The Ag(Invar)composite powder prepared by ball milling was used to fabricate the Cu/Ag(Invar)composites.Microstructures and properties of the composites were studied after sintering and thermo-mechanical treatment.The...The Ag(Invar)composite powder prepared by ball milling was used to fabricate the Cu/Ag(Invar)composites.Microstructures and properties of the composites were studied after sintering and thermo-mechanical treatment.The results indicatethat during ball milling,micro-forging weld and work-hardening fracture result in that the average particle size of the Ag(Invar)powder increases rapidly at first,and then decreases sharply,finally tends to be constant.Compared with the Cu/Invar ones,thesinterability of the composites is greatly improved,resulting in that the pores in them are smaller in amount and size.After thethermo-mechanical treatment,the Cu/Ag(Invar)composites are nearly fully dense with the optimum phase composition and elementdistribution.More importantly,Cu and the Invar alloy in the composites distribute continuously in a three-dimensional(3D)networkstructure.Cu/Invar interface diffusion is effectively inhibited by the Ag barrier layer,leading to a great improvement of themechanical and thermal properties of the Cu/Ag(Invar)composites.展开更多
Transition metal oxides gain considerable research attentions as potential anode materials for lithium ion batteries,but their applications are hindered due to their poor electronic conductivity,weak cycle stability a...Transition metal oxides gain considerable research attentions as potential anode materials for lithium ion batteries,but their applications are hindered due to their poor electronic conductivity,weak cycle stability and drastic volume change.Here,a NiO@graphene composite with a unique 3D conductive network structure is prepared through a simple strategy.When applied as anode material for Li-ion batteries,at 50 mA g^(−1),the NiO@graphene displays a high reversible capacity of 1366 mAh g^(−1) and a stable cyclability of 205 mAh g^(−1) after 500 cycles.Even at a high rate of 10 A g^(−1),it displays a favorable reversible capacity of 711 mAh g^(−1).Remarkably,when it recovers back to 0.05 A g^(−1),a reversible capacity of 1741 mAh g^(−1) is achieved.Thus,the NiO@graphene composite with 3D structure shows good application prospects as an alternative anode for advanced lithium ion batteries.展开更多
基金Project(2014DFA50860) supported by the International Science&Technology Cooperation Program of China
文摘The Ag(Invar)composite powder prepared by ball milling was used to fabricate the Cu/Ag(Invar)composites.Microstructures and properties of the composites were studied after sintering and thermo-mechanical treatment.The results indicatethat during ball milling,micro-forging weld and work-hardening fracture result in that the average particle size of the Ag(Invar)powder increases rapidly at first,and then decreases sharply,finally tends to be constant.Compared with the Cu/Invar ones,thesinterability of the composites is greatly improved,resulting in that the pores in them are smaller in amount and size.After thethermo-mechanical treatment,the Cu/Ag(Invar)composites are nearly fully dense with the optimum phase composition and elementdistribution.More importantly,Cu and the Invar alloy in the composites distribute continuously in a three-dimensional(3D)networkstructure.Cu/Invar interface diffusion is effectively inhibited by the Ag barrier layer,leading to a great improvement of themechanical and thermal properties of the Cu/Ag(Invar)composites.
基金supported by the Science&Technology Department of Sichuan Province(No.2019YJ0665)the Opening Project of Material Corrosion and Protection Key Laboratory of Sichuan Province(No.2020CL10)。
文摘Transition metal oxides gain considerable research attentions as potential anode materials for lithium ion batteries,but their applications are hindered due to their poor electronic conductivity,weak cycle stability and drastic volume change.Here,a NiO@graphene composite with a unique 3D conductive network structure is prepared through a simple strategy.When applied as anode material for Li-ion batteries,at 50 mA g^(−1),the NiO@graphene displays a high reversible capacity of 1366 mAh g^(−1) and a stable cyclability of 205 mAh g^(−1) after 500 cycles.Even at a high rate of 10 A g^(−1),it displays a favorable reversible capacity of 711 mAh g^(−1).Remarkably,when it recovers back to 0.05 A g^(−1),a reversible capacity of 1741 mAh g^(−1) is achieved.Thus,the NiO@graphene composite with 3D structure shows good application prospects as an alternative anode for advanced lithium ion batteries.
