Oxidation of n-butanol and 2-pentanol using molecular oxygen in supercritical (SC) CO2 with and without co-solvent is investigated. The results showed that the reaction selectivity is high when the reaction is carried...Oxidation of n-butanol and 2-pentanol using molecular oxygen in supercritical (SC) CO2 with and without co-solvent is investigated. The results showed that the reaction selectivity is high when the reaction is carried out in SC CO2. It has been observed that co-solvent affects conversion and selectivity of the reaction considerably.展开更多
Excess molar enthalpies,H^E,for the binary mixtures of 2-pentanol with n-alkanes(n-heptane,n-octane,and nnonane)have been determined at three different temperatures T=(293.15,298.15 and 303.15)K and normal atmospheric...Excess molar enthalpies,H^E,for the binary mixtures of 2-pentanol with n-alkanes(n-heptane,n-octane,and nnonane)have been determined at three different temperatures T=(293.15,298.15 and 303.15)K and normal atmospheric pressure over the entire composition range using a Calvet microcalorimeter.All mixtures show endothermic mixing with the maximum values of the excess enthalpies occurring in the n-alkane-rich region.The H^Edata are smoothed using Redlich–Kister equation.The applicability of the Treszczanowicz–Benson,ERAS,Renon–Prausnitz and Chen–Bagley models to correlate H^Eof studied mixtures is tested,and the agreement between experimental and theoretical results is satisfactory.Each model includes a self-association equilibrium constant that represents hydrogen bonding and an adjustable parameter that reflects physical interactions.展开更多
基金supported by National Natural Science Foundation of China(20073056).
文摘Oxidation of n-butanol and 2-pentanol using molecular oxygen in supercritical (SC) CO2 with and without co-solvent is investigated. The results showed that the reaction selectivity is high when the reaction is carried out in SC CO2. It has been observed that co-solvent affects conversion and selectivity of the reaction considerably.
文摘Excess molar enthalpies,H^E,for the binary mixtures of 2-pentanol with n-alkanes(n-heptane,n-octane,and nnonane)have been determined at three different temperatures T=(293.15,298.15 and 303.15)K and normal atmospheric pressure over the entire composition range using a Calvet microcalorimeter.All mixtures show endothermic mixing with the maximum values of the excess enthalpies occurring in the n-alkane-rich region.The H^Edata are smoothed using Redlich–Kister equation.The applicability of the Treszczanowicz–Benson,ERAS,Renon–Prausnitz and Chen–Bagley models to correlate H^Eof studied mixtures is tested,and the agreement between experimental and theoretical results is satisfactory.Each model includes a self-association equilibrium constant that represents hydrogen bonding and an adjustable parameter that reflects physical interactions.
