The energy levels and lifetimes of 3pns ^3po (n = 7 - 35) and 3pnd ^3p0 (n = 6 - 17) series of neutral silicon are calculated and predicted by means of multichannel quantum defect theory (MQDT). In addition, the...The energy levels and lifetimes of 3pns ^3po (n = 7 - 35) and 3pnd ^3p0 (n = 6 - 17) series of neutral silicon are calculated and predicted by means of multichannel quantum defect theory (MQDT). In addition, the perturbation caused by core-excited state 3s3p^3 is discussed. The 3pnd ^3p0 series, especially 3p4d ^3p0, 3p5d ^3P0, and 3p6d ^3P0 are perturbed strongly by the core-excited state 3s3p3 ^3P0. These cause the lifetime of 3pnd ^3P0 (n = 5 - 7) to be less than that of 3p4d 3Po. The lifetimes of 3p14d ^3P0 (65479.14 cm^-1) and 3p16d ^3p0 (65608.77 cm^-1) are less than that of their frontal states respectively, because these states are perturbed by 3p22s ^3p0 (65476.48 cm-1) and 3p30s ^3p0 (65608.99 cm^-1) respectively.展开更多
基金supported by the Basic Research Foundation of Xi'an University of Architecture and Technology (No.JC0510)the Foundation for Talents of Xi'an University of Architecture and Technology (No.RC0604)the Foundation of Education Department of Shaanxi Province (No.08JK343).
文摘The energy levels and lifetimes of 3pns ^3po (n = 7 - 35) and 3pnd ^3p0 (n = 6 - 17) series of neutral silicon are calculated and predicted by means of multichannel quantum defect theory (MQDT). In addition, the perturbation caused by core-excited state 3s3p^3 is discussed. The 3pnd ^3p0 series, especially 3p4d ^3p0, 3p5d ^3P0, and 3p6d ^3P0 are perturbed strongly by the core-excited state 3s3p3 ^3P0. These cause the lifetime of 3pnd ^3P0 (n = 5 - 7) to be less than that of 3p4d 3Po. The lifetimes of 3p14d ^3P0 (65479.14 cm^-1) and 3p16d ^3p0 (65608.77 cm^-1) are less than that of their frontal states respectively, because these states are perturbed by 3p22s ^3p0 (65476.48 cm-1) and 3p30s ^3p0 (65608.99 cm^-1) respectively.