The dispersion of K\-2CO\-3 on \%γ\%\|Al\-2O\-3 and the adsorption performance of K\-2CO\-3/\%γ\%\|Al\-2O\-3 to SO\-2 are investigated.The results show that K\-2CO\-3 can disperse onto the surface of \%γ\%\|Al\-2O\...The dispersion of K\-2CO\-3 on \%γ\%\|Al\-2O\-3 and the adsorption performance of K\-2CO\-3/\%γ\%\|Al\-2O\-3 to SO\-2 are investigated.The results show that K\-2CO\-3 can disperse onto the surface of \%γ\%\|Al\-2O\-3 as a monolayer and the dispersion threshold is 0.31\[\%m\%(K\-2CO\-3)/\%m\%(\%γ\%\|Al\-2O\-3), \%m\%/g\], which is close to the theoretical value calculated by assuming a bidentate vertical dispersion model of CO\-2 on the \%γ\%\|Al\-2O\-3 surface . The SO\-2 adsorption\|capacity on K\-2CO\-3/\%γ\%\|Al\-2O\-3 sample increases with the K\-2CO\-3 loading and reaches an extremum at its threshold. The adsorbent conversion of K\-2CO\-3/\%γ\%\|Al\-2O\-3 at the threshold is up to 72%. When the loading is higher than the threshold, the SO\-2 adsorption capacity decreases at first, then increases again. This phenomenon is caused by the reaction between SO\-2 and the bulk phase of K\-2CO\-3 crystallites. The sample decreases with the loading, and the sample with \{0.10\}\[\%m\%(K\-2CO\-3)/\%m(γ\%\|Al\-2O\-3), \%m\%/g\] loading shows the highest regeneration percentage of 63%. Compared with Na\-2CO\-3/\%γ\%\|Al\-2O\-3, K\-2CO\-3/\%γ\%\|Al\-2O\-3 might have some advantages.展开更多
The carbonation characteristics of K2CO3/Al2O3 supported sorbent for CO2 capture was investigated with thermogravimetric apparatus(TGA),X-ray diffraction(XRD),scanning electron microscopy analysis(SEM)and N2 adsorptio...The carbonation characteristics of K2CO3/Al2O3 supported sorbent for CO2 capture was investigated with thermogravimetric apparatus(TGA),X-ray diffraction(XRD),scanning electron microscopy analysis(SEM)and N2 adsorption.The results showed that the carbonation rate of K2CO3 before being loaded on Al2O3 was slow.However,the K2CO3/Al2O3supported sorbent showed excellent carbonation performance.The difference in carbonation behavior between K2CO3and K2CO3/Al2O3supported sorbent was analyzed from the microscopic view.The analytical reagent K2CO3 sample was of monoclinic crystal structure and could react quickly with H2O in the experimental carbonation environment to produce K2CO3·1.5H2O,which was unfavorable to carbonation reaction.When K2CO3was loaded on Al2O3,the surface area and porosity of the sorbent was improved greatly.So the carbonation properties of the K2CO3/Al2O3 supported sorbent was also improved.展开更多
文摘The dispersion of K\-2CO\-3 on \%γ\%\|Al\-2O\-3 and the adsorption performance of K\-2CO\-3/\%γ\%\|Al\-2O\-3 to SO\-2 are investigated.The results show that K\-2CO\-3 can disperse onto the surface of \%γ\%\|Al\-2O\-3 as a monolayer and the dispersion threshold is 0.31\[\%m\%(K\-2CO\-3)/\%m\%(\%γ\%\|Al\-2O\-3), \%m\%/g\], which is close to the theoretical value calculated by assuming a bidentate vertical dispersion model of CO\-2 on the \%γ\%\|Al\-2O\-3 surface . The SO\-2 adsorption\|capacity on K\-2CO\-3/\%γ\%\|Al\-2O\-3 sample increases with the K\-2CO\-3 loading and reaches an extremum at its threshold. The adsorbent conversion of K\-2CO\-3/\%γ\%\|Al\-2O\-3 at the threshold is up to 72%. When the loading is higher than the threshold, the SO\-2 adsorption capacity decreases at first, then increases again. This phenomenon is caused by the reaction between SO\-2 and the bulk phase of K\-2CO\-3 crystallites. The sample decreases with the loading, and the sample with \{0.10\}\[\%m\%(K\-2CO\-3)/\%m(γ\%\|Al\-2O\-3), \%m\%/g\] loading shows the highest regeneration percentage of 63%. Compared with Na\-2CO\-3/\%γ\%\|Al\-2O\-3, K\-2CO\-3/\%γ\%\|Al\-2O\-3 might have some advantages.
文摘The carbonation characteristics of K2CO3/Al2O3 supported sorbent for CO2 capture was investigated with thermogravimetric apparatus(TGA),X-ray diffraction(XRD),scanning electron microscopy analysis(SEM)and N2 adsorption.The results showed that the carbonation rate of K2CO3 before being loaded on Al2O3 was slow.However,the K2CO3/Al2O3supported sorbent showed excellent carbonation performance.The difference in carbonation behavior between K2CO3and K2CO3/Al2O3supported sorbent was analyzed from the microscopic view.The analytical reagent K2CO3 sample was of monoclinic crystal structure and could react quickly with H2O in the experimental carbonation environment to produce K2CO3·1.5H2O,which was unfavorable to carbonation reaction.When K2CO3was loaded on Al2O3,the surface area and porosity of the sorbent was improved greatly.So the carbonation properties of the K2CO3/Al2O3 supported sorbent was also improved.
