The microstructures and corrosion behaviors of AA2198-T851 alloy and weld were analyzed under corrosive conditions. Weld was formed using an innovative fiber laser welding process with AA2319 Al-Cu filler wire. The me...The microstructures and corrosion behaviors of AA2198-T851 alloy and weld were analyzed under corrosive conditions. Weld was formed using an innovative fiber laser welding process with AA2319 Al-Cu filler wire. The metallurgic morphology and distribution of the chemical compositions were determined using imaging techniques such as optical micrograph, scanning electron micrograph, high-resolution transmission electron microscopy, energy-dispersive X-ray spectrometry and X-ray diffraction. Corrosion was evaluated using an immersion test and electrochemical impedance spectroscopy in 3.5% NaC1 solution at room temperature. Results indicate that the parent alloy suffered from pitting corrosion during the initial 4-h immersion which was caused by the inhomogeneous distribution of its chemical compo- nents and the different intermetallics formed during the rolling process. The weld experienced dendritic boundary corrosion under the same conditions due to the addition of the Al-Cu filler and rapid solidification during laser welding, which led to the precipitates Cu enrichment along the grain boundary. When a welding joint was immersed in the solution for 5 days, a big crack was observed across the center of the weld. In comparison, there was good corrosion resistance in the heat- affected zone with a compact protective film.展开更多
基金National Nature Science Foundation of China(51205196,51275003)Natural Science Foundation of Jiangsu Province(BK20151469)+1 种基金the Fundamental Research Funds for the Central Universities(NJ20150023)Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
基金financially supported by the National Natural Science Foundation of China (Grant Number: 51505010)Beijing Natural Science Foundation (Grant Number: 2152007)
文摘The microstructures and corrosion behaviors of AA2198-T851 alloy and weld were analyzed under corrosive conditions. Weld was formed using an innovative fiber laser welding process with AA2319 Al-Cu filler wire. The metallurgic morphology and distribution of the chemical compositions were determined using imaging techniques such as optical micrograph, scanning electron micrograph, high-resolution transmission electron microscopy, energy-dispersive X-ray spectrometry and X-ray diffraction. Corrosion was evaluated using an immersion test and electrochemical impedance spectroscopy in 3.5% NaC1 solution at room temperature. Results indicate that the parent alloy suffered from pitting corrosion during the initial 4-h immersion which was caused by the inhomogeneous distribution of its chemical compo- nents and the different intermetallics formed during the rolling process. The weld experienced dendritic boundary corrosion under the same conditions due to the addition of the Al-Cu filler and rapid solidification during laser welding, which led to the precipitates Cu enrichment along the grain boundary. When a welding joint was immersed in the solution for 5 days, a big crack was observed across the center of the weld. In comparison, there was good corrosion resistance in the heat- affected zone with a compact protective film.
