将机器人采集到的温度、湿度和位置等数据信息传送至云平台服务器,便于云端数据分析、机器人数据共享以及人机信息交互等。本文应用第4代移动通信技术(the 4th generation mobile communication technology,4G)无线传输技术,设计的机器...将机器人采集到的温度、湿度和位置等数据信息传送至云平台服务器,便于云端数据分析、机器人数据共享以及人机信息交互等。本文应用第4代移动通信技术(the 4th generation mobile communication technology,4G)无线传输技术,设计的机器人与云平台无线数据传输系统主要包括硬件和软件实现2个部分,硬件方面机器人通过32位微控制器(STMicroelectronics32,STM32)嵌入式系统与4G模块组合,将传感器采集到的数据信息,通过Internet网络传输到云平台服务器中,软件部分运用C语言编程通过网络透传模式(transmission control protocol/user datagram protocol, TCP/UDP)实现无线通信过程,最终实验验证了机器人与云平台服务器之间的双向无线数据传输功能。展开更多
Cryogenic insulation material rigid polyurethane(PU)foams were developed using bio-based and recycled feedstock.Polyols obtained from tall oil fatty acids produced as a side stream of wood biomass pulping and recycled...Cryogenic insulation material rigid polyurethane(PU)foams were developed using bio-based and recycled feedstock.Polyols obtained from tall oil fatty acids produced as a side stream of wood biomass pulping and recycled polyethylene terephthalate were used to develop rigid PU foam formulations.The 4th generation physical blowing agents with low global warming potential and low ozone depletion potential were used to develop rigid PU foam cryogenic insulation with excellent mechanical and thermal properties.Obtained rigid PU foams had a thermal conductivity coefficient as low as 0.0171 W/m·K and an apparent density of 37-40 kg/m^(3).The developed rigid PU foams had anisotropic compression strength properties,which were higher parallel to the foaming direction.Moreover,the compression strength was also influenced by the type of applied bio-based polyol.The bio-based polyols with higher OH group functionality delivered higher crosslinking density of polymer matrix;thus,the mechanical properties were also higher.The mechanical strength of the foams increased when materials were tested at liquid nitrogen temperature due to the stiffening of the polymer matrix.The thermal properties of the developed materials were determined using differential scanning calorimetry,dynamic mechanical analysis,and thermogravimetric analysis methods.Lastly,the developed rigid PU foams had good adhesion to the aluminium substrate before and after applying cyroshock and an excellent safety coefficient of 4-5.Rigid PU foams developed using Solstice LBA delivered adhesion strength of~0.5 MPa and may be considered for application as cryogenic insulation in the aerospace industry.展开更多
The interaction between two 4th generation of new cephalosporin drugs and papain was studied through spectroscopy method at different temperatures. Their dissociation constants were calculated by using theoretical for...The interaction between two 4th generation of new cephalosporin drugs and papain was studied through spectroscopy method at different temperatures. Their dissociation constants were calculated by using theoretical formula of fluorescence quenching and fluorescence enhancement, respectively, and their corresponding thermodynamic functions, dipole-dipole non-radiative energy-transfer-efficiency and the action distances of acceptor-substrate etc. were calculated further. Analysis reveals that, the quenching on papain by cefpirome and cefepime is basically due to the dipole-dipole non-radiation energy-transfer and certain dynamic collision between donor and acceptor, the interaction between drug and papain is mainly hydrophobic which may provide useful information for pharmacological and metabolic study on papain. In this paper fluorescence quenching is regarded as negative fluorescence enhancement, and two kinds of theoretical formula of fluorescence quenching and fluorescence enhancement were used to calculate the experimental data of fluorescence quenching of a same batch, and very close results were obtained but with certain difference. The results not only display the equivalence of the two theoretical equations when treating acceptor-substrate action, but also show that the thermodynamic data based on the theoretical formula of fluorescence enhancement （4）, which is deduced by us, are more reasonable. So we suggest that even in the process of studying the fluorescence quenching between receptor-substrate, using the theoretical formula of fluorescence enhancement （4） can get more reliable results.展开更多
文摘将机器人采集到的温度、湿度和位置等数据信息传送至云平台服务器,便于云端数据分析、机器人数据共享以及人机信息交互等。本文应用第4代移动通信技术(the 4th generation mobile communication technology,4G)无线传输技术,设计的机器人与云平台无线数据传输系统主要包括硬件和软件实现2个部分,硬件方面机器人通过32位微控制器(STMicroelectronics32,STM32)嵌入式系统与4G模块组合,将传感器采集到的数据信息,通过Internet网络传输到云平台服务器中,软件部分运用C语言编程通过网络透传模式(transmission control protocol/user datagram protocol, TCP/UDP)实现无线通信过程,最终实验验证了机器人与云平台服务器之间的双向无线数据传输功能。
基金funded by projects“Smart Materials,Photonics,Technologies and Engineering Ecosystem(MOTE)”(Contract No.VPP-EM-FOTONIKA-2022/1-0001)“Bio-Based Cryogenic Insulation for Aerospace Application(BioSpace)”(Contract No.4000135271/21/NL/SC).
文摘Cryogenic insulation material rigid polyurethane(PU)foams were developed using bio-based and recycled feedstock.Polyols obtained from tall oil fatty acids produced as a side stream of wood biomass pulping and recycled polyethylene terephthalate were used to develop rigid PU foam formulations.The 4th generation physical blowing agents with low global warming potential and low ozone depletion potential were used to develop rigid PU foam cryogenic insulation with excellent mechanical and thermal properties.Obtained rigid PU foams had a thermal conductivity coefficient as low as 0.0171 W/m·K and an apparent density of 37-40 kg/m^(3).The developed rigid PU foams had anisotropic compression strength properties,which were higher parallel to the foaming direction.Moreover,the compression strength was also influenced by the type of applied bio-based polyol.The bio-based polyols with higher OH group functionality delivered higher crosslinking density of polymer matrix;thus,the mechanical properties were also higher.The mechanical strength of the foams increased when materials were tested at liquid nitrogen temperature due to the stiffening of the polymer matrix.The thermal properties of the developed materials were determined using differential scanning calorimetry,dynamic mechanical analysis,and thermogravimetric analysis methods.Lastly,the developed rigid PU foams had good adhesion to the aluminium substrate before and after applying cyroshock and an excellent safety coefficient of 4-5.Rigid PU foams developed using Solstice LBA delivered adhesion strength of~0.5 MPa and may be considered for application as cryogenic insulation in the aerospace industry.
文摘The interaction between two 4th generation of new cephalosporin drugs and papain was studied through spectroscopy method at different temperatures. Their dissociation constants were calculated by using theoretical formula of fluorescence quenching and fluorescence enhancement, respectively, and their corresponding thermodynamic functions, dipole-dipole non-radiative energy-transfer-efficiency and the action distances of acceptor-substrate etc. were calculated further. Analysis reveals that, the quenching on papain by cefpirome and cefepime is basically due to the dipole-dipole non-radiation energy-transfer and certain dynamic collision between donor and acceptor, the interaction between drug and papain is mainly hydrophobic which may provide useful information for pharmacological and metabolic study on papain. In this paper fluorescence quenching is regarded as negative fluorescence enhancement, and two kinds of theoretical formula of fluorescence quenching and fluorescence enhancement were used to calculate the experimental data of fluorescence quenching of a same batch, and very close results were obtained but with certain difference. The results not only display the equivalence of the two theoretical equations when treating acceptor-substrate action, but also show that the thermodynamic data based on the theoretical formula of fluorescence enhancement （4）, which is deduced by us, are more reasonable. So we suggest that even in the process of studying the fluorescence quenching between receptor-substrate, using the theoretical formula of fluorescence enhancement （4） can get more reliable results.
