The crystal structure of the title compound（C19H15F3N2O2,Mr = 360.33） was determined by single-crystal X-ray diffraction.The crystal belongs to triclinic,space group P1,with a = 6.5604（7）,b = 13.9614（16）,c = 18....The crystal structure of the title compound（C19H15F3N2O2,Mr = 360.33） was determined by single-crystal X-ray diffraction.The crystal belongs to triclinic,space group P1,with a = 6.5604（7）,b = 13.9614（16）,c = 18.1790（18） ,α = 102.749（7）,β = 97.542（6）,γ = 94.355（4）°,V = 1600.5（3） 3,Z = 4,Dc = 1.495 g/cm3,λ（MoKα） = 0.71070,F（000） = 744,μ（MoKα） = 0.122 mm-1,R = 0.0434 and wR = 0.1051.A total of 7590 unique reflections were collected,of which 5429 with ｜F｜2 ≥ 2σ｜F｜2 were observed.The two cyclohexene rings in the molecule adopt boat-boat conformations with the deviations of ring atoms C（9） and C10 from the C（5）/C（6）/C（7）/C（8） plane（Ⅰ） by 1.1204（0.0023） and 1.1132（0.0023） ,respectively,whereas from the C（2）/C（3）/C（5）/C（8） plane（Ⅱ） by 1.1627（0.0022） and 1.1818（0.0021） ,respectively.In the cyclopropane and lactam rings,atoms C（11） and N（1） point towards the double bond of C（9）-C（10） and the dihedral angle between the ring plane（Ⅲ） containing C（1）,C（2）,C（3） and C（4） and plane（IV） consisting of C（6）,C（7） and C（11） is 55.76（0.07）°.The dihedral angles between planes Ⅳ and Ⅰ and Ⅱ and Ⅲare 63.58（0.07）° and 58.10（0.06）°,respectively.The dihedral angle between the benzene ring C（13）～ C（18） and plane Ⅳ is 42.41（0.06）°.展开更多
利用中国区域550个站点逐日地面气温及降水资料,评估了参与政府间气候变化专门委员会第四次报告(the fourth assessment report of the intergovernmental panel on climate change,IPCCAR4)的13个新一代全球气候系统模式及多模式集合...利用中国区域550个站点逐日地面气温及降水资料,评估了参与政府间气候变化专门委员会第四次报告(the fourth assessment report of the intergovernmental panel on climate change,IPCCAR4)的13个新一代全球气候系统模式及多模式集合对中国近40 a(1961—2000年)地面气温和降水的模拟能力,结果表明:最新全球模式对中国地区地面气温年变化及空间分布的模拟结果均较好,但在整个模拟区域地面气温模拟值系统性偏低,东部地区模拟效果好于中西部;对于降水,大部分模式能模拟出中国降水的年变化及空间分布特征,但模拟的区域性差别较大,多数模式对中国东部季风区夏季雨带北抬的过程有一定的模拟能力,但模拟雨带位置偏北。新一代全球模式能模拟出温度的线性变化趋势,但对温度及降水的年际变率模拟能力较低。比较多种评估指标得出,模式集合对温度的模拟效果最好,模式UKMO-HadCM3对降水的模拟效果最好。展开更多
By using the simulative results of more than 20 climate system models which were provided by the fourth assessment report of the Intergovernmental Panel on Climate Change(IPCC),the climate change in Dalian area in the...By using the simulative results of more than 20 climate system models which were provided by the fourth assessment report of the Intergovernmental Panel on Climate Change(IPCC),the climate change in Dalian area in the 21st century under the different scenarios(SRES A2,SRES A1B and SRES B1) were analyzed and predicted with the multi-model's aggregative simulative results via the interpolation downscaling calculation.The results showed that the climate in Dalian would have the obvious warming and wetting tendency in the 21st century as a whole.The annual average warming tendency of air temperature would be 2.45-3.46 ℃/100 years,and the annual precipitation increase trend would be 5.8%-16.3% per 100 years.The warming in winter would be the most obvious,and the precipitation increase would be comparatively obvious in winter and spring.The precipitation decrease would be comparatively obvious in autumn in the previous period of 21st century.In A2,A1B and B1 scenarios,the air temperatures in the late period of 21st century would respectively be 3.46,3.44 and 2.45 ℃ higher than in the ordinary years,and the annual precipitation would respectively be 16.3%,11.8% and 5.79% more than in the ordinary years.展开更多
文摘The crystal structure of the title compound（C19H15F3N2O2,Mr = 360.33） was determined by single-crystal X-ray diffraction.The crystal belongs to triclinic,space group P1,with a = 6.5604（7）,b = 13.9614（16）,c = 18.1790（18） ,α = 102.749（7）,β = 97.542（6）,γ = 94.355（4）°,V = 1600.5（3） 3,Z = 4,Dc = 1.495 g/cm3,λ（MoKα） = 0.71070,F（000） = 744,μ（MoKα） = 0.122 mm-1,R = 0.0434 and wR = 0.1051.A total of 7590 unique reflections were collected,of which 5429 with ｜F｜2 ≥ 2σ｜F｜2 were observed.The two cyclohexene rings in the molecule adopt boat-boat conformations with the deviations of ring atoms C（9） and C10 from the C（5）/C（6）/C（7）/C（8） plane（Ⅰ） by 1.1204（0.0023） and 1.1132（0.0023） ,respectively,whereas from the C（2）/C（3）/C（5）/C（8） plane（Ⅱ） by 1.1627（0.0022） and 1.1818（0.0021） ,respectively.In the cyclopropane and lactam rings,atoms C（11） and N（1） point towards the double bond of C（9）-C（10） and the dihedral angle between the ring plane（Ⅲ） containing C（1）,C（2）,C（3） and C（4） and plane（IV） consisting of C（6）,C（7） and C（11） is 55.76（0.07）°.The dihedral angles between planes Ⅳ and Ⅰ and Ⅱ and Ⅲare 63.58（0.07）° and 58.10（0.06）°,respectively.The dihedral angle between the benzene ring C（13）～ C（18） and plane Ⅳ is 42.41（0.06）°.
文摘利用中国区域550个站点逐日地面气温及降水资料,评估了参与政府间气候变化专门委员会第四次报告(the fourth assessment report of the intergovernmental panel on climate change,IPCCAR4)的13个新一代全球气候系统模式及多模式集合对中国近40 a(1961—2000年)地面气温和降水的模拟能力,结果表明:最新全球模式对中国地区地面气温年变化及空间分布的模拟结果均较好,但在整个模拟区域地面气温模拟值系统性偏低,东部地区模拟效果好于中西部;对于降水,大部分模式能模拟出中国降水的年变化及空间分布特征,但模拟的区域性差别较大,多数模式对中国东部季风区夏季雨带北抬的过程有一定的模拟能力,但模拟雨带位置偏北。新一代全球模式能模拟出温度的线性变化趋势,但对温度及降水的年际变率模拟能力较低。比较多种评估指标得出,模式集合对温度的模拟效果最好,模式UKMO-HadCM3对降水的模拟效果最好。
基金Supported by The National Natural Science Fund(40971294)The General Project of Humanities and Social Sciences in Liaoning Education Department(2009A405)The Science and Technology Plan Project of Dalian Technology Bureau(2008E13SF189,2009E11SF230)
文摘By using the simulative results of more than 20 climate system models which were provided by the fourth assessment report of the Intergovernmental Panel on Climate Change(IPCC),the climate change in Dalian area in the 21st century under the different scenarios(SRES A2,SRES A1B and SRES B1) were analyzed and predicted with the multi-model's aggregative simulative results via the interpolation downscaling calculation.The results showed that the climate in Dalian would have the obvious warming and wetting tendency in the 21st century as a whole.The annual average warming tendency of air temperature would be 2.45-3.46 ℃/100 years,and the annual precipitation increase trend would be 5.8%-16.3% per 100 years.The warming in winter would be the most obvious,and the precipitation increase would be comparatively obvious in winter and spring.The precipitation decrease would be comparatively obvious in autumn in the previous period of 21st century.In A2,A1B and B1 scenarios,the air temperatures in the late period of 21st century would respectively be 3.46,3.44 and 2.45 ℃ higher than in the ordinary years,and the annual precipitation would respectively be 16.3%,11.8% and 5.79% more than in the ordinary years.
