A novel cobalt（Ⅱ） coordination polymer, [Co（tdc）（bpmp）（H2O）]n（1）, was hydrothermally synthesized using 2,5-thiophenedicarboxylate（tdc） and bis（4-pyridylmethyl）piperazine（bpmp） ligand as the organic li...A novel cobalt（Ⅱ） coordination polymer, [Co（tdc）（bpmp）（H2O）]n（1）, was hydrothermally synthesized using 2,5-thiophenedicarboxylate（tdc） and bis（4-pyridylmethyl）piperazine（bpmp） ligand as the organic linkers. X-ray single-crystal diffraction determination reveals that 1 crystallizes in the monoclinic Cc space group, with a = 18.836（2）, b = 5.9540（7）, c = 20.414（2） A, β = 97.4300（10）°, V = 2270.1（5） A3, Z = 4, Mr = 515.44, Dc = 1.508 Mg/m^3, μ = 0.890 mm-1, F（000） = 1068, the final R = 0.0263 and w R = 0.0665 for 3714 observed reflections with I 2σ（I）. In compound 1, the Co（Ⅱ） ions are connected by tdc2- anions to form a 1D double chain, and such chains are further linked by bpmp ligands to form a three-dimensional（3D） structure. Topologically, the structure of 1 represents a uninodal 3D dia（6^6） topology. What＇s more, powder X-ray diffraction patterns and photocatalytic property for 1 have also been investigated.展开更多
基金supported by the Natural Science Foundation of Henan Province(132300410326)
文摘A novel cobalt（Ⅱ） coordination polymer, [Co（tdc）（bpmp）（H2O）]n（1）, was hydrothermally synthesized using 2,5-thiophenedicarboxylate（tdc） and bis（4-pyridylmethyl）piperazine（bpmp） ligand as the organic linkers. X-ray single-crystal diffraction determination reveals that 1 crystallizes in the monoclinic Cc space group, with a = 18.836（2）, b = 5.9540（7）, c = 20.414（2） A, β = 97.4300（10）°, V = 2270.1（5） A3, Z = 4, Mr = 515.44, Dc = 1.508 Mg/m^3, μ = 0.890 mm-1, F（000） = 1068, the final R = 0.0263 and w R = 0.0665 for 3714 observed reflections with I 2σ（I）. In compound 1, the Co（Ⅱ） ions are connected by tdc2- anions to form a 1D double chain, and such chains are further linked by bpmp ligands to form a three-dimensional（3D） structure. Topologically, the structure of 1 represents a uninodal 3D dia（6^6） topology. What＇s more, powder X-ray diffraction patterns and photocatalytic property for 1 have also been investigated.
