The microstructures and corrosion behaviors of AA2198-T851 alloy and weld were analyzed under corrosive conditions. Weld was formed using an innovative fiber laser welding process with AA2319 Al-Cu filler wire. The me...The microstructures and corrosion behaviors of AA2198-T851 alloy and weld were analyzed under corrosive conditions. Weld was formed using an innovative fiber laser welding process with AA2319 Al-Cu filler wire. The metallurgic morphology and distribution of the chemical compositions were determined using imaging techniques such as optical micrograph, scanning electron micrograph, high-resolution transmission electron microscopy, energy-dispersive X-ray spectrometry and X-ray diffraction. Corrosion was evaluated using an immersion test and electrochemical impedance spectroscopy in 3.5% NaC1 solution at room temperature. Results indicate that the parent alloy suffered from pitting corrosion during the initial 4-h immersion which was caused by the inhomogeneous distribution of its chemical compo- nents and the different intermetallics formed during the rolling process. The weld experienced dendritic boundary corrosion under the same conditions due to the addition of the Al-Cu filler and rapid solidification during laser welding, which led to the precipitates Cu enrichment along the grain boundary. When a welding joint was immersed in the solution for 5 days, a big crack was observed across the center of the weld. In comparison, there was good corrosion resistance in the heat- affected zone with a compact protective film.展开更多
To better understand the stress-corrosion behavior of friction stir welding(FSW),the effects of the microstructure on the stress-corrosion behavior of the FSW in a 2198-T34 aluminum alloy were investigated.The experim...To better understand the stress-corrosion behavior of friction stir welding(FSW),the effects of the microstructure on the stress-corrosion behavior of the FSW in a 2198-T34 aluminum alloy were investigated.The experimental results show that the low-angle grain boundary(LABs)of the stir zone(SZ)of FSW is significantly less than that of heated affected zone(HAZ),thermo-mechanically affected zone(TMAZ),and parent materials(PM),but the grain boundary precipitates(GBPs)T1(Al2CuLi)were less,which has a slight effect on the stress corrosion.The dislocation density in SZ was greater than that in other regions.The residual stress in SZ was+67 MPa,which is greater than that in the TMAZ.The residual stress in the HAZ and PM is-8 MPa and-32 MPa,respectively,and both compressive stresses.The corrosion potential in SZ is obviously less than that in other regions.However,micro-cracks were formed in the SZ at low strain rate,which indicates that the grain boundary characters and GBPs have no significant effect on the crack initiation in the stress-corrosion process of the AA2198-T34.Nevertheless,the residual tensile stress has significant effect on the crack initiation during the stress-corrosion process.展开更多
基金National Nature Science Foundation of China(51205196,51275003)Natural Science Foundation of Jiangsu Province(BK20151469)+1 种基金the Fundamental Research Funds for the Central Universities(NJ20150023)Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
基金financially supported by the National Natural Science Foundation of China (Grant Number: 51505010)Beijing Natural Science Foundation (Grant Number: 2152007)
文摘The microstructures and corrosion behaviors of AA2198-T851 alloy and weld were analyzed under corrosive conditions. Weld was formed using an innovative fiber laser welding process with AA2319 Al-Cu filler wire. The metallurgic morphology and distribution of the chemical compositions were determined using imaging techniques such as optical micrograph, scanning electron micrograph, high-resolution transmission electron microscopy, energy-dispersive X-ray spectrometry and X-ray diffraction. Corrosion was evaluated using an immersion test and electrochemical impedance spectroscopy in 3.5% NaC1 solution at room temperature. Results indicate that the parent alloy suffered from pitting corrosion during the initial 4-h immersion which was caused by the inhomogeneous distribution of its chemical compo- nents and the different intermetallics formed during the rolling process. The weld experienced dendritic boundary corrosion under the same conditions due to the addition of the Al-Cu filler and rapid solidification during laser welding, which led to the precipitates Cu enrichment along the grain boundary. When a welding joint was immersed in the solution for 5 days, a big crack was observed across the center of the weld. In comparison, there was good corrosion resistance in the heat- affected zone with a compact protective film.
基金the National Natural Science Foundation of China(No.51771139)the Hunan Natural Science Foundation(No.2019JJ60062)。
文摘To better understand the stress-corrosion behavior of friction stir welding(FSW),the effects of the microstructure on the stress-corrosion behavior of the FSW in a 2198-T34 aluminum alloy were investigated.The experimental results show that the low-angle grain boundary(LABs)of the stir zone(SZ)of FSW is significantly less than that of heated affected zone(HAZ),thermo-mechanically affected zone(TMAZ),and parent materials(PM),but the grain boundary precipitates(GBPs)T1(Al2CuLi)were less,which has a slight effect on the stress corrosion.The dislocation density in SZ was greater than that in other regions.The residual stress in SZ was+67 MPa,which is greater than that in the TMAZ.The residual stress in the HAZ and PM is-8 MPa and-32 MPa,respectively,and both compressive stresses.The corrosion potential in SZ is obviously less than that in other regions.However,micro-cracks were formed in the SZ at low strain rate,which indicates that the grain boundary characters and GBPs have no significant effect on the crack initiation in the stress-corrosion process of the AA2198-T34.Nevertheless,the residual tensile stress has significant effect on the crack initiation during the stress-corrosion process.
