The oxidation of 3-picoline to nicotinic acid took place efficiently in an ethanol solution with 02 as the oxidant under the catalysis of T（o-Cl）PPMn at 40--150 ℃ and 0.5--3.0 MPa oxygen pressure. The influences of...The oxidation of 3-picoline to nicotinic acid took place efficiently in an ethanol solution with 02 as the oxidant under the catalysis of T（o-Cl）PPMn at 40--150 ℃ and 0.5--3.0 MPa oxygen pressure. The influences of temperature, oxygen pressure, reaction time, concentration of 3-picoline, concentration of sodium hydroxide, and concentration of T（o-Cl）PPMn catalyst, etc. on the production of nicotinic acid were investigated. The results show that T（o-Cl）PPMn presented excellent catalytic activity in the oxidation Of 3-pieoiine to nicotinic acid and the yield of nicotinic acid varied greatly with the reaction temperature, oxygen pressure, T（o-Cl）PPMn concentration, etc.展开更多
In an electrolytic cell with a proton exchange membrane, nicotinic acid was synthesized at the PbO2 anode. The relationship between the current density and the potential at different concentrations of 3-picoline and s...In an electrolytic cell with a proton exchange membrane, nicotinic acid was synthesized at the PbO2 anode. The relationship between the current density and the potential at different concentrations of 3-picoline and sulfuric acid as well as at different temperatures was studied with polarization curves. The effects of the concentrations of sulfuric acid and 3-picoline, the anode potential and the reaction temperature on the selectivity and the current efficiency were explored. The optimum conditions were determined by orthogonal experiments. Under optimum conditions the selectivity and the current efficiency for the synthesis of nicotinic acid might reach 89% and 65%, respectively. The, concentrations of 3-picoline and nicotinic acid were analyzed with high performance liquid chromatography and the product was characterized with elemental analysis, chromatography-mass spectrometry and IR spectrometry.展开更多
V-Mo-P oxide catalyst system was directly prepared from ll-molybdo-l-vanado phosphoric acid by thermal decomposition. Supported V-Mo-P oxide catalysts were prepared by wet impregnation method. Catalysts were character...V-Mo-P oxide catalyst system was directly prepared from ll-molybdo-l-vanado phosphoric acid by thermal decomposition. Supported V-Mo-P oxide catalysts were prepared by wet impregnation method. Catalysts were characterized by FTIR （Fourier transform infrared）, XRD （X-ray diffraction） and TPD （temperature programmed desorption）. The catalytic activity of V-Mo-P oxide catalysts were investigated for vapour phase ammoxidation of 3-picoline. The unsupported catalyst showed 92.1% yield where as V-Mo-P oxide/HZSM-5 showed the highest yield （80.4%） amongst the supported catalysts.展开更多
基金Supported by the National Natural Science Foundation of China(No.20576005)
文摘The oxidation of 3-picoline to nicotinic acid took place efficiently in an ethanol solution with 02 as the oxidant under the catalysis of T（o-Cl）PPMn at 40--150 ℃ and 0.5--3.0 MPa oxygen pressure. The influences of temperature, oxygen pressure, reaction time, concentration of 3-picoline, concentration of sodium hydroxide, and concentration of T（o-Cl）PPMn catalyst, etc. on the production of nicotinic acid were investigated. The results show that T（o-Cl）PPMn presented excellent catalytic activity in the oxidation Of 3-pieoiine to nicotinic acid and the yield of nicotinic acid varied greatly with the reaction temperature, oxygen pressure, T（o-Cl）PPMn concentration, etc.
文摘In an electrolytic cell with a proton exchange membrane, nicotinic acid was synthesized at the PbO2 anode. The relationship between the current density and the potential at different concentrations of 3-picoline and sulfuric acid as well as at different temperatures was studied with polarization curves. The effects of the concentrations of sulfuric acid and 3-picoline, the anode potential and the reaction temperature on the selectivity and the current efficiency were explored. The optimum conditions were determined by orthogonal experiments. Under optimum conditions the selectivity and the current efficiency for the synthesis of nicotinic acid might reach 89% and 65%, respectively. The, concentrations of 3-picoline and nicotinic acid were analyzed with high performance liquid chromatography and the product was characterized with elemental analysis, chromatography-mass spectrometry and IR spectrometry.
文摘V-Mo-P oxide catalyst system was directly prepared from ll-molybdo-l-vanado phosphoric acid by thermal decomposition. Supported V-Mo-P oxide catalysts were prepared by wet impregnation method. Catalysts were characterized by FTIR （Fourier transform infrared）, XRD （X-ray diffraction） and TPD （temperature programmed desorption）. The catalytic activity of V-Mo-P oxide catalysts were investigated for vapour phase ammoxidation of 3-picoline. The unsupported catalyst showed 92.1% yield where as V-Mo-P oxide/HZSM-5 showed the highest yield （80.4%） amongst the supported catalysts.
