Magnetization convenience is crucial consideration for design of valve magnetic actuators.The existing repulsive-magnetic-coupling of 2D maglev valve is not oriented to the integral-magnetization-processes,resulting i...Magnetization convenience is crucial consideration for design of valve magnetic actuators.The existing repulsive-magnetic-coupling of 2D maglev valve is not oriented to the integral-magnetization-processes,resulting in the high assembly cost.This paper presents a novel tractive-magnetic-coupling(TMC)and its application on a 2D electro-hydraulic proportional flow valve(2D-EHPFV),whose configuration not only fulfill the requirements of 2D valve,but also oriented to integral-magnetization-process.To investigate the output torque of TMC,a detailed analytical model considering leakage flux,edge effect and tooth magnetic saturation is formulated based on the equivalent magnetic circuit method.To facilitate the magnetic saturation calculation,a special magnetic permeability database is established for tooth region of TMC using Ansoft/Maxwell software.Prototype of TMC is machined and an exclusive experimental platform is built.Torque-displacement characteristics under different working airgap and tooth number are measured.The experimental results are in good agreement with the analytical results,which verifies the correctness of the analytical model.Then the TMC is integrated into the 2D-EHPFV by replacing the repulsive-magnetic-coupling.Prototype of 2D-EHPFV is designed and manufactured to test the no-load flow characteristics,load flow characteristics,leakage characteristics,frequency characteristics and step response.Under working pressure of 15 MPa,the maximum no-load flow rate is 82.2 L/min with the hysteresis of 2.6%,and the amplitude and phase frequency width is 21.6 Hz,and 28.9 Hz.The detailed experimental results show that TMC can be applied to 2D valves to form 2D-EHPFV,which can reduce hysteresis and cost,and improve response speed.展开更多
To investigate the band structure is one of the key approaches to study the fundamental properties of a novel material.We report here the precision band mapping of a 2-dimensional(2D) spin-orbit(SO) coupling in an opt...To investigate the band structure is one of the key approaches to study the fundamental properties of a novel material.We report here the precision band mapping of a 2-dimensional(2D) spin-orbit(SO) coupling in an optical lattice.By applying the microwave spin-injection spectroscopy, the band structure and spin-polarization distribution are achieved simultaneously.The band topology is also addressed with observing the band gap close and re-open at the Dirac points.Furthermore, the lattice depth and the Raman coupling strength are precisely calibrated with relative errors in the order of 10^(-3).Our approach could also be applied for exploring the exotic topological phases with even higher dimensional system.展开更多
Based on the two-component relativistic effective core potential and matched basis sets cc-pwcvnz-pp （n=Q, 5）, combining the completed basis-set extrapolation of electronic correlation energy and the fourth-order po...Based on the two-component relativistic effective core potential and matched basis sets cc-pwcvnz-pp （n=Q, 5）, combining the completed basis-set extrapolation of electronic correlation energy and the fourth-order polynomial fitting technique, the bond length and spectroscopic constants of Hg2 are studied by the coupled cluster theory with spin-orbit coupling. Spin-orbit coupling is included in the post Hartree-Fock procedure, i.e., in the coupled- cluster iteration, to obtain more reliable theoretical results. The results show that our theoretical values agree with the experimental values very well and will be helpful to understand the spectral character of Hg2.展开更多
Fabrication of large-area atomically thin transition metal dichalcogenides is of critical importance for the preparation of new heterojunction-based devices.In this paper, we report the fabrication and optical investi...Fabrication of large-area atomically thin transition metal dichalcogenides is of critical importance for the preparation of new heterojunction-based devices.In this paper, we report the fabrication and optical investigation of large-scale chemical vapor deposition(CVD)-grown monolayer MoS2 and exfoliated few-layer GaS heterojunctions.As revealed by photoluminescence(PL) characterization, the as-fabricated heterojunctions demonstrated edge interaction between the two layers.The heterojunction was sensitive to annealing and showed increased interaction upon annealing at 300℃ under vacuum conditions, which led to changes in both the emission peak position and intensity resulting from the strong coupling interaction between the two layers.Low-temperature PL measurements further confirmed the strong coupling interaction.In addition, defect-related GaS luminescence was observed in our few-layer GaS, and the PL mapping provided evidence of edge interaction coupling between the two layers.These findings are interesting and provide the basis for creating new material systems with rich functionalities and novel physical effects.展开更多
Considering phase changes associated with a high-temperature molten material cooled down from the outside,this work presents an improvement of the modelling and the numerical simulation of such processes for an applic...Considering phase changes associated with a high-temperature molten material cooled down from the outside,this work presents an improvement of the modelling and the numerical simulation of such processes for an application pertaining to the safety of light water nuclear reactors.Postulating a core meltdown accident,the behaviour of the core melt(aka corium)into a steel vessel is of tremendous importance when evaluating the vessel integrity.Evaluating correctly the heat fluxes requires the numerical simulation of the interaction between the liquid material and its solid counterpart which forms during the solidification process,but also may melt back.To simulate this configuration,encoun-tered in various industrial applications,one considers a bi-phase model constituted by a liquid phase in contact and interaction with its solid phase.The liquid phase may solidify in presence of low energetic source,while the solid phase may melt due to an intense heat flux from the high-temperature liquid.In the frame of the in-house legacy code,several simplifying assumptions(0D multi-layer discretization,instantaneous heat transfer via a quadratic temperature profile in solids)are made for the modelling of such phase changes.In the present work,these shortcomings are illustrated and further overcome by solving a 2D heat conduction model in the solid by a mixed Raviart-Thomas finite element method coupled to the liquid phase due to heat and mass exchanges through Stefan condition.The liquid phase is modeled with a 0D multi-layer approach.The 0D-liquid and 2D-solid mod-els are coupled by a Stefan like phase change interface model.Several sanity checks are performed to assess the validity of the approach on 1D and 2D academical configurations for which exact or reference solutions are available.Then more advanced situations(genu-ine multi-dimensional phase changes and an"industrial-like scenario")are simulated to verify the appropriate behavior of the obtained coupled simulation scheme.展开更多
In order to consider the influence of temperature and underground water movement, an elastoplastic model and a 2D FEM stress fields on the migration of radioactive nuclide with code for analysis of coupled thermo-hyd...In order to consider the influence of temperature and underground water movement, an elastoplastic model and a 2D FEM stress fields on the migration of radioactive nuclide with code for analysis of coupled thermo-hydro-mechanical （THM） processes in saturated and unsaturated porous media were extended and improved through introducing the percolation and migration equation, so that the code can be used for solving the temperature field, flow field, stress field and nuclide concentration field simultaneously. The states of temperatures, pore pressures and nuclide concentrations in the near field of a hypothetical nuclear waste repository were investigated. The influence of the half life of the radioactive nuclide on the temporal change of nuclide concentration was analyzed considering the thermo-hydro-mechanical-migratory coupling. The results show that, at the boundary of the vitrified waste, the concentration of radioactive nuclide with a half life of 10 a falls after a period of rising, with the maximum value of 0.182 mol/m3 and the minimum value of 0.181 mol/m^3 at the end of computation. For a half life of 1 000 a, the concentration of radioactive nuclide always increases with the increase of the time during the computation period; and the maximum value is 1.686 mol/m^3 at the end of the computation. Therefore, under the condition of THM coupling, the concentration of radioactive nuclide with a shorter half life will decrease more quickly with water flow; but for the radioactive nuclide with a longer half life, its concentration will keep at a higher level for a longer time in the migration process.展开更多
Combining vacuum preloading technology and electroosmosis can improve the treatment effect of soft soil foundation by utilizing the advantages of both methods.Many studies indicate that the soil electrical potential i...Combining vacuum preloading technology and electroosmosis can improve the treatment effect of soft soil foundation by utilizing the advantages of both methods.Many studies indicate that the soil electrical potential is non-linearly distributed in the treatment process by the combined method.However,in the previous theoretical study,the non-linear-distribution impacts of soil’s electrical potential on soft soil foundation treatment have not been considered.It is always assumed to be linear distribution,which is different from the experimental results.In this paper,the coupling consolidation model of this technology under the two-dimensional plane strain condition is initially established;and the well resistance effect,the vacuum load decreasing along the soil depth and the non-linear variation of electrical potential in the soil are considered.Then,the analytical solutions of the average excess pore water pressure and soil’s consolidation degree in the anode affected area are acquired based on the soil’s electrical potential distribution.Finally,the rationality of the analytical solution is testified by conducting an experimental model test,which proves the scientificity of the analytical solution.The analytical solution is adopted to better predict the dissipation of excess pore water pressure and soil consolidation degree when using the combined technology.This study can provide a reference with more accuracy for the engineering practices of this combined technology in the future.展开更多
High mobility quasi two-dimensional electron gas(2DEG)found at the CaZrO_(3)/SrTiO_(3) nonpolar heterointerface is attractive and provides a platform for the development of functional devices and nanoelectronics.Here ...High mobility quasi two-dimensional electron gas(2DEG)found at the CaZrO_(3)/SrTiO_(3) nonpolar heterointerface is attractive and provides a platform for the development of functional devices and nanoelectronics.Here we report that the carrier density and mobility at low temperature can be tuned by gate voltage at the CaZrO_(3)/SrTiO_(3) interface.Furthermore,the magnitude of Rashba spin-orbit interaction can be modulated and increases with the gate voltage.Remarkably,the diffusion constant and the spin-orbit relaxation time can be strongly tuned by gate voltage.The diffusion constant increases by a factor of~19.98 and the relaxation time is reduced by a factor of over three orders of magnitude while the gate voltage is swept from-50 V to 100 V.These findings not only lay a foundation for further understanding the underlying mechanism of Rashba spin-orbit coupling,but also have great significance in developing various oxide functional devices.展开更多
The coupler is fundamental for a coupled model to realize complex interactions among component models.This paper focuses on the coupling process of Wave-Circulation(W-C) coupled model which consists of MASNUM(key labo...The coupler is fundamental for a coupled model to realize complex interactions among component models.This paper focuses on the coupling process of Wave-Circulation(W-C) coupled model which consists of MASNUM(key laboratory of marine science and numerical modeling wave model)and POM(Princeton Ocean Model).The current coupling module of this coupled model is based on the inefficient I/O file,which has already become a performance bottleneck especially when the coupled model utilizes a large number of processes.To improve the performance of the W-C model,a flexible coupling module based on the model coupling toolkit(MCT) is designed and implemented to replace the current I/O file coupling module in the coupled model.Empirical studies that we have carried out demonstrate that our online coupling module can dramatically improve the parallel performance of the coupled model.The online coupling module outperforms the I/O file coupling module.When processes increase to 96,the whole process of EXP-C takes only 695.8 seconds,which is only 58.8%of the execution time of EXP-F.Based on our experiments under 2D Parallel Decomposition(2DPD),we suggest setting parallel decomposition strategies automatically to component models in order to achieve high parallel efficiency.展开更多
A novel color image encryption scheme is developed to enhance the security of encryption without increasing the complexity. Firstly, the plain color image is decomposed into three grayscale plain images, which are con...A novel color image encryption scheme is developed to enhance the security of encryption without increasing the complexity. Firstly, the plain color image is decomposed into three grayscale plain images, which are converted into the frequency domain coefficient matrices(FDCM) with discrete cosine transform(DCT) operation. After that, a twodimensional(2D) coupled chaotic system is developed and used to generate one group of embedded matrices and another group of encryption matrices, respectively. The embedded matrices are integrated with the FDCM to fulfill the frequency domain encryption, and then the inverse DCT processing is implemented to recover the spatial domain signal. Eventually,under the function of the encryption matrices and the proposed diagonal scrambling algorithm, the final color ciphertext is obtained. The experimental results show that the proposed method can not only ensure efficient encryption but also satisfy various sizes of image encryption. Besides, it has better performance than other similar techniques in statistical feature analysis, such as key space, key sensitivity, anti-differential attack, information entropy, noise attack, etc.展开更多
As one of the most important ways to reduce the greenhouse gas emission,carbon dioxide（CO2）enhanced gas recovery（CO2-EGR） is attractive since the gas recovery can be enhanced simultaneously with CO2sequestration.B...As one of the most important ways to reduce the greenhouse gas emission,carbon dioxide（CO2）enhanced gas recovery（CO2-EGR） is attractive since the gas recovery can be enhanced simultaneously with CO2sequestration.Based on the existing equation of state（EOS） module of TOUGH2 MP,extEOS7C is developed to calculate the phase partition of H2O-CO2-CH4-NaCl mixtures accurately with consideration of dissolved NaCI and brine properties at high pressure and temperature conditions.Verifications show that it can be applied up to the pressure of 100 MPa and temperature of 150℃.The module was implemented in the linked simulator TOUGH2MP-FLAC3 D for the coupled hydro-mechanical simulations.A simplified three-dimensional（3D）1/4 model（2.2 km×1 km×1 km） which consists of the whole reservoir,caprock and baserock was generated based on the geological conditions of a gas field in the North German Basin.The simulation results show that,under an injection rate of 200,000 t/yr and production rate of 200,000 sm3/d,CO2breakthrough occurred in the case with the initial reservoir pressure of 5 MPa but did not occur in the case of 42 MPa.Under low pressure conditions,the pressure driven horizontal transport is the dominant process;while under high pressure conditions,the density driven vertical flow is dominant.Under the considered conditions,the CO2-EGR caused only small pressure changes.The largest pore pressure increase（2 MPa） and uplift（7 mm） occurred at the caprock bottom induced by only CO2injection.The caprock had still the primary stress state and its integrity was not affected.The formation water salinity and temperature variations of ±20℃ had small influences on the CO2-EGR process.In order to slow down the breakthrough,it is suggested that CO2-EGR should be carried out before the reservoir pressure drops below the critical pressure of CO2.展开更多
Due to the high population density and economic property in urban environments,urban flooding can result in substantial economic losses.However,accurate urban flood modeling and assessing the associated damages are ch...Due to the high population density and economic property in urban environments,urban flooding can result in substantial economic losses.However,accurate urban flood modeling and assessing the associated damages are challenging due to complex urban layouts and rugged topography.Furthermore,the rapid development of urban underground spaces has introduced additional complexities.To address the demanding need for accurate flood modeling and damage assessment in cities,a fine-scale flood damage assessment method was proposed in this study,based on the 1D/2D coupled hydrodynamic model,which can not only assess the flood damage on the ground surface but also evaluate the flood loss in underground spaces.Taking the Gangxi drainage area in Wuhan City,China as a case,this study extensively discussed the flood inundation processes on the ground surface as well as in the buildings and underground spaces,under different rainfall scenarios with the return period ranging from 2 to 200 years.Based on the high spatial-temporal hydrodynamic simulations,the flood damage degrees were evaluated for the buildings and underground spaces with different industry types.The results indicated that the inundation of buildings and underground spaces in densely built cities cannot be neglected in urban flood modeling.Buildings with public service attributes can have a higher flood damage degree,as compared with other types of buildings and underground spaces.展开更多
We report magnetization and Raman spectroscopy study on single crystals of VOCl,a van der Waals antiferromagnetic material.Magnetization measurement confirms an antiferromagnetic transition at 79 K and a magnetic easy...We report magnetization and Raman spectroscopy study on single crystals of VOCl,a van der Waals antiferromagnetic material.Magnetization measurement confirms an antiferromagnetic transition at 79 K and a magnetic easy axis along crystallographic a direction.The temperature-dependent Raman spectrum reveals five peaks at 30 K.Below the Neel temperature TN,the Raman-active modes 247 cm^(−1) and 404 cm^(−1) remarkably deviate from the standard Boltzmann function,which is ascribed to the strong magnetoelastic coupling between spins and phonons.We further observe an anomaly in 383 cm^(−1) mode at around 150 K.This coincides with the broad maximum in VOCl’s magnetic susceptibility,suggesting a development of short-ranged magnetic order at this temperature.展开更多
In this study, 1D and 2D shallow-water models were coupled to simulate unsteady flow in channel networks and embayment. The 1D model solved the 1D shallow-water equations (St. Venant) using the Preissmann box method a...In this study, 1D and 2D shallow-water models were coupled to simulate unsteady flow in channel networks and embayment. The 1D model solved the 1D shallow-water equations (St. Venant) using the Preissmann box method and targeted long narrow reaches of the river networks, while the 2D model targeted broad channels and embayment and solved the 2D shallow-water equations using a semi-implicit scheme applied to an unstructured grid of triangular cells. The 1D and 2D models were solved simultaneously by building a matrix for the free surface elevation at every 1D junction and 2D cell center. Velocities were then computed explicitly based on the results at the previous time step and the updated water level. The originality of the scheme arose from a novel coupling method. The results showed that the coupled 1D/2D model produced identical results as the full 2D model in classical to benchmark problems with considerable savings in computational effort. Application of the model to the Pearl River Estuary in southern China showed that complex patterns of tidal wave propagation could be efficiently modeled.展开更多
This paper points out that a successful numerical simulation is to construct a correct conceptional model which is very dose to the natural condition. A new model, two dimensional coupled three dimensional model (2D -...This paper points out that a successful numerical simulation is to construct a correct conceptional model which is very dose to the natural condition. A new model, two dimensional coupled three dimensional model (2D -3D ) is presented in the Present paper,which is the most suitable one for the dual - structured - aquifer system. An example of Wenyinghu area is shown.By using the 2D-3D model, a satisfied result of the simulated area is achieved.展开更多
To investigate the bedding influence on coal mechanical behaviour in underground environments such as coal or rock burst, simulations of dynamic SHPB tests of pre-stressed coal specimens with different bedding angles ...To investigate the bedding influence on coal mechanical behaviour in underground environments such as coal or rock burst, simulations of dynamic SHPB tests of pre-stressed coal specimens with different bedding angles were carried out using a particle flow code 2-dimensional(PFC2D). Three impact velocities of 4, 8 and 12 m/s were selected to study dynamic behaviours of coal containing bedding planes under different dynamic loads. The simulation results showed that the existence of bedding planes leads to the degradation of the mechanical properties and their weakening effect significantly depends on the angle h between the bedding planes and load direction. With h increaseing from 0° to 90°, the strength first decreased and subsequently increased and specimens became most vulnerable when h was 30° or 45°.Five failure modes were observed in the specimens in the context of macro-cracks. Furthermore, energy characteristics combined with ultimate failure patterns revealed that maximum accumulated energy and failure intensity have a positive relation with the strength of specimen. When bedding planes were parallel or perpendicular to loading direction, specimens absorbed more energy and experienced more violent failure with increased number of cracks. In contrast, bedding planes with h of 30° or 45° reduced the specimens' ability of storing strain energy to the lowest with fewer cracks observed after failure.展开更多
The rapid recombination of photo-generated electron-hole pairs,insufficient active sites,and strong photocorrosion have considerably restricted the practical application of Cd S in photocatalytic fields.Herein,we desi...The rapid recombination of photo-generated electron-hole pairs,insufficient active sites,and strong photocorrosion have considerably restricted the practical application of Cd S in photocatalytic fields.Herein,we designed and constructed a 2D/2D/2D layered heterojunction photocatalyst with cascaded 2D coupling interfaces.Experiments using electron spin resonance spectroscopy,ultraviolet photoelectron spectroscopy,and in-situ irradiation X-ray photoelectron spectroscopy were conducted to confirm the 2D layered CdS/WO_(3) step-scheme(S-scheme)heterojunctions and CdS/MX ohmic junctions.Impressively,it was found that the strong interfacial electric fields in the S-scheme heterojunction photocatalysts could effectively promote spatially directional charge separation and transport between CdS and WO_(3) nanosheets.In addition,2D Ti_(3)C_(2) MXene nanosheets with a smaller work function and excellent metal conductivity when used as a co-catalyst could build ohmic junctions with Cd S nanosheets,thus providing a greater number of electron transfer pathways and hydrogen evolution sites.Results showed that the highest visible-light hydrogen evolution rate of the optimized MX-Cd S/WO_(3) layered multi-heterostructures could reach as high as 27.5 mmol/g/h,which was 11.0 times higher than that of pure CdS nanosheets.Notably,the apparent quantum efficiency reached 12.0% at 450 nm.It is hoped that this study offers a reliable approach for developing multifunctional photocatalysts by integrating S-scheme and ohmic-junction built-in electric fields and rationally designing a 2D/2D interface for efficient light-to-hydrogen fuel production.展开更多
This paper presents a novel two-dimensional maglev servo proportional cartridge valve(2 D maglev valve),where a contactless maglev coupling is introduced between electro-mechanical converter and valve body to realize ...This paper presents a novel two-dimensional maglev servo proportional cartridge valve(2 D maglev valve),where a contactless maglev coupling is introduced between electro-mechanical converter and valve body to realize functions of force transmission,spool position feedback and linear-rotary motion conversion.Such configuration can effectively reduce cost of both valve manufacturing and electro-mechanical converter,while still maintain features of 2 D valve such as null pilot leakage,high power-to-weight ratio and excellent anti-pollution capacity.Firstly,the characteristic equation of the valve is derived using linear theory,and the stability criterion is established for parameter determination.The influences of crucial structural parameters such as initial height of overlapping area,width of high-pressure and low-pressure holes,acting radius of magnetic force,pitch angle of maglev coupling,length of sensitive chamber and system pressure on the dynamic response are investigated based on AMESim numerical simulation.The prototype valve is then designed and manufactured and a special test rig is built.The no-load flow characteristic,load flow characteristic,leakage characteristic,amplitude and phase frequency characteristics and step response under different system pressures are measured.The experimental results are in a good agreement with the simulated analysis.As an over-damped system,the prototype valve has excellent working stability,which can reach a no-load flow rate of 105.9 L/min with hysteresis of 3.51%,amplitude bandwidth of 28.7 Hz and phase bandwidth of 42.8 Hz under 21 MPa.The research indicates that the 2 D maglev valve can be a potential solution of flow rate control valve for flight control surface system of civil aircraft with high pressure and large flow rate application.展开更多
基金Supported by National Natural Science Foundation of China(Grant Nos.51975524,52375067)Zhejiang Provincial Natural Science Foundation of China(Grant No.Y23E050014).
文摘Magnetization convenience is crucial consideration for design of valve magnetic actuators.The existing repulsive-magnetic-coupling of 2D maglev valve is not oriented to the integral-magnetization-processes,resulting in the high assembly cost.This paper presents a novel tractive-magnetic-coupling(TMC)and its application on a 2D electro-hydraulic proportional flow valve(2D-EHPFV),whose configuration not only fulfill the requirements of 2D valve,but also oriented to integral-magnetization-process.To investigate the output torque of TMC,a detailed analytical model considering leakage flux,edge effect and tooth magnetic saturation is formulated based on the equivalent magnetic circuit method.To facilitate the magnetic saturation calculation,a special magnetic permeability database is established for tooth region of TMC using Ansoft/Maxwell software.Prototype of TMC is machined and an exclusive experimental platform is built.Torque-displacement characteristics under different working airgap and tooth number are measured.The experimental results are in good agreement with the analytical results,which verifies the correctness of the analytical model.Then the TMC is integrated into the 2D-EHPFV by replacing the repulsive-magnetic-coupling.Prototype of 2D-EHPFV is designed and manufactured to test the no-load flow characteristics,load flow characteristics,leakage characteristics,frequency characteristics and step response.Under working pressure of 15 MPa,the maximum no-load flow rate is 82.2 L/min with the hysteresis of 2.6%,and the amplitude and phase frequency width is 21.6 Hz,and 28.9 Hz.The detailed experimental results show that TMC can be applied to 2D valves to form 2D-EHPFV,which can reduce hysteresis and cost,and improve response speed.
基金supported by the National Key R&D Program of China (2016YFA0301601 and 2016YFA0301604)the National Natural Science Foundation of China (11674301, 11761161003, and 11625522)the Thousand-Young-Talent Program of China
文摘To investigate the band structure is one of the key approaches to study the fundamental properties of a novel material.We report here the precision band mapping of a 2-dimensional(2D) spin-orbit(SO) coupling in an optical lattice.By applying the microwave spin-injection spectroscopy, the band structure and spin-polarization distribution are achieved simultaneously.The band topology is also addressed with observing the band gap close and re-open at the Dirac points.Furthermore, the lattice depth and the Raman coupling strength are precisely calibrated with relative errors in the order of 10^(-3).Our approach could also be applied for exploring the exotic topological phases with even higher dimensional system.
基金Supported by the Start-Up Funds of Xi’an Polytechnic University under Grant No BS1211the Scientific Research Program Funded by Shaanxi Provincial Education Department under Grant No 2013JK0679
文摘Based on the two-component relativistic effective core potential and matched basis sets cc-pwcvnz-pp （n=Q, 5）, combining the completed basis-set extrapolation of electronic correlation energy and the fourth-order polynomial fitting technique, the bond length and spectroscopic constants of Hg2 are studied by the coupled cluster theory with spin-orbit coupling. Spin-orbit coupling is included in the post Hartree-Fock procedure, i.e., in the coupled- cluster iteration, to obtain more reliable theoretical results. The results show that our theoretical values agree with the experimental values very well and will be helpful to understand the spectral character of Hg2.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11104250,61274099,and 11774313)the Science Technology Department of Zhejiang Province,China(Grant No.2012C21007)+1 种基金Zhejiang Province Innovation Team,China(Grant No.2011R50012)Zhejiang Provincial Natural Science Foundation,China(Grant No.LY17A040003)
文摘Fabrication of large-area atomically thin transition metal dichalcogenides is of critical importance for the preparation of new heterojunction-based devices.In this paper, we report the fabrication and optical investigation of large-scale chemical vapor deposition(CVD)-grown monolayer MoS2 and exfoliated few-layer GaS heterojunctions.As revealed by photoluminescence(PL) characterization, the as-fabricated heterojunctions demonstrated edge interaction between the two layers.The heterojunction was sensitive to annealing and showed increased interaction upon annealing at 300℃ under vacuum conditions, which led to changes in both the emission peak position and intensity resulting from the strong coupling interaction between the two layers.Low-temperature PL measurements further confirmed the strong coupling interaction.In addition, defect-related GaS luminescence was observed in our few-layer GaS, and the PL mapping provided evidence of edge interaction coupling between the two layers.These findings are interesting and provide the basis for creating new material systems with rich functionalities and novel physical effects.
基金funded by CEA,EDF and Framatomefinancial and scientific support of CEA Cadarache.
文摘Considering phase changes associated with a high-temperature molten material cooled down from the outside,this work presents an improvement of the modelling and the numerical simulation of such processes for an application pertaining to the safety of light water nuclear reactors.Postulating a core meltdown accident,the behaviour of the core melt(aka corium)into a steel vessel is of tremendous importance when evaluating the vessel integrity.Evaluating correctly the heat fluxes requires the numerical simulation of the interaction between the liquid material and its solid counterpart which forms during the solidification process,but also may melt back.To simulate this configuration,encoun-tered in various industrial applications,one considers a bi-phase model constituted by a liquid phase in contact and interaction with its solid phase.The liquid phase may solidify in presence of low energetic source,while the solid phase may melt due to an intense heat flux from the high-temperature liquid.In the frame of the in-house legacy code,several simplifying assumptions(0D multi-layer discretization,instantaneous heat transfer via a quadratic temperature profile in solids)are made for the modelling of such phase changes.In the present work,these shortcomings are illustrated and further overcome by solving a 2D heat conduction model in the solid by a mixed Raviart-Thomas finite element method coupled to the liquid phase due to heat and mass exchanges through Stefan condition.The liquid phase is modeled with a 0D multi-layer approach.The 0D-liquid and 2D-solid mod-els are coupled by a Stefan like phase change interface model.Several sanity checks are performed to assess the validity of the approach on 1D and 2D academical configurations for which exact or reference solutions are available.Then more advanced situations(genu-ine multi-dimensional phase changes and an"industrial-like scenario")are simulated to verify the appropriate behavior of the obtained coupled simulation scheme.
基金Project(2010CB732101) supported by the National Basic Research Program of China Project(SKLQ 008) supported by the Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering of China
文摘In order to consider the influence of temperature and underground water movement, an elastoplastic model and a 2D FEM stress fields on the migration of radioactive nuclide with code for analysis of coupled thermo-hydro-mechanical （THM） processes in saturated and unsaturated porous media were extended and improved through introducing the percolation and migration equation, so that the code can be used for solving the temperature field, flow field, stress field and nuclide concentration field simultaneously. The states of temperatures, pore pressures and nuclide concentrations in the near field of a hypothetical nuclear waste repository were investigated. The influence of the half life of the radioactive nuclide on the temporal change of nuclide concentration was analyzed considering the thermo-hydro-mechanical-migratory coupling. The results show that, at the boundary of the vitrified waste, the concentration of radioactive nuclide with a half life of 10 a falls after a period of rising, with the maximum value of 0.182 mol/m3 and the minimum value of 0.181 mol/m^3 at the end of computation. For a half life of 1 000 a, the concentration of radioactive nuclide always increases with the increase of the time during the computation period; and the maximum value is 1.686 mol/m^3 at the end of the computation. Therefore, under the condition of THM coupling, the concentration of radioactive nuclide with a shorter half life will decrease more quickly with water flow; but for the radioactive nuclide with a longer half life, its concentration will keep at a higher level for a longer time in the migration process.
基金Project(51979087)supported by the National Natural Science Foundation of ChinaProject(BK20180776)supported by the Jiangsu Natural Science Foundation,ChinaProject(202006710002)supported by the China Scholarship Council。
文摘Combining vacuum preloading technology and electroosmosis can improve the treatment effect of soft soil foundation by utilizing the advantages of both methods.Many studies indicate that the soil electrical potential is non-linearly distributed in the treatment process by the combined method.However,in the previous theoretical study,the non-linear-distribution impacts of soil’s electrical potential on soft soil foundation treatment have not been considered.It is always assumed to be linear distribution,which is different from the experimental results.In this paper,the coupling consolidation model of this technology under the two-dimensional plane strain condition is initially established;and the well resistance effect,the vacuum load decreasing along the soil depth and the non-linear variation of electrical potential in the soil are considered.Then,the analytical solutions of the average excess pore water pressure and soil’s consolidation degree in the anode affected area are acquired based on the soil’s electrical potential distribution.Finally,the rationality of the analytical solution is testified by conducting an experimental model test,which proves the scientificity of the analytical solution.The analytical solution is adopted to better predict the dissipation of excess pore water pressure and soil consolidation degree when using the combined technology.This study can provide a reference with more accuracy for the engineering practices of this combined technology in the future.
基金supported by the National Natural Science Foundation of China(Grants Nos.92065110,11974048,and 12074334)。
文摘High mobility quasi two-dimensional electron gas(2DEG)found at the CaZrO_(3)/SrTiO_(3) nonpolar heterointerface is attractive and provides a platform for the development of functional devices and nanoelectronics.Here we report that the carrier density and mobility at low temperature can be tuned by gate voltage at the CaZrO_(3)/SrTiO_(3) interface.Furthermore,the magnitude of Rashba spin-orbit interaction can be modulated and increases with the gate voltage.Remarkably,the diffusion constant and the spin-orbit relaxation time can be strongly tuned by gate voltage.The diffusion constant increases by a factor of~19.98 and the relaxation time is reduced by a factor of over three orders of magnitude while the gate voltage is swept from-50 V to 100 V.These findings not only lay a foundation for further understanding the underlying mechanism of Rashba spin-orbit coupling,but also have great significance in developing various oxide functional devices.
基金Supported by the National High Technology Research and Development Programme(No.2010AA012400,2010AA012302)the National Natural Science Foundation of China(No.61040048)
文摘The coupler is fundamental for a coupled model to realize complex interactions among component models.This paper focuses on the coupling process of Wave-Circulation(W-C) coupled model which consists of MASNUM(key laboratory of marine science and numerical modeling wave model)and POM(Princeton Ocean Model).The current coupling module of this coupled model is based on the inefficient I/O file,which has already become a performance bottleneck especially when the coupled model utilizes a large number of processes.To improve the performance of the W-C model,a flexible coupling module based on the model coupling toolkit(MCT) is designed and implemented to replace the current I/O file coupling module in the coupled model.Empirical studies that we have carried out demonstrate that our online coupling module can dramatically improve the parallel performance of the coupled model.The online coupling module outperforms the I/O file coupling module.When processes increase to 96,the whole process of EXP-C takes only 695.8 seconds,which is only 58.8%of the execution time of EXP-F.Based on our experiments under 2D Parallel Decomposition(2DPD),we suggest setting parallel decomposition strategies automatically to component models in order to achieve high parallel efficiency.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.62105004 and 52174141)the College Student Innovation and Entrepreneurship Fund Project(Grant No.202210361053)+1 种基金Anhui Mining Machinery and Electrical Equipment Coordination Innovation Center,Anhui University of Science&Technology(Grant No.KSJD202304)the Anhui Province Digital Agricultural Engineering Technology Research Center Open Project(Grant No.AHSZNYGC-ZXKF021)。
文摘A novel color image encryption scheme is developed to enhance the security of encryption without increasing the complexity. Firstly, the plain color image is decomposed into three grayscale plain images, which are converted into the frequency domain coefficient matrices(FDCM) with discrete cosine transform(DCT) operation. After that, a twodimensional(2D) coupled chaotic system is developed and used to generate one group of embedded matrices and another group of encryption matrices, respectively. The embedded matrices are integrated with the FDCM to fulfill the frequency domain encryption, and then the inverse DCT processing is implemented to recover the spatial domain signal. Eventually,under the function of the encryption matrices and the proposed diagonal scrambling algorithm, the final color ciphertext is obtained. The experimental results show that the proposed method can not only ensure efficient encryption but also satisfy various sizes of image encryption. Besides, it has better performance than other similar techniques in statistical feature analysis, such as key space, key sensitivity, anti-differential attack, information entropy, noise attack, etc.
基金funded by the National Natural Science Foundation of China(Grant No.NSFC51374147)the German Society for Petroleum and Coal Science and Technology(Grant No.DGMK680-4)
文摘As one of the most important ways to reduce the greenhouse gas emission,carbon dioxide（CO2）enhanced gas recovery（CO2-EGR） is attractive since the gas recovery can be enhanced simultaneously with CO2sequestration.Based on the existing equation of state（EOS） module of TOUGH2 MP,extEOS7C is developed to calculate the phase partition of H2O-CO2-CH4-NaCl mixtures accurately with consideration of dissolved NaCI and brine properties at high pressure and temperature conditions.Verifications show that it can be applied up to the pressure of 100 MPa and temperature of 150℃.The module was implemented in the linked simulator TOUGH2MP-FLAC3 D for the coupled hydro-mechanical simulations.A simplified three-dimensional（3D）1/4 model（2.2 km×1 km×1 km） which consists of the whole reservoir,caprock and baserock was generated based on the geological conditions of a gas field in the North German Basin.The simulation results show that,under an injection rate of 200,000 t/yr and production rate of 200,000 sm3/d,CO2breakthrough occurred in the case with the initial reservoir pressure of 5 MPa but did not occur in the case of 42 MPa.Under low pressure conditions,the pressure driven horizontal transport is the dominant process;while under high pressure conditions,the density driven vertical flow is dominant.Under the considered conditions,the CO2-EGR caused only small pressure changes.The largest pore pressure increase（2 MPa） and uplift（7 mm） occurred at the caprock bottom induced by only CO2injection.The caprock had still the primary stress state and its integrity was not affected.The formation water salinity and temperature variations of ±20℃ had small influences on the CO2-EGR process.In order to slow down the breakthrough,it is suggested that CO2-EGR should be carried out before the reservoir pressure drops below the critical pressure of CO2.
基金National Natural Science Foundation of China,Grant/Award Numbers:41890820,51725902,52209098Special Fund for Science and Technology Innovation Strategy of Guangdong Province,Grant/Award Number:gdsky2023-02+1 种基金Newton Advanced Fellowships from the NSFC and the UK Royal Society,Grant/Award Numbers:52061130219,NAF\R1\201156Science and Technology Innovation Program from Water Resources of Guangdong Province,Grant/Award Numbers:2022-01,2023-05。
文摘Due to the high population density and economic property in urban environments,urban flooding can result in substantial economic losses.However,accurate urban flood modeling and assessing the associated damages are challenging due to complex urban layouts and rugged topography.Furthermore,the rapid development of urban underground spaces has introduced additional complexities.To address the demanding need for accurate flood modeling and damage assessment in cities,a fine-scale flood damage assessment method was proposed in this study,based on the 1D/2D coupled hydrodynamic model,which can not only assess the flood damage on the ground surface but also evaluate the flood loss in underground spaces.Taking the Gangxi drainage area in Wuhan City,China as a case,this study extensively discussed the flood inundation processes on the ground surface as well as in the buildings and underground spaces,under different rainfall scenarios with the return period ranging from 2 to 200 years.Based on the high spatial-temporal hydrodynamic simulations,the flood damage degrees were evaluated for the buildings and underground spaces with different industry types.The results indicated that the inundation of buildings and underground spaces in densely built cities cannot be neglected in urban flood modeling.Buildings with public service attributes can have a higher flood damage degree,as compared with other types of buildings and underground spaces.
基金supported by the National Natural Science Foundation of China(Grant Nos.U2032213,U1832214,and 11774352)。
文摘We report magnetization and Raman spectroscopy study on single crystals of VOCl,a van der Waals antiferromagnetic material.Magnetization measurement confirms an antiferromagnetic transition at 79 K and a magnetic easy axis along crystallographic a direction.The temperature-dependent Raman spectrum reveals five peaks at 30 K.Below the Neel temperature TN,the Raman-active modes 247 cm^(−1) and 404 cm^(−1) remarkably deviate from the standard Boltzmann function,which is ascribed to the strong magnetoelastic coupling between spins and phonons.We further observe an anomaly in 383 cm^(−1) mode at around 150 K.This coincides with the broad maximum in VOCl’s magnetic susceptibility,suggesting a development of short-ranged magnetic order at this temperature.
基金financially supporrted by the National Key Research and Development Program of China(Grant No.2017YFC1404200)the National Natural Science Foundation of China(Grant Nos.51779150 and 51979040)
文摘In this study, 1D and 2D shallow-water models were coupled to simulate unsteady flow in channel networks and embayment. The 1D model solved the 1D shallow-water equations (St. Venant) using the Preissmann box method and targeted long narrow reaches of the river networks, while the 2D model targeted broad channels and embayment and solved the 2D shallow-water equations using a semi-implicit scheme applied to an unstructured grid of triangular cells. The 1D and 2D models were solved simultaneously by building a matrix for the free surface elevation at every 1D junction and 2D cell center. Velocities were then computed explicitly based on the results at the previous time step and the updated water level. The originality of the scheme arose from a novel coupling method. The results showed that the coupled 1D/2D model produced identical results as the full 2D model in classical to benchmark problems with considerable savings in computational effort. Application of the model to the Pearl River Estuary in southern China showed that complex patterns of tidal wave propagation could be efficiently modeled.
文摘This paper points out that a successful numerical simulation is to construct a correct conceptional model which is very dose to the natural condition. A new model, two dimensional coupled three dimensional model (2D -3D ) is presented in the Present paper,which is the most suitable one for the dual - structured - aquifer system. An example of Wenyinghu area is shown.By using the 2D-3D model, a satisfied result of the simulated area is achieved.
基金the Chinese Scholarship Council (No. 201706370022) for the financial support to the joint Ph.D. programme at the University of Wollongong,Australia
文摘To investigate the bedding influence on coal mechanical behaviour in underground environments such as coal or rock burst, simulations of dynamic SHPB tests of pre-stressed coal specimens with different bedding angles were carried out using a particle flow code 2-dimensional(PFC2D). Three impact velocities of 4, 8 and 12 m/s were selected to study dynamic behaviours of coal containing bedding planes under different dynamic loads. The simulation results showed that the existence of bedding planes leads to the degradation of the mechanical properties and their weakening effect significantly depends on the angle h between the bedding planes and load direction. With h increaseing from 0° to 90°, the strength first decreased and subsequently increased and specimens became most vulnerable when h was 30° or 45°.Five failure modes were observed in the specimens in the context of macro-cracks. Furthermore, energy characteristics combined with ultimate failure patterns revealed that maximum accumulated energy and failure intensity have a positive relation with the strength of specimen. When bedding planes were parallel or perpendicular to loading direction, specimens absorbed more energy and experienced more violent failure with increased number of cracks. In contrast, bedding planes with h of 30° or 45° reduced the specimens' ability of storing strain energy to the lowest with fewer cracks observed after failure.
文摘The rapid recombination of photo-generated electron-hole pairs,insufficient active sites,and strong photocorrosion have considerably restricted the practical application of Cd S in photocatalytic fields.Herein,we designed and constructed a 2D/2D/2D layered heterojunction photocatalyst with cascaded 2D coupling interfaces.Experiments using electron spin resonance spectroscopy,ultraviolet photoelectron spectroscopy,and in-situ irradiation X-ray photoelectron spectroscopy were conducted to confirm the 2D layered CdS/WO_(3) step-scheme(S-scheme)heterojunctions and CdS/MX ohmic junctions.Impressively,it was found that the strong interfacial electric fields in the S-scheme heterojunction photocatalysts could effectively promote spatially directional charge separation and transport between CdS and WO_(3) nanosheets.In addition,2D Ti_(3)C_(2) MXene nanosheets with a smaller work function and excellent metal conductivity when used as a co-catalyst could build ohmic junctions with Cd S nanosheets,thus providing a greater number of electron transfer pathways and hydrogen evolution sites.Results showed that the highest visible-light hydrogen evolution rate of the optimized MX-Cd S/WO_(3) layered multi-heterostructures could reach as high as 27.5 mmol/g/h,which was 11.0 times higher than that of pure CdS nanosheets.Notably,the apparent quantum efficiency reached 12.0% at 450 nm.It is hoped that this study offers a reliable approach for developing multifunctional photocatalysts by integrating S-scheme and ohmic-junction built-in electric fields and rationally designing a 2D/2D interface for efficient light-to-hydrogen fuel production.
基金the National Natural Science Foundation of China(Nos.51975524 and 51405443)the National Key Research and Development Program(No.2019YFB2005201)。
文摘This paper presents a novel two-dimensional maglev servo proportional cartridge valve(2 D maglev valve),where a contactless maglev coupling is introduced between electro-mechanical converter and valve body to realize functions of force transmission,spool position feedback and linear-rotary motion conversion.Such configuration can effectively reduce cost of both valve manufacturing and electro-mechanical converter,while still maintain features of 2 D valve such as null pilot leakage,high power-to-weight ratio and excellent anti-pollution capacity.Firstly,the characteristic equation of the valve is derived using linear theory,and the stability criterion is established for parameter determination.The influences of crucial structural parameters such as initial height of overlapping area,width of high-pressure and low-pressure holes,acting radius of magnetic force,pitch angle of maglev coupling,length of sensitive chamber and system pressure on the dynamic response are investigated based on AMESim numerical simulation.The prototype valve is then designed and manufactured and a special test rig is built.The no-load flow characteristic,load flow characteristic,leakage characteristic,amplitude and phase frequency characteristics and step response under different system pressures are measured.The experimental results are in a good agreement with the simulated analysis.As an over-damped system,the prototype valve has excellent working stability,which can reach a no-load flow rate of 105.9 L/min with hysteresis of 3.51%,amplitude bandwidth of 28.7 Hz and phase bandwidth of 42.8 Hz under 21 MPa.The research indicates that the 2 D maglev valve can be a potential solution of flow rate control valve for flight control surface system of civil aircraft with high pressure and large flow rate application.
