开更多
关键词 g-C_(3)N_(5) 异质结 电荷转移机制 光催化 有机污染物
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乙酰丙酸改性对HZSM-5甲醇芳构化催化剂积炭行为的影响
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作者 李剑 乔永伟 +1 位作者 刘冲 杨丽娜 《石油学报(石油加工)》 北大核心 2026年第1期76-85,共10页
采用乙酰丙酸对HZSM-5甲醇芳构化催化剂进行酸处理改性,制得改性催化剂样品Lx-Z5(x为乙酰丙酸溶液质量分数,%)。为研究改性对催化剂积炭行为的影响,采用XRD、N_(2)吸附-脱附、NH_(3)-TPD、Py-FTIR和TGA/DTG等分析手段对新鲜的HZSM-5和Lx... 采用乙酰丙酸对HZSM-5甲醇芳构化催化剂进行酸处理改性,制得改性催化剂样品Lx-Z5(x为乙酰丙酸溶液质量分数,%)。为研究改性对催化剂积炭行为的影响,采用XRD、N_(2)吸附-脱附、NH_(3)-TPD、Py-FTIR和TGA/DTG等分析手段对新鲜的HZSM-5和Lx-Z5及失活的HZSM-5和Lx-Z5催化剂进行表征并评价其催化性能。结果表明,改性未破坏HZSM-5拓扑结构,但使其孔径、介孔孔体积增加,酸量及酸强度降低,Brønsted(B)/Lewis(L)酸量比(A_(B)/A_(L))增加,其中,L1.0-Z5催化剂样品的变化最显著。Lx-Z5催化剂的孔径、介孔孔体积及A_(B)/A_(L)的增加提升了苯-甲苯-二甲苯(BTX)选择性,孔径和介孔孔体积的增大、酸量及酸强度的降低减少了平均积炭速率、内积炭比例,提高了轻质积炭量,改性后再生性能更优。不同含量乙酰丙酸溶液改性中,L1.0-Z5样品的BTX选择性最高,使用寿命最长,平均积炭速率最低,容炭能力最强;相比HZSM-5催化剂,L1.0-Z5样品的BTX选择性、使用寿命分别增加5.55百分点和82 h,平均积炭速率降低0.36%/h。 展开更多
关键词 HZSM-5 乙酰丙酸改性 甲醇芳构化 寿命 积炭行为
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WO_(3)和TiO_(2)共掺V_(2)O_(5)复合薄膜的制备及其光电特性
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作者 王伟 李毅 +1 位作者 刘红薇 施张庆 《电子元件与材料》 北大核心 2026年第1期9-17,共9页
选用五氧化二钒、三氧化钨、二氧化钛粉末和过氧化氢溶液为原料,采用溶胶-凝胶法和后退火工艺在氟掺杂氧化锡导电玻璃基底上制备了三氧化钨和二氧化钛共掺五氧化二钒复合薄膜。通过场发射扫描电子显微镜、X射线衍射仪和X射线光电子能谱... 选用五氧化二钒、三氧化钨、二氧化钛粉末和过氧化氢溶液为原料,采用溶胶-凝胶法和后退火工艺在氟掺杂氧化锡导电玻璃基底上制备了三氧化钨和二氧化钛共掺五氧化二钒复合薄膜。通过场发射扫描电子显微镜、X射线衍射仪和X射线光电子能谱仪等表征了最佳配比下复合薄膜的表面形貌、结构和化学组成,利用分光光度计等测试手段分析了复合薄膜的光电特性。结果表明,在400~1200 nm波长范围内,复合薄膜在室温下的平均透过率为52.99%。当温度从室温升至400℃时,复合薄膜的电阻和透过率变化幅度分别达到83.7%和16.12%。在0~3.1 V的偏压下,复合薄膜的透过率随电压的增大而升高,在400~1200 nm波长范围内,平均透过率升高约12.21%;当偏压大于3.1 V时,复合薄膜的透过率随电压的增大而降低。经过多次高低温循环测试,该复合薄膜的光电特性具有较好的可逆热致光电性,在新型光电器件和传感器等领域展现出潜在应用前景。 展开更多
关键词 复合薄膜 V_(2)O_(5) TiO_(2) WO_(3) 溶胶-凝胶 光电特性
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3H核心胜任力导向下医学模拟中心在临床医学“5+3”一体化培养中的实践与思考
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作者 杨丹丹 蔡浩雷 +3 位作者 丰婷婷 李楠 张莉娜 唐碧云 《中国高等医学教育》 2026年第1期22-23,57,共3页
文章阐述了浙江大学医学院附属第二医院医学模拟中心在临床医学“5+3”一体化教育模式下临床实践能力培养方案的实施路径。中心以3H核心胜任力为导向,通过构建医学模拟教育平台、分层递进的课程体系、专业化师资队伍及多元化情境模拟课... 文章阐述了浙江大学医学院附属第二医院医学模拟中心在临床医学“5+3”一体化教育模式下临床实践能力培养方案的实施路径。中心以3H核心胜任力为导向,通过构建医学模拟教育平台、分层递进的课程体系、专业化师资队伍及多元化情境模拟课程,系统提升了医学生的岗位胜任力。在此基础上,进一步分析了当前医学模拟中心的主要价值与面临的挑战,提出了对策建议。 展开更多
关键词 医学模拟中心 5+3”一体化 医学教育
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5-羟甲基糠醛电催化氧化制备2,5-呋喃二羧酸的工艺研究
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作者 郑华均 杭怡欣 +3 位作者 郑文彬 赵浙菲 吕卓清 郑灵霞 《浙江工业大学学报》 北大核心 2026年第1期1-7,共7页
对5-羟甲基糠醛(HMF)电催化氧化制备2,5-呋喃二羧酸(FDCA)体系进行工艺优化和放大研究。通过简单的一步水热合成Ni_(3)S_(2)/NF,采用扫描电子显微镜(SEM)对其进行表征,通过线性扫描伏安法对制备的材料进行电化学测试,结果表明,放大面积... 对5-羟甲基糠醛(HMF)电催化氧化制备2,5-呋喃二羧酸(FDCA)体系进行工艺优化和放大研究。通过简单的一步水热合成Ni_(3)S_(2)/NF,采用扫描电子显微镜(SEM)对其进行表征,通过线性扫描伏安法对制备的材料进行电化学测试,结果表明,放大面积后水热法仍可制得表面均一、性能良好的电极。单因素实验结果表明:电解性能与反应温度、电解液流量等操作参数有关。在温度为35℃、电解液流量为150 L/h、恒电流为4.5 A的条件下进行HMF电合成FDCA实验,电流效率和转化率分别达到86.50%和99.58%,FDCA产率高达93.60%。 展开更多
关键词 5-羟甲基糠醛 2 5-呋喃二羧酸 电催化氧化 生产工艺
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HPLC-DAD法测定益气养血口服液中5-羟甲基糠醛
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作者 马彧 王丹彧 +2 位作者 马晓静 宋瑩 崔业波 《质量安全与检验检测》 2026年第1期34-37,共4页
本研究建立了益气养血口服液中5-羟甲基糠醛(5-HMF)的检测方法。采用HPLC-DAD法,Caprisil C_(18)-IP为色谱柱(250 mm×4.6 mm,5μm);流动相为甲醇-0.05%磷酸,梯度洗脱;体积流量为1.0 mL/min;柱温25℃;检测波长284 nm。结果显示,5-... 本研究建立了益气养血口服液中5-羟甲基糠醛(5-HMF)的检测方法。采用HPLC-DAD法,Caprisil C_(18)-IP为色谱柱(250 mm×4.6 mm,5μm);流动相为甲醇-0.05%磷酸,梯度洗脱;体积流量为1.0 mL/min;柱温25℃;检测波长284 nm。结果显示,5-羟甲基糠醛在2.539~55.389μg/mL内线性关系良好(r=1.0000),平均加样回收率为97.0%,RSD为0.2%。不同企业生产的样品中均检出5-羟甲基糠醛。5-羟甲基糠醛的产生可能与益气养血口服液生产工艺相关,建议在益气养血口服液的标准中增加5-羟甲基糠醛检查项。本研究建立的方法简便、准确,可为企业质量控制提供参考。 展开更多
关键词 5-羟甲基糠醛 益气养血口服液 高效液相色谱法
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高产多抗玉米新品种徐农5号的选育与应用
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作者 黄忠勤 李小珊 苏在兴 《浙江农业科学》 2026年第3期562-565,共4页
徐农5号是江苏徐淮地区徐州农业科学研究所以RT212为母本、HL210为父本杂交选育而成的普通玉米新品种,适宜在黄淮海夏玉米区种植。该品种具有丰产性好、综合抗逆性强、适应性广等特点。本文介绍了徐农5号的选育过程、特征特性、产量表... 徐农5号是江苏徐淮地区徐州农业科学研究所以RT212为母本、HL210为父本杂交选育而成的普通玉米新品种,适宜在黄淮海夏玉米区种植。该品种具有丰产性好、综合抗逆性强、适应性广等特点。本文介绍了徐农5号的选育过程、特征特性、产量表现、综合抗性及栽培技术,以期为推广应用提供参考。 展开更多
关键词 高产多抗 玉米 徐农5 品种选育 产量
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